CN106566127A - Decorative PVC material with good light-proofness and preparation method of decorative PVC material - Google Patents
Decorative PVC material with good light-proofness and preparation method of decorative PVC material Download PDFInfo
- Publication number
- CN106566127A CN106566127A CN201610965307.4A CN201610965307A CN106566127A CN 106566127 A CN106566127 A CN 106566127A CN 201610965307 A CN201610965307 A CN 201610965307A CN 106566127 A CN106566127 A CN 106566127A
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- CN
- China
- Prior art keywords
- pvc material
- preparation
- decorative pvc
- barium
- photosensitiveness
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a decorative PVC material with good light-proofness and a preparation method of the decorative PVC material. The decorative PVC material is prepared from the following raw materials in parts by weight: 80-100 of PVC resin, 3-5 of barium laurate, 3-5 of cadmium neocaprate, 1-2 of zinc naphthenate, 1-2 of diphenyl cotyl phosphate, 2-3 of red phosphorus, 1-2 of ammonium molybdate, 0.1-0.2 of barium dilaurate, 0.5-1 of spindle oil, 5-10 of polyethylene wax, 20-30 of trioctyl trimellitate, 10-15 of zirconium oxide, 5-7 of carbonyl iron powder, 0.3-0.5 of dihydromyricetin, 2-4 of glass beads and 5-10 of modified additives. Not only are the chemical property and weather resistance of the material strengthened, but also the moisture absorbability and permeability of the material are improved, so that the obtained indoor decorative PVC material has favorable mechanical property as well as moisture absorbability and moisture regulating property and is capable of effectively improving the comfort level of an indoor environment and excellent in slip resistance.
Description
Technical field
The present invention relates to the material modified technical fields of PVC, more particularly to a kind of good decoration of PVC materials of anti-photosensitiveness and its system
Preparation Method.
Background technology
PVC is polrvinyl chloride, is one of most wide plastics variety of application, has been widely used for pipe profile, builds
Build the fields such as furniture, interior decoration, sports equipment, medical material.But it is PVC product generally existing poor mechanical property, steady to light, heat
Qualitative low defect, and the enhancing with people's environmental consciousness and the raising to indoor environment requirement, current PVC material is got over
It is difficult to accord with the demands of the market to get over, limits the application of its furnishing fields indoors.Therefore, the combination property of PVC material is improved,
The surcharge of PVC material is lifted, is the latency development direction of current PVC house decorative materials.In PVC rooms in the market
Ornament materials resistance to soiling is less desirable, requires further improvement.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of good decoration of PVC materials of anti-photosensitiveness and
Its preparation method.
The present invention is achieved by the following technical solutions：
Good decoration of PVC materials of a kind of anti-photosensitiveness and preparation method thereof, it is characterised in that it is by the original of following weight parts
Material is obtained：
Polyvinyl chloride resin 80-100, barium laurate 3-5, neodecanoic acid cadmium 3-5, zinc naphthenate 1-2, the monooctyl ester 1- of phosphorous acid hexichol one
2, red phosphorus 2-3, ammonium molybdate 1-2, dilaurate barium 0.1-0.2, bobbin oil 0.5-1, Tissuemat E 5-10, trioctyl trimellitate (TOTM)
20-30, zirconium oxide 10-15, carbonyl iron dust 5-7, dihydromyricetin 0.3-0.5, glass microballoon 2-4, modified additive 5-10；
Described modified additive is prepared by the raw materials in：Mannitol 6-8, sodium hexameta phosphate 0.1-0.15, mistake
Potassium sulfate 0.2-0.4, nano aluminium oxide 3-5, jade powder 10-15, corn starch 1-2, silane resin acceptor kh-550 0.1-0.2,
Water 80-100；After jade powder, corn starch, nano aluminium oxide are mixed with potassium peroxydisulfate equal proportion, the scaling loss at 600-700 DEG C
4-5 hours, are then ground to nanometer powder, admix equal equivalent to the Mannitol and sodium hexameta phosphate agitating of powder body weight 3-5%
It is even, drying, then obtain final product into powder with surplus stock co-grinding.
