CN106577666A - Ternary combined weeding composition - Google Patents
Ternary combined weeding composition Download PDFInfo
- Publication number
- CN106577666A CN106577666A CN201611049572.4A CN201611049572A CN106577666A CN 106577666 A CN106577666 A CN 106577666A CN 201611049572 A CN201611049572 A CN 201611049572A CN 106577666 A CN106577666 A CN 106577666A
- Authority
- CN
- China
- Prior art keywords
- monooctyl ester
- chlorine
- cyhalofop
- different monooctyl
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
- A01N39/04—Aryloxy-acetic acids; Derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a ternary combined weeding composition and application thereof and relates to the technical field of combination of pesticides. The ternary combined weeding composition comprises the following effective components of cyhalofop-butyl, fluroxypyr ester and MCPA-isooctyl, the weight ratio of the cyhalofop-butyl, the fluroxypyr ester and the MCPA-isooctyl is (5-15):(1-5):(1-7), and the weight of the cyhalofop-butyl, the fluroxypyr ester and the MCPA-isooctyl accounts for 1%-18% of the total weight of the composition. According to the ternary combined weeding composition, the herbicide controlling spectrum can be remarkably amplified, and the integral preventing and removing effect for the rice field weeds is improved. At the same time, the composition has good safety to the rice and is a very good novel pesticide composition for preventing and removing annual weeds in the rice field.
Description
Technical field
The invention belongs to agrochemicals field, problem is prevented and kill off more particularly, to a kind of for solving rice terrace annual grassy weeds
Ternary built Herbicidal combinations.
Background technology
Cyhalofop-butyl (Cyhalofop-butyl) belongs to aryloxyphenoxypropionic class herbicide, and the mechanism of action is acetyl
CoA carboxylase inhibitor, stops fatty acid synthesis, and the growth division of cell can not be normally carried out, and membranous system etc. is tied containing fat
Structure is destroyed, and finally results in Plant death.It is efficient to Semen Euphorbiae to Oryza sativa L. high safety, there is certain preventive effect to low age barnyard grass, but
It is undesirable to cyhalofop-butyl resistant biotypes grass family effect.
The different monooctyl ester of fluroxypyr (Fluroxypyr-meptyl) belongs to pyridine fluoroacetic acid class herbicide, with interior suction
Conduction, after seedling is used, and the reaction of classical hormones class herbicide occurs in sensitive crop.Herba Galii Teneri, field are prevented and kill off suitable for rice terrace
Flos Calystegiae sepii, Herba Capsellae, Herba stellariae mediae, volume stem Herba Amaranthi tricoloriss, Herba Portulacae, the broad leaved weed such as Alternanthera philoxeroides, to grass family and sedge weed effect compared with
Difference.
The different monooctyl ester of the chlorine of 2 first 4 (MCPA) belongs to phenoxy acetic acid class selectivity hormone like herbicide, is easily that root and leaf portion are inhaled
Receive, be mainly used in preventing and kill off various annual and perennial broadleaf weed in the regions such as Oryza sativa L., Semen Tritici aestivi, Semen Pisi sativi, lawn, to Rhizoma Cyperi
Son, Herba Caricis Phacotae, sweet wine intestinal, Herba monochoriae vaginaliss, Sagittaria trifolia L. Var. Angusti-folia(Sieb.) Kitag.(Sagittaria sagittifolia L.) and other effects are notable, but poor to grassy weed preventive effect.
There is different degrees of defect in the herbicide kind containing single-activity component, on control of weeds such as after continuous use
Weeds easily develop immunity to drugs, and weed control spectrum narrows, the problems such as cause environmental pollution.
Rationally compounding is to improve preventive effect, expand weed control spectrum, widen use time to herbicide, delays shift of weed community
Speed, reduce that pesticide is single to use brought resistance risk, mitigate the pollution to environment, reduce use cost and mitigation removed
A kind of effective ways of careless agent residual.
The content of the invention
In order to overcome the deficiencies in the prior art, the present invention to provide a kind of poison more high and low to crop safety, low-residual, kill
Grass spectrum is wide, can effectively delay the ternary built Herbicidal combinations of herbicide resistance.
