CN106565011A - Method and system for treating Microcystin-containing algae organic wastewater - Google Patents
Method and system for treating Microcystin-containing algae organic wastewater Download PDFInfo
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- CN106565011A CN106565011A CN201610839190.5A CN201610839190A CN106565011A CN 106565011 A CN106565011 A CN 106565011A CN 201610839190 A CN201610839190 A CN 201610839190A CN 106565011 A CN106565011 A CN 106565011A
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- 241000195493 Cryptophyta Species 0.000 title claims abstract description 79
- 238000000034 method Methods 0.000 title claims abstract description 39
- 239000002351 wastewater Substances 0.000 title claims abstract description 33
- 108010067094 microcystin Proteins 0.000 title abstract description 15
- SRUWWOSWHXIIIA-UKPGNTDSSA-N Cyanoginosin Chemical compound N1C(=O)[C@H](CCCN=C(N)N)NC(=O)[C@@H](C)[C@H](C(O)=O)NC(=O)[C@H](CC(C)C)NC(=O)[C@H](C)NC(=O)C(=C)N(C)C(=O)CC[C@H](C(O)=O)N(C)C(=O)[C@@H](C)[C@@H]1\C=C\C(\C)=C\[C@H](C)[C@@H](O)CC1=CC=CC=C1 SRUWWOSWHXIIIA-UKPGNTDSSA-N 0.000 title abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 15
- JIGDOBKZMULDHS-UHFFFAOYSA-N cyanogenosin-RR Natural products N1C(=O)C(CCCN=C(N)N)NC(=O)C(C)C(C(O)=O)NC(=O)C(CCCN=C(N)N)NC(=O)C(C)NC(=O)C(=C)N(C)C(=O)CCC(C(O)=O)NC(=O)C(C)C1C=CC(C)=CC(C)C(OC)CC1=CC=CC=C1 JIGDOBKZMULDHS-UHFFFAOYSA-N 0.000 claims abstract description 11
- 108010004476 microcystin RR Proteins 0.000 claims abstract description 11
- JIGDOBKZMULDHS-UUHBQKJESA-N microcystin RR Chemical compound C([C@H](OC)[C@@H](C)\C=C(/C)\C=C\[C@H]1[C@@H](C(=O)N[C@H](CCC(=O)N(C)C(=C)C(=O)N[C@H](C)C(=O)N[C@@H](CCCN=C(N)N)C(=O)N[C@H]([C@H](C)C(=O)N[C@@H](CCCN=C(N)N)C(=O)N1)C(O)=O)C(O)=O)C)C1=CC=CC=C1 JIGDOBKZMULDHS-UUHBQKJESA-N 0.000 claims abstract description 11
- JIGDOBKZMULDHS-HZJVMCKBSA-N microcystin RR Natural products CO[C@@H](Cc1ccccc1)[C@@H](C)C=C(C)C=C[C@@H]2NC(=O)[C@H](CCCNC(=N)N)NC(=O)[C@@H](C)[C@@H](NC(=O)[C@H](CCCNC(=N)N)NC(=O)[C@@H](C)NC(=O)C(=C)N(C)C(=O)CC[C@@H](NC(=O)[C@H]2C)C(=O)O)C(=O)O JIGDOBKZMULDHS-HZJVMCKBSA-N 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 239000004744 fabric Substances 0.000 claims abstract description 7
- 230000005518 electrochemistry Effects 0.000 claims abstract description 5
- 239000003053 toxin Substances 0.000 claims description 33
- 231100000765 toxin Toxicity 0.000 claims description 33
- 108700012359 toxins Proteins 0.000 claims description 33
- 239000000126 substance Substances 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 16
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 12
- 238000012545 processing Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 7
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- 244000005700 microbiome Species 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 238000012546 transfer Methods 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 239000004020 conductor Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 238000011282 treatment Methods 0.000 abstract description 5
- 230000002906 microbiologic effect Effects 0.000 abstract description 4
- 108010049746 Microcystins Proteins 0.000 abstract description 3
- 238000004064 recycling Methods 0.000 abstract description 3
- 239000011521 glass Substances 0.000 abstract description 2
- 239000002957 persistent organic pollutant Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 239000005422 algal bloom Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000003651 drinking water Substances 0.000 description 3
- 235000020188 drinking water Nutrition 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000004071 biological effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000012851 eutrophication Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 230000005180 public health Effects 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 1
- 241000192710 Microcystis aeruginosa Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- FRYDSOYOHWGSMD-UHFFFAOYSA-N [C].O Chemical compound [C].O FRYDSOYOHWGSMD-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000008953 bacterial degradation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011953 bioanalysis Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
