CN106589824A - Moisture-proof resin liquid composition for terrace and preparation method thereof - Google Patents
Moisture-proof resin liquid composition for terrace and preparation method thereof Download PDFInfo
- Publication number
- CN106589824A CN106589824A CN201611162460.XA CN201611162460A CN106589824A CN 106589824 A CN106589824 A CN 106589824A CN 201611162460 A CN201611162460 A CN 201611162460A CN 106589824 A CN106589824 A CN 106589824A
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- Prior art keywords
- component
- terrace
- resinses
- fluid composition
- moisture barrier
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a moisture-proof resin liquid composition for a terrace and a preparation method thereof. The moisture-proof resin liquid composition for the terrace comprises a polymer of 4,4'-isopropylidenedi-phenol and 1-chloro-2,3-epoxy-propan, a co-polymer of 4,4-methylenebisphenol, the 4,4'-isopropylidenedi-phenol and the 1-chloro-2,3-epoxy-propan, a glycidyl ether, an accessory ingredient, hydrogenated alkyl aniline, benzyl alcohol, 2,4,6-tri(dimethylamino) mesitol, polypropylene oxide amine-terminated polyether and other components. The resin liquid composition provided by the invention has lower mixing viscosity and longer operating period, can change from hydrophile to hydrophobicity through curing reaction so as to have a favorable moisture-proof performance, and avoids the occurrence of bubbles of the resin terrace.
Description
Technical field
The present invention relates to epoxide terrace correlative technology field, specifically a kind of terrace Moisture barrier resinses fluid composition
And preparation method thereof.
Background technology
Epoxide terrace is a kind of high intensity, floor wear-resistant, attractive in appearance, with seamless, quality be solid, resistance to chemical reagents
The advantages of good, anti-corrosion, dust-proof, easy maintenance, cheap maintenance cost, it is widely used in the middle of office and factory floor.
Epoxide terrace is got blister and is mostly occurred in Stall or basement, more than second floor is also happened occasionally sometimes, and epoxide terrace rises
Blister typically finds that soon after construction that the epoxide terrace of some morning pavings just has blister afternoon.
The content of the invention
The invention aims to make up the deficiencies in the prior art, there is provided a kind of ground for avoiding blister phenomenon from occurring
Level ground Moisture barrier resinses fluid composition and preparation method thereof.
In order to reach the purpose of the present invention, technical scheme is as follows：
A kind of terrace Moisture barrier resinses fluid composition, it is characterised in that including component A and B component, by weight percentage
Meter, component A includes：
By weight percentage, B component includes：
Wherein the ratio of component A and B component is 100:30～100:45.
Preferably, the molecule of the polymer of described 4,4 '-(1- methyl ethylidene) biphenol and (chloromethyl) oxirane
, 200～400, epoxide equivalent is 150～200 for amount.
Preferably, described 4,4 dihydroxydiphenyl methane, 4,4 '-(1- methyl ethylidene) biphenol and (chloromethyl) ring
, 200～400, epoxide equivalent is 150～200 for the molecular weight of the co-polymer of oxidative ethane.
Preferably, the defoamer is organic silicon defoamer, and the penetrant is organosilicon-modified acrylic, described attached
Adhesion promoter is the organosilicon auxiliary agent with epoxy result, and the wetting agent is organosilicon-modified acrylic agent.
Preferably, the molecular weight of the polypropylene oxide cardinal extremity amino-polyether is 200～300, active hydrogen equivalent weight 40～
65。
Preferably, the molecular weight of the copolymer for being based on 1,6 hexanediol expoxy propane and oxirane 1000～
3000。
Preferably, in the B component, hydrogenation polyalkylbenzene amine, benzyl alcohol, 2,4,6- tri- (dimethylamino methyl) phenol
Can in the form of respective monomer, can also be three monomers compositionss.
