CN106590634A - Preparation of doped zinc sulfide with micro-nano composite structure and application thereof in augmented reality - Google Patents
Preparation of doped zinc sulfide with micro-nano composite structure and application thereof in augmented reality Download PDFInfo
- Publication number
- CN106590634A CN106590634A CN201611079268.4A CN201611079268A CN106590634A CN 106590634 A CN106590634 A CN 106590634A CN 201611079268 A CN201611079268 A CN 201611079268A CN 106590634 A CN106590634 A CN 106590634A
- Authority
- CN
- China
- Prior art keywords
- doped zinc
- micro
- nano
- zinc sulphide
- augmented reality
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/56—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing sulfur
- C09K11/562—Chalcogenides
- C09K11/565—Chalcogenides with zinc cadmium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/08—Sulfides
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/011—Arrangements for interaction with the human body, e.g. for user immersion in virtual reality
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/017—Gesture based interaction, e.g. based on a set of recognized hand gestures
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06V—IMAGE OR VIDEO RECOGNITION OR UNDERSTANDING
- G06V40/00—Recognition of biometric, human-related or animal-related patterns in image or video data
- G06V40/20—Movements or behaviour, e.g. gesture recognition
- G06V40/28—Recognition of hand or arm movements, e.g. recognition of deaf sign language
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
Abstract
The invention relates to the field of augmented reality, and discloses preparation of doped zinc sulfide with a micro-nano composite structure and application thereof in augmented reality. Specifically, the invention discloses a doped zinc sulfide material with a micro-nano composite structure prepared by a crushing technology, and realizes application thereof in augmented reality. Because the micro-nano composite structure enhances the friction of the doped zinc sulfide, the mechanoluminescence of the doped zinc sulfide is greatly enhanced, and as for an ultrasensitive sensor, the detection limit is 5Pa when calculated according to pressure intensity, and the detection limit is 1muJ when calculated according to energy. When the doped zinc sulfide is encapsulated and stuck to each part of a human body, micromotions of the human body can be converted into varicolored optical signals in real time, so the reality is augmented in the angle of material, and the response time is 10ms. Because dynamic force is converted into visible light, the augmented realization brings a new mode of expression for the body actions and body micromotions of a human. When the human is emotionally excited, the actions are faster, and the light intensity is stronger; and when the human is smooth in mood, the actions are slower, and the light intensity is weaker.
Description
Technical field
The present invention relates to augmented reality field, in particular it relates to obtain micro-nano using ultrasonication and wet method blending technology
The doped zinc sulphide material of composite construction, and realize its application in augmented reality.
Background technology
Augmented reality is an important directions of emulation technology.It passes through computer technology, by virtual Information application to very
The real world, real environment and virtual object have been added to same picture or space in real time while existing.Augmented reality
Technology contain multimedia, three-dimensional modeling, real-time video show and control, Multi-sensor Fusion, real-time tracking and registration, scene
New technique and the new tools such as fusion.Augmented reality is provided in general, different from the appreciable information of the mankind.Increasing
Strong field of reality, is concentrated mainly on the research to picture perception at present, and it is by good passive of program setting that experiencer obtains
How the augmented reality experience of formula, prepare new material carrier, realizes the accurate perception to power optics output, widens enhancing existing
Real range of application, it is an important developing direction to produce a kind of brand-new active augmented reality experience.It is existing with strengthening
Real game and the development of sector application, put forward higher requirement to new principle new technology new material, realize dimensional micro mechanical signal
Many perception and multi output be still a major challenge.
Augmented reality is to develop very fast field in recent years.In order to reach the purpose of augmented reality, originally existing
The entity information (visual information, sound, taste, tactile etc.) experienced is difficult in the certain hour spatial dimension in the real world, is led to
Triggering corresponding event is crossed, the real world that is added to after scientific and technical analog simulation again is perceived by human sensory, super so as to reach
More real sensory experience.Such as technical scheme disclosed in Chinese Patent Application No. CN201510213943.7 proposes one kind
The gesture identification method and augmented reality glasses system of augmented reality glasses.Obtaining depth camera first is strengthened by captured in real-time
Scene in front of Reality glasses and the depth image that obtains, and the depth value and depth map of finger tip are calculated based on depth image
The two-dimensional coordinate of finger tip as in；Secondly the two-dimensional coordinate of finger tip in depth image is changed using transition matrix, and according to
The two-dimensional coordinate being converted to, generates a virtual target in the display interface of augmented reality glasses；Last analysis in real time refers to
Point depth value size variation situation, and in display interface virtual target change in location situation, to trigger corresponding event.
