CN106589691A - Fireproof and wear-resistant composite fiber material - Google Patents

Fireproof and wear-resistant composite fiber material Download PDF

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Publication number
CN106589691A
CN106589691A CN201611143357.0A CN201611143357A CN106589691A CN 106589691 A CN106589691 A CN 106589691A CN 201611143357 A CN201611143357 A CN 201611143357A CN 106589691 A CN106589691 A CN 106589691A
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CN
China
Prior art keywords
parts
wear
fiber material
antioxidant
fire prevention
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611143357.0A
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Chinese (zh)
Inventor
王举
孙益民
芮定文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Original Assignee
ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd filed Critical ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Priority to CN201611143357.0A priority Critical patent/CN106589691A/en
Publication of CN106589691A publication Critical patent/CN106589691A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The invention provides a fireproof and wear-resistant composite fiber material which is prepared from the following raw materials in parts by weight: 40 to 50 parts of wood fibers, 80 to 120 parts of polyvinyl chloride, 3 to 5 parts of a coupling agent, 3 to 5 parts of a compatilizer, 1 to 3 parts of a lubricating agent, 0.5 to 1 part of graphene, 5 to 10 parts of a flame retardant, 1 to 2 parts of an antioxidant and 0.5 to 1 part of an anti-aging agent. The fireproof and wear-resistant composite fiber material improves the wear resistance and the hardness of a wood-plastic material; moreover, due to the arrangement of the reasonable flame retardant, the fire resistance of a wood material is improved.

Description

One kind fire prevention, wear-resisting complex fiber material
Technical field
The present invention relates to technical field of composite materials, and in particular to one kind fire prevention, wear-resisting complex fiber material.
Background technology
Surface abrasion resistance of the wood plastic composite using in is its important performance indications.So-called material wear ability is referred to It resists the ability of abrasion under certain friction condition, and abrasion is that material surface is rubbed, extrudes, impacted, degraded and this A kind of several combined factors surface change procedure produced when acting on, is characterized in that wearing part is surface, shape and body The physical propertys such as product change, without the change of chemical property.With science and technology continuous development and people's demand it is continuous Improve, the also more diversification of the requirement to wood plastic composite.
In the potential application such as building materials, furniture, packaging field, the wearability and case hardness of wood plastic composite are also important Performance indications;Wherein timber is flammable materials, is combined the several functions for improving composite wood material, improves its range of application, It is the key for improving product competitiveness, wherein for the fire prevention of composite wood is also have higher requirement.
The content of the invention
(One)The technical problem of solution
Not enough for prior art, the present invention provides a kind of fire prevention, wear-resisting complex fiber material, improves the wear-resisting of Wood-plastic material Property and hardness, while be provided with rational fire retardant, improve wood materials fire resistance.
(Two)Technical scheme
To realize object above, the present invention is achieved by the following technical programs:
The raw material composition of one kind fire prevention, wear-resisting complex fiber material, including following parts by weight:Wood fibre 40-50 parts, polychlorostyrene Ethene 80-120 parts, coupling agent 3-5 parts, compatilizer 3-5 parts, lubricant 1-3 parts, Graphene 0.5-1 parts, fire retardant 5-10 parts, Antioxidant 1-2 parts and age resistor 0.5-1 parts.
45 parts of the wood fibre, 110 parts of polyvinyl chloride, 4 parts of coupling agent, 4 parts of compatilizer, 2 parts of lubricant, Graphene 0.8 part of 0.8 part, 8 parts of fire retardant, 1.5 parts of antioxidant and age resistor.
The fire retardant adopts pyrophosphate based flame retardant.The antioxidant adopts the antioxidant of 1010 models.The phase Appearance agent is the liquor-saturated grafting compatilizer of maleic acid.
The lubricant is paraffin oil.
(Three)Beneficial effect
The present invention provides a kind of fire prevention, wear-resisting complex fiber material, and compared with prior art advantage is:The present invention is by wooden Then fiber is aided with dispensing and auxiliary agent, and the composite that Jing hot pressing is obtained has good wearability and case hardness, resultant force Excellent performance is learned, construction material and furniture material field is can be applicable to.The present invention is modified to wood fibre, makes wood powder fiber With good interfacial adhesion, wearability and case hardness, the wearability and hardness of Wood-plastic material are improve, while being provided with rationally Fire retardant, improve wood materials fire resistance.
Specific embodiment
To make purpose, technical scheme and the advantage of the embodiment of the present invention clearer, with reference to the embodiment of the present invention pair Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is a part of the invention Embodiment, rather than the embodiment of whole.Based on the embodiment in the present invention, those of ordinary skill in the art are not making wound The every other embodiment obtained under the premise of the property made work, belongs to the scope of protection of the invention.
The raw material composition of one kind fire prevention, wear-resisting complex fiber material, including following parts by weight:It is 45 parts of wood fibre, poly- 110 parts of vinyl chloride, 4 parts of coupling agent, 4 parts of compatilizer, 2 parts of lubricant, 0.8 part of Graphene, 8 parts of fire retardant, 1.5 parts of antioxidant and 0.8 part of age resistor;The fire retardant adopts pyrophosphate based flame retardant, the antioxidant to adopt the antioxidant of 1010 models, institute It is the liquor-saturated grafting compatilizer of maleic acid to state compatilizer, and the lubricant is paraffin oil.
The present invention is by wood fibre and then is aided with dispensing and auxiliary agent, and the composite that Jing hot pressing is obtained has good resistance to Mill property and case hardness, comprehensive mechanical property is excellent, can be applicable to construction material and furniture material field.The present invention is to wooden fibre Dimension is modified, and makes wood powder fiber have good interfacial adhesion, wearability and case hardness, improves the wear-resisting of Wood-plastic material Property and hardness, while be provided with rational fire retardant, improve wood materials fire resistance.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality Body or operation make a distinction with another entity or operation, and not necessarily require or imply these entities or deposit between operating In any this actual relation or order.And, term " including ", "comprising" or its any other variant are intended to Nonexcludability is included, so that a series of process, method, article or equipment including key elements not only will including those Element, but also including other key elements being not expressly set out, or also include for this process, method, article or equipment Intrinsic key element.In the absence of more restrictions, the key element for being limited by sentence "including a ...", it is not excluded that Also there is other identical element in process, method, article or equipment including the key element.
Above example only to illustrate technical scheme, rather than a limitation;Although with reference to the foregoing embodiments The present invention has been described in detail, it will be understood by those within the art that:It still can be to aforementioned each enforcement Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic;And these modification or Replace, do not make the spirit and scope of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution.