The technical solution adopted for the present invention to solve the technical problems is：A kind of ternary built Herbicidal combinations, including with
Lower active component：The different monooctyl ester of cyhalofop-butyl, fluroxypyr and the different monooctyl ester of the chlorine of 2 first 4, the cyhalofop-butyl, chlorine fluorine pyrrole oxygen second
The different monooctyl ester of acid and the different monooctyl ester weight ratio of the chlorine of 2 first 4 are (5-15):(1-5):(1-7).
Further, ternary built Herbicidal combinations of the present invention, the different monooctyl ester of cyhalofop-butyl, fluroxypyr and
The preferred weight ratio of the different monooctyl ester of the chlorine of 2 first 4 is 10:3:4.
Further, pesticidal preparations auxiliary element is contained in the ternary built Herbicidal combinations, to make agricultural is adapted to
On the dosage form that uses.
Further, ternary built Herbicidal combinations of the present invention, the different monooctyl ester of cyhalofop-butyl, fluroxypyr and
The weight of the different monooctyl ester of the chlorine of 2 first 4 accounts for the 1-80% of composition total weight.
Further, ternary built Herbicidal combinations of the present invention, it is characterised in that described ternary built weeding
The dosage form that compositionss can be processed is to dispersible oil-suspending agent, cream, aqueous emulsion etc..
Further, ternary built Herbicidal combinations of the present invention, it is characterised in that described ternary built weeding
The dosage form auxiliary element of compositionss is water, carrier, surfactant etc..
Further, ternary built Herbicidal combinations of the present invention, it is characterised in that described ternary built weeding
Compositionss can be used for preventing and kill off rice terrace annual grassy weeds.
The usage frequency and usage amount of the ternary built Herbicidal combinations of the present invention is with plant growth, weeds generation, day
Gas changes and has a small amount of change, and the purpose of effective preventing and treating can be reached by using appropriate dosage.
Ternary built Herbicidal combinations its active component cyhalofop-butyl of the present invention, the different monooctyl ester of fluroxypyr and 2 first 4
Common use after the different monooctyl ester compounding of chlorine, with potentiation or summation action, overcomes the deficiency of herbicidal performance containing single-activity component, drop
Low production cost and use cost, and expand weed control spectrum, rice terrace annual grassy weeds can be effectively prevented and kill off, it has efficient, low
Many advantages, such as poison, low-residual, low cost.
The pesticide such as surfactant used and carrier auxiliary element belongs to ring in the ternary built Herbicidal combinations of the present invention
Protect type, low toxicity, low-residual, to rice safety will not produce murder by poisoning to crop, fish and shrimp and water body in use.
In sum, the invention has the beneficial effects as follows, it is convenient to apply, low cost, reduces usage amount, reduces times for spraying,
Broad weed-killing spectrum, can effectively delay herbicide resistance to produce, and herbicidal effect is very remarkable.
Specific embodiment
In order that those skilled in the art are better understood from the present invention program, below by the technology in inventive embodiments
Scheme carries out clear, complete description.
In following examples effective ingredient using cyhalofop-butyl, the different monooctyl ester of fluroxypyr and the different monooctyl ester of the chlorine of 2 first 4 and
Auxiliary element is commercially available.
Embodiment 1
Cyhalofop-butyl 20%, the different monooctyl ester 6% of fluroxypyr, the different monooctyl ester 8% of the chlorine of 2 first 4, calcium dodecyl benzene sulfonate
7%, styrylphenol polyoxyethylene ether 3%, alkylaryl polyoxyethylene poly-oxygen propylene aether 4%, poly- trisiloxanes 5%, oil
Sour methyl ester 20%, aromatic hydrocarbons S-150 solvent naphtha surpluses.By above-mentioned all the components in the ratio mix homogeneously.Can be prepared by
The chloro milk oil (10 of 34% 2 first of cyanogen fluorine chlorine fluorine 4:3:4).
Embodiment 2
Cyhalofop-butyl 15%, the different monooctyl ester 3% of fluroxypyr, the different monooctyl ester 7% of the chlorine of 2 first 4, calcium dodecyl benzene sulfonate
7%, styrylphenol polyoxyethylene ether 4%, castor oil polyoxyethylene ether 4%, fatty alcohol-polyoxyethylene ether 3%, succinic acid
Di-isooctyl sulfonate 6%, methyl naphthalene higher aliphatic hydrocarbon ils 10%, aromatic hydrocarbons S-150 solvent naphtha surpluses.By above-mentioned all the components
In the ratio mix homogeneously.Can be prepared by the chloro milk oil (15 of 25% 2 first of cyanogen fluorine chlorine fluorine 4:3:7).