Good decoration of PVC materials of described a kind of anti-photosensitiveness and preparation method thereof, it is characterised in that comprise the following steps：
(1) raw material is weighed by weight, first first uses barium laurate, neodecanoic acid cadmium, zinc naphthenate, the monooctyl ester of phosphorous acid hexichol one
15-20% soak with hydrochloric acid, stands, clarification, centrifugation, solid washed with water to neutrality, co-ground after mixing with bobbin oil after drying
10-15min, is subsequently adding 70-90 DEG C of Tissuemat E, stirring 5-10min, obtains mixed slurry；
(2) mixed slurry in polyvinyl chloride resin, modified additive and (1) is stirred prior to 50-60 DEG C, 1000-1500r/min
5-10min, is subsequently adding remaining raw material and continues blending 10-20min at a high speed in 120-140 DEG C, is eventually adding double screw extruder
In 100-140 DEG C of melting extrusion pelletize, good decoration of PVC materials of anti-photosensitiveness and preparation method thereof is obtained final product after cooling.
It is an advantage of the invention that：This by the further optimization of formula, and with the addition of glass microballoon so that tubing is put
Optical property improves so that can promote the dispersion of inorganic filler in the course of processing of PVC, improves the flowing of PVC melts
Property, moreover it is possible to lift tensile strength and elongation at break, changes polyethylene products when using Tissuemat E, good toughness, hardness
Low shortcoming, so as to get interior decoration PVC it is material modified with good mechanical performance and moisture absorption humidity, can effectively change
The comfort level of kind indoor environment, and with stain resistant, it is easy to clean the characteristics of, with higher surcharge and practical value.
Specific embodiment
Good decoration of PVC materials of a kind of anti-photosensitiveness and preparation method thereof, it is obtained by the raw material of following weight parts：
Polyvinyl chloride resin 80-100, barium laurate 3-5, neodecanoic acid cadmium 3-5, zinc naphthenate 1-2, the monooctyl ester 1- of phosphorous acid hexichol one
2, red phosphorus 2-3, ammonium molybdate 1-2, dilaurate barium 0.1-0.2, bobbin oil 0.5-1, Tissuemat E 5-10, trioctyl trimellitate (TOTM)
20-30, zirconium oxide 10-15, carbonyl iron dust 5-7, dihydromyricetin 0.3-0.5, glass microballoon 2-4, modified additive 5-10；
Wherein modified additive is prepared by the raw materials in：Acrylic acid 6, methylene diacrylamide 0.1, potassium peroxydisulfate
0.2, nano aluminium oxide 3, kieselguhr 10, xanthan gum 1, Silane coupling agent KH550 0.1, water 80；The preparation method of modified additive is
Kieselguhr, xanthan gum, nano aluminium oxide and potassium peroxydisulfate are added to the water into 50 DEG C, 600r/min stirring 0.5h, third is subsequently adding
Stir 2h under olefin(e) acid and methylene diacrylamide similarity condition, cooled and filtered washing, be dried completely under the conditions of 100 DEG C with
Remaining raw material mixing 10min, grinds uniform after cooling, obtain final product.
Good decoration of PVC materials of a kind of anti-photosensitiveness and preparation method thereof, comprises the following steps：
(1) raw material is weighed by weight, first by barium laurate, neodecanoic acid cadmium, zinc naphthenate, the monooctyl ester of phosphorous acid hexichol one and ingot
Co-ground 10min after seed oil mixing, is subsequently adding 60 DEG C of Tissuemat E, 1000r/min stirring 5min, obtains mixed slurry；
(2) by the mixed slurry in polyvinyl chloride resin, modified additive and (1) prior to 50 DEG C, 1000r/min stirring 5min, then
Add remaining raw material to continue blending 10min at a high speed in 120 DEG C, be eventually adding double screw extruder in 100-140 DEG C of melting extrusion
Pelletize, obtains final product good decoration of PVC materials of anti-photosensitiveness and preparation method thereof after cooling.
