CN106581729A - High-toughness medical cotton swab capable of quickly stopping bleeding - Google Patents

High-toughness medical cotton swab capable of quickly stopping bleeding Download PDF

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Publication number
CN106581729A
CN106581729A CN201611041085.3A CN201611041085A CN106581729A CN 106581729 A CN106581729 A CN 106581729A CN 201611041085 A CN201611041085 A CN 201611041085A CN 106581729 A CN106581729 A CN 106581729A
Authority
CN
China
Prior art keywords
cotton
polylactic acid
polyethylene glycol
composite
cotton swab
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201611041085.3A
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Chinese (zh)
Inventor
李慧康
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuyang Huili Medical Instrument Co Ltd
Original Assignee
Fuyang Huili Medical Instrument Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuyang Huili Medical Instrument Co Ltd filed Critical Fuyang Huili Medical Instrument Co Ltd
Priority to CN201611041085.3A priority Critical patent/CN106581729A/en
Publication of CN106581729A publication Critical patent/CN106581729A/en
Withdrawn legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/22Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
    • A61L15/26Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/18Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing inorganic materials
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/22Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
    • A61L15/28Polysaccharides or their derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42Use of materials characterised by their function or physical properties

Abstract

The invention discloses a high-toughness medical cotton swab capable of quickly stopping bleeding. The cotton swab comprises a cotton bar and composite fiber cotton wrapping the end of the cotton bar. The reproducible and degradable composite polylactic acid fiber cotton is used for taking the place of a traditional absorbent cotton ball, production cost is reduced, inherent defects of absorbent cotton are overcome, the prepared composite fiber cotton has good toughness and strength, hydrophilia is effectively improved, and polydopamine-polyethylene glycol is grafted on the surface of the composite fiber cotton so that hydrophilia and biocompatibility of the fiber can be further improved; halloysite doped nanotubes, polydopamine, polyethylene glycol and other raw materials are used together, the cotton swab has the effects of quickly stopping bleeding, sucking liquid, promoting wound healing and the like, and additional application value of the cotton swab is improved.

