CN106589995A - Decorative board with pest proof function - Google Patents
Decorative board with pest proof function Download PDFInfo
- Publication number
- CN106589995A CN106589995A CN201611003631.4A CN201611003631A CN106589995A CN 106589995 A CN106589995 A CN 106589995A CN 201611003631 A CN201611003631 A CN 201611003631A CN 106589995 A CN106589995 A CN 106589995A
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- parts
- decorative board
- decorative panel
- pressure
- stabilizer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention belongs to the technical field of wood plastic composite boards, and in particular relates to a decorative board with a pest control function, and the decorative board comprises the following raw materials: a wood plastic stabilizer, polymer of rosin allyl alcohol ester, phosphogypsum, dihydrocumic acid, larch extract, tannin extract, total flavonoids of Lithocarpus polystachyus, bagasse fiber and water. Compared with the prior art, the decorative board has the advantages of good mechanical properties and low imbibition rate and low heat shrinkage rate, the dimensional stability of decorative board can be ensured, the raw materials are well compatible and strong in plasticity, and can be customized according to the need to achieve modeling; the decorative board can effectively prevent pests and termites, and is easy to clean, free of maintenance, highly environmental-friendly and pollution-free, the fire protection grade can reach B1 level, comprehensive performance are superior, and the decorative board is suitable for popularization and use.
Description
Technical field
The invention belongs to wood-plastic composite panel technical field, and in particular to a kind of decorative panel with insect prevention function.
Background technology
Wood-plastic composite panel is one kind mainly by timber(Lignose, plant cellulose)Based on material and thermoplasticity it is high
Molecular material(Plastics)With processing aid etc., after mix homogeneously again the heating extrusion molding of Jing die apparatus and made by high-tech it is green
Colour circle protects new decorative material, has the performance and feature of timber and plastics concurrently, is the NEW TYPE OF COMPOSITE material that can substitute timber and plastics
Material, with expanding economy, the improvement of people's living standards, people have higher wanting to the speed and quality of Decoration Industry
Ask, wood-plastic composite panel compare common wood loss it is low, be not required to paint or water paint coating process, easy construction, price be adapted to,
Long service life, maintenance cost are low, therefore are increasingly liked by masses, in actual use, according to wood-plastic composite panel
The differentiation of purposes, needs to strengthen some functions again, as the material in wood-plastic composite panel includes the wooden material in part
Material, therefore in some areas it is possible that situation about being eaten into by worm or Coptotermes formosanus Shtrari., it is therefore desirable to research is carried out to corresponding function and is changed
Enter.
The content of the invention
The purpose of the present invention is for existing problem, there is provided a kind of decorative panel with insect prevention function.
The present invention is achieved by the following technical solutions:A kind of decorative panel with insect prevention function, by following weight portion
Raw material make:Wood moulding stabilizer 3-5 parts, polymer of rosin allyl alcohol ester 5-8 parts, ardealite 6-10 parts, dihydrocumic acid 4-6 parts,
Larch extract 8-12 parts, Pasania cuspidata total flavones 5-7 parts, sugarcane fiber 15-22 parts, water 18-22 parts;
Wherein, wood moulding stabilizer is made up of the raw material of following weight portion:Rare-earth stabilizer XT-2 8-10 parts, graphite powder 5-8 parts,
Potassium pyrophosphate 3-5 parts, calcium stearate 2-4 parts, the double stearylamine 4-8 parts of vinyl, methyl acetate 7-10 parts, dichloromethane 2-3 parts,
BBP(Butyl Benzyl Phthalate 2-3 part, diethylene glycol ether 2-4 parts, oxidized microcrystalline wax 3-4 parts, polyol ester 3-6 parts, tetrahydro-anthraquinone
1-2 parts, tremolite powder 6-8 parts, polyvinyl butyral resin 2-4 parts, amino silicane coupling agent 15-20 parts.
Used as further improvement of these options, the polymer of rosin allyl alcohol ester is obtained using microwave heating polymerization, soft
Change point and be not less than 320 DEG C.