A kind of terrace preparation method of Moisture barrier resinses fluid composition, it is characterised in that including step：
Component A
1.1) by 4,4 '-(1- methyl ethylidene) biphenol and the polymer and 4,4 dihydroxies of (chloromethyl) oxirane
Base diphenyl methane, 4,4 '-(1- methyl ethylidene) biphenols are heated to 50 and take the photograph with the co-polymer of (chloromethyl) oxirane
After family name's degree, in putting into clean production axe；
1.2) put into after Oleum Ricini glycidyl ether, hexanediol glycidyl ether, benzyl group glycidyl ether with this, opened
Dynamic stirring, using moderate-speed mixer；
1.3) after stirring, moderate-speed mixer puts into successively defoamer, penetrant, adhesion promoter, wetting agent,
Stirring 40 minutes；
1.4) sample, after reaching quality control index, finished product packing；
B component
1.1) polyalkylbenzene amine, benzyl alcohol, 2,4,6- tri- (dimethylamino methyl) phenol or combinations thereof, input will be hydrogenated
To in clean production axe；
1.2) polypropylene oxide cardinal extremity amino-polyether is put into this, based on 1,6 hexanediol expoxy propane and oxirane
After copolymer, stirring is started, using moderate-speed mixer；Stirring 40 minutes
1.3) sample, after reaching quality control index, finished product packing.
After the completion of component A and B component are each prepared, mixing and stirring, using certain construction, such as roller coating, trowel
Apply, spraying so as to which uniform dressing is in substrate surface.
The device have the advantages that：
Solve a following difficult problem：Such as terrace basal plane moisture content height；Basal plane does not make damp-proof layer；Fresh concrete rapid construction
Resin ground.The resin liquid compositionss are with relatively low mixing viscosity, with the longer operation phase, with anti-by solidification
Should make that said composition is hydrophilic to turn hydrophobic, and then cause said composition that there is good humidity resistance, it is to avoid the water of resin terrace
Steep raising is given birth to.
Specific embodiment
With reference to embodiment, the invention will be further described, but protection scope of the present invention is not limited solely to implement
Example.
Embodiment 1
A kind of terrace Moisture barrier resinses fluid composition, including component A and B component, by weight percentage, component A bag
Include：
Wherein defoamer be BYK 066N, penetrant be BYK 333, adhesion promoter be this 208 of hamming, moistening
Agent is the 3782 of BYK.
By weight percentage, B component includes：
Wherein the ratio of component A and B component is 100:30.
Hydrogenation polyalkylbenzene amine, benzyl alcohol and (dimethylamino methyl) phenol of 2,4,6- tri- are carried by U.S.'s gas companies
For each with monomeric form presence.Polypropylene oxide cardinal extremity amino-polyether be the graceful D230 of Hensel, D220, D400, T403,
One or more in D2000, T3000, D203, D205 etc..In the present embodiment, polypropylene oxide cardinal extremity amino-polyether is selected
Be D230, molecular weight is 230, and active hydrogen equivalent weight is 45.
Embodiment 2
A kind of terrace Moisture barrier resinses fluid composition, including component A and B component, by weight percentage, component A bag
Include：
Wherein defoamer be BYK 066N, penetrant be BYK 333, adhesion promoter be this 208 of hamming, moistening
Agent is the 3782 of BYK.
By weight percentage, B component includes：
Wherein the ratio of component A and B component is 100:35.
Hydrogenation polyalkylbenzene amine, benzyl alcohol and (dimethylamino methyl) phenol of 2,4,6- tri- are carried by U.S.'s gas companies
For existing with three monomers compositionss together.Polypropylene oxide cardinal extremity amino-polyether be the graceful D230 of Hensel, D220, D400,
One or more in T403, D2000, T3000, D203, D205 etc..In the present embodiment, polypropylene oxide cardinal extremity amino gathers
What ether was selected is the compositionss of D230 and D220, and molecular weight is 260, and active hydrogen equivalent weight is 55.
Embodiment 3
A kind of terrace Moisture barrier resinses fluid composition, including component A and B component, by weight percentage, component A bag
Include：
Wherein defoamer be BYK 066N, penetrant be BYK 333, adhesion promoter be this 208 of hamming, moistening
Agent is the 3782 of BYK.
