CN106590444A - Acid-/base-resistant adhesive for sports floors - Google Patents

Acid-/base-resistant adhesive for sports floors Download PDF

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Publication number
CN106590444A
CN106590444A CN201611083234.2A CN201611083234A CN106590444A CN 106590444 A CN106590444 A CN 106590444A CN 201611083234 A CN201611083234 A CN 201611083234A CN 106590444 A CN106590444 A CN 106590444A
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CN
China
Prior art keywords
parts
acid
athletic floor
alkali
ethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611083234.2A
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Chinese (zh)
Inventor
张明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SICHUAN ZHONGSU HIGH POLYMER MATERIAL Co Ltd
Original Assignee
SICHUAN ZHONGSU HIGH POLYMER MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SICHUAN ZHONGSU HIGH POLYMER MATERIAL Co Ltd filed Critical SICHUAN ZHONGSU HIGH POLYMER MATERIAL Co Ltd
Priority to CN201611083234.2A priority Critical patent/CN106590444A/en
Publication of CN106590444A publication Critical patent/CN106590444A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention relates to an acid-/base-resistant adhesive for sports floors. The adhesive is prepared from the following raw materials in parts by weight: 3-6 parts of ethyl cellulose, 1-3 parts of polyvinyl alcohol, 0.5-1 part of sodium diacetate, 5-9 parts of perfluoroalkyl ethyl methacrylate, 1-4 parts of methacrylamide, 10-18 parts of isocyanate, 2-5 parts of ferric oxide, 10-15 parts of rosin, 5-8 parts of ethyl orthosilicate, 1-2 parts of propylene glycol methyl ether acetate, 5-9 parts of acrylate monomer, 15-20 parts of ethyl acetate, 2-7 parts of alkyl polyglucoside, 1-3 parts of shell-core rubber powder, 1-2 parts of ammonium chloride, 8-12 parts of polyether polyol, 2-5 parts of plasticizer, 4-11 parts of trichloropropyl phosphate, 3-6 parts of sodium hydroxide and 3-10 parts of silicon micropowder. The adhesive disclosed by the invention has relatively high peeling strength and tensile strength, and the damage to surroundings and the injury to human bodies can be reduced while the conventional use demands are met.