Used as further improvement of these options, it is 60-80 μ that the length of the sugarcane fiber is 0.4-1.6mm, width
m。
A kind of decorative panel with insect prevention function, its preparation method are comprised the following steps:
(1)Ardealite, sugarcane fiber are ground to form into the powder that particle diameter is 300-400 μm, polymer of rosin allyl alcohol ester, larch is added
Tannic extract mix homogeneously, is heated to melting in far-infrared baking oven, is subsequently adding surplus stock, with 200-300 rev/min of speed
After stirring 15-20 minutes, slurry is obtained;
(2)Gained slurry is poured in mould, after pulp gel, the finish mix embryo of pressurizing and dehydrating is forced, moulding pressure is 4MPa,
After the completion of cooling and demolding;
(3)Compressing product is put in steam-cured template, sending into pressure steaming kettle carries out autoclave curing;Maintenance processes are liter temperature rise
Pressed as 6 hours, 140 DEG C are risen to from room temperature, rise to 1.2MPa from normal pressure;Constant temperature and pressure 3 hours, steam pressure is 0.9MPa, permanent
135 DEG C of temperature;Decrease temperature and pressure 6 hours, is down to room temperature from 140 DEG C, is down to normal pressure from 0.9MPa;Maintenance sloughs steam-cured template after terminating
As semi-finished product;
(4)Obtain being adapted to the decorative panel of size according to dimensional requirement finishing, it is 10% that drying machine is dried to moisture content, is obtained final product.
The present invention has advantages below compared to existing technology:The present invention prepare decorative panel mechanical property it is good, imbibition rate and
Percent thermal shrinkage is low, it is ensured that the dimensional stability of decorative panel, and between raw material, the compatibility is good, and plasticity is strong, can realize as needed
Customization moulding;Can effectively insect prevention, termite-proof, easy cleaning, Maintenance free and maintenance, high-environmental, nuisanceless, fire-protection rating can
Up to B1 levels, comprehensive performance is superior, is suitable to promote the use of.
Specific embodiment
Embodiment 1
A kind of decorative panel with insect prevention function, is made up of the raw material of following weight portion:3 parts of wood moulding stabilizer, polymerized rosin propylene
8 parts of alcohol ester, 6 parts of ardealite, 4 parts of dihydrocumic acid, 12 parts of larch extract, 5 parts of Pasania cuspidata total flavones, 16 parts of sugarcane fiber,
22 parts of water;
Wherein, wood moulding stabilizer is made up of the raw material of following weight portion:8 parts of rare-earth stabilizer XT-2,5 parts of graphite powder, pyrophosphoric acid
3 parts of potassium, 4 parts of calcium stearate, vinyl double 4 parts of stearylamine, 10 parts of methyl acetate, 2 parts of dichloromethane, BBP(Butyl Benzyl Phthalate
3 parts, 2 parts of diethylene glycol ether, 3 parts of oxidized microcrystalline wax, 6 parts of polyol ester, 1 part of tetrahydro-anthraquinone, 8 parts of tremolite powder, polyvinyl alcohol
2 parts of butyral, 20 parts of amino silicane coupling agent.
Wherein, the polymer of rosin allyl alcohol ester is obtained using microwave heating polymerization, and softening point is not less than 320 DEG C;The sugarcane
The length of slag fiber is 0.4-1.6mm, width is 60-80 μm.
A kind of decorative panel with insect prevention function, its preparation method are comprised the following steps:
(1)Ardealite, sugarcane fiber are ground to form into the powder that particle diameter is 300-400 μm, polymer of rosin allyl alcohol ester, larch is added
Tannic extract mix homogeneously, is heated to melting in far-infrared baking oven, is subsequently adding surplus stock, is stirred with 250 revs/min of speed
After 20 minutes, slurry is obtained;
(2)Gained slurry is poured in mould, after pulp gel, the finish mix embryo of pressurizing and dehydrating is forced, moulding pressure is 4MPa,
After the completion of cooling and demolding;
(3)Compressing product is put in steam-cured template, sending into pressure steaming kettle carries out autoclave curing;Maintenance processes are liter temperature rise
Pressed as 6 hours, 140 DEG C are risen to from room temperature, rise to 1.2MPa from normal pressure;Constant temperature and pressure 3 hours, steam pressure is 0.9MPa, permanent
135 DEG C of temperature;Decrease temperature and pressure 6 hours, is down to room temperature from 140 DEG C, is down to normal pressure from 0.9MPa;Maintenance sloughs steam-cured template after terminating
As semi-finished product;
(4)Obtain being adapted to the decorative panel of size according to dimensional requirement finishing, it is 10% that drying machine is dried to moisture content, is obtained final product.