Embodiment 3
Cyhalofop-butyl 10%, the different monooctyl ester 3% of fluroxypyr, the different monooctyl ester 4% of the chlorine of 2 first 4, calcium dodecyl benzene sulfonate
5%, castor oil polyoxyethylene ether 4%, polyoxyethylene polyoxypropylene block copolymer 3%, organic silicon defoamer 0.1% is organic
Bentonite 3%, soybean oil supplies 100%.By above-mentioned each composition according to the ratio mix homogeneously, the grinding of Jing horizontal sand mills makes
Resulting material mean diameter is less than 5 microns.Can be prepared by the chlorine of 17% 2 first of cyanogen fluorine chlorine fluorine 4 and dispersible oil-suspending agent (10:3:
4)。
Embodiment 4
Cyhalofop-butyl 10%, the different monooctyl ester 3% of fluroxypyr, the different monooctyl ester 1% of the chlorine of 2 first 4, calcium dodecyl benzene sulfonate
8%, styrylphenol polyoxyethylene ether 7%, fatty alcohol-polyoxyethylene ether 3%, organobentonite 3%, methyl oleate is supplied
100%.By above-mentioned each composition according to the ratio mix homogeneously, the grinding of Jing horizontal sand mills is less than resulting material mean diameter
5 microns.Can be prepared by the chlorine of 14% 2 first of cyanogen fluorine chlorine fluorine 4 and dispersible oil-suspending agent (10:3:1).
Embodiment 5
Cyhalofop-butyl 20%, the different monooctyl ester 6% of fluroxypyr, the different monooctyl ester 8% of the chlorine of 2 first 4, polyoxyethylene polyoxypropylene is embedding
Section copolymer 3%, fatty alcohol-polyoxyethylene ether 4%, organic silicon defoamer 0.2%, xanthan gum 0.15%, Propylene Glycol 5%, benzene first
Sour sodium 0.1%, aromatic hydrocarbons S-150 solvent naphthas 20%, water surplus.After mentioned component is weighed according to the ratio, according to
Lower step operation.Cyhalofop-butyl, the different monooctyl ester of fluroxypyr, the chlorine of 2 first 4 three kinds of active compounds of different monooctyl ester are dissolved in into aromatic hydrocarbons S-150
In number solvent naphtha, polyoxyethylene polyoxypropylene block copolymer, fatty alcohol-polyoxyethylene ether is added to be emulsified into oil phase, it is stand-by；Will
Xanthan gum, Propylene Glycol, sodium benzoate and defoamer are added to the water into water phase；Water phase, high speed shear are slowly added to in oil phase
30min, you can make the chlorine water Emulsion (10 of 34% 2 first of cyanogen fluorine chlorine fluorine 4:3:4).
Embodiment 6
Cyhalofop-butyl 15%, the different monooctyl ester 3% of fluroxypyr, the different monooctyl ester 4% of the chlorine of 2 first 4, castor oil polyoxyethylene ether
3%, alkylphenol polyoxyethylene phosphate ester 2%, polyoxyethylene polyoxypropylene block copolymer 1.5%, xanthan gum 0.1%, virtue
Hydrocarbon S-150 solvent naphthas 25%, organobentonite 3%, Kazon 0.1%, Propylene Glycol 4%, organic silicon defoamer 0.2%, more than water
Amount.After mentioned component is weighed according to the ratio, operate according to following steps.First by cyhalofop-butyl, fluroxypyr
Different monooctyl ester, the chlorine of 2 first 4 three kinds of active compounds of different monooctyl ester are dissolved in aromatic hydrocarbons S-150 solvent naphthas, add castor oil polyoxyethylene ether, alkane
Base phenol polyethenoxy ether phosphate and polyoxyethylene polyoxypropylene block copolymer are emulsified into oil phase, stand-by.Then by organic bentonite
Profit soil, Propylene Glycol, Kazon, organic silicon defoamer are added to the water into water phase.Then water phase, high speed shear are slowly added to in oil phase
30min.Can be prepared by the chlorine water Emulsion (15 of 22% 2 first of cyanogen fluorine chlorine fluorine 4:3:4).