The method is aligned with the fingertip location under human eye visual angle by the fingertip location for positioning augmented reality glasses, realizes accurately knowing
The purpose of other user gesture.
But above-mentioned technology is because program is simulated emulation, is pre-set passive type augmented reality,
The development and change of outside are adapted at any time can not.
The content of the invention
The invention aims to widen the scope of augmented reality, the angle with performance is prepared from material structure, there is provided
A kind of high sensitivity, to the new opplication direction with multi output is perceived human body dimensional micro mechanical signal more.
To achieve these goals, in a first aspect, the invention provides micro-nano compound structure can strengthen doped zinc sulphide
The new discovery of mechanoluminescence susceptiveness.
Preferably, a diameter of 5-200nm of the nano-particle.
Preferably, a diameter of 2-50 μm of the micron doped zinc sulphide granule.
Preferably, the micro-nano particle diameter ratio is 20, when mol ratio is 1: 200, the mechanoluminescence spirit of doped zinc sulphide
Quick property is most strong.
Preferably, the nano-particle selected from silicon dioxide, doped zinc sulphide, zinc sulfide, Graphene, graphite alkene, white carbon black,
In titanium dioxide, diamond, aluminium oxide, gold, silver, copper, zirconium dioxide, nickel oxide, Zinc Oxide, Calcium Carbonate and CNT one
Plant or various.
Second aspect, the invention provides the doped zinc sulphide preparation method of micro-nano compound structure, wherein, it is broken including ultrasound
Broken method and wet method blending method.
Preferably, transition metal element doped zinc sulfide powder is scattered in ethanol, at room temperature ultrasonication 72-
96 hours, ultrasonic power was 1600-2000W, obtained micro-nano particle diameter ratio for 20-30, doped zinc sulphide powder and ethanol
Mass ratio is 1: 10, is often worked the 2-3 seconds during ultrasonication, the rest 1-2 seconds, it is to avoid system is overheated.
Preferably, it is better than 100nm doped zinc sulphide particle effects using 100nm silica nanosphere effects to be better than
100nm polystyrene spheres.
Preferably, by 100nm silica nanospheres and 2 μm of doped zinc sulphide micron particle according to 200: 1 points of mol ratio
Dissipate in ethanol, 48-72 hours are stirred at 60 DEG C, is dried at 25-60 DEG C.The silica nanosphere uniform adsorption for obtaining is being mixed
On miscellaneous Zinc sulphide micron granule, micro-nano compound structure is formed.
The third aspect, the invention provides it is a kind of by high-sensitive mechanoluminescence materials application to the new of augmented reality field
Thinking.
Preferably, the realization rate of augmented reality is that the doped zinc sulphide of micro-nano compound structure is affixed on human body each muscle
The position such as group, heart and pulse, when a certain action is completed, respective muscle position can be luminous, by collect data with
Analysis, can obtain the health status such as emotion, strength and the pulse beat of people, realize many perception, and the form table by light
Reveal and, realize multi output.
Preferably, the light of the augmented reality is visible ray, and wave-length coverage can cover visible light wave range, with orange light, green
Light, blue light and white light are most commonly seen.
By above-mentioned technical proposal, strengthen the friction of doped zinc sulphide using micro-nano compound structure, so as to greatly strengthen
The mechanoluminescence susceptiveness of doped zinc sulphide, is applied to augmented reality field.Super-sensitive self-luminescent material causes the present invention
Have compared to traditional monitor and the wider array of range of application of sensor and outstanding performance, have in augmented reality great
Using value.More excellent, there is to small dynamic force prepared sensor hypersensitive, high-precision real-time optical to ring
Should, calculating according to pressure, in 5Pa, according to energy balane, test limit can perceive the heart in the hypersensor of 1 μ J to test limit
The dimensional micro mechanical signals such as pulse are jumped, high accuracy response is realized, response time is 10ms, it is achieved thereby that real-time response.Due to
Which is that dynamic force is converted into visible ray, thus it is this strengthen realize being the limb action that gives people and body fine motion bring it is new
Expression way.People it is excited when, action is very fast, and light intensity is stronger；When the emotion of people is steady, action is slower, and light intensity is weaker.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Description of the drawings
Accompanying drawing is, for providing a further understanding of the present invention, and to constitute the part of description, with following tool
Body embodiment is used for explaining the present invention together, but is not construed as limiting the invention.In the accompanying drawings：
Fig. 1 be the present invention prepare the schematic diagram of doped zinc sulphide of micro-nano compound structure, scanning electron microscope diagram piece,
The XRD figure of data and curves and doped zinc sulphide between transmitting light intensity and input kinetic energy；Micro-nano compound structure is schematically illustrate a selected in a
Frictional property can be strengthened, so as to the susceptiveness significantly there is provided mechanoluminescence, the scanning electron microscope of doped zinc sulphide in b
Figure, about 2 μm of microns Particle size in figure, nanoparticle size is about 100nm, and a micron doped zinc sulphide, micro-nano are illustrated in c
Response performance of the doped zinc sulphide and mixed nanometer zinc sulfide of composite construction to power.