Description

A kind of acid and alkali-resistance athletic floor adhesive
Technical field
The present invention relates to technical field of floor, more particularly, to a kind of acid and alkali-resistance athletic floor adhesive.
Background technology
With expanding economy, present sports center uses in a large number athletic floor, athletic floor to be generally divided into interior Athletic floor and the big class of outdoor sport floor two.Such as indoor Badminton Stadium, Basketball hall, gymnasium, dancing room, outdoor plumage Ball top field, basketball court etc..Athletic floor is widely used in various sports centers, for example:Shuttlecock, table tennis, vollyball, tennis, Basketball, handball, the competition and training venue of indoor football, multi-functional venue, all kinds of gymnasiums, dancing room, school, sports goods Shop, office, hotel, space for activities of hospital etc..Athletic floor will be protected regularly, to prevent water, chemical substance, The injury that ultraviolet irradiation etc. is caused to athletic floor, binding agent can be good at being attached on plastic sports floor, prevent Injury to floor, but existing base plate binding agent generally existing abnormal smells from the patient is larger, and not enough, viscosity is not uniform special enough for viscosity A kind of point, it is impossible to enough meet use requirement, it is therefore desirable to high performance binding agent, improves the service life of athletic floor.
The content of the invention
It is an object of the invention to provide a kind of not mouldy, non-volatile, good weatherability and with the adhesive of certain elasticity.
In order to realize foregoing invention purpose, technical scheme is specific as follows:
A kind of acid and alkali-resistance athletic floor adhesive, including the raw material of following weight portion makes:Ethyl cellulose 3-6 parts, polyethylene Alcohol 1-3 parts, sodium diacetate 0.5-1 parts, perfluor alkyl ethide methacrylate 5-9 parts, Methacrylamide 1-4 parts, isocyanide Acid esters 10-18 parts, iron sesquioxide 2-5 parts, Colophonium 10-15 parts, tetraethyl orthosilicate 5-8 parts, propylene glycol methyl ether acetate 1-2 Part, acrylate monomer 5-9 parts, ethyl acetate 15-20 parts, alkyl polyglycoside 2-7 parts, shell core rubber powder 1-3 parts, ammonium chloride 1-2 Part, polyether polyol 8-12 part, plasticizer 2-5 parts, TCPP 4-11 parts, sodium hydroxide 3-6 parts, silicon powder 3-10 Part.
Further, the acid and alkali-resistance athletic floor adhesive, including the raw material of following weight portion is made:Ethyl cellulose 4-6 parts, polyvinyl alcohol 1-2 parts, sodium diacetate 0.5-1 parts, perfluor alkyl ethide methacrylate 5-7 parts, methacryl Amine 1-3 parts, isocyanates 10-14 parts, iron sesquioxide 3-5 parts, Colophonium 12-14 parts, tetraethyl orthosilicate 7-8 parts, Propylene Glycol first Ether acetate 1-1.5 parts, acrylate monomer 7-9 parts, ethyl acetate 15-18 parts, alkyl polyglycoside 4-7 parts, shell core rubber powder 1- 1.5 parts, ammonium chloride 1-1.5 parts, polyether polyol 10-12 part, plasticizer 3-5 parts, TCPP 4-8 parts, sodium hydroxide 3-5 parts, silicon powder 3-6 parts.
Further, the acid and alkali-resistance athletic floor adhesive, is made up of the raw material of following weight portion:Ethyl cellulose 5 It is part, 1.5 parts of polyvinyl alcohol, 0.5 part of sodium diacetate, 6 parts of perfluor alkyl ethide methacrylate, 2 parts of Methacrylamide, different 12 parts of cyanate, 4 parts of iron sesquioxide, 13 parts of Colophonium, 7.5 parts of tetraethyl orthosilicate, 1 part of propylene glycol methyl ether acetate, acrylic acid 8 parts of ester monomer, 17 parts of ethyl acetate, 6 parts of alkyl polyglycoside, 1 part of shell core rubber powder, 1 part of ammonium chloride, 11 parts of polyether polyol, increasing 4 parts of agent of modeling, 6 parts of TCPP, 4 parts of sodium hydroxide, 5 parts of silicon powder.
Further, the plasticizer is tributyl citrate and/or phthalic acid two(2- ethyl hexyls)Ester.
The present invention prepares the adhesive using the conventional preparation method in this area.
The acid and alkali-resistance athletic floor adhesive is used for plastics athletic floor.
Beneficial effects of the present invention:
The athletic floor adhesive of the present invention, it is possible to increase the water proofing property of athletic floor, while anti-ultraviolet wound can be supported Evil, improves the service life on floor.Nontoxic, pollution-free, odorlessness of the invention, safety and environmental protection, its abundant raw material source is reduced Production cost, each raw material cooperates and improves its stability, acid-alkali-corrosive-resisting, and it also has good elasticity, colour retention And low temperature flexibility, it is non-volatile, it may have outstanding anti-pressure ability.The adhesive of the present invention has higher peel strength and drawing Intensity is stretched, can meet conventional using the injury reduced while needs to environment and human body.
Harm.
Specific embodiment
Present disclosure is described in further detail with reference to embodiment.
Embodiment 1
A kind of acid and alkali-resistance athletic floor adhesive, including the raw material of following weight portion makes:3 parts of ethyl cellulose, polyvinyl alcohol 1 Part, 0.5 part of sodium diacetate, 5 parts of perfluor alkyl ethide methacrylate, 1 part of Methacrylamide, 10 parts of isocyanates, three Aoxidize 2 parts of two ferrum, 10 parts of Colophonium, 5 parts of tetraethyl orthosilicate, 1 part of propylene glycol methyl ether acetate, 5 parts of acrylate monomer, acetic acid second 15 parts of ester, 2 parts of alkyl polyglycoside, shell core rubber powder 1-3 parts, 1 part of ammonium chloride, 8 parts of polyether polyol, 2 parts of plasticizer, phosphoric acid trichlorine 4 parts of propyl ester, 3 parts of sodium hydroxide, 3 parts of silicon powder.
Embodiment 2
A kind of acid and alkali-resistance athletic floor adhesive, including the raw material of following weight portion makes:6 parts of ethyl cellulose, polyvinyl alcohol 3 Part, 1 part of sodium diacetate, 9 parts of perfluor alkyl ethide methacrylate, 4 parts of Methacrylamide, 18 parts of isocyanates, three oxygen Change 5 parts of two ferrum, 14 parts of Colophonium, 8 parts of tetraethyl orthosilicate, 1 part of propylene glycol methyl ether acetate, 9 parts of acrylate monomer, ethyl acetate 18 parts, 7 parts of alkyl polyglycoside, 1.5 parts of shell core rubber powder, 1 part of ammonium chloride, 12 parts of polyether polyol, 5 parts of plasticizer, phosphoric acid trichlorine 8 parts of propyl ester, 3 parts of sodium hydroxide, 3 parts of silicon powder.
Embodiment 3
A kind of acid and alkali-resistance athletic floor adhesive, is made up of the raw material of following weight portion:5 parts of ethyl cellulose, polyvinyl alcohol 1.5 Part, 0.5 part of sodium diacetate, 6 parts of perfluor alkyl ethide methacrylate, 2 parts of Methacrylamide, 12 parts of isocyanates, three Aoxidize 4 parts of two ferrum, 13 parts of Colophonium, 7.5 parts of tetraethyl orthosilicate, 1 part of propylene glycol methyl ether acetate, 8 parts of acrylate monomer, acetic acid 17 parts of ethyl ester, 6 parts of alkyl polyglycoside, 1 part of shell core rubber powder, 1 part of ammonium chloride, 11 parts of polyether polyol, 4 parts of plasticizer, tricresyl phosphate 6 parts of chlorine propyl ester, 4 parts of sodium hydroxide, 5 parts of silicon powder.
Embodiment 4
A kind of acid and alkali-resistance athletic floor adhesive, including the raw material of following weight portion makes:4 parts of ethyl cellulose, polyvinyl alcohol 2 Part, 1 part of sodium diacetate, 6 parts of perfluor alkyl ethide methacrylate, 3 parts of Methacrylamide, 16 parts of isocyanates, three oxygen Change 4 parts of two ferrum, 15 parts of Colophonium, 8 parts of tetraethyl orthosilicate, 2 parts of propylene glycol methyl ether acetate, 9 parts of acrylate monomer, ethyl acetate 20 parts, 7 parts of alkyl polyglycoside, 3 parts of shell core rubber powder, 2 parts of ammonium chloride, 12 parts of polyether polyol, 5 parts of plasticizer, phosphoric acid trichlorine third 11 parts of ester, 6 parts of sodium hydroxide, 10 parts of silicon powder.
Although reference be made herein to invention has been described for explanatory embodiment of the invention, and above-described embodiment is only this Bright preferably embodiment, embodiments of the present invention are simultaneously not restricted to the described embodiments, it should be appreciated that people in the art Member can be designed that a lot of other modification and embodiment, and these modifications and embodiment will fall in principle disclosed in the present application Within scope and spirit.