Embodiment 2
A kind of decorative panel with insect prevention function, is made up of the raw material of following weight portion:4 parts of wood moulding stabilizer, polymerized rosin propylene
6 parts of alcohol ester, 8 parts of ardealite, 5 parts of dihydrocumic acid, 10 parts of larch extract, 5 parts of Pasania cuspidata total flavones, 19 parts of sugarcane fiber,
20 parts of water;
Wherein, wood moulding stabilizer is made up of the raw material of following weight portion:9 parts of rare-earth stabilizer XT-2,6 parts of graphite powder, pyrophosphoric acid
4 parts of potassium, 3 parts of calcium stearate, vinyl double 6 parts of stearylamine, 8 parts of methyl acetate, 2 parts of dichloromethane, BBP(Butyl Benzyl Phthalate 3
Part, the contracting of 3 parts of diethylene glycol ether, 4 parts of oxidized microcrystalline wax, 5 parts of polyol ester, 1 part of tetrahydro-anthraquinone, 7 parts of tremolite powder, polyvinyl alcohol
3 parts of butyraldehyde, 18 parts of amino silicane coupling agent.
Remainder is in the same manner as in Example 1.
Embodiment 3
A kind of decorative panel with insect prevention function, is made up of the raw material of following weight portion:5 parts of wood moulding stabilizer, polymerized rosin propylene
5 parts of alcohol ester, 10 parts of ardealite, 4 parts of dihydrocumic acid, 8 parts of larch extract, 5 parts of Pasania cuspidata total flavones, 15 parts of sugarcane fiber,
22 parts of water;
Wherein, wood moulding stabilizer is made up of the raw material of following weight portion:10 parts of rare-earth stabilizer XT-2,5 parts of graphite powder, burnt phosphorus
3 parts of sour potassium, 4 parts of calcium stearate, vinyl double 8 parts of stearylamine, 10 parts of methyl acetate, 3 parts of dichloromethane, phthalic acid fourth benzyls
2 parts of ester, 2 parts of diethylene glycol ether, 3 parts of oxidized microcrystalline wax, 6 parts of polyol ester, 1 part of tetrahydro-anthraquinone, 8 parts of tremolite powder, polyethylene
2 parts of butyral, 20 parts of amino silicane coupling agent.
Remainder is in the same manner as in Example 1.
In order to verify the using effect of decorative panel in the present invention, matched group is set, matched group is the fire prevention purchased by market
Grade is the common PLASTIC LAMINATED of B1, and its performance is detected, as a result as follows:
Table 1
By data in table 1, in matched group, decorative panel rupture strength and impact strength are all close with embodiment, but real
Applying bulking factor and percent thermal shrinkage in a 1-3 substantially reduces, and the decorative panel dimensional stability prepared in illustrating the present invention is high.
Coptotermes formosanus Shtrari. experiment is simultaneously set, by embodiment 1-3 and the made decorative panel of matched group cut into length and width specification for 50mm ×
The bar shaped plank of 20mm, weighs 2 ± 0.2g Coptotermes formosanus Shtrari. respectively and is put in independent experimental provision, in each assay device by each 10 pieces
The distilled water of the fine sand and 5g of 200g cleanings is placed into, is raised 5 days at ambient temperature, bar shaped plank is respectively put into into phase then
In the assay device answered, check decorative panel to receive moth degree after 24 hours, represented have by moth degree by the integrity value of bar shaped plank
Body result is as follows:
Table 2
The mothproof effect that decorative panel in the present invention be can be seen that by data in table 2 is significantly improved, and can extend making for decorative panel
Use the time limit.
Claims (4)
1. a kind of decorative panel with insect prevention function, it is characterised in that be made up of the raw material of following weight portion:Wood moulding stabilizer 3-
5 parts, polymer of rosin allyl alcohol ester 5-8 parts, ardealite 6-10 parts, dihydrocumic acid 4-6 parts, larch extract 8-12 parts, Pasania cuspidata
Total flavones 5-7 parts, sugarcane fiber 15-22 parts, water 18-22 parts;
Wherein, wood moulding stabilizer is made up of the raw material of following weight portion:Rare-earth stabilizer XT-2 8-10 parts, graphite powder 5-8 parts,
Potassium pyrophosphate 3-5 parts, calcium stearate 2-4 parts, the double stearylamine 4-8 parts of vinyl, methyl acetate 7-10 parts, dichloromethane 2-3 parts,
BBP(Butyl Benzyl Phthalate 2-3 part, diethylene glycol ether 2-4 parts, oxidized microcrystalline wax 3-4 parts, polyol ester 3-6 parts, tetrahydro-anthraquinone
1-2 parts, tremolite powder 6-8 parts, polyvinyl butyral resin 2-4 parts, amino silicane coupling agent 15-20 parts.
2. as claimed in claim 1 a kind of decorative panel with insect prevention function, it is characterised in that the polymer of rosin allyl alcohol ester is adopted
Obtained with microwave heating polymerization, softening point is not less than 320 DEG C.