Fig. 2 is the mechanoluminescence performance map of variety classes nano-particle of the present invention and micron doped zinc sulphide composite construction.
Fig. 3 is the datagram that the present invention is applied to augmented reality.The doped zinc sulphide of micro-nano compound structure is affixed on into handss in a
14 joints for referring to, by taking hand motion as an example, illustrate the augmented reality application to gesture, are principal component analysiss in b
(PCA), in c it is hierarchical cluster analysis (HCA).
Specific embodiment
Hereinafter the specific embodiment of the present invention is described in detail.It should be appreciated that described herein concrete
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
Herein the end points and any value of disclosed scope is not limited to the accurate scope or value, these scopes or
Value should be understood to comprising the value for being close to these scopes or value.For numerical range, between the endpoint value of each scope, respectively
Between the endpoint value of individual scope and single point value, and individually one or more can be obtained with combination with one another between point value
New numerical range, these numerical rangies should be considered concrete open herein.
The present inventor has found in the course of the study, by nanometer is introduced in the doped zinc sulphide to micron
Grain, can play enhancing friction, so as to substantially increase the mechanoluminescence performance of doped zinc sulphide.Its susceptiveness is according to pressure gage
Calculate, in 5Pa, according to energy balane, test limit improves a number than the susceptiveness of micron doped zinc sulphide in 1 μ J to test limit
More than magnitude, the dimensional micro mechanical signals such as pulse beat can be perceived, realize high accuracy response, response time is 10ms, so as to
Realize real-time response.The doped zinc sulphide of micro-nano compound structure can be prepared by ultrasonication, it is also possible to be blended by wet method
Arrive.By material attachment in the positions such as human body each muscle group, heart and pulse, when a certain action is completed, respective muscle
Position can be luminous, by collecting data and analysis, can obtain the health status such as emotion, strength and the pulse beat of people, real
It is now to perceive more, and showed by the form of light, realize multi output.As which is that dynamic force is converted into visible ray, institute
To give augmented reality new definition.The augmented reality experience of the passive type good by program setting different from the past, what which gave people
Limb action and body fine motion bring new expression way, are a kind of brand-new active augmented reality applications.
Based on this, in a first aspect, the invention provides micro-nano compound structure can strengthen the spirit of doped zinc sulphide mechanoluminescence
The new discovery of quick property.
Term " micro-nano be combined " refers to that nano-particle (piece, ellipse, taper and irregularly shaped) uniform adsorption is mixed in micron
The composite construction formed by miscellaneous sulfuration zinc surface.Doped zinc sulphide be a kind of mechanoluminescence material, by dynamic pressure when meeting
Launch light, and light intensity with suffered pressure into positive correlation.
Preferably, the nano-particle selected from silicon dioxide, doped zinc sulphide, zinc sulfide, Graphene, graphite alkene, white carbon black,
In titanium dioxide, diamond, aluminium oxide, gold, silver, copper, zirconium dioxide, nickel oxide, Zinc Oxide, Calcium Carbonate and CNT one
Plant or various.
According to the present invention, in theory, as long as the material of nanoscale can as the adsorbate of micron doped zinc sulphide,
But it was found by the inventors of the present invention that the diameter of nano material performance of final prepared material in 5-200nm can be obtained
Further lifted.It is more highly preferred to, the micro-nano particle diameter ratio is 20, and mol ratio is 1: 200.
Second aspect, the invention provides the doped zinc sulphide preparation method of micro-nano compound structure, wherein, it is broken including ultrasound
Broken method and wet method blending method.