Description

It is a kind of can quick-acting haemostatic powder high tenacity medical cotton stick
Technical field
The present invention relates to medical cotton stick technical field, more particularly to it is a kind of can quick-acting haemostatic powder high tenacity medical cotton stick.
Background technology
Medical cotton stick is a kind of very common medical treatment and nursing articles for use, is in materials such as modeling rod, paper rod, wooden sticks by absorbent cotton Sign pole on roll up cotton molding after obtain, Main Function is to sterilize, sample etc., and use range is quite varied.Due to cotton swab it is direct With Wound contact, therefore there is to the quality of absorbent cotton higher requirement, the absorbent cotton that traditional medical cotton stick is adopted mostly is cotton Flower is obtained Jing after alkalilye degreasing, although which has good skin-friendly and water absorption, yet with natural cotton is used, easily Breed bacteria, and production cost is higher, causes disinfecting cotton swab product made by many absorbent cottons inferior is occurred in that on market, directly Connect the health for having influence on user.
Polylactic acid is a kind of with carbohydrates such as starch, celluloses as raw material, is made Jing after hydrolysis, fermentation, purification, polymerization The standby renewable polyester material for obtaining, i.e. the processing characteristics with macromolecule resin, and the compatibility with biomaterial, is one Preferable Green Polymer Material is planted, and operation suture thread, artificial skin, artificial blood vessel, soft tissue is mainly used as in medical field Filler, tissue engineering bracket etc., it can be seen that, if replacing traditional absorbent cotton with polylactic acid, by improve cotton swab some lack Fall into, obtain the higher product of cost performance, lift patient's experience.There is stronger hydrophobicity yet with polylactic acid surface, Need to be modified which process.《The acid fiber by polylactic of surface grafting polyvinylpyrrolidone is modified》One text is in partial hydrolysiss Polylactic acid fiber surface graft polymerization polyvinylpyrrolidone, obtains and has certain absorptive modified polylactic acid fiber, but Be that this method is not easy to large-scale production, and the water absorption of fiber still suffer from larger gap than absorbent cotton, needs do into The modification of one step.
The content of the invention
The object of the invention is exactly for the defect for making up prior art, there is provided it is a kind of can quick-acting haemostatic powder high tenacity medical cotton Sign.
The present invention is achieved by the following technical solutions:
It is a kind of can quick-acting haemostatic powder high tenacity medical cotton stick, by swab stick and be rolled in the composite fibre cotton of swab stick end and constitute, it is described Composite fibre cotton be made up of the raw material of following weight portion:Particles of polylactic acid 12-15, nano-cellulose whisker 1-2, polyoxyethylene Alkene 3-5, halloysite nanotubes 0.1-0.2, Polyethylene Glycol 4-8, Dopamine Hydrochloride 5-10, Tris-HCl buffer solution are appropriate, go Ionized water 300-500.
The preparation method of described composite fibre cotton is:
(1) particles of polylactic acid is mixed with nano-cellulose whisker, polyethylene glycol oxide, halloysite nanotubes, high-speed stirred mixing Melt spinning is carried out after uniform, spinning temperature is 215-225 DEG C, and spinning speed is 2000-3500 m/min, makes average grain Footpath is standby for 1-15 μm of composite polylactic acid fiber;
(2)First take in the deionized water input reaction vessel of 150-200 weight portions, be subsequently added Dopamine Hydrochloride, stir to which Tris-HCl buffer solution is added after being completely dissolved, regulation system pH value is 8-8.5, is subsequently dividedly in some parts step(1)Prepare Composite polylactic acid fiber, immersion treatment 4-5d are standby;
(3)By in the deionized water input reactor of surplus, Polyethylene Glycol is added, is stirred to which and is completely dissolved rear Deca Tris- HCl buffer solution, regulation system pH value are 8-8.5, are subsequently added into step(2)Composite polylactic acid fiber after middle immersion treatment, Continue immersion treatment 30-50h, process is taken out after terminating, products therefrom is Jing washing, Jing openers, spice, combing, lapping after being dried, Obtain final product.
It is an advantage of the invention that:
(1)Replace traditional rayon balls using the composite polylactic acid cellucotton of renewable degradable, reduce production cost, solve The intrinsic defect of absorbent cotton of having determined, has no adverse effects to skin.
(2)The composite polylactic acid fiber for using is the raw materials such as nano-cellulose whisker, polyethylene glycol oxide, halloysite nanotubes Obtain with polylactic acid blend spinning, effectively raise the hydrophilic of polylactic acid, while its mechanical property also improved, tool There are good toughness and intensity, additionally, the composite fiber surface is grafted with poly-dopamine-Polyethylene Glycol, further improve fibre The hydrophilic and biocompatibility of dimension.
(3)The raw materials such as halloysite nanotubes and poly-dopamine, Polyethylene Glycol that adulterate in the composite fibre cotton are used together, and have The effects such as quick-acting haemostatic powder, imbibition, promotion wound healing, improve the additional use value of cotton swab.
(4)The cotton swab production process of the invention is simply efficient, the equal reusable edible of links material, to environment without bad Affect.
Specific embodiment
It is a kind of can quick-acting haemostatic powder high tenacity medical cotton stick, by swab stick and be rolled in the composite fibre cotton of swab stick end and constitute, Described composite fibre cotton is made up of the raw material of following weight portion:Particles of polylactic acid 12, nano-cellulose whisker 1, polyoxyethylene Alkene 3, halloysite nanotubes 0.1, Polyethylene Glycol 4, Dopamine Hydrochloride 5, Tris-HCl buffer solution are appropriate, deionized water 300.
The preparation method of wherein composite fibre cotton is:
(1) particles of polylactic acid is mixed with nano-cellulose whisker, polyethylene glycol oxide, halloysite nanotubes, high-speed stirred mixing Melt spinning is carried out after uniform, spinning temperature is 215 DEG C, and spinning speed is 2000 ms/min, and it is 10 μm to make mean diameter Composite polylactic acid fiber is standby;
(2)First take in the deionized water input reaction vessel of 150 weight portions, be subsequently added Dopamine Hydrochloride, stir complete to which Tris-HCl buffer solution is added after dissolving, regulation system pH value is 8.5, is subsequently dividedly in some parts step(1)What is prepared is compound poly- Acid fiber, immersion treatment 4d are standby;
(3)By in the deionized water input reactor of surplus, Polyethylene Glycol is added, is stirred to which and is completely dissolved rear Deca Tris- HCl buffer solution, regulation system pH value are 8.2, are subsequently added into step(2)Composite polylactic acid fiber after middle immersion treatment, after Continuous immersion treatment 30h, process are taken out after terminating, and products therefrom is Jing washing, Jing openers, spice, combing, lapping after being dried, and obtains final product.
The pure white softness of composite fibre cotton for preparing detects to which that without mottle, abnormal flavour testing result is:
Whiteness:85;Soluble substance in water(100ml)< 0.5%:Acid-base value:The equal invariant color of indicator;Water absorption:19.6g/g;Meet The requirement of medical cotton stick.

Claims (2)