3. as claimed in claim 1 a kind of decorative panel with insect prevention function, it is characterised in that the length of the sugarcane fiber is
0.4-1.6mm, width are 60-80 μm.
4. as claimed in claim 1 a kind of decorative panel with insect prevention function, it is characterised in that its preparation method includes following step
Suddenly:
(1)Ardealite, sugarcane fiber are ground to form into the powder that particle diameter is 300-400 μm, polymer of rosin allyl alcohol ester, larch is added
Tannic extract mix homogeneously, is heated to melting in far-infrared baking oven, is subsequently adding surplus stock, with 200-300 rev/min of speed
After stirring 15-20 minutes, slurry is obtained;
(2)Gained slurry is poured in mould, after pulp gel, the finish mix embryo of pressurizing and dehydrating is forced, moulding pressure is 4MPa,
After the completion of cooling and demolding;
(3)Compressing product is put in steam-cured template, sending into pressure steaming kettle carries out autoclave curing;Maintenance processes are liter temperature rise
Pressed as 6 hours, 140 DEG C are risen to from room temperature, rise to 1.2MPa from normal pressure;Constant temperature and pressure 3 hours, steam pressure is 0.9MPa, permanent
135 DEG C of temperature;Decrease temperature and pressure 6 hours, is down to room temperature from 140 DEG C, is down to normal pressure from 0.9MPa;Maintenance sloughs steam-cured template after terminating
As semi-finished product;
(4)Obtain being adapted to the decorative panel of size according to dimensional requirement finishing, it is 10% that drying machine is dried to moisture content, is obtained final product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201611003631.4A CN106589995A (en) | 2016-11-15 | 2016-11-15 | Decorative board with pest proof function |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201611003631.4A CN106589995A (en) | 2016-11-15 | 2016-11-15 | Decorative board with pest proof function |
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Publication Number | Publication Date |
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CN106589995A true CN106589995A (en) | 2017-04-26 |
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CN201611003631.4A Pending CN106589995A (en) | 2016-11-15 | 2016-11-15 | Decorative board with pest proof function |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107140878A (en) * | 2017-07-12 | 2017-09-08 | 合肥信亚达智能科技有限公司 | Building materials prepared by a kind of utilization lake mud and preparation method thereof |
CN108641193A (en) * | 2018-06-21 | 2018-10-12 | 安徽鸿森塑业有限公司 | A method of reducing polypropylene agglomerate molding shrinkage |
Citations (4)
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JP2003025308A (en) * | 2001-07-18 | 2003-01-29 | Matsushita Electric Works Ltd | Wood flooring |
CN101618565A (en) * | 2009-04-28 | 2010-01-06 | 王勇 | Manufacture method of environment-friendly wood substrate composite material |
CN101698749A (en) * | 2009-11-03 | 2010-04-28 | 北京林业大学 | Wood-plastic composite material and prepration method thereof |
CN105062109A (en) * | 2015-07-17 | 2015-11-18 | 安徽万兴实业有限公司 | Anti-bacterial and mould-proof wood-plastic composite |
-
2016
- 2016-11-15 CN CN201611003631.4A patent/CN106589995A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003025308A (en) * | 2001-07-18 | 2003-01-29 | Matsushita Electric Works Ltd | Wood flooring |
CN101618565A (en) * | 2009-04-28 | 2010-01-06 | 王勇 | Manufacture method of environment-friendly wood substrate composite material |
CN101698749A (en) * | 2009-11-03 | 2010-04-28 | 北京林业大学 | Wood-plastic composite material and prepration method thereof |
CN105062109A (en) * | 2015-07-17 | 2015-11-18 | 安徽万兴实业有限公司 | Anti-bacterial and mould-proof wood-plastic composite |
Non-Patent Citations (3)
Title |
---|
张斌: "木粉/落叶松栲胶复合模压成板工艺", 《东北林业大学学报》 * |
红河彝族辞典编攥委员会 编: "《红河彝族辞典》", 31 July 2002, 云南民族出版社 * |
郑子樵 等: "《稀土功能材料》", 30 September 2003, 化学工业出版社 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107140878A (en) * | 2017-07-12 | 2017-09-08 | 合肥信亚达智能科技有限公司 | Building materials prepared by a kind of utilization lake mud and preparation method thereof |
CN108641193A (en) * | 2018-06-21 | 2018-10-12 | 安徽鸿森塑业有限公司 | A method of reducing polypropylene agglomerate molding shrinkage |
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