Indoor biometricses are tested
In order to prevent and treat the rice terrace annual grassy weeds in agricultural production, inventor is different with cyhalofop-butyl, fluroxypyr
Monooctyl ester and the chlorine of 2 first 4 three kinds of compositions of different monooctyl ester have carried out Toxicity Determination research, concrete grammar：Indoor pot method carries out stem and leaf
Spraying treatment, tests reference《The part of farm-chemical indoor determination test rule herbicide the 9th》.
1. reagent agent
The different monooctyl ester 95% of the different chlorine of 96% and 2 first of monooctyl ester 4 of cyhalofop-butyl 97.4%, fluroxypyr.
2. target is tested
Barnyard grass, Herba Digitariae, Herba Murdanniae Triquetrae, seed collection dries in 2014 Nian9Yue Zhejiang provinces and cities Jinhua Bai Longqiao towns, and 4 is Celsius
Degree constant temperature preserves stand-by.
3. testing equipment
Beaker, electronic balance, liquid-transfering gun, spray tower (Nanjing Agriculturing Mechanization Inst., Ministry of Agriculture, 3WPSH-500D, spray
Mist pressure 3.0kg/cm3)
4. experimental procedure
Using potted plant stem and leaf spraying treatment method (NY/T155.9.2008)：It is built-in quantitative in polypots (10cm*9cm*7cm)
Air-dried fine earth, will sow in polypots body for trying target seed, broadcast rear fine earth and cover thickness 0.2cm.Warm indoor cultivation is positioned over,
The moisturizing by the way of bottom-irrigating daily, keeps ground moistening.Treat that target length is started medication to the 3-4 leaf phases, often process and repeat 4
It is secondary, and the process without medicament is set as control.Material is tried after process and is positioned over warmhouse booth culture, the aggrieved feelings of routine observation target
Condition, determines fresh weight inhibition.
4.1. medicament configuration and design
Single dose and dosage：Cyhalofop-butyl (numbering A)：5th, 10 and 15ga.i/667m2(numbering is respectively A1～A3)；Chlorine fluorine
The different monooctyl ester of pyrrole fluoroacetic acid (numbering B)：1st, 3 and 5ga.i/667m2(numbering is respectively B1～B3)；The different monooctyl ester of the chlorine of 2 first 4 (numbering C)：
1st, 4 and 7ga.i/667m2(numbering is respectively C1～C3)
Mixed and proportioning：Cyhalofop-butyl (numbering A1～A3), the different monooctyl ester of fluroxypyr (numbering B1～B3) and 2 first 4
The different monooctyl ester of chlorine (numbering C1～C3), each dosage is compounded into respectively 27 complex treatments.
4.2. data statisticss and analysis：
4.2.1 according to investigation statisticses, calculating Germination suppression rate (%)
Fresh weight inhibition (%)=(control fresh weight strain number-process fresh weight strain number)/control fresh weight strain number * 100%
4.2.2colby method
The activity after three kinds of pharmacy mix is tested using Colby methods, mixture calculation of effect formula is：E0=a*b*
c/100(3-1), E0Preventive effect/100 of 1 preventive effect * herbicide of=herbicide, 2 preventive effect * herbicide 32；E is that the actual measurement after a, b, c mixed is prevented
Effect；In formula, A represents the actual measurement preventive effect of medicament 1；B represents the actual measurement preventive effect of medicament 2；C represents the actual measurement preventive effect of medicament 3；E0For A,
Theoretical preventive effect after B, C are mixed；E is the actual measurement preventive effect after A, B, C mixed；Work as E-E0During ＞ 10%, the medicament after mixture is illustrated
Produce potentiation；Work as E-E0During ＜ -10%, illustrate that the medicament after mixture produces antagonism；And work as E-E0Value between ±
When 10%, illustrate the medicament after mixture to producing summation action.
5. test results and analysis
The synergy of the cyhalofop-butyl of table 1, the different monooctyl ester of fluroxypyr and the different monooctyl ester mixture of the chlorine of 2 first 4 to barnyard grass
As it can be seen from table 1 cyhalofop-butyl is different better than the different monooctyl ester of fluroxypyr and the chlorine of 2 first 4 to barnyard grass preventive effect
Monooctyl ester.When the ratio of three is at (5-15):(1-5):(1-7) when between, to the actual preventive effect and theoretical preventive effect of barnyard grass after using with
Difference 9.19-29.29%, preventive effect in be added or potentiation, wherein when three kinds of ratios be 10:3:4 potentiations are most notable.
