CN106566608A - Emulsified paraffin release agent and preparation method thereof - Google Patents

Emulsified paraffin release agent and preparation method thereof Download PDF

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Publication number
CN106566608A
CN106566608A CN201610909922.3A CN201610909922A CN106566608A CN 106566608 A CN106566608 A CN 106566608A CN 201610909922 A CN201610909922 A CN 201610909922A CN 106566608 A CN106566608 A CN 106566608A
Authority
CN
China
Prior art keywords
parts
oil
release agent
paraffin
emulsifier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610909922.3A
Other languages
Chinese (zh)
Inventor
宫振鑫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DALIAN MINGYUANQUAN TECHNOLOGY DEVELOPMENT Co Ltd
Original Assignee
DALIAN MINGYUANQUAN TECHNOLOGY DEVELOPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DALIAN MINGYUANQUAN TECHNOLOGY DEVELOPMENT Co Ltd filed Critical DALIAN MINGYUANQUAN TECHNOLOGY DEVELOPMENT Co Ltd
Priority to CN201610909922.3A priority Critical patent/CN106566608A/en
Publication of CN106566608A publication Critical patent/CN106566608A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/045Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B7/00Moulds; Cores; Mandrels
    • B28B7/38Treating surfaces of moulds, cores, or mandrels to prevent sticking
    • B28B7/384Treating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B7/00Moulds; Cores; Mandrels
    • B28B7/38Treating surfaces of moulds, cores, or mandrels to prevent sticking
    • B28B7/388Treating surfaces of moulds, cores, or mandrels to prevent sticking with liquid material, e.g. lubricating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/289Partial esters containing free hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/36Release agents or mold release agents

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Moulds, Cores, Or Mandrels (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses an emulsified paraffin release agent, which is characterized by being prepared from the following raw materials (by weight): 10-25 parts of paraffin, 5-8 parts of stearic acid, 5-10 parts of animal oil or plant oil, 5-10 parts of a co-emulsifier, 1-10 parts of sodium hydroxide and 1-10 parts of ethyl 4-hydroxybenzoate. The release agent of the invention is mainly used in molding of a concrete material. The release agent is sprayed on the surface of a mould, and is used for preventing a product from being glued with the mould so as to have an effect of isolating the product from the mould. Then, the product can be greatly moulded. The release agent of the invention has a good demoulding effect.