Claims (2)
1. good decoration of PVC materials of a kind of anti-photosensitiveness and preparation method thereof, it is characterised in that it is by the raw material of following weight parts
It is obtained：
Polyvinyl chloride resin 80-100, barium laurate 3-5, neodecanoic acid cadmium 3-5, zinc naphthenate 1-2, the monooctyl ester 1-2 of phosphorous acid hexichol one is red
Phosphorus 2-3, ammonium molybdate 1-2, dilaurate barium 0.1-0.2, bobbin oil 0.5-1, Tissuemat E 5-10, trioctyl trimellitate (TOTM) 20-
30th, zirconium oxide 10-15, carbonyl iron dust 5-7, dihydromyricetin 0.3-0.5, glass microballoon 2-4, modified additive 5-10；
Described modified additive is prepared by the raw materials in：Mannitol 6-8, sodium hexameta phosphate 0.1-0.15, persulfuric acid
Potassium 0.2-0.4, nano aluminium oxide 3-5, jade powder 10-15, corn starch 1-2, silane resin acceptor kh-550 0.1-0.2, water 80-
100；After jade powder, corn starch, nano aluminium oxide are mixed with potassium peroxydisulfate equal proportion, scaling loss 4-5 is little at 600-700 DEG C
When, nanometer powder is then ground to, admix, baking uniform equivalent to the Mannitol and sodium hexameta phosphate agitating of powder body weight 3-5%
It is dry, then obtain final product into powder with surplus stock co-grinding.
2. a kind of good decoration of PVC materials of anti-photosensitiveness according to claim 1 and preparation method thereof, it is characterised in that bag
Include following steps：
(1) raw material is weighed by weight, first barium laurate, neodecanoic acid cadmium, zinc naphthenate, the monooctyl ester of phosphorous acid hexichol one is first used into 15-
20% soak with hydrochloric acid, stands, clarification, centrifugation, solid washed with water to neutrality, co-ground 10- after mixing with bobbin oil after drying
15min, is subsequently adding 70-90 DEG C of Tissuemat E, stirring 5-10min, obtains mixed slurry；
(2) by the mixed slurry in polyvinyl chloride resin, modified additive and (1) prior to 50-60 DEG C, 1000-1500r/min stirring 5-
10min, is subsequently adding remaining raw material and continues at a high speed blending 10-20min in 120-140 DEG C, be eventually adding double screw extruder in
100-140 DEG C of melting extrusion pelletize, obtains final product good decoration of PVC materials of anti-photosensitiveness and preparation method thereof after cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610965307.4A CN106566127A (en) | 2016-10-28 | 2016-10-28 | Decorative PVC material with good light-proofness and preparation method of decorative PVC material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610965307.4A CN106566127A (en) | 2016-10-28 | 2016-10-28 | Decorative PVC material with good light-proofness and preparation method of decorative PVC material |
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| Publication Number | Publication Date |
|---|---|
| CN106566127A true CN106566127A (en) | 2017-04-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610965307.4A Pending CN106566127A (en) | 2016-10-28 | 2016-10-28 | Decorative PVC material with good light-proofness and preparation method of decorative PVC material |
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| CN (1) | CN106566127A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408859A (en) * | 2013-07-18 | 2013-11-27 | 吴江市利达上光制品有限公司 | Composite sound absorption plastic preparation method |
| CN104877262A (en) * | 2015-05-20 | 2015-09-02 | 苏州宏恒化工有限公司 | Polyvinyl chloride decoration plate and preparation method thereof |
| CN105255051A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Sound absorbing and noise lowering interior decoration PVC modified material and preparation method thereof |
-
2016
- 2016-10-28 CN CN201610965307.4A patent/CN106566127A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408859A (en) * | 2013-07-18 | 2013-11-27 | 吴江市利达上光制品有限公司 | Composite sound absorption plastic preparation method |
| CN104877262A (en) * | 2015-05-20 | 2015-09-02 | 苏州宏恒化工有限公司 | Polyvinyl chloride decoration plate and preparation method thereof |
| CN105255051A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Sound absorbing and noise lowering interior decoration PVC modified material and preparation method thereof |
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