CN106587803A - Waterproof brick taking water-based drilling rock debris as aggregate - Google Patents

Waterproof brick taking water-based drilling rock debris as aggregate Download PDF

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Publication number
CN106587803A
CN106587803A CN201611046604.5A CN201611046604A CN106587803A CN 106587803 A CN106587803 A CN 106587803A CN 201611046604 A CN201611046604 A CN 201611046604A CN 106587803 A CN106587803 A CN 106587803A
Authority
CN
China
Prior art keywords
waterproof
water
brick
parts
based drilling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611046604.5A
Other languages
Chinese (zh)
Inventor
李明月
李凤娟
贺远鹏
李小龙
刘军海
宿辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CNOOC Energy Technology and Services Ltd
Safety and Environmental Protection Branch of CNOOC Energy Technology and Services Ltd
Original Assignee
CNOOC Energy Technology and Services Ltd
Safety and Environmental Protection Branch of CNOOC Energy Technology and Services Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CNOOC Energy Technology and Services Ltd, Safety and Environmental Protection Branch of CNOOC Energy Technology and Services Ltd filed Critical CNOOC Energy Technology and Services Ltd
Priority to CN201611046604.5A priority Critical patent/CN106587803A/en
Publication of CN106587803A publication Critical patent/CN106587803A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/0481Other specific industrial waste materials not provided for elsewhere in C04B18/00
    • C04B18/049Wastes from oil or other wells, e.g. drilling mud
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention belongs to the field of solid waste recycling, and discloses a waterproof brick taking water-based drilling rock debris as aggregate. The waterproof brick is prepared from, by weight, 28-32 parts of water-based drilling rock debris, 28-32 parts of cement, 18-22 parts of stone nitrate, 12-18 parts of river sand, 4-6 parts of a cement-based permeable crystallization type waterproof agent. Accordingly, the environmental problem that soil and water resources are polluted by the water-based drilling rock debris for large-scale mining of petroleum, natural gas and the like, the governance cost is reduced, and the solid waste recycling effects of eliminating pollution and turning waste into wealth are achieved; raw materials for preparing the waterproof brick are widely distributed in a domestic market and are good in economic performance and easy to obtain; by adding the cement-based permeable crystallization type waterproof agent, the waterproof function is increased, a better anti-permeability effect is achieved, and the waterproof brick has practical value for being used for well field enclosing walls, houses and other well field environmentally-friendly buildings including places such as a sludge tank, a diversion trench, a leachate collection tank and a well field pavement.