The synergy of the cyhalofop-butyl of table 2, the different monooctyl ester of fluroxypyr and the different monooctyl ester mixture of the chlorine of 2 first 4 to Herba Digitariae
From table 2 it can be seen that cyhalofop-butyl and the different monooctyl ester of fluroxypyr have certain preventive effect to Herba Digitariae.When three's
Ratio is at (5-15):(1-5):(1-7) when between, to the actual preventive effect and difference 8.72- of theoretical preventive effect of Herba Digitariae after using with
42.16%, preventive effect is in be added or potentiation, wherein when three kinds of ratios are 10:3:4 potentiations are most notable.
The synergy of the cyhalofop-butyl of table 3, the different monooctyl ester of fluroxypyr and the different monooctyl ester mixture of the chlorine of 2 first 4 to Herba Murdanniae Triquetrae
From table 3 it can be seen that cyhalofop-butyl single dose is invalid to Herba Murdanniae Triquetrae, when the ratio of three is at (5-15):(1-5):(1-
7) when between, to the actual preventive effect and difference 11.04-27.83% of theoretical preventive effect of Herba Murdanniae Triquetrae after using with, preventive effect is made in potentiation
With wherein when proportions are 10:3:4 potentiations are most notable.
Comprehensive analysis of The Combined, the different monooctyl ester of cyhalofop-butyl, fluroxypyr and the different monooctyl ester three mixture of the chlorine of 2 first 4
At (5-15):(1-5):(1-7) when between, three's mixture is to the synergy type for examination target barnyard grass, Herba Digitariae, Herba Murdanniae Triquetrae
Addition or potentiation.Work as cyhalofop-butyl：The different monooctyl ester of fluroxypyr：Different monooctyl ester=10 of the chlorine of 2 first 4:3:When 4, its potentiation
Effect is the most notable.
Field efficacy verifies example
Field control effectiveness test prevents and kill off direct sowing of rice field weed
, in Anhui Province Mingguang City, the region rice terrace is using herbicide history for many decades for test and Selection；Soil fertilizer
Power is unanimously medium；Experimental field rice varieties：Jing rice, long-grained nonglutinous rice；Planting patternss：Rice direct seeding field；Field main weeds have Semen Euphorbiae,
The weeds such as barnyard grass, dried tuber, sweet wine intestinal, Herba monochoriae vaginaliss, Herba Murdanniae Triquetrae.Test sets altogether 8 process, and each process sets 3 repetitions.Processing 1 is
The chloro milk oil (10 of 34% 2 first of cyanogen fluorine chlorine fluorine 4:3:4)；It is the chloro milk oil (15 of 25% 2 first of cyanogen fluorine chlorine fluorine 4 to process 2:3:7)；
Process 3 and dispersible oil-suspending agent (10 for the chlorine of 14% 2 first of cyanogen fluorine chlorine fluorine 4:3:1)；It is 22% cyanogen fluorine chlorine fluorine 2 to process 4
The chlorine water Emulsion (10 of first 4:3:4)；It is 10% cyhalofop-butyl missible oil (commercial) to process 5；It is that 288g/L fluroxypyrs are different to process 6
Monooctyl ester cream；It is the solvable powder of the chlorine sodium of 56%2 first 4 to process 7；8 are processed for control (not applying herbicide), the leaf phase of Oryza sativa L. 3, is adopted
Stem and leaf nebulization medication.Above medicament is provided by research and development department of Zhejiang Tianfeng Biological Science Co., Ltd..
Respondent and method：Observe within 7 days after medication each treatment agent on paddy growth situation affect and weeds it is aggrieved
Situation.30 days after medication, range estimation barnyard grass, Semen Euphorbiae, dried tuber, Herba Murdanniae Triquetrae preventive effect and the total preventive effect of field weed community.
The cyhalofop-butyl of table 3, the different monooctyl ester of fluroxypyr and the different monooctyl ester ternary built of the chlorine of 2 first 4 respectively process transplanted rice field
30 days field control effectiveness test results of medication.
According to investigation, 7 days after Oryza sativa L. medication, the different monooctyl ester of cyhalofop-butyl of the present invention, fluroxypyr and 2 first 4
The different monooctyl ester ternary built ternary built Herbicidal combinations of chlorine are fine to Jing rice and long-grained nonglutinous rice safety in the range of test dose, Oryza sativa L.