Claims (5)

1. a kind of acid and alkali-resistance athletic floor adhesive, it is characterised in that make including the raw material of following weight portion:Ethyl cellulose 3-6 parts, polyvinyl alcohol 1-3 parts, sodium diacetate 0.5-1 parts, perfluor alkyl ethide methacrylate 5-9 parts, methacryl Amine 1-4 parts, isocyanates 10-18 parts, iron sesquioxide 2-5 parts, Colophonium 10-15 parts, tetraethyl orthosilicate 5-8 parts, Propylene Glycol first Ether acetate 1-2 parts, acrylate monomer 5-9 parts, ethyl acetate 15-20 parts, alkyl polyglycoside 2-7 parts, shell core rubber powder 1-3 Part, ammonium chloride 1-2 parts, polyether polyol 8-12 part, plasticizer 2-5 parts, TCPP 4-11 parts, sodium hydroxide 3-6 parts, Silicon powder 3-10 parts.
2. acid and alkali-resistance athletic floor adhesive according to claim 1, it is characterised in that including the raw material system of following weight portion Into:Ethyl cellulose 4-6 parts, polyvinyl alcohol 1-2 parts, sodium diacetate 0.5-1 parts, perfluor alkyl ethide methacrylate 5-7 Part, Methacrylamide 1-3 parts, isocyanates 10-14 parts, iron sesquioxide 3-5 parts, Colophonium 12-14 parts, tetraethyl orthosilicate 7- 8 parts, propylene glycol methyl ether acetate 1-1.5 parts, acrylate monomer 7-9 parts, ethyl acetate 15-18 parts, alkyl polyglycoside 4-7 parts, Shell core rubber powder 1-1.5 parts, ammonium chloride 1-1.5 parts, polyether polyol 10-12 part, plasticizer 3-5 parts, TCPP 4-8 Part, sodium hydroxide 3-5 parts, silicon powder 3-6 parts.
3. acid and alkali-resistance athletic floor adhesive according to claim 1 or claim 2, it is characterised in that by the raw material of following weight portion Make:5 parts of ethyl cellulose, 1.5 parts of polyvinyl alcohol, 0.5 part of sodium diacetate, 6 parts of perfluor alkyl ethide methacrylate, first 2 parts of base acrylamide, 12 parts of isocyanates, 4 parts of iron sesquioxide, 13 parts of Colophonium, 7.5 parts of tetraethyl orthosilicate, propylene glycol monomethyl ether It is 1 part of acetate, 8 parts of acrylate monomer, 17 parts of ethyl acetate, 6 parts of alkyl polyglycoside, 1 part of shell core rubber powder, 1 part of ammonium chloride, poly- 11 parts of ethoxylated polyhydric alcohol, 4 parts of plasticizer, 6 parts of TCPP, 4 parts of sodium hydroxide, 5 parts of silicon powder.
4. acid and alkali-resistance athletic floor adhesive according to claim 1 or claim 2, it is characterised in that the plasticizer is citric acid Tributyl and/or phthalic acid two(2- ethyl hexyls)Ester.
5. by acid and alkali-resistance athletic floor adhesive applications described in claim 1 or 2 in plastics athletic floor.
CN201611083234.2A 2016-11-30 2016-11-30 Acid-/base-resistant adhesive for sports floors Pending CN106590444A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611083234.2A CN106590444A (en) 2016-11-30 2016-11-30 Acid-/base-resistant adhesive for sports floors

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611083234.2A CN106590444A (en) 2016-11-30 2016-11-30 Acid-/base-resistant adhesive for sports floors

Publications (1)

Publication Number Publication Date
CN106590444A true CN106590444A (en) 2017-04-26

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CN201611083234.2A Pending CN106590444A (en) 2016-11-30 2016-11-30 Acid-/base-resistant adhesive for sports floors

Country Status (1)

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CN (1) CN106590444A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104479604A (en) * 2014-10-30 2015-04-01 田琳琳 Adhesive for motion floor
CN104497895A (en) * 2014-11-27 2015-04-08 青岛崂乡茶制品有限公司 Novel wood floor adhesive
CN105778586A (en) * 2016-05-04 2016-07-20 成都纳硕科技有限公司 Photocuring paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104479604A (en) * 2014-10-30 2015-04-01 田琳琳 Adhesive for motion floor
CN104497895A (en) * 2014-11-27 2015-04-08 青岛崂乡茶制品有限公司 Novel wood floor adhesive
CN105778586A (en) * 2016-05-04 2016-07-20 成都纳硕科技有限公司 Photocuring paint

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Application publication date: 20170426

RJ01 Rejection of invention patent application after publication