Description

A kind of utilization water-based drilling landwaste does the waterproof brick of aggregate
Technical field
The invention belongs to solid waste resource utilization field, and in particular to a kind of landwaste waterproof brick.
Background technology
With the fast development of petroleum industry, drilling process can produce substantial amounts of well drilling detritus, and the garbage is oil gas field One of main industrial solid castoff produced in development process.
In recent years, as drilling well difficulty becomes big, drilling fluid property is continuously increased, and additive and poisonous and harmful element are also increasingly Increase, resulting well drilling detritus are generally containing pollutant such as substantial amounts of petroleum hydrocarbon, salt and macromolecule polyalcohols.With The reinforcement of people's environmental consciousness, harm and impact of the high salt-containing drilling landwaste on environment receives much concern, and many countries are all by it It is classified as the important content of environmental improvement.In line with the purpose that high salt-containing drilling solid waste is administered:One is to eliminate pollution, environmental protection;Two It is to recycle, turns harm into good.
From the point of view of available data, both at home and abroad to the generally individually leading cured of high waste salt-containing drilling thing process, Ran Houzai Comprehensive utilization is done, but the stacking of high salt-containing drilling solid waste (landwaste) and solidification need to take the place of larger area, build mud Stock tank carries out storage and is also required to substantial amounts of raw material and workman, and the place demand for stacking waste mud (landwaste) increases accordingly Greatly.
The China's oil construction of natural gas fields is very fast, and remaining substantial amounts of well drilling detritus after completion, landwaste is utilized in construction material On be the treatment measures for meeting current national environmental protection energy saving policy.Currently, sintering-free clay brick and composite brick are used as energy-saving wall Body material is progressively subject to people's attention, and more work has particularly been carried out in terms of the development of sintering-free clay brick.Gao Han Salt well drilling detritus make waterproof brick, and well drilling detritus harmless treatment is changed into into recycling treatment, are the certainty under environmental protection policy Trend.
The content of the invention
The water-based drilling landwaste for being generation in the scale recovery process such as oil, natural gas to be solved by this invention is to soil The technical problem that earth environment and water environment are polluted, there is provided a kind of utilization water-based drilling landwaste does the waterproof brick of aggregate, leads to Addition cementitious capillary crystalline waterproofing agent is crossed, impervious good, self-healing performance is good, cohesive force is strong, nothing to have landwaste waterproof brick The characteristics of poison is harmless, disclosure satisfy that comprcssive strength and waterproof brick and its application.
In order to solve above-mentioned technical problem, the present invention is achieved by following technical scheme:
A kind of utilization water-based drilling landwaste does the waterproof brick of aggregate, composed of the following components by weight:
Preferably, a kind of utilization water-based drilling landwaste does the waterproof brick of aggregate, composed of the following components by weight:
The invention has the beneficial effects as follows:
The present invention does aggregate and waterproof brick is obtained using water-based drilling landwaste, solves the exploitation of the scales such as oil, natural gas Water-based drilling landwaste contaminated soil and water resource environmental problem, saved the cost of enterprise governance water-based drilling landwaste, it is real The effect that the solid wastes recycling for showed abatement of pollution, turning waste into wealth is utilized;Each raw material of the waterproof brick is prepared in China market point Extensively, economic performance is preferably, simple and easy to get for cloth;By adding cementitious capillary crystalline waterproofing agent, water-proof function is increased, had There is more preferable impermeable effect, with more pollution effects are prevented, for well site enclosure wall, house and other well site environment protection architecture bags Include the places such as sludge-tank, guiding gutter, leachate collection pool, well site road surface more with practical value, increased oil, natural pneumatic drill Well well site anti-seepage effect.
Specific embodiment
Below by specific embodiment, the present invention is described in further detail:
Following examples can make those skilled in the art that the present invention is more completely understood, but limit this never in any form Invention.
It is raw materials used in various embodiments of the present invention to be described as follows:
Water-based drilling landwaste:Jing Leachings are checked, and pollutant are less than GB 5085.3-2007《Hazardous waste differentiates mark Quasi- leaching characteristic identification》Standard limited value, its particle diameter distribution is:According to percetage by weight, its particle diameter distribution is:The mesh of > 10:7-9%; 10-20 mesh:14-16%;20-40 mesh:23%-26%;40-60 mesh:18-22%;60-100 mesh:20-22%;100-200 mesh: 5-7%;The mesh of > 200:5-7%;
Cement:Common construction material, such as 42.5 Portland cement;
Stone nitre:Common construction material, according to percetage by weight, its particle diameter distribution is:The mesh of > 10:38-42%;10-20 mesh: 20-25%;20-40 mesh:18-22%;40-60 mesh:5-8%;60-100 mesh:3-5%;100-200 mesh:1-3%;The mesh of > 200: 2-4%;
River sand:Common construction material, according to percetage by weight, its particle diameter distribution is:The mesh of > 10:7-9%;10-20 mesh:4- 6%;20-40 mesh:29-33%;40-60 mesh:45-48%;60-100 mesh:5-8%;100-200 mesh:0-2%;The mesh of > 200:1- 3%;
Cementitious capillary crystalline waterproofing agent:Common construction material, meets national standard《Cement-base infiltration crystallization type water-proof Coating》(GB18445-2001).
Embodiment 1:
As a example by produce product 100kg of the present invention, by 31.1kg water-based drilling landwaste, 31.1kg Portland cements C425,20kg stone nitre, 13.3kg river sands and 4.5kg cementitious capillary crystalline waterproofing agents are mixed.
The weight of above-mentioned raw materials is:
Embodiment 2
As a example by produce product 100kg of the present invention, by 30kg water-based drilling landwaste, 30kg Portland cement C425, 20kg stone nitres, 15kg river sands and 5kg cementitious capillary crystalline waterproofing agents are mixed.
The weight of above-mentioned raw materials is:
Embodiment 3
As a example by produce product 100kg of the present invention, by 29.1kg water-based drilling landwaste, 29.1kg Portland cements C425,20kg stone nitre and 16.3kg river sands, 5.5kg cementitious capillary crystalline waterproofing agents are mixed.
The weight of above-mentioned raw materials is:
The specific implementation method of three above embodiment manufacturing process is specific as follows:
After by the material rate mix of brickmaking, adds water the press-forming machine that enter after stirring in blender, pressure Make and the maintenance place with rain shade is delivered to after type, can obtain into after being air-dried about 28 days using cool place after automatic brick stacking machine piling Product exempt from the building materials that the different solid brick of shape size, hollow brick, interior neck brick etc. can be practical.Carry out in blender churned mechanically Mixing cycle, general control was in 20-60s.Note:
1) cementitious capillary crystalline waterproofing agent for weighing directly is measured disastrously with cement, mix homogeneously;
2) can not stir in the weather of rainy day and icing;
3) 30 minutes after slip mixing in be finished, and be stirred continuously in use, forbid to add water in addition;
4) it is unhardened to forbid water seasoning before;
Added material should take into full account the capacity of agitator, easily cause material splashing more than mixed capacity and stir not .
The laboratory test results of three above embodiment are as follows:
1) waterproof brick Leaching testing result and analysis:
According to《Solid waste toxicity leaching method horizontal vibration method》Step described in (HJ 557-2010) is to conserving day Number carried out toxotest for the adobe body of 28 days, had one or more pollutant levels in leachate more than GB 5086.3-2007《Hazardous waste judging standard leaching characteristic identification》The threshold value of defined, then the waterproof brick be determined to have leaching Go out toxicity, it is off quality and can not be put into and normally use.
It can be seen from the test results that embodiment 1, embodiment 2, the made waterproof brick of embodiment 3 items Testing index is respectively less than 《Hazardous waste judging standard leaching characteristic identification》Concentration limit in (GB 5086.3-2007).
2) waterproof brick performance detection testing result and analysis:
By comparative example 1, embodiment 2, the waterproof brick performance indications of embodiment 3 are as follows:
1. specification:(permissible variation in dimension meets (solid brick) 240mm × 115mm × 53mm《Concrete solid brick and decoration Brick》(NYT671-2003) high-class product);
2. weight:2.2~3.0 kilograms/block (because raw material is different, weight can difference);
3. the key technical indexes:
Comprcssive strength:29.8~33.3MPa/cm, meansigma methodss > 30MPa;Frost resistance:Brick is placed in into -20 DEG C of environment jellies 4 little When.Melt 4 hours in 15~20 DEG C of water, repeatedly after 15 times, loss of strength rate is less than 20%, and rate of weight loss is less than 2%, and outward appearance is complete It is good, without peeling phenomenon;Brick 1500~1600kg/m3 of dry weight, water absorption rate 5.5%~6.5%, coefficient of softing 0.9~0.97,60 Its shrinkage value<0.4mm/m;It is impervious:Maximum infiltration depth < 30mm.
It can be seen that, the waterproof brick of the present invention can disclosure satisfy that《Concrete solid brick and decorative brick》(NYT671-2003) standard Require.Very low according further to impervious experimental data landwaste waterproof brick water absorption rate, anti-permeability performance is especially good;Other need not be used Waterproof material can reach water-proof function, more superior than existing other materials for walls;Used in well site enclosure wall, house and other well sites Environment protection architecture includes sludge-tank, guiding gutter, leachate collection pool, well site road surface etc., increased oil, gas drilling well site and prevents Ooze effect.