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- 238000004065 wastewater treatment Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/005—Combined electrochemical biological processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
Abstract
The invention discloses a method and system for treating Microcystin-containing algae organic wastewater. The system comprises a vessel, wherein the vessel is filled with the algae organic wastewater containing Microcystin-RR and other algae organic matters, an anode is mounted at one internal end of the vessel, a cathode is mounted at the other internal end of the vessel, the anode and the cathode are connected with an external circuit resistor through power lines, the vessel is made from an organic glass material, the upper end of the vessel is provided with a gas collecting gas through a ventilating pipe, the anode is made from a carbon brush, and the cathode is made from pt-catalyst coated carbon cloth. According to the method and the system, through integrating characteristics of microbiological treatment and electrochemistry, electric power is generated while Microcystins and other algae organic pollutants are removed, the recycling of algae organic wastewater resources is achieved, and a novel effective method for removing the Microcystins is found.
Description
Technical field
The present invention relates to field of waste water treatment, and in particular to a kind of process containing Algae toxins algae organic wastewater method and
System.
Background technology
The fast development of social economy and the continuous quickening of social process of industrialization, it is increasingly serious along with environmental pollution.
Wherein prominent is that the irrational life of people, the mode of production result in the nutrient salts such as nitrogen in waters, phosphorus and be enriched with a large number, is caused
Global waters eutrophication is increasingly serious, causes algae distorted proliferation, and wawter bloom occurs.In the last few years, China's algal bloom frequency
Send out.Algae organic wastewater containing Algae toxins is mainly by the substantial amounts of carbon hydrate produced in algal bloom its metabolic process
Cracking after thing, protein, Microcystin and its death is discharged into the composition of the Organic substance in water, and this is also to cause water pollution
Principal element.Research finds that 80% blue-green alga bloom can detect secondary metabolite --- Microcystin
(microcystins).This is the ring-type heptapeptide compound that a class has biological activity, and what other metabolism of it and algae were produced has
Machine thing is compared, and hazardness is maximum.Microcystin have very strong liver, kidney and other organs toxicity and promotees carcinous, is recognized
To be seriously to threaten the environmental contaminants of wild animals and plants and human health and obtain extensive concern.To ensure drinking for resident
Water security, the United Nations has formulated drinking water Microcystin limit standard, and its highest allows content for 1 μ g/L, China's Ministry of Public Health
This standard is continued to use in calendar year 2001, and has specified that Microcystis aeruginosa Algae toxins are one of drinking water quality essential items for inspection in 2006.With
Increasingly sharpening for water body eutrophication degree frequently to break out with algal bloom, Algae toxins pollution be China or even the world most
One of main environmental problem, seriously threatens mankind's drinking water safety, water ecosystem and mankind's public health security, into
To affect a key factor of sustainable utilization of water resource and restriction society and economy sustainable development, it is to ecological balance shadow
Ring and loss is difficult to the appraisal.Therefore, how Algae toxins are safely and effectively removed, so as to control Algae toxins concentration in water body,
An environmental science difficult problem of whole mankind's facing is become.