Description

Emulsified paraffin release agent and preparation method thereof
Technical field
The present invention relates to a kind of concrete parting agent, specifically a kind of emulsified paraffin release agent and preparation method thereof.
Background technology
Concrete prefabricated element or prefabrication, such as building block, plate, beam, pier, dam, bridge, in its irrigation process, it is necessary to make With template or mould.In order that the concrete after hardening is easy to the demoulding and does not damage template, one is often brushed in template or mould Layer releasing agent.For a long time, it is domestic frequently with machine oil, used oil, emulsified machine oil etc. or animals and plants oil foot, poor oil Jing saponification and Into so-called liquid soap agent as releasing agent.The species of releasing agent mainly has following several:
1st, pure oils.Releasing agent is can configure including each vegetable oil, animal oil and mineral oil.But at present mineral are adopted mostly Oil.The various light lubricating oils that i.e. petroleum industry is produced, such as machinery oil.For reduces cost, many units use industry Used oil, but impurity is more in used oil, it is easier to pollute concrete surface.Be also possible in some used oil containing sulphuric acid, PCB etc. is harmful to the material of concrete and masterplate.
2nd, emulsifying oils.Oil emulsion great majority petroleum oil, emulsifying agent, stabilizer are formulated, and are additionally added sometimes Rust-inhibiting additive.Replace pure petroleum oil with emulsifying agent, can not only save a large amount of oil plants, and releasing agent matter can be improved Amount, reduces demoulding cost.This kind of releasing agent can be divided into Water-In-Oil(W/O)Type and oil-in-water(O/W)Type.Steel membrane is generally used for, Can be used on wooden model.Easily it is dried after brushing, thin film is formed after some dryings can repeatedly apply multiple, not only saving of labor but also material-saving, Substantially reduce demoulding cost.
3rd, paraffin class.Paraffin has good demolding performace, and after being heated fusing, mixing by appropriate solvent is stirred evenly makes With.Paraffin release agent can be used on steel, plank sheathing and concrete pedestal, often stay in concrete surface when paraffin content is higher Paraffin residue, is an impediment to the bonding of concrete surface, thus its range of application is subject to a definite limitation.
4th, fatty acid.This kind of releasing agent typically contains solvent, such as gasoline, kerosene, benzene, Oleum Terebinthinae etc..The releasing agent With the good demoulding and rustless property, concrete surface is not polluted, resistance of rainwater washing against, often applying once can use three times.Fat Acids releasing agent is mostly with the alkali of concrete(Free lime)Chemically reactive.
5th, class is painted.This kind of releasing agent price is higher, but can be reused several times, economically still suitable.Such as alcohol Sour varnish releasing agent.
The content of the invention
It is an object of the invention to provide a kind of emulsified paraffin release agent and preparation method thereof.
Emulsified paraffin release agent, it is characterised in that make including the raw material of following mass fractions:
10~25 parts of paraffin
5~8 parts of stearic acid
5~10 parts of animal oil or vegetable oil
5~10 parts of co-emulsifier
Sodium hydroxide 1-10 parts
Ethyl hydroxybenzoate 1-10 parts.
Its preferred proportioning raw materials is:
15~20 parts of paraffin
6~7 parts of stearic acid
7~8 parts of animal oil or vegetable oil
6~8 parts of co-emulsifier
Sodium hydroxide 2-5 parts
Ethyl hydroxybenzoate 2-4 parts.
Further, the co-emulsifier is in dichloroethanes, carbon tetrachloride, hexamethylene, ethyl acetate, butyl acetate It is a kind of.
Further, the sodium hydroxide is replaced by potassium hydroxide.
In addition, the preparation method of emulsified paraffin release agent, by paraffin, stearic acid, co-emulsifier, animal oil or plant Oil, ethyl hydroxybenzoate add a vessel in heating to 60~80 DEG C of fusings, by water, alkaline agent, are placed in another container, and mix homogeneously adds Heat is to 75~85 DEG C;Oil phase is consistent substantially with water phase temperature, then water be mutually slowly added to vigorous stirring oil Xiang Zhong, slowly emulsifying, phase inversion, mixing speed slows down gradually with emulsifying temperature reduction, stirs to room temperature and goes out product, obtains white Oil-in-water emulsion.
The releasing agent of the present invention is mainly used in concrete material molding, and releasing agent is to be sprayed on die surface, for preventing Only product and the bonding of mould, so as to serve the effect isolated with mould, make product shape very well, and stripping result is good.
Specific embodiment
Explanation is further explained to the present invention with reference to specific embodiment.
Embodiment 1
Formula is that preparation method is with embodiment 1.
10 parts of paraffin
5 parts of stearic acid
5 parts of animal oil or vegetable oil
5 parts of co-emulsifier
1 part of sodium hydroxide
1 part of ethyl hydroxybenzoate.
The preparation method of emulsified paraffin release agent, by paraffin, stearic acid, co-emulsifier, animal oil or vegetable oil, Ni Bo Golden ethyl ester adds a vessel in heating to 60~80 DEG C of fusings, by water, alkaline agent, is placed in another container, and mix homogeneously is heated to 75 ~85 DEG C;Oil phase is consistent substantially with water phase temperature, then water is mutually slowly added in oil phase with vigorous stirring, slowly Slow emulsifying, phase inversion, mixing speed slows down gradually with emulsifying temperature reduction, stirs to room temperature and goes out product, obtains white oil-in-water Type Emulsion.
Embodiment 2
Formula is that preparation method is with embodiment 1.
25 parts of paraffin
8 parts of stearic acid
10 parts of animal oil or vegetable oil
10 parts of co-emulsifier
10 parts of sodium hydroxide
10 parts of ethyl hydroxybenzoate
Embodiment 3
Formula is that preparation method is with embodiment 1.
15 parts of paraffin
6 parts of stearic acid
6 parts of animal oil or vegetable oil
6 parts of co-emulsifier
5 parts of sodium hydroxide
3 parts of ethyl hydroxybenzoate.
Embodiment 4
Formula is that preparation method is with embodiment 1.
20 parts of paraffin
6 parts of stearic acid
8 parts of animal oil or vegetable oil
6 parts of co-emulsifier
8 parts of sodium hydroxide
5 parts of ethyl hydroxybenzoate.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope of present disclosure, technology according to the present invention scheme and its Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.