Claims (2)

1. a kind of utilization water-based drilling landwaste does the waterproof brick of aggregate, it is characterised in that composed of the following components by weight:
2. a kind of utilization water-based drilling landwaste according to claim 1 does the waterproof brick of aggregate, it is characterised in that by weight Part is composed of the following components:
CN201611046604.5A 2016-11-23 2016-11-23 Waterproof brick taking water-based drilling rock debris as aggregate Pending CN106587803A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107840623A (en) * 2017-11-29 2018-03-27 中国石油化工股份有限公司 A kind of discarded slurry making burn-free bricks and preparation method thereof
CN108046681A (en) * 2017-12-06 2018-05-18 胜利油田博友泥浆技术有限责任公司 A kind of no aggregate baking-free building block brick and its production method
CN110015870A (en) * 2019-05-07 2019-07-16 中国石油集团渤海石油装备制造有限公司 It is non-burning brick and preparation method thereof that a kind of water-based drilling discards solid phase
CN112408925A (en) * 2020-11-24 2021-02-26 中国环境科学研究院 Method for preparing autoclaved brick by utilizing natural gas water-based drilling solid waste
CN114956720A (en) * 2022-05-05 2022-08-30 克拉玛依市聚能资源综合利用有限责任公司 Process for manufacturing non-fired building material by adopting waste drilling water-based mud and rock debris

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CN101113087A (en) * 2006-07-26 2008-01-30 任荣 Application of well drilling detritus in building materials

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107840623A (en) * 2017-11-29 2018-03-27 中国石油化工股份有限公司 A kind of discarded slurry making burn-free bricks and preparation method thereof
CN107840623B (en) * 2017-11-29 2020-10-16 中国石油化工股份有限公司 Baking-free brick prepared from waste slurry and preparation method thereof
CN108046681A (en) * 2017-12-06 2018-05-18 胜利油田博友泥浆技术有限责任公司 A kind of no aggregate baking-free building block brick and its production method
CN110015870A (en) * 2019-05-07 2019-07-16 中国石油集团渤海石油装备制造有限公司 It is non-burning brick and preparation method thereof that a kind of water-based drilling discards solid phase
CN112408925A (en) * 2020-11-24 2021-02-26 中国环境科学研究院 Method for preparing autoclaved brick by utilizing natural gas water-based drilling solid waste
CN114956720A (en) * 2022-05-05 2022-08-30 克拉玛依市聚能资源综合利用有限责任公司 Process for manufacturing non-fired building material by adopting waste drilling water-based mud and rock debris

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Application publication date: 20170426