CN106582511A - Air purifier and preparation method thereof - Google Patents

Air purifier and preparation method thereof Download PDF

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Publication number
CN106582511A
CN106582511A CN201611195619.8A CN201611195619A CN106582511A CN 106582511 A CN106582511 A CN 106582511A CN 201611195619 A CN201611195619 A CN 201611195619A CN 106582511 A CN106582511 A CN 106582511A
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CN
China
Prior art keywords
consumption
preparation
weight portions
air purifying
zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611195619.8A
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Chinese (zh)
Inventor
郭常青
吴学军
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Anhui Leking Environment Technology Co Ltd
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Anhui Leking Environment Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201611195619.8A priority Critical patent/CN106582511A/en
Publication of CN106582511A publication Critical patent/CN106582511A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/165Natural alumino-silicates, e.g. zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/14Diatomaceous earth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42Materials comprising a mixture of inorganic materials

Abstract

The invention discloses an air purifier and a preparation method thereof. The preparation method comprises the following steps: mixing zeolite, kieselguhr, nano titanium dioxide, gypsum powder, sepiolite and a dispersing agent to obtain mixed powder M; and adding water into the mixed powder M for mixing and granulation to obtain the air purifier. According to the air purifier and the preparation method thereof, the problems that the common air purifier is relatively low in adsorption rate for harmful substances, particularly for substances such as hydrogen sulfide and ammonia, short in service life and single in function are solved.

