CN106590349A - Anticorrosive coating containing compound modifier - Google Patents
Anticorrosive coating containing compound modifier Download PDFInfo
- Publication number
- CN106590349A CN106590349A CN201611238735.3A CN201611238735A CN106590349A CN 106590349 A CN106590349 A CN 106590349A CN 201611238735 A CN201611238735 A CN 201611238735A CN 106590349 A CN106590349 A CN 106590349A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- mentioned
- sodium
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses an anticorrosive coating containing a compound modifier. The coating is composed of a component A and a component B. The component A is prepared from, by weight, 75-85 parts of epoxy resin E51, 15-20 parts of high chlorinated polyethylene resin, 5-10 parts of titanium oxide, 3-5 parts of aluminum silicate, 3-5 parts of sodium dodecyl sulfate, 2-4 parts of sodium diacetate, 3-4 parts of coumarone, 3-4 parts of ethyl acrylate, 4-6 parts of nanometer clay, 2-3 parts of polyacrylamide, 2-3 parts of diethylamine, 2-3 parts of dibutyl phthalate, 4-6 parts of ethylene glycol, 3-4 parts of ferrocene, 1-2 parts of extylene diamine tetra (mextylene phosphonic acid) sodium, 2-3 parts of triethanolamine, 1-2 parts of fatty alcohol-polyoxyethylene ether, 10-16 parts of the compound modifier, 25-30 parts of xylene, 8-10 parts of n-butyl alcohol, 0.8-1 part of N-[3-(trimethoxysilyl)propyl]anline and 0.5-1 part of dimethicone. A produced film has the good metal adhesive force, small structure pores and the compact structure, has the good adhesive force, good flexibility, high shock strength and high corrosion resistance and has the efficient protection effect on base metal.
Description
Technical field
The invention mainly relates to a kind of coating, more particularly to a kind of anticorrosive paint containing composite modifier.
Background technology
With industrial technological advancement, the use of metal material is more and more extensive, and the etching problem of metal and its component is time
And the every field of national economy, massive losses are caused to human society.In order to reduce the loss of corrosion, people take very
Many safeguard procedures, but protective measure most universal, most economical, most practical so far or coating protection, in various anti-corrosion skills
In art, the aseptic technic of coating is most widely used.Anticorrosion with coat with its easy construction, it is economic and practical, receive device area, shape
Constraint the features such as and be widely used；
Critical role is occupied in anticorrosive paint in numerous paint kind epoxy resin, anti-corrosion of metal is widely used as and is used
A kind of coating material, with excellent cohesive force, chemical-resistant resistance, anticorrosion and water resistance, its yield increases day by day, new varieties phase
After appearance, it is extremely rising coating variety, by the kind for adding different fillers and adjustment curing agent, can makes
The anti-corrosive paint of epoxy resin of different properties, it is adaptable to the anticorrosion needs of different occasions, reaches good protected effect.
But metal current anticorrosive paint technology is present, and anticorrosion time limit is short, abrasion resistance is poor, paint film is unstable, environmental pollution
The problems such as limit which is fast-developing, in order to improve the performance of epoxy coating, which is modified and is anticipated with important science
Justice and commercial value.
The content of the invention
The object of the invention is just to provide a kind of anticorrosive paint containing composite modifier.