By weight percentage, B component includes：
Wherein the ratio of component A and B component is 100:45.
Hydrogenation polyalkylbenzene amine, benzyl alcohol and (dimethylamino methyl) phenol of 2,4,6- tri- are carried by U.S.'s gas companies
For each with monomeric form presence.Polypropylene oxide cardinal extremity amino-polyether be the graceful D230 of Hensel, D220, D400, T403,
One or more in D2000, T3000, D203, D205 etc..In the present embodiment, polypropylene oxide cardinal extremity amino-polyether is selected
Be D205, molecular weight is 300, and active hydrogen equivalent weight is 60.
Embodiment 4
A kind of terrace Moisture barrier resinses fluid composition, including component A and B component, by weight percentage, component A bag
Include：
Wherein defoamer be BYK 066N, penetrant be BYK 333, adhesion promoter be this 208 of hamming, moistening
Agent is the 3782 of BYK.
By weight percentage, B component includes：
Wherein the ratio of component A and B component is 100:40.
Hydrogenation polyalkylbenzene amine, benzyl alcohol and (dimethylamino methyl) phenol of 2,4,6- tri- are carried by U.S.'s gas companies
For each with monomeric form presence.Polypropylene oxide cardinal extremity amino-polyether be the graceful D230 of Hensel, D220, D400, T403,
One or more in D2000, T3000, D203, D205 etc..In the present embodiment, polypropylene oxide cardinal extremity amino-polyether is selected
Be D205, molecular weight is 300, and active hydrogen equivalent weight is 60.
Finally it should be noted that：Above example only not limits technology described in the invention to illustrate the present invention
Scheme, therefore, although this specification with reference to each above-mentioned embodiment pair present invention has been detailed description, this
Field it is to be appreciated by one skilled in the art that still can modify to the present invention or equivalent, and all are without departing from this
The technical scheme of the spirit and scope of invention and its improvement, it all should cover in scope of the presently claimed invention.
Claims (8)
1. a kind of terrace Moisture barrier resinses fluid composition, it is characterised in that including component A and B component, by weight percentage
Meter, component A includes：
Wherein the ratio of component A and B component is 100:30～100:45.
2. terrace according to claim 1 Moisture barrier resinses fluid composition, it is characterised in that described 4,4 '-(1- methyl
Ethylidene) biphenol and (chloromethyl) oxirane polymer molecular weight 200～400, epoxide equivalent is 150～200.
3. terrace according to claim 1 Moisture barrier resinses fluid composition, it is characterised in that described 4,4 dihydroxy two
The molecular weight of the co-polymer of phenylmethane, 4,4 '-(1- methyl ethylidene) biphenol and (chloromethyl) oxirane 200～
400, epoxide equivalent is 150～200.
4. terrace according to claim 1 Moisture barrier resinses fluid composition, it is characterised in that the defoamer is organic
Silicon defoaming agent, the penetrant is organosilicon-modified acrylic, and the adhesion promoter is with the organic of epoxy result
Silicon additive, the wetting agent is organosilicon-modified acrylic agent.
5. terrace according to claim 1 Moisture barrier resinses fluid composition, it is characterised in that the polypropylene oxide base
, 200～300, active hydrogen equivalent weight is 40～65 for the molecular weight of amine terminated polyether.
6. terrace according to claim 1 Moisture barrier resinses fluid composition, it is characterised in that it is described be based on 1,6 oneself two
The molecular weight of the copolymer of alcohol expoxy propane and oxirane is 1000～3000.
7. terrace according to claim 1 Moisture barrier resinses fluid composition, it is characterised in that in the B component, hydrogen
Change polyalkylbenzene amine, benzyl alcohol, 2,4,6- tri- (dimethylamino methyl) phenol can in the form of respective monomer, can also
It is the compositionss of three monomers.