Claims (6)

1. a kind of fire prevention, wear-resisting complex fiber material, it is characterised in that:Constitute including the raw material of following parts by weight:Wooden fibre Dimension 40-50 parts, polyvinyl chloride 80-120 parts, coupling agent 3-5 parts, compatilizer 3-5 parts, lubricant 1-3 parts, Graphene 0.5-1 parts, Fire retardant 5-10 parts, antioxidant 1-2 parts and age resistor 0.5-1 parts.
2. a kind of fire prevention according to claim 1, wear-resisting complex fiber material, it is characterised in that the wood fibre 45 Part, 110 parts of polyvinyl chloride, 4 parts of coupling agent, 4 parts of compatilizer, 2 parts of lubricant, 0.8 part of Graphene, 8 parts of fire retardant, antioxidant 1.5 parts and 0.8 part of age resistor.
3. a kind of fire prevention according to claim 1, wear-resisting complex fiber material, it is characterised in that the fire retardant is adopted Pyrophosphate based flame retardant.
4. a kind of fire prevention according to claim 1, wear-resisting complex fiber material, it is characterised in that the antioxidant is adopted The antioxidant of 1010 models.
5. a kind of fire prevention according to claim 1, wear-resisting complex fiber material, it is characterised in that the compatilizer is horse Carry out sour liquor-saturated grafting compatilizer.
6. a kind of fire prevention according to claim 1, wear-resisting complex fiber material, it is characterised in that the lubricant is stone Wax oil.
CN201611143357.0A 2016-12-13 2016-12-13 Fireproof and wear-resistant composite fiber material Pending CN106589691A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611143357.0A CN106589691A (en) 2016-12-13 2016-12-13 Fireproof and wear-resistant composite fiber material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611143357.0A CN106589691A (en) 2016-12-13 2016-12-13 Fireproof and wear-resistant composite fiber material

Publications (1)

Publication Number Publication Date
CN106589691A true CN106589691A (en) 2017-04-26

Family

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Application Number Title Priority Date Filing Date
CN201611143357.0A Pending CN106589691A (en) 2016-12-13 2016-12-13 Fireproof and wear-resistant composite fiber material

Country Status (1)

Country Link
CN (1) CN106589691A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108359195A (en) * 2018-03-30 2018-08-03 江苏冰溶管业有限公司 A kind of PVC pipeline for building and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105017676A (en) * 2015-04-21 2015-11-04 江苏中超电缆股份有限公司 Graphene-containing high heat conduction polyvinyl chloride sheath material for cable, and cable
CN105440475A (en) * 2015-10-30 2016-03-30 嘉善贝马五金配件有限公司 Lignocellulose-toughened polyvinyl chloride automobile internal decorating material and preparation method therefor
CN105924856A (en) * 2016-07-07 2016-09-07 安徽国风木塑科技有限公司 High-strength anticorrosion compound fiber wood-plastic composite and preparation method thereof
CN106118110A (en) * 2016-07-22 2016-11-16 东北林业大学 A kind of polyolefin-based wood plastic composite of nonisulated heat conduction and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105017676A (en) * 2015-04-21 2015-11-04 江苏中超电缆股份有限公司 Graphene-containing high heat conduction polyvinyl chloride sheath material for cable, and cable
CN105440475A (en) * 2015-10-30 2016-03-30 嘉善贝马五金配件有限公司 Lignocellulose-toughened polyvinyl chloride automobile internal decorating material and preparation method therefor
CN105924856A (en) * 2016-07-07 2016-09-07 安徽国风木塑科技有限公司 High-strength anticorrosion compound fiber wood-plastic composite and preparation method thereof
CN106118110A (en) * 2016-07-22 2016-11-16 东北林业大学 A kind of polyolefin-based wood plastic composite of nonisulated heat conduction and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
徐应麟等: "《电线电缆手册 第2册 第2版 增订本》", 30 April 2014 *
李国能等: "《塑料模压成型技术问答》", 30 June 2012 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108359195A (en) * 2018-03-30 2018-08-03 江苏冰溶管业有限公司 A kind of PVC pipeline for building and preparation method thereof

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Application publication date: 20170426