Description

Air purifying preparation and preparation method thereof
Technical field
The present invention relates to air purifying preparation and preparation method thereof.
Background technology
The quality of room air is the key factor for affecting health and thought mood.At present, the sky for adopting both at home and abroad Gas purifying method, mainly there is air suction method, covering method, oxidizing process etc..Using suction method, heavy mechanical equipment is needed, occupied The environment such as room, compartment, lavatory are difficult to carry out;Covering method is, to spray aromatic substance covering smell, but can not to eliminate smell substance Injury to human body;Oxidizing process is to produce negative oxygen ion using electrolysis principle to carry out disinfection air purification, but effect is not Ideal, and price is higher.Air purifying preparation is, using solid absorbent, strong oxidizer and aromatic substance, room air to be entered The process of row comprehensive purifying, can thoroughly eliminate peculiar smell, purify air.Common air purifying preparation to the adsorption rate of harmful substance compared with It is low, it is particularly relatively low to the absorptivity of the materials such as hydrogen sulfide and ammonia, and also useful life is low, single function.
The content of the invention
It is an object of the invention to provide a kind of air purifying preparation and preparation method thereof, solves common air purifying preparation pair The adsorption rate of harmful substance is relatively low, particularly relatively low to the absorptivity of the materials such as hydrogen sulfide and ammonia, and useful life is low, function Single problem.
To achieve these goals, the invention provides a kind of preparation method of air purifying preparation, the preparation method bag Include:
(1) by zeolite, diatomite, nano titanium oxide, land plaster, sepiolite and dispersant, mixed powder is obtained M;
(2) the mixed powder M is added water mixing granulation, obtains the air purifying preparation;
Wherein, relative to the zeolite of 100 weight portions, the diatomaceous consumption be 2-12 weight portions, the nano-silica The consumption for changing titanium is 1-8 weight portions, and the consumption of the land plaster is 4-20 weight portions, and the consumption of the sepiolite is 5-25 weight Part, the consumption of the dispersant is 1-4 weight portions, and the consumption of the water is 30-50 weight portions.
By above-mentioned technical proposal, the invention provides a kind of preparation method of air purifying preparation, the preparation method bag Include:By zeolite, diatomite, nano titanium oxide, land plaster, sepiolite and dispersant, mixed powder M is obtained;Will be described Mixed powder M adds water mixing granulation, the air purifying preparation is obtained, by the synergy between each raw material so that obtained Air purifying preparation possesses excellent adsorption capacity, and validity period limit for height, and the species for adsorbing Harmful species is more.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
The specific embodiment of the present invention is described in detail below.It should be appreciated that described herein concrete Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
Herein the end points and any value of disclosed scope is not limited to the accurate scope or value, these scopes or Value should be understood to the value comprising close these scopes or value.For number range, between the endpoint value of each scope, respectively Between the endpoint value of individual scope and single point value, and individually one or more can be obtained with combination with one another between point value New number range, these number ranges should be considered concrete open herein.
The invention provides a kind of preparation method of air purifying preparation, the preparation method includes:
(1) by zeolite, diatomite, nano titanium oxide, land plaster, sepiolite and dispersant, mixed powder is obtained M;
(2) the mixed powder M is added water mixing granulation, obtains the air purifying preparation;
Wherein, relative to the zeolite of 100 weight portions, the diatomaceous consumption be 2-12 weight portions, the nano-silica The consumption for changing titanium is 1-8 weight portions, and the consumption of the land plaster is 4-20 weight portions, and the consumption of the sepiolite is 5-25 weight Part, the consumption of the dispersant is 1-4 weight portions, and the consumption of the water is 30-50 weight portions.
In order to improve the adsorption efficiency of obtained adsorbent, the present invention it is a kind of preferred embodiment in, relative to The zeolite of 100 weight portions, the diatomaceous consumption is 5-8 weight portions, and the consumption of the nano titanium oxide is 3-5 weight Part, the consumption of the land plaster is 8-15 weight portions, and the consumption of the sepiolite is 10-20 weight portions, the use of the dispersant Measure as 2-3 weight portions, the consumption of the water is 35-45 weight portions.
In order to improve the dispersive property between raw material, the present invention it is a kind of preferred embodiment in, the dispersant For one or more in sodium metasilicate, sodium tripolyphosphate and calgon.
The present invention it is a kind of preferred embodiment in, in order to further improve the adsorption efficiency of obtained adsorbent, The content of silica is more than 90% in the diatomite, and the diatomaceous particle diameter is 200-280 mesh.
The present invention it is a kind of preferred embodiment in, in order to further improve the adsorption efficiency of obtained adsorbent, The particle diameter of the nano titanium oxide is 10-20nm, and the zeolite is in scolecite, heulandite, sodalite or modenite One or more.
Present invention also offers a kind of air purifying preparation, the air purifying preparation is obtained by above-mentioned preparation method.
Hereinafter will be described the present invention by embodiment.In following examples, zeolite and diatomite are Beijing The commercially available product that Guo Tou flourishing age Science and Technology Co., Ltd. provides, nano titanium oxide is carried for Beijing Deco Dao Jin Science and Technology Ltd.s For commercially available product.The content of silica is more than 90% in the diatomite, and the diatomaceous particle diameter is 200-280 mesh;Institute The particle diameter for stating nano titanium oxide is 10-20nm.
Embodiment 1
By 100g zeolites, 5g diatomite, 3g nano titanium oxides, 8g land plasters, 10g sepiolites and 2g dispersants, Obtain mixed powder M;The mixed powder M is added into 35g water mixing granulations, the air purifying preparation is obtained.
Embodiment 2
By 100g zeolites, 8g diatomite, 5g nano titanium oxides, 15g land plasters, 20g sepiolites and 3g dispersants, Obtain mixed powder M;The mixed powder M is added into 45g water mixing granulations, the air purifying preparation is obtained.
Embodiment 3
100g zeolites, 6g diatomite, 4g nano titanium oxides, 12g land plasters, 15g sepiolites and 2.5g dispersants are mixed Close, obtain mixed powder M;The mixed powder M is added into 40g water mixing granulations, the air purifying preparation is obtained.
Embodiment 4
Method according to embodiment 1 is prepared, except for the difference that, relative to the zeolite of 100g, the diatomaceous consumption For 2g, the consumption of the nano titanium oxide is 1g, and the consumption of the land plaster is 4g, and the consumption of the sepiolite is 5g, institute The consumption for stating dispersant is 1g, and the consumption of the water is 30g.
Embodiment 5
Method according to embodiment 1 is prepared, except for the difference that, relative to the zeolite of 100g, the diatomaceous consumption For 12g, the consumption of the nano titanium oxide is 8g, and the consumption of the land plaster is 20g, and the consumption of the sepiolite is 25g, The consumption of the dispersant is 4g, and the consumption of the water is 50g.
Comparative example 1
Method according to embodiment 1 is prepared, except for the difference that, relative to the zeolite of 100g, the diatomaceous consumption For 1g, the consumption of the nano titanium oxide is 0.5g, and the consumption of the land plaster is 3g, and the consumption of the sepiolite is 3g, The consumption of the dispersant is 0.5g, and the consumption of the water is 30g.
Comparative example 2
Method according to embodiment 1 is prepared, except for the difference that, relative to the zeolite of 100g, the diatomaceous consumption For 15g, the consumption of the nano titanium oxide is 10g, and the consumption of the land plaster is 25g, and the consumption of the sepiolite is 30g, the consumption of the dispersant is 6g, and the consumption of the water is 55g.
Test case
Detection embodiment 1-5, air purifying preparation prepared by comparative example 1 and 2 is respectively to hydrogen sulfide and the absorptivity of ammonia, detection Structure is shown in Table 1.
Table 1
Embodiment is numbered Absorptivity (%) to hydrogen sulfide Absorptivity (%) to ammonia
Embodiment 1 82 25
Embodiment 2 85 30
Embodiment 3 88 28
Embodiment 4 75 25
Embodiment 5 70 22
Comparative example 1 55 12
Comparative example 2 59 15
Absorption of the air purifying preparation obtained within the scope of the present invention to hydrogen sulfide and ammonia is can be seen that by upper table data Rate is higher, and air purifying preparation obtained within the scope of the present invention is relatively low to the absorptivity of hydrogen sulfide and ammonia, of the invention preferred In the range of obtained air purifying preparation it is better.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment Detail, the present invention range of the technology design in, various simple variants can be carried out to technical scheme, this A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can The combination of energy is no longer separately illustrated.
Additionally, can also be combined between a variety of embodiments of the present invention, as long as it is without prejudice to this The thought of invention, it should equally be considered as content disclosed in this invention.