Claims (5)

1. emulsified paraffin release agent, it is characterised in that make including the raw material of following mass fractions:
10~25 parts of paraffin
5~8 parts of stearic acid
5~10 parts of animal oil or vegetable oil
5~10 parts of co-emulsifier
Sodium hydroxide 1-10 parts
Ethyl hydroxybenzoate 1-10 parts.
2. emulsified paraffin release agent according to claim 1, it is characterised in that proportioning raw materials are:
15~20 parts of paraffin
6~7 parts of stearic acid
7~8 parts of animal oil or vegetable oil
6~8 parts of co-emulsifier
Sodium hydroxide 2-5 parts
Ethyl hydroxybenzoate 2-4 parts.
3. emulsified paraffin release agent according to claim 1 and 2, it is characterised in that the co-emulsifier be dichloroethanes, One kind in carbon tetrachloride, hexamethylene, ethyl acetate, butyl acetate.
4. emulsified paraffin release agent according to claim 1, it is characterised in that the sodium hydroxide is by potassium hydroxide generation Replace.
5. the preparation method of the emulsified paraffin release agent according to any one of claim 1-4, it is characterised in that by paraffin, Stearic acid, co-emulsifier, animal oil or vegetable oil, ethyl hydroxybenzoate add a vessel in heating to 60~80 DEG C fusing, by water, Alkaline agent, it is placed in another container, mix homogeneously is heated to 75~85 DEG C;Oil phase is set to be consistent substantially with water phase temperature, then Water is mutually slowly added in oil phase with vigorous stirring, slowly emulsifying, phase inversion, mixing speed with emulsifying temperature reduce and gradually Slow down, stir to room temperature and go out product, obtain white oil-in-water emulsion.
CN201610909922.3A 2016-10-19 2016-10-19 Emulsified paraffin release agent and preparation method thereof Pending CN106566608A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610909922.3A CN106566608A (en) 2016-10-19 2016-10-19 Emulsified paraffin release agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610909922.3A CN106566608A (en) 2016-10-19 2016-10-19 Emulsified paraffin release agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106566608A true CN106566608A (en) 2017-04-19

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CN (1) CN106566608A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108559612A (en) * 2018-04-19 2018-09-21 广州市浪奇实业股份有限公司 A kind of preparation method of soap-base lubricant
CN110846107A (en) * 2019-11-05 2020-02-28 中交第二航务工程局有限公司 Defoaming and releasing agent for concrete and preparation method thereof
CN112574799A (en) * 2020-12-11 2021-03-30 许辉 Profile steel friction reducer and preparation method and application thereof
CN113773900A (en) * 2021-10-11 2021-12-10 南京友西科技集团股份有限公司 Release agent for improving adhesive force of concrete decorative surface material and use method thereof
CN114515815A (en) * 2022-02-22 2022-05-20 马鞍山中集瑞江润滑油有限公司 Water-based magnetic release agent
CN115161101A (en) * 2022-02-22 2022-10-11 马鞍山中集瑞江润滑油有限公司 Releasing agent for bright cement products
CN115678653A (en) * 2022-09-09 2023-02-03 山东德利森绿能建材科技有限公司 Environment-friendly degradable fine aggregate concrete release agent and preparation method thereof
CN116590081A (en) * 2023-04-03 2023-08-15 中原内配集团安徽有限责任公司 Release agent for cylinder sleeve production release

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101838581A (en) * 2009-03-19 2010-09-22 张伟 Mould release agent

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101838581A (en) * 2009-03-19 2010-09-22 张伟 Mould release agent

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108559612A (en) * 2018-04-19 2018-09-21 广州市浪奇实业股份有限公司 A kind of preparation method of soap-base lubricant
CN108559612B (en) * 2018-04-19 2021-11-26 广州市浪奇实业股份有限公司 Preparation method of soap-based lubricant
CN110846107A (en) * 2019-11-05 2020-02-28 中交第二航务工程局有限公司 Defoaming and releasing agent for concrete and preparation method thereof
CN112574799A (en) * 2020-12-11 2021-03-30 许辉 Profile steel friction reducer and preparation method and application thereof
CN113773900A (en) * 2021-10-11 2021-12-10 南京友西科技集团股份有限公司 Release agent for improving adhesive force of concrete decorative surface material and use method thereof
CN114515815A (en) * 2022-02-22 2022-05-20 马鞍山中集瑞江润滑油有限公司 Water-based magnetic release agent
CN115161101A (en) * 2022-02-22 2022-10-11 马鞍山中集瑞江润滑油有限公司 Releasing agent for bright cement products
CN115678653A (en) * 2022-09-09 2023-02-03 山东德利森绿能建材科技有限公司 Environment-friendly degradable fine aggregate concrete release agent and preparation method thereof
CN116590081A (en) * 2023-04-03 2023-08-15 中原内配集团安徽有限责任公司 Release agent for cylinder sleeve production release
CN116590081B (en) * 2023-04-03 2024-05-10 中原内配集团安徽有限责任公司 Release agent for cylinder sleeve production release

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SE01 Entry into force of request for substantive examination
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Application publication date: 20170419