Growth is normal, has no that blade such as is burnt, turns to be yellow, withering at the abnormal phenomena.As can be seen here the present invention is in the range of certain dosage
To Jing rice and long-grained nonglutinous rice safety.
As can be seen that the ternary built Herbicidal combinations pair of the present invention from 30 days result of the tests after the land for growing field crops medication of table 3
Rice terrace annual grassy weeds barnyard grass, Semen Euphorbiae, dried tuber, Herba Murdanniae Triquetrae preventive effect more than 86%, field efficacy more than 88% is bright
It is aobvious to be better than control single dose, compare control single dose and there is raising herbicidal effect, expand the remarkable advantages such as weed control spectrum.
As can be seen here, the ternary built Herbicidal combinations are to rice safety and herbicidal in the range of certain using dosage
Can be excellent, with potential agricultural extension value.
During the patented invention, also many embodiments are numerous to list herein.
To sum up virulence test and field experiment are as a result, it was confirmed that the present invention contains cyhalofop-butyl, the different monooctyl ester of fluroxypyr
With the ternary built Herbicidal combinations of the different monooctyl ester of the chlorine of 2 first 4, be mainly used in preventing and kill off rice terrace annual grassy weeds, to field grass family,
Cyperaceae and broad leaved weed have good preventive effect, and to rice safety.Ternary built Herbicidal combinations of the present invention
Unique with the mechanism of action, using dosage is low, broad weed-killing spectrum, the advantages of herbicidal effect is outstanding.So, the present invention is containing cyanogen fluorine grass
The research and development and popularization of the different monooctyl ester of ester, fluroxypyr and the different monooctyl ester ternary built Herbicidal combinations of the chlorine of 2 first 4 have huge Jing
Ji and social benefit.
Claims (5)
1. a kind of ternary built Herbicidal combinations, it is characterised in that including following active component：Cyhalofop-butyl, chlorine fluorine pyrrole oxygen second
The weight ratio of the different monooctyl ester of acid and the different monooctyl ester of the chlorine of 2 first 4, the different monooctyl ester of the cyhalofop-butyl, fluroxypyr and the different monooctyl ester of the chlorine of 2 first 4
For（5-15）:（1-5）:（1-7）.
2. ternary built Herbicidal combinations according to claim 1, it is characterised in that the cyhalofop-butyl, chlorine fluorine pyrrole oxygen
The weight of 2-ethyl hexyl ethanoate and the different monooctyl ester of the chlorine of 2 first 4 accounts for the 1-80% of composition total weight.
3. ternary built Herbicidal combinations according to claim 1 and 2, it is characterised in that the ternary built weeding group
Contain pesticidal preparations auxiliary element in compound.
4. the application of ternary built Herbicidal combinations according to claim 3, it is characterised in that the ternary built weeding
The dosage form of compositionss is cream, dispersibles oil-suspending agent, aqueous emulsion.
5. the application of ternary built Herbicidal combinations according to claim 4, it is characterised in that the ternary built weeding
Compositionss are used to prevent and kill off rice terrace annual grassy weeds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611049572.4A CN106577666A (en) | 2016-11-24 | 2016-11-24 | Ternary combined weeding composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611049572.4A CN106577666A (en) | 2016-11-24 | 2016-11-24 | Ternary combined weeding composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106577666A true CN106577666A (en) | 2017-04-26 |
Family
ID=58591902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611049572.4A Pending CN106577666A (en) | 2016-11-24 | 2016-11-24 | Ternary combined weeding composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106577666A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108739849A (en) * | 2018-07-18 | 2018-11-06 | 浙江天丰生物科学有限公司 | A kind of Herbicidal composition for paddy fields containing anilofos |