According to the present invention, there is no particular limitation for described two methods, as long as can be by nano-particle uniform adsorption in micro-
On rice doped zinc sulphide.Sonioation method is scattered in transition metal element doped zinc sulfide powder in ethanol, in room
The lower ultrasonication 72-96 hours of temperature, ultrasonic power is 1600-2000W, obtains micro-nano particle diameter ratio for 20-30, doping sulfuration
Zinc powder is 1: 10 with the mass ratio of ethanol, is often worked the 2-3 seconds during ultrasonication, the rest 1-2 seconds.Wet method blending method is by 100nm
Silica nanosphere and 2 μm of doped zinc sulphide micron particle are scattered in ethanol according to mol ratio 200: 1, are stirred at 60 DEG C
48-72 hours, are dried at 25-60 DEG C.The silica nanosphere uniform adsorption for obtaining on doped zinc sulphide micron particle, shape
Into micro-nano compound structure.Under preferable case, wet method blending method more cheap and simple.
According to the present invention, be not particularly limited in the species of the nano-particle, if can uniform adsorption in micro-
The reinforced effects of mechanoluminescence can be produced on rice doped zinc sulphide.Preferably, the nano-particle is selected from silicon dioxide, doping
Zinc sulfide, zinc sulfide, Graphene, graphite alkene, white carbon black, titanium dioxide, diamond, aluminium oxide, gold, silver, copper, zirconium dioxide, oxygen
Change one or more in nickel, Zinc Oxide, Calcium Carbonate and CNT.But in situations where it is preferred, in order to further improve institute
State sensitivity and the precision of material, the Mohs' hardness of the nano-particle is the bigger the better, more preferably diamond, two
One or more of silicon oxide and aluminium oxide, it is considered to cost factor, more preferably silicon dioxide.
The third aspect, present invention also offers it is a kind of by high-sensitive mechanoluminescence materials application to augmented reality field
New approaches.
Although it was found by the inventors of the present invention that the augmented reality at single position is extremely important, working as each muscle group, heart
Observed with the position such as pulse simultaneously, i.e., it is when perceiving with multi output more, with more realistic meaning, when a certain action is completed,
Respective muscle position can be luminous, by collecting data and analysis, can obtain the health such as emotion, strength and the pulse beat of people
Situation, and showed by the form of visible ray.
It was found by the inventors of the present invention that the light of the augmented reality is visible ray, wave-length coverage can cover visible light wave
Section, it is in practice, the most commonly used with orange light, green glow, blue light and white light.
During by the materials application of the present invention in human body augmented reality, the doped zinc sulphide pair of described micro-nano compound structure
Small dynamic force can show the excellent specific property of hypersensitive, high accuracy and real-time optical response, and its susceptiveness is calculated according to pressure,
In 5Pa, according to energy balane, test limit improves an order of magnitude than the susceptiveness of micron doped zinc sulphide in 1 μ J to test limit
More than, the dimensional micro mechanical signals such as pulse beat can be perceived, high accuracy response is realized, response time is 10ms, so as to realize
Real-time response.
Hereinafter will be described the present invention by embodiment.
Embodiment 1
The present embodiment is used for the preparation method of the doped zinc sulphide for illustrating micro-nano compound structure of the present invention and in augmented reality
On application
(1) preparation of the doped zinc sulphide of micro-nano compound structure
By zinc sulfide (ZnS: Mn) granule (commercially available product of the Shanghai Ke Yan photoelectricity technology corporation, Ltd.s) stirring point of additive Mn
Dissipate in ethanol (granule is 1: 10 with ethanol mass ratio), magnetic agitation 2 hours, (new sesame is biological in Ningbo to be placed in cell crushing instrument
Commercially available product of Science and Technology Co., Ltd.'s trade mark for JY92-IIN) in ultrasonication 72 hours at room temperature, ultrasonic power is
2000, often work during ultrasonication 2 seconds, rest 1 second.Drying is stirred under room temperature, the sulfur of the additive Mn of micro-nano compound structure is obtained
Change zinc (ZnS: Mn) granule, shown in scanning electron microscope (Hitachi JSM-7500F) picture of the granule and picture as Fig. 1 b in kind, this
In the mechanoluminescence performance curve as Fig. 1 c of grain shown in Nano/microparticles.