8. a kind of terrace preparation method of Moisture barrier resinses fluid composition, it is characterised in that including step：
Component A
1.1) by 4,4 '-(1- methyl ethylidene) biphenol and the polymer and 4,4 dihydroxy two of (chloromethyl) oxirane
Phenylmethane, 4,4 '-(1- methyl ethylidene) biphenol are heated to 50 degrees Celsius with the co-polymer of (chloromethyl) oxirane
Afterwards, in putting into clean production axe；
1.2) put into after Oleum Ricini glycidyl ether, hexanediol glycidyl ether, benzyl group glycidyl ether with this, start and stir
Mix, using moderate-speed mixer；
1.3) after stirring, moderate-speed mixer puts into successively defoamer, penetrant, adhesion promoter, wetting agent, stirring
40 minutes；
1.4) sample, after reaching quality control index, finished product packing；
B component
1.1) polyalkylbenzene amine, benzyl alcohol, 2,4,6- tri- (dimethylamino methyl) phenol or combinations thereof will be hydrogenated, will be put into dry
In net production axe；
1.2) polypropylene oxide cardinal extremity amino-polyether, the copolymerization based on 1,6 hexanediol expoxy propane and oxirane are put into this
After thing, stirring is started, stirred 40 minutes using the rotating speed of 400～600 turns/Min；
1.3) sample, after reaching quality control index, finished product packing,
After the completion of component A and B component are each prepared, mixing and stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611162460.XA CN106589824B (en) | 2016-12-15 | 2016-12-15 | A kind of terrace Moisture barrier resins liquid composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611162460.XA CN106589824B (en) | 2016-12-15 | 2016-12-15 | A kind of terrace Moisture barrier resins liquid composition and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106589824A true CN106589824A (en) | 2017-04-26 |
| CN106589824B CN106589824B (en) | 2018-11-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611162460.XA Active CN106589824B (en) | 2016-12-15 | 2016-12-15 | A kind of terrace Moisture barrier resins liquid composition and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3787520A (en) * | 1971-08-16 | 1974-01-22 | Ford Motor Co | Powdered coating compositions containing a glycidyl ester copolymer,a phenolic hydroxy crosslinking agent,and a flow control agent |
| JP2011116913A (en) * | 2009-12-07 | 2011-06-16 | Mitsubishi Electric Corp | Thermocurable resin composition, thermoconductive resin sheet and production method, and power module |
| CN102863876A (en) * | 2012-09-06 | 2013-01-09 | 中科院广州化学有限公司 | Organic silicon modified epoxy floor paint and preparation method and application thereof |
| CN104250510A (en) * | 2014-09-30 | 2014-12-31 | 洛阳双瑞防腐工程技术有限公司 | Solvent-free epoxy self-leveling roller coating floor paint and preparation and use method thereof |
| CN105238225A (en) * | 2015-11-23 | 2016-01-13 | 福州皇家地坪有限公司 | Solvent-free epoxy self-leveling terrace |
-
2016
- 2016-12-15 CN CN201611162460.XA patent/CN106589824B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3787520A (en) * | 1971-08-16 | 1974-01-22 | Ford Motor Co | Powdered coating compositions containing a glycidyl ester copolymer,a phenolic hydroxy crosslinking agent,and a flow control agent |
| JP2011116913A (en) * | 2009-12-07 | 2011-06-16 | Mitsubishi Electric Corp | Thermocurable resin composition, thermoconductive resin sheet and production method, and power module |
| CN102863876A (en) * | 2012-09-06 | 2013-01-09 | 中科院广州化学有限公司 | Organic silicon modified epoxy floor paint and preparation method and application thereof |
| CN104250510A (en) * | 2014-09-30 | 2014-12-31 | 洛阳双瑞防腐工程技术有限公司 | Solvent-free epoxy self-leveling roller coating floor paint and preparation and use method thereof |
| CN105238225A (en) * | 2015-11-23 | 2016-01-13 | 福州皇家地坪有限公司 | Solvent-free epoxy self-leveling terrace |
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| Publication number | Publication date |
|---|---|
| CN106589824B (en) | 2018-11-23 |
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