| CN112244035A (en) * | 2020-10-26 | 2021-01-22 | 安徽润农腾辉生物科技有限公司 | Weeding composition containing halosulfuron-methyl, fluroxypyr and 2-methyl-4-chloro |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101653117A (en) * | 2009-08-31 | 2010-02-24 | 江苏辉丰农化股份有限公司 | Cyhalofop-butyl-containing paddy field herbicide composition |
| CN101999357A (en) * | 2010-12-17 | 2011-04-06 | 上海生农生化制品有限公司 | Herbicide composition and application thereof |
| CN102204534A (en) * | 2011-04-12 | 2011-10-05 | 安徽丰乐农化有限责任公司 | Cyhalofop-butyl and fluroxypyr stem-leaf herbicide for paddy field |
| CN102657172A (en) * | 2012-04-05 | 2012-09-12 | 李娟� | Weeding composition for wheat fields |
| CN104222086A (en) * | 2013-06-10 | 2014-12-24 | 新沂市汉菱生物工程有限公司 | A preparing method of a fluroxipir/2-methyl-4-chlorophenoxy acetic acid microemulsion |
-
2016
- 2016-11-24 CN CN201611049572.4A patent/CN106577666A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101653117A (en) * | 2009-08-31 | 2010-02-24 | 江苏辉丰农化股份有限公司 | Cyhalofop-butyl-containing paddy field herbicide composition |
| CN101999357A (en) * | 2010-12-17 | 2011-04-06 | 上海生农生化制品有限公司 | Herbicide composition and application thereof |
| CN102204534A (en) * | 2011-04-12 | 2011-10-05 | 安徽丰乐农化有限责任公司 | Cyhalofop-butyl and fluroxypyr stem-leaf herbicide for paddy field |
| CN102657172A (en) * | 2012-04-05 | 2012-09-12 | 李娟� | Weeding composition for wheat fields |
| CN104222086A (en) * | 2013-06-10 | 2014-12-24 | 新沂市汉菱生物工程有限公司 | A preparing method of a fluroxipir/2-methyl-4-chlorophenoxy acetic acid microemulsion |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108739849A (en) * | 2018-07-18 | 2018-11-06 | 浙江天丰生物科学有限公司 | A kind of Herbicidal composition for paddy fields containing anilofos |
| CN112244035A (en) * | 2020-10-26 | 2021-01-22 | 安徽润农腾辉生物科技有限公司 | Weeding composition containing halosulfuron-methyl, fluroxypyr and 2-methyl-4-chloro |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110150302B (en) | Herbicide composition and application thereof | |
| CN102273459A (en) | Weeding composition containing pyribenzoxim and cyhalofopbutyl | |
| CN105211072B (en) | Herbicidal combinations | |
| CN104365658B (en) | A kind of compound synergic herbicide and preparation technology thereof | |
| CN104106584A (en) | Cornfield compounded herbicide composition | |
| CN104521988B (en) | A kind of containing methylsulfonyl bacterium azoles and the complex composition of tiger glue adipic acid copper and preparation | |
| CN104186491B (en) | A kind of radix bupleuri field weeding composition and pharmaceutical preparation thereof | |
| CN106577666A (en) | Ternary combined weeding composition | |
| CN106879608A (en) | Herbicidal combinations containing benzobicylon, pretilachlor and penoxsuam | |
| CN104106576B (en) | A kind of containing metazachlor with the Herbicidal combinations of metribuzin | |
| CN102283231B (en) | Oil suspending agent composition containing nicosulfuron and fluroxypyr | |
| CN105532657B (en) | It is a kind of for Herbicidal combinations of monocot crops and application thereof | |
| CN105409992B (en) | A kind of bactericidal composition and its application | |
| CN107114397A (en) | A kind of herbicidal composition containing anilofos, cyhalofop-butyl He metamifop | |
| CN106879618A (en) | Containing benzobicylon, pyrazosulfuron, pretilachlor Herbicidal combinations | |
| CN106577667A (en) | Herbicidal composition containing cyhalofop-butyl, fluroxypyr-meptyl and acifluorfen | |
| CN112753702A (en) | Weeding composition containing oxaziclomefone, clomazone and pyrazosulfuron-ethyl | |
| CN106577695A (en) | Herbicidal composition | |
| CN102461527A (en) | Mixed weeding composition containing bispyribac-sodium and bentazone | |
| CN111264540A (en) | Weeding composition containing oxadiargyl | |
| CN108124901A (en) | A kind of Herbicidal combinations containing anilofos, penoxsuam and fluroxypyr | |
| CN106106457B (en) | The Herbicidal combinations of dichloroquinoline humulone and diflufenican | |
| CN109832296A (en) | A kind of herbicidal composition containing anilofos, cyhalofop-butyl and pyraclonil | |
| CN102217624A (en) | Metamifop compound herbicide | |
| CN106577668A (en) | Multi-component compound weeding composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170426 |
|
| RJ01 | Rejection of invention patent application after publication |