(2) application of the doped zinc sulphide of micro-nano compound structure on augmented reality
ZnS: Mn granule of the micro-nano compound structure that step (1) is obtained and silicone rubber (the limited public affairs of Beijing sea cowry Cisco skill
Department's commercially available product) mix for 7: 3 ratio according to mass ratio, stir 10 minutes, taking 10g mixture makes which in square culture dish
(130mm*130mm) natural levelling in, 80 DEG C solidify 30 minutes, obtain uniform thin film, are divided into the square of 10mm*10mm
Decile.14 joints of finger are affixed on, when people makes gesture, the position of correspondence activity can send orange light.Pass through
Data and analysis are collected, the sign language of people can be read in the form of light, realized perceiving more, and visible ray can also be read
Person directly reads, and realizes the multi output of information, shown in many perception enhanced to reality and multi-output data as Fig. 3 b, 3c.
Embodiment 2
The present embodiment is used for the preparation method of the doped zinc sulphide for illustrating micro-nano compound structure of the present invention and in augmented reality
On application
(1) preparation of the doped zinc sulphide of micro-nano compound structure
By zinc sulfide (ZnS: Mn) granule (commercially available product of the Shanghai Ke Yan photoelectricity technology corporation, Ltd.s) stirring point of additive Mn
Dissipate in ethanol (granule with ethanol mass ratio be 1: 10), magnetic agitation 2 hours, add 200 times of additive Mns zinc sulfide (ZnS:
Mn) silica nanosphere (Aladdin commercially available product) of the 100nm of granule mol ratio, stirs drying under room temperature, obtains micro-nano multiple
Zinc sulfide (ZnS: the Mn) granule of the additive Mn of structure is closed, the mechanoluminescence performance of granule obtained by this kind of method is shown in Fig. 2.
(2) application of the doped zinc sulphide of micro-nano compound structure on augmented reality
ZnS: Mn granule of the micro-nano compound structure that step (1) is obtained and silicone rubber (the limited public affairs of Beijing sea cowry Cisco skill
Department's commercially available product) mix for 7: 3 ratio according to mass ratio, stir 10 minutes, taking 10g mixture makes which in square culture dish
(130mm*130mm) natural levelling in, 80 DEG C solidify 30 minutes, obtain uniform thin film, are divided into the square of 10mm*10mm
Decile.The muscle group of face is affixed on, when people makes expression, the position of correspondence activity can send orange light.By collecting number
According to analysis, can read the expression language of people in the form of light, realize perceive, and visible ray can also be direct by reader
Read, realize the multi output of information.
Embodiment 3
The present embodiment is used for the preparation method of the doped zinc sulphide for illustrating micro-nano compound structure of the present invention and in augmented reality
On application
(1) preparation of the doped zinc sulphide of micro-nano compound structure
By zinc sulfide (ZnS: Cu) granule (commercially available product of the Shanghai Ke Yan photoelectricity technology corporation, Ltd.s) stirring point of Copper-cladding Aluminum Bar
Dissipate in ethanol (granule with ethanol mass ratio be 1: 10), magnetic agitation 2 hours, add 200 times of Copper-cladding Aluminum Bars zinc sulfide (ZnS:
Cu) silica nanosphere (Aladdin commercially available product) of the 200nm of granule mol ratio, stirs drying under room temperature, obtains micro-nano multiple
Zinc sulfide (ZnS: the Cu) granule of the Copper-cladding Aluminum Bar of structure is closed, the mechanoluminescence performance of granule obtained by this kind of method is shown in Fig. 2.
(2) application of the doped zinc sulphide of micro-nano compound structure on augmented reality
ZnS: Cu granule of the micro-nano compound structure that step (1) is obtained and silicone rubber (the limited public affairs of Beijing sea cowry Cisco skill
Department's commercially available product) mix for 7: 3 ratio according to mass ratio, stir 10 minutes, taking 10g mixture makes which in square culture dish
(130mm*130mm) natural levelling in, 80 DEG C solidify 30 minutes, obtain uniform thin film, are divided into the square of 10mm*10mm
Decile.The muscle group of wrist is affixed on, when people's beat pulse, the position of correspondence activity can send the light of green.By collecting number
According to analysis, can read the pulse of people in the form of light, realize perceive, and visible ray can also directly be read by reader
Go out, realize the multi output of information.
Embodiment 4
The present embodiment is used for the preparation method of the doped zinc sulphide for illustrating micro-nano compound structure of the present invention and in augmented reality
On application
Method according to embodiment 1 prepares the doped zinc sulphide of micro-nano compound structure, and except for the difference that, the doped chemical is
Lead.
Embodiment 5
The present embodiment is used for the preparation method of the doped zinc sulphide for illustrating micro-nano compound structure of the present invention and in augmented reality
On application
Method according to embodiment 1 prepares the doped zinc sulphide of micro-nano compound structure, except for the difference that, described ultrasonication
Time is 96 hours, and ultrasonic power is 1600W.