The present invention is achieved by the following technical solutions：
A kind of anticorrosive paint containing composite modifier, it is made up of first and second liang of components, and described first component is by following heavy
The raw material composition of amount part：Epoxy resin E51 75-85, HCPE 15-20, titanium dioxide 5-10, aluminium silicate 3-5,
Dodecyl sodium sulfate 3-5, sodium diacetate 2-4, coumarone 3-4, ethyl acrylate 3-4, nanoclay 4-6, polyacrylamide
2-3, diethylamine 2-3, dibutyl phthalate 2-3, ethylene glycol 4-6, ferrocene 3-4, ethylenediamine tetramethylene fork Alendronate
1-2, triethanolamine 2-3, fatty alcohol-polyoxyethylene ether 1-2, composite modifier 10-16, dimethylbenzene 25-30, n-butyl alcohol 8-10, N-
Phenyl -3- TSL 8330 0.8-1, dimethicone 0.5-1；Described composite modifier is by following heavy
The raw material composition of amount part：35-40 Baume degrees waterglass 40-50, aluminum sulfate 90-100, nanometer silicon dioxide particle 35-45,
Sorbitan monooleate 1-2, polyoxyethylene ether 1-2, sodium carboxymethyl cellulose 1-2, dodecylbenzene sodium sulfonate 2-4, mistake
Oxidation diisopropylbenzene (DIPB) 1-2, N- phenyl -3- TSL 8330 0.8-1, VTES 0.6-1,
Hydrochloric acid, appropriate amount of water；The preparation method of described composite modifier is comprised the following steps：
（1）The hydrochloric acid solution that concentration is 8-10% is added dropwise in the 35-40 Baume degrees waterglass of above-mentioned weight portion, constantly
Measure mixed liquor PH, when PH be 4.5-5 when, stop add, it is standby；
（2）The sodium carboxymethyl cellulose of above-mentioned weight portion and dodecylbenzene sodium sulfonate mixing are dissolved in into 15-20 times of water CN
In 103173049 B description page 32/3, B must be expected；
（3）Suitable quantity of water is added in the aluminum sulfate of above-mentioned weight portion, the 35-40 being slowly added to after above-mentioned acidifying under agitation
Baume degrees water glass solution, the above-mentioned material B of period continuous Deca, the PH of regulation system between 9-10, the reaction temperature of system
For 75-85 DEG C, continue stirring 3-5 minutes after the 35-40 Baume degrees water glass solution completion of dropping after above-mentioned acidifying, reaction knot
Beam；
（4）Mixed liquor after reaction is terminated is aged 2-3 hours at 85-95 DEG C；
（5）The nanometer silicon dioxide particle of above-mentioned weight portion is distributed in water, the suspension of nano-silica-containing is obtained, with
Batch mixing mixing after above-mentioned ageing, adds remaining each raw material, high speed 1500-2000 rev/min centrifugal mixer 20-30 minutes, dries
It is dry, superfines are ground into, as described composite modifier；
The preparation method of described first component is：
（1）By the epoxy resin E51 of above-mentioned weight portion, HCPE, dimethylbenzene and n-butyl alcohol mixing and stirring；
（2）Add remaining each raw material fully dispersed uniform, be then ground to fineness up to 50-60 μm, obtain final product the first group
Part；Described component B is made up of the raw material of following weight parts：M-xylene diamine 80-90,1,2- phenylenediamine 7-10, diformazan
Benzene 10-16, n-butyl alcohol 6-10, ethyl acetate 6-10；The preparation method of described component B is by each original of above-mentioned weight portion
During material mixing adds dispersion tank, start height and stir, be uniformly dispersed, filter, obtain final product the component B；By the first and second two groups obtained above
Part is according to 6-10：, than mixing, stirring 30-40 minutes are to uniform, you can coat or be sprayed on Jing oil removings, processing of rust removing for 1 weight
Metal surface.
It is an advantage of the invention that：The paint film of present invention production is good to metal adhesion, and structure pore is little, compact structure, tool
There is excellent adhesive force, pliability is good, excellent in cushion effect, decay resistance strong, efficient protection is played to parent metal and is made
With the composite modifier of addition further increases the surface gloss and physical and mechanical propertiess of paint film so that paint film has more
Scrub resistance well, weatherability, enhance the quality of paint film.