1. it is a kind of can quick-acting haemostatic powder high tenacity medical cotton stick, by swab stick and be rolled in the composite fibre cotton of swab stick end and constitute, its It is characterised by, described composite fibre cotton is made up of the raw material of following weight portion:Particles of polylactic acid 12-15, nano-cellulose are brilliant Palpus 1-2, polyethylene glycol oxide 3-5, halloysite nanotubes 0.1-0.2, Polyethylene Glycol 4-8, Dopamine Hydrochloride 5-10, Tris-HCl are delayed Rush that solution is appropriate, deionized water 300-500.
2. it is as claimed in claim 1 it is a kind of can quick-acting haemostatic powder high tenacity medical cotton stick, it is characterised in that described compound fibre The preparation method of vinylon and cotton blend is:
(1) particles of polylactic acid is mixed with nano-cellulose whisker, polyethylene glycol oxide, halloysite nanotubes, high-speed stirred mixing Melt spinning is carried out after uniform, spinning temperature is 215-225 DEG C, and spinning speed is 2000-3500 m/min, makes average grain Footpath is standby for 1-15 μm of composite polylactic acid fiber;
(2)First take in the deionized water input reaction vessel of 150-200 weight portions, be subsequently added Dopamine Hydrochloride, stir to which Tris-HCl buffer solution is added after being completely dissolved, regulation system pH value is 8-8.5, is subsequently dividedly in some parts step(1)Prepare Composite polylactic acid fiber, immersion treatment 4-5d are standby;
(3)By in the deionized water input reactor of surplus, Polyethylene Glycol is added, is stirred to which and is completely dissolved rear Deca Tris- HCl buffer solution, regulation system pH value are 8-8.5, are subsequently added into step(2)Composite polylactic acid fiber after middle immersion treatment, Continue immersion treatment 30-50h, process is taken out after terminating, products therefrom is Jing washing, Jing openers, spice, combing, lapping after being dried, Obtain final product.
CN201611041085.3A 2016-11-24 2016-11-24 High-toughness medical cotton swab capable of quickly stopping bleeding Withdrawn CN106581729A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611041085.3A CN106581729A (en) 2016-11-24 2016-11-24 High-toughness medical cotton swab capable of quickly stopping bleeding

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611041085.3A CN106581729A (en) 2016-11-24 2016-11-24 High-toughness medical cotton swab capable of quickly stopping bleeding

Publications (1)

Publication Number Publication Date
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108424522A (en) * 2018-04-13 2018-08-21 河南省科学院能源研究所有限公司 A kind of nano-cellulose/poly-dopamine/polyethylene glycol composite material and preparation method
WO2019016367A1 (en) * 2017-07-21 2019-01-24 Speed Care Mineral Ug (Haftungsbeschränkt) New kind of wound dressing for haemostasis
IT201700122757A1 (en) * 2017-10-27 2019-04-27 Univ Degli Studi Di Palermo A composition comprising a cellulose nanofiber and halloysite nanotube, a film, and a composite comprising the same
JP2019094482A (en) * 2017-10-27 2019-06-20 日本製紙株式会社 Composition containing cellulose nanofibers and halloysite nanotubes, and film and composite containing the same
CN112870432A (en) * 2021-01-14 2021-06-01 东华大学 Photo-repairable nanofiber hydrogel dressing and preparation method thereof
CN113855845A (en) * 2021-09-28 2021-12-31 四川大学 Modified chitosan porous gel hemostatic gauze with hydrophilic surface and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103479481A (en) * 2013-10-21 2014-01-01 陈燕 Novel cotton swab
CN104689461A (en) * 2015-02-17 2015-06-10 李晓静 Disinfectant-containing medical cotton swab
CN105239270A (en) * 2015-10-14 2016-01-13 嘉兴润之缘养生文化有限公司 Polylactic acid fiber non-woven fabric used for hygienic material
CN105566872A (en) * 2015-12-23 2016-05-11 暨南大学 Polydopamine-modified halloysite nanotube / polylactic acid composite material and preparation and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103479481A (en) * 2013-10-21 2014-01-01 陈燕 Novel cotton swab
CN104689461A (en) * 2015-02-17 2015-06-10 李晓静 Disinfectant-containing medical cotton swab
CN105239270A (en) * 2015-10-14 2016-01-13 嘉兴润之缘养生文化有限公司 Polylactic acid fiber non-woven fabric used for hygienic material
CN105566872A (en) * 2015-12-23 2016-05-11 暨南大学 Polydopamine-modified halloysite nanotube / polylactic acid composite material and preparation and application thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019016367A1 (en) * 2017-07-21 2019-01-24 Speed Care Mineral Ug (Haftungsbeschränkt) New kind of wound dressing for haemostasis
CN110621354A (en) * 2017-07-21 2019-12-27 矿物快速护理有限公司 Novel wound dressing for hemostasis
CN110621354B (en) * 2017-07-21 2023-03-10 矿物快速护理有限公司 Novel wound dressing for hemostasis
IT201700122757A1 (en) * 2017-10-27 2019-04-27 Univ Degli Studi Di Palermo A composition comprising a cellulose nanofiber and halloysite nanotube, a film, and a composite comprising the same
JP2019094482A (en) * 2017-10-27 2019-06-20 日本製紙株式会社 Composition containing cellulose nanofibers and halloysite nanotubes, and film and composite containing the same
JP7266235B2 (en) 2017-10-27 2023-04-28 日本製紙株式会社 Composition containing cellulose nanofiber and halloysite nanotube, film and composite containing the same
CN108424522A (en) * 2018-04-13 2018-08-21 河南省科学院能源研究所有限公司 A kind of nano-cellulose/poly-dopamine/polyethylene glycol composite material and preparation method
CN112870432A (en) * 2021-01-14 2021-06-01 东华大学 Photo-repairable nanofiber hydrogel dressing and preparation method thereof
CN113855845A (en) * 2021-09-28 2021-12-31 四川大学 Modified chitosan porous gel hemostatic gauze with hydrophilic surface and preparation method thereof

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Application publication date: 20170426