Embodiment 6
The present embodiment is used for the preparation method of the doped zinc sulphide for illustrating micro-nano compound structure of the present invention and in augmented reality
On application
Method according to embodiment 1 prepares the doped zinc sulphide of micro-nano compound structure, except for the difference that, in step (1), ultrasound
Often work when broken 3 seconds, rest 1.5 seconds.
Embodiment 7
The present embodiment is used for the preparation method of the doped zinc sulphide for illustrating micro-nano compound structure of the present invention and in augmented reality
On application
Method according to embodiment 1 prepares the doped zinc sulphide of micro-nano compound structure, except for the difference that, in step (2), described
Thin film is affixed at human heart, and during heart beating, the position of correspondence activity can send orange light.By collecting data and analysis, can
To read the beat intensity and frequency of people in the form of light, many perception are realized, and visible ray can also be directly read by reader,
Realize the multi output of information.
Embodiment 8
The present embodiment is used for the preparation method of the doped zinc sulphide for illustrating micro-nano compound structure of the present invention and in augmented reality
On application
Method according to embodiment 1 prepares the doped zinc sulphide of micro-nano compound structure, except for the difference that, in step (2), micro-nano
ZnS: Mn granule of composite construction and silicone rubber (Beijing sea cowry thinks Science and Technology Ltd.'s commercially available product) are according to the ratio that mass ratio is 6: 4
Example mixing.
Comparative example 1
This comparative example is used for the preparation method of the doped zinc sulphide of the micro-nano compound structure for illustrating reference and in augmented reality
On application
Method according to embodiment 1 prepares the doped zinc sulphide of micro-nano compound structure, except for the difference that, the ultrasonication work(
Rate is 100W.
Comparative example 2
This comparative example is used for the preparation method of the doped zinc sulphide of the micro-nano compound structure for illustrating reference and in augmented reality
On application
Method according to embodiment 1 prepares the doped zinc sulphide of micro-nano compound structure, except for the difference that, the micro-nano for obtaining
ZnS: Mn granule of composite construction and silicone rubber (Beijing sea cowry thinks Science and Technology Ltd.'s commercially available product) are according to the ratio that mass ratio is 5: 5
Example mixing.
Test case
(1) obtained by dripping tower experimental technique with the sensitivity parameter that pressure is calculated, by six axle powers and torque sensor
Pressure is obtained, light intensity is obtained by slr camera.Six axle powers and torque sensor are that the ATT companies trade mark is the commercially available of Nano17
Product.Slr camera be Canon 600D, 50-1.8mm micro-lenss.
(2) obtained by dripping tower experimental technique with the sensitivity parameter of energy balane, luminous energy is obtained by slr camera, led to
The conversion Calculation that gravitional force is crossed with kinetic energy obtains the sensitivity represented with energy.Slr camera is Canon 600D, 50-1.8mm
Micro-lenss.
(3) optical signalling matches precision for measurement 100 times and benchmark result of the comparison with action.
(4) the real-time response time is with high-speed camera video recording acquisition, 1000 frame recording per second.High-speed camera is Vision
Commercially available product of the Research companies trade mark for Phantom HD GOLD.
During the film hardening for being used, air dry oven used for Shanghai Fuma Experiment Equipment Co., Ltd.'s trade mark is
The commercially available product of DGX-9053B-1.
Table 1
By such as upper table 1 as can be seen that compared with comparative example 1-2, the doping of micro-nano compound structure prepared by the present invention vulcanizes
When for augmented reality, which has higher sensitivity, matching precision to zinc, and is capable of achieving real-time response.And at this
In the case of invention is preferred, for example, the species of nano-particle, diameter ratio of micro-nano particle etc. are changed, the material of the preparation
Mechanoluminescence performance further can be lifted.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, the present invention range of the technology design in, various simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance
In the case of shield, can be combined by any suitable means.In order to avoid unnecessary repetition, the present invention to it is various can
The compound mode of energy is no longer separately illustrated.
Additionally, combination in any between a variety of embodiments of the present invention, can also be carried out, as long as which is without prejudice to this
The thought of invention, which should equally be considered as content disclosed in this invention.
Claims (8)
1. the doped zinc sulphide of micro-nano compound structure is prepared and its application on augmented reality.