A kind of anticorrosive paint containing composite modifier of specific embodiment embodiment 1, it is by first and second liang of component groups
Into described first component is made up of the raw material of following weight parts (kilogram)：Epoxy resin E51 75-85, high chlorinated polyethylene
Olefine resin（Chlorinity 65%-M）15-20, titanium dioxide 5-10, aluminium silicate 3-5, dodecyl sodium sulfate 3-5, sodium diacetate 2-4,
Coumarone 3-4, ethyl acrylate 3-4, nanoclay 4-6, polyacrylamide 2-3, diethylamine 2-3, dibutyl phthalate
2-3, ethylene glycol 4-6, ferrocene 3-4, ethylenediamine tetramethylene fork Alendronate 1-2, triethanolamine 2-3, aliphatic alcohol polyethenoxy
Ether 1-2, composite modifier 10-16, dimethylbenzene 25-30, n-butyl alcohol 8-10, N- phenyl -3- TSL 8330s
0.8-1, dimethicone 0.5-1；Described composite modifier is made up of the raw material of following weight parts：35-40 ripples
U.S. degree waterglass 50, aluminum sulfate 100, nanometer silicon dioxide particle 45, sorbitan monooleate 2, polyoxyethylene ether 2, carboxylic
Sodium carboxymethylcellulose pyce 1, dodecylbenzene sodium sulfonate 4, cumyl peroxide 2, N- phenyl -3-CN aminopropyl trimethoxies
Silane 0.8, VTES 1, hydrochloric acid, appropriate amount of water；
The preparation method of described composite modifier is comprised the following steps：
（1）The hydrochloric acid solution that concentration is 10% is added dropwise in the 35-40 Baume degrees waterglass of above-mentioned weight portion, constantly
The PH of mixed liquor is determined, when PH is 4.5, stops adding, it is standby；
（2）The sodium carboxymethyl cellulose of above-mentioned weight portion and dodecylbenzene sodium sulfonate mixing are dissolved in 20 times of water, B must be expected；
（3）Suitable quantity of water is added in the aluminum sulfate of above-mentioned weight portion, the 35-40 ripples after above-mentioned acidifying are slowly added under agitation
U.S. degree water glass solution, between 10, the reaction temperature of system is 85 for the above-mentioned material B of period continuous Deca, the PH of regulation system
DEG C, continuing stirring 5 minutes after the 35-40 Baume degrees water glass solution completion of dropping after above-mentioned acidifying, reaction terminates；（4）Will
Mixed liquor after reaction terminates is aged 3 hours at 95 DEG C；
（5）The nanometer silicon dioxide particle of above-mentioned weight portion is distributed in water, the suspension of nano-silica-containing is obtained, with
Batch mixing mixing after above-mentioned ageing, adds remaining each raw material, 2000 revs/min of high speed centrifugal mixer 30 minutes, drying to crush
Into superfines, as described composite modifier；
The preparation method of described first component is：
（1）By the epoxy resin E51 of above-mentioned weight portion, HCPE, dimethylbenzene and n-butyl alcohol mixing and stirring；
（2）Add remaining each raw material fully dispersed uniform, be then ground to fineness up to 60 μm, obtain final product the first component；
Described component B is made up of the raw material of following weight parts：M-xylene diamine 90,1,2- phenylenediamines 10, dimethylbenzene 16, just
Butanol 10, ethyl acetate 10；The preparation method of described component B is：Each raw material mixing of above-mentioned weight portion is added into dispersion
In tank, start height and stir, be uniformly dispersed, filter, obtain final product the component B；By first and second liang of components obtained above according to 10：1 weight
Than mixing, stirring 40 minutes is to uniform, you can coat or be sprayed on the metal surface of Jing oil removings, processing of rust removing for amount.Performance is surveyed
Examination：100 days cut salt mist experiments：Paint film without foaming, without coming off, at cut corrosion diffusion 0.9mm；100 days salt fog realities
Test：Paint film comes off without foaming, nothing, non-corroding；Abrasion resistance is tested：Pass through for 10000 times, paint film is without breakage；Acid resistance（5%
Sulfuric acid solution, 25 DEG C, 50h）：Paint film comes off without foaming, nothing, non-corroding；Alkali resistance（5% sodium hydroxide solution, 25 DEG C,
600h）：Paint film comes off without foaming, nothing, non-corroding；Resistance to salt water（5% sodium chloride solution, 25 DEG C, 800h）：Paint film without rise
Bubble, nothing come off, non-corroding；Pliability 1mm；Adhesive force 13Mpa.