Claims (7)

1. a kind of preparation method of air purifying preparation, it is characterised in that the preparation method includes:
(1) by zeolite, diatomite, nano titanium oxide, land plaster, sepiolite and dispersant, mixed powder M is obtained;
(2) the mixed powder M is added water mixing granulation, obtains the air purifying preparation;
Wherein, relative to the zeolite of 100 weight portions, the diatomaceous consumption be 2-12 weight portions, the nano titanium oxide Consumption be 1-8 weight portions, the consumption of the land plaster is 4-20 weight portions, and the consumption of the sepiolite is 5-25 weight portions, The consumption of the dispersant is 1-4 weight portions, and the consumption of the water is 30-50 weight portions.
2. preparation method according to claim 1, it is characterised in that relative to the zeolite of 100 weight portions, the diatomite Consumption be 5-8 weight portions, the consumption of the nano titanium oxide is 3-5 weight portions, and the consumption of the land plaster is 8-15 weights Amount part, the consumption of the sepiolite is 10-20 weight portions, and the consumption of the dispersant is 2-3 weight portions, and the consumption of the water is 35-45 weight portions.
3. preparation method according to claim 1 and 2, it is characterised in that the dispersant is sodium metasilicate, sodium tripolyphosphate With one or more in calgon.
4. preparation method according to claim 1, it is characterised in that the content of silica is more than in the diatomite 90%, the diatomaceous particle diameter is 200-280 mesh.
5. preparation method according to claim 1, it is characterised in that the particle diameter of the nano titanium oxide is 10-20nm.
6. preparation method according to claim 1, it is characterised in that the zeolite be scolecite, heulandite, sodalite or One or more in modenite.
7. a kind of air purifying preparation, it is characterised in that system of the air purifying preparation by described in any one in claim 1-6 Preparation Method is obtained.
CN201611195619.8A 2016-12-22 2016-12-22 Air purifier and preparation method thereof Pending CN106582511A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611195619.8A CN106582511A (en) 2016-12-22 2016-12-22 Air purifier and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201611195619.8A CN106582511A (en) 2016-12-22 2016-12-22 Air purifier and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106582511A true CN106582511A (en) 2017-04-26

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101623621A (en) * 2009-07-29 2010-01-13 傅桂云 Adsorbing material for effectively adsorbing formaldehyde and other harmful substances in air
CN102989308A (en) * 2012-11-28 2013-03-27 欧阳杰 Multifunctional air cleaning agent
CN104841472A (en) * 2015-04-03 2015-08-19 马鞍山锐凯特新材料有限公司 Supported room temperature air cleaning non-photocatalyst and preparation method thereof
WO2016100217A1 (en) * 2014-12-19 2016-06-23 Ep Minerals, Llc Opaline biogenic silica/expanded perlite composite products

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101623621A (en) * 2009-07-29 2010-01-13 傅桂云 Adsorbing material for effectively adsorbing formaldehyde and other harmful substances in air
CN102989308A (en) * 2012-11-28 2013-03-27 欧阳杰 Multifunctional air cleaning agent
WO2016100217A1 (en) * 2014-12-19 2016-06-23 Ep Minerals, Llc Opaline biogenic silica/expanded perlite composite products
CN104841472A (en) * 2015-04-03 2015-08-19 马鞍山锐凯特新材料有限公司 Supported room temperature air cleaning non-photocatalyst and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
潘兆橹,等: "《应用矿物学》", 30 September 1993, 武汉工业大学出版社 *

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Application publication date: 20170426