2. structure according to claim 1, wherein, the micro-nano compound structure is that nano-particle adsorbs on micron particle
Gained；
Preferably, a diameter of 5-200nm of the nano-particle；
Preferably, a diameter of 2-50 μm of the micron doped zinc sulphide granule；
Preferably, the micro-nano particle diameter ratio is 20, when mol ratio is 1: 200, the mechanoluminescence susceptiveness of doped zinc sulphide
It is most strong.
3. preparation according to claim 1, wherein, the doped zinc sulphide preparation method of the micro-nano compound structure includes：
Transition metal element doped zinc sulfide powder is scattered in ethanol, at room temperature ultrasonication 72-96 hours, ultrasonic power
For 1600-2000W, micro-nano particle diameter ratio is obtained for 20-30；
Preferably, doped zinc sulphide powder and the mass ratio of ethanol are 1: 10, are often worked the 2-3 seconds during ultrasonication, rest 1-2
Second, it is to avoid system is overheated.
4. the nano-particle according to claim 1,2 and 3, wherein, nano-particle can be a micron doped zinc sulphide ultrasound
Crush, or added by the way of wet-mixed-drying, under the premise of particle diameter identical, nano-particle is not
Family name's hardness is higher, and the doped zinc sulphide mechanoluminescence performance of micro-nano compound structure is better；
Preferably, using 100nm silica nanosphere effects be better than 100nm doped zinc sulphide particle effects be better than 100nm gather
Styrene ball；
Preferably, 100nm silica nanospheres and 2 μm of doped zinc sulphide micron particle are scattered according to mol ratio 200: 1
In ethanol, 48-72 hours are stirred at 60 DEG C, is dried at 25-60 DEG C.The silica nanosphere uniform adsorption for obtaining is in doping sulfur
Change on zinc micron particle, form micro-nano compound structure.
5. augmented reality application according to claim 1, wherein, different from depended software and the augmented reality of animation, institute
The augmented reality stated is to prepare angle from material, perceives multi output the truly human action of realization more, allows people's
It can be luminous that a dimension, i.e. emotion have been expressed more with action, and the power of light is relevant with emotion height action speed, not only
On daytime, and the exchange of body language can also be realized at night between men, this body language is exactly light, is the mankind
The upgrading of expression meanses, the enhancing to reality.
6. augmented reality according to claim 5, wherein, realization rate is to paste the doped zinc sulphide of micro-nano compound structure
In positions such as human body each muscle group, heart and pulses, when a certain action is completed, respective muscle position can be luminous,
By collecting data and analysis, the health status such as emotion, strength and the pulse beat of people can be obtained, realize perceiving more, and
Showed by the form of light, realize multi output；
Preferably, the light of the augmented reality is visible ray, and wave-length coverage can cover visible light wave range, with orange light, green glow, indigo plant
Light and white light are most commonly seen.
7. the nano-particle according to claim 1,2,3 and 4, wherein, except spherical nanoparticle, also containing lamellar, ellipse
The pattern of circle, taper and irregular polygon；
Preferably, the nano-particle is selected from silicon dioxide, doped zinc sulphide, zinc sulfide, Graphene, graphite alkene, white carbon black, dioxy
Change titanium, diamond, aluminium oxide, gold, silver, copper, zirconium dioxide, nickel oxide, Zinc Oxide, the one kind in Calcium Carbonate and CNT or
It is various.