Claims (1)
1. a kind of anticorrosive paint containing composite modifier, it is characterised in that it is made up of first and second liang of components, described first group
Part is made up of the raw material of following weight parts：Epoxy resin E51 75-85, HCPE 15-20, titanium dioxide 5-
10th, aluminium silicate 3-5, dodecyl sodium sulfate 3-5, sodium diacetate 2-4, coumarone 3-4, ethyl acrylate 3-4, nanoclay 4-
6th, polyacrylamide 2-3, diethylamine 2-3, dibutyl phthalate 2-3, ethylene glycol 4-6, ferrocene 3-4, ethylenediamine tetraacetic are sub-
Methyl fork Alendronate 1-2, triethanolamine 2-3, fatty alcohol-polyoxyethylene ether 1-2, composite modifier 10-16, dimethylbenzene 25-30,
N-butyl alcohol 8-10, N- phenyl -3- TSL 8330 0.8-1, dimethicone 0.5-1；It is described compound to change
Property agent is made up of the raw material of following weight parts：35-40 Baume degrees waterglass 40-50, aluminum sulfate 90-100, nano-silica
Silicon carbide particle 35-45, sorbitan monooleate 1-2, polyoxyethylene ether 1-2, sodium carboxymethyl cellulose 1-2, dodecyl
Benzene sulfonic acid sodium salt 2-4, cumyl peroxide 1-2, N- phenyl -3- TSL 8330 0.8-1, three second of vinyl
TMOS 0.6-1, hydrochloric acid, appropriate amount of water；The preparation method of described composite modifier is comprised the following steps：（1）Above-mentioned heavy
The hydrochloric acid solution that concentration is 8-10% is added dropwise in the 35-40 Baume degrees waterglass of amount part, mixed liquor is constantly determined
PH, when pH is 4.5-5, stops adding, standby；（2）By the sodium carboxymethyl cellulose and detergent alkylate of above-mentioned weight portion
Sodium sulfonate mixing is dissolved in 15-20 times of water, must expect B；（3）Suitable quantity of water is added in the aluminum sulfate of above-mentioned weight portion, in stirring
Under the conditions of be slowly added to the 35-40 Baume degrees water glass solutions after above-mentioned acidifying, the above-mentioned material B of period continuous Deca, regulation system
PH between 9-10, the reaction temperature of system is 75-85 DEG C, the 35-40 Baume degrees water glass solution drop after above-mentioned acidifying
Add, reaction terminates；（4）Mixed liquor after reaction is terminated is aged 2-3 at 85-95 DEG C
Hour；（5）The nanometer silicon dioxide particle of above-mentioned weight portion is distributed in water, the suspension of nano-silica-containing is obtained,
Mix with the batch mixing after above-mentioned ageing, the remaining each raw material of addition, high speed 1500-2000 rev/min centrifugal mixer 20-30 minutes,
Drying, is ground into superfines, as described composite modifier；The preparation method of described first component is：（1）By above-mentioned weight
Part epoxy resin E51, HCPE, dimethylbenzene and n-butyl alcohol mixing and stirring；（2）Add remaining each original
Material is fully dispersed uniform, is then ground to fineness up to 50-60 μm, obtains final product the first component；Described component B is by under
State the raw material composition of weight portion：M-xylene diamine 80-90,1,2- phenylenediamine 7-10, dimethylbenzene 10-16, n-butyl alcohol 6-10, vinegar
Acetoacetic ester 6-10；The preparation method of described component B is：Each raw material mixing of above-mentioned weight portion is added in dispersion tank, is opened
Dynamic height is stirred, and is uniformly dispersed, and is filtered, is obtained final product the component B；By first and second liang of components obtained above according to 7-10：1 weight ratio