Microcystin is the ring-type heptapeptide that a class has biological activity, and with interval double bond, stable chemical nature is acidproof resistance to
Alkali, the coagulation of general water treatment technology, precipitates, boils (even if 300 DEG C of high temperature) and also its effective removal can not be belonged to into difficult degradation
Biological organic toxin, can retain in natural water environment for a long time.The method for eliminating Algae toxins in water body at present is main
There are Physical, chemical method and bioanalysises etc., but Physical and chemical method have in actual applications certain limitation, it is such as living
Property the Physical such as carbon adsorption and membrane filter method it is relatively costly, there is certain difficulty in concrete operations and enforcement, and effect is unstable
It is fixed, and chemical method easily causes the Environmental Residues of poisonous and harmful substance, causes the generation of secondary pollution, and water ecological environment is brought not
The impact of profit.In the last few years, studies have found that bacterial degradation Algae toxins often have low cost, efficiency is higher, be not likely to produce two
Secondary pollution and beneficial to the advantages of restoration of the ecosystem, therefore be that a kind of environmentally friendly very promising Algae toxins remove skill
Art, widely attracts attention in recent years, but the environmental safety due to antibacterial itself etc., so as to from practice also
There is larger gap.
In a word, these methods for removing Algae toxins are typically necessary the input energy or chemical reagent, and not only input cost is huge
Greatly, it is and cumbersome.In the face of China all there is algal bloom in numerous large-size lakes, have substantial amounts of Algae toxins and other algae to have
Organic pollutants need to process, and existing these methods either have very big difficulty from practical operation or economic investment.
Microbiological fuel cell is a kind of new wastewater through organic matter treatment technology, and it can process wastewater through organic matter
Electric current is produced simultaneously.Its ultimate principle is, with microorganism as catalyst, the Organic substance in waste water to be directly converted into the dress of electric energy
Put, antibacterial passes to negative electrode in anodic oxidation Organic substance, the electronics of generation by external circuit, the proton in solution then passes through proton
, to movable cathode, last proton, electronics is combined with terminal electron acceptor in negative electrode for exchange membrane or solution medium, completes whole life
The electronic transfer process of thing electrochemistry.
The content of the invention
To solve the above problems, the invention provides a kind of process contains the method for the algae organic wastewater of Algae toxins and is
System, with reference to the characteristics of microbial treatments and electrochemistry, while Microcystin and other algae organic pollutions are removed, produces
Electric energy is given birth to, the recycling of algae organic wastewater resource has been realized, the also removal for Microcystin have found a kind of new
Effective method.
For achieving the above object, the technical scheme taken of the present invention is：
A kind of system for processing the algae organic wastewater containing Algae toxins, including container, are filled with the container and contain algae
The algae organic wastewater of toxin Microcystin-RR and other algae Organic substances, side is provided with anode in the container,
Interior opposite side is provided with negative electrode, and the anode and negative electrode are connected with external circuitses resistance by power line, and the container is adopted to be had
Machine glass material, the pmma material is polymethyl methacrylate, and the container upper end is provided with gas collection by breather
Bag.
Preferably, the container upper end is additionally provided with and changes the mouth of a river, changes on the mouth of a river and is connected with lid.
Preferably, the anode is made up of carbon brush, and negative electrode is the carbon cloth composition for scribbling platinum pt catalyst, and conductive material is titanium
Silk.
Present invention also offers a kind of process the algae method for processing organic wastewater containing Algae toxins, comprise the steps：
S1, the algae organic wastewater containing Algae toxins Microcystin-RR and other algae Organic substances is placed in into installation
Have in the container of negative electrode and anode, and outer meeting resistance is provided between negative electrode and anode；
, at anodic oxidation Organic substance (including Microcystin), the electronics of generation is passed to by external circuit for S2, microorganism
Negative electrode, the proton in solution then by solution medium to movable cathode, with terminal electron acceptor in negative electrode tie by last proton, electronics
Close, complete whole bioelectrochemical electronic transfer process, complete the removal of algae Organic substance.
Wherein, the anode is made up of carbon brush, and negative electrode is the carbon cloth composition for scribbling platinum pt catalyst.
Wherein, the container adopts pmma material, and the container upper end is provided with collection airbag by breather.
The invention has the advantages that：
With reference to the characteristics of microbial treatments and electrochemistry, the same of Microcystin and other algae organic pollutions is being removed
When, electric energy is generated, the recycling of algae organic wastewater resource is realized, the also removal for Microcystin have found one kind
New effective method.
Description of the drawings
Fig. 1 is a kind of structural representation of the system for processing the algae organic wastewater containing Algae toxins of the embodiment of the present invention.
Specific embodiment
In order that objects and advantages of the present invention become more apparent, the present invention is carried out