8. in the doped zinc sulphide of the micro-nano compound structure in claim 2 and 7 described in any one, claim 3 and 4 arbitrarily
Application of the doped zinc sulphide preparation method of the micro-nano compound structure described in augmented reality.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611079268.4A CN106590634A (en) | 2016-11-30 | 2016-11-30 | Preparation of doped zinc sulfide with micro-nano composite structure and application thereof in augmented reality |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611079268.4A CN106590634A (en) | 2016-11-30 | 2016-11-30 | Preparation of doped zinc sulfide with micro-nano composite structure and application thereof in augmented reality |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106590634A true CN106590634A (en) | 2017-04-26 |
Family
ID=58595937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611079268.4A Pending CN106590634A (en) | 2016-11-30 | 2016-11-30 | Preparation of doped zinc sulfide with micro-nano composite structure and application thereof in augmented reality |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106590634A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1468936A (en) * | 2003-06-10 | 2004-01-21 | 山东宇光电子科技有限公司 | Electroluminescent composite coated ZnS:Cu/Cu.Mn material and its prepn process |
| CN1855177A (en) * | 2005-04-21 | 2006-11-01 | 则武伊势电子株式会社 | Phosphor for low-voltage electron beam, method of producing the same, and vacuum fluorescent display |
| US20070172580A1 (en) * | 2006-01-26 | 2007-07-26 | Osram Sylvania Inc. | Moisture-resistant Electroluminescent Phosphor with High Initial Brightness and Method of Making |
| CN103881707A (en) * | 2013-12-30 | 2014-06-25 | 安徽师范大学 | Phosphorescent energy transfer system, synthesis method, application of system and detection method of single-stranded deoxyribonucleotide |
| US20140291480A1 (en) * | 2012-12-19 | 2014-10-02 | Basf Se | Detector for optically detecting at least one object |
| CN105987781A (en) * | 2015-02-10 | 2016-10-05 | 北京纳米能源与系统研究所 | Dynamic stress sensor and manufacturing method thereof, and dynamic stress measurement system |
-
2016
- 2016-11-30 CN CN201611079268.4A patent/CN106590634A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1468936A (en) * | 2003-06-10 | 2004-01-21 | 山东宇光电子科技有限公司 | Electroluminescent composite coated ZnS:Cu/Cu.Mn material and its prepn process |
| CN1855177A (en) * | 2005-04-21 | 2006-11-01 | 则武伊势电子株式会社 | Phosphor for low-voltage electron beam, method of producing the same, and vacuum fluorescent display |
| US20070172580A1 (en) * | 2006-01-26 | 2007-07-26 | Osram Sylvania Inc. | Moisture-resistant Electroluminescent Phosphor with High Initial Brightness and Method of Making |
| US20140291480A1 (en) * | 2012-12-19 | 2014-10-02 | Basf Se | Detector for optically detecting at least one object |
| CN103881707A (en) * | 2013-12-30 | 2014-06-25 | 安徽师范大学 | Phosphorescent energy transfer system, synthesis method, application of system and detection method of single-stranded deoxyribonucleotide |
| CN105987781A (en) * | 2015-02-10 | 2016-10-05 | 北京纳米能源与系统研究所 | Dynamic stress sensor and manufacturing method thereof, and dynamic stress measurement system |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105302337B (en) | High-resolution and three-dimensional (3D) the mouse mobile control system of high sensitive, mobile controller part and its motion detection method | |
| CN104102412B (en) | A kind of hand-held reading device and method thereof based on augmented reality | |
| US9229540B2 (en) | Deriving input from six degrees of freedom interfaces | |
| CN102576466B (en) | For the system and method for trace model | |
| DE212019000172U1 (en) | Handed determination system for virtual controllers | |
| JP2009037620A (en) | Three-dimensional virtual input and simulation device | |
| KR20150103723A (en) | Extramissive spatial imaging digital eye glass for virtual or augmediated vision | |
| CN106200985A (en) | Desktop type individual immerses virtual reality interactive device | |
| CN102665838A (en) | Methods and systems for determining and tracking extremities of a target | |
| CN106326930A (en) | Method for determining position of tracked object in virtual reality and device and system thereof | |
| CN102831380A (en) | Body action identification method and system based on depth image induction | |
| CN104090465B (en) | Three-dimensional interactive projection imaging method | |
| CN104637080B (en) | A kind of three-dimensional drawing system and method based on man-machine interaction | |
| Tsai et al. | Unity game engine: Interactive software design using digital glove for virtual reality baseball pitch training | |
| CN103207667A (en) | Man-machine interaction control method and application thereof | |
| CN102243528A (en) | Providing directional force feedback in free space | |
| CN109166181A (en) | A kind of mixing motion capture system based on deep learning | |
| CN110140100B (en) | Three-dimensional augmented reality object user interface functionality | |
| Sun et al. | A flexible lightweight triboelectric nanogenerator for protector and scoring system in taekwondo competition monitoring | |
| Hou et al. | A Delta‐Parallel‐Inspired Human Machine Interface by Using Self‐Powered Triboelectric Nanogenerator Toward 3D and VR/AR Manipulations | |
| CN109800645A (en) | A kind of motion capture system and its method | |
| CN106590634A (en) | Preparation of doped zinc sulfide with micro-nano composite structure and application thereof in augmented reality | |
| Rajappa et al. | Application and scope analysis of Augmented Reality in marketing using image processing technique | |
| Grimm et al. | VR/AR input devices and tracking | |
| Muhiddin et al. | Kinect 4… holographic optical tweezers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170426 |
|
| WD01 | Invention patent application deemed withdrawn after publication |