Mixing, stirring 30-40 minutes are to uniform, you can coat or be sprayed on the metal surface of Jing oil removings, processing of rust removing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611238735.3A CN106590349A (en) | 2016-12-28 | 2016-12-28 | Anticorrosive coating containing compound modifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611238735.3A CN106590349A (en) | 2016-12-28 | 2016-12-28 | Anticorrosive coating containing compound modifier |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106590349A true CN106590349A (en) | 2017-04-26 |
Family
ID=58604598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611238735.3A Withdrawn CN106590349A (en) | 2016-12-28 | 2016-12-28 | Anticorrosive coating containing compound modifier |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106590349A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107841233A (en) * | 2017-11-29 | 2018-03-27 | 镇江兴润土石方工程有限公司 | A kind of green new excavator antirusting paint |
| CN111961520A (en) * | 2020-08-18 | 2020-11-20 | 苏州上格五金有限公司 | Screw anticorrosion treatment process |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173049A (en) * | 2013-02-26 | 2013-06-26 | 安徽明珠颜料科技有限公司 | Compound modifier-containing anticorrosive coating |
-
2016
- 2016-12-28 CN CN201611238735.3A patent/CN106590349A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173049A (en) * | 2013-02-26 | 2013-06-26 | 安徽明珠颜料科技有限公司 | Compound modifier-containing anticorrosive coating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107841233A (en) * | 2017-11-29 | 2018-03-27 | 镇江兴润土石方工程有限公司 | A kind of green new excavator antirusting paint |
| CN111961520A (en) * | 2020-08-18 | 2020-11-20 | 苏州上格五金有限公司 | Screw anticorrosion treatment process |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103173049B (en) | A kind of protective system containing composite modifier | |
| CN103173102A (en) | Anticorrosive coating containing rron oxide red | |
| CN103173103A (en) | Anticorrosive paint containing sepiolite powder | |
| CN103173094A (en) | Anticorrosive paint containing dimethyl sulfoxide | |
| CN110564189A (en) | inorganic nano-coating and preparation method thereof | |
| CN103173101A (en) | Salt spray resistant anticorrosive paint | |
| CN104592856A (en) | Waterborne epoxy anti-corrosion coating added with chitosan | |
| CN109867289A (en) | A kind of preparation method of high stability inorganic-organic hybridization nano silica solution | |
| CN101445676B (en) | High-efficient zinc-rich anti-corrosive paint and preparation method thereof | |
| CN106590349A (en) | Anticorrosive coating containing compound modifier | |
| CN104530776A (en) | Preparation method of corrosion-resistant aluminum pigment | |
| CN112778860A (en) | Reflective heat-insulation sand-containing multicolor paint | |
| CN103173100B (en) | A kind of acid proof protective system | |
| CN106318130A (en) | High-performance epoxy resin heavy anti-corrosion paint | |
| CN103173050B (en) | A kind of protective system containing ferrocene | |
| CN103173092A (en) | Anticorrosive paint with high adhesive force | |
| CN113025147A (en) | Water-based wall surface hand-sprayed paint and preparation method thereof | |
| CN107227093B (en) | A kind of epoxy polypyrrole metal anti-corrosive paint and preparation method thereof | |
| CN105348899A (en) | Coupling agent | |
| CN102604537B (en) | Water-based metal antiseptic paint and preparation method thereof | |
| CN107266951A (en) | A kind of preparation method and applications of silicate mineral reductive modification graphene oxide | |
| CN103173093B (en) | A kind of protective system | |
| CN111117336A (en) | Modified graphene oxide dispersion liquid, preparation method thereof and application of modified graphene oxide dispersion liquid in coating | |
| CN106590351A (en) | High-adhesion anti-corrosion paint | |
| CN106590350A (en) | Anticorrosive coating containing sea-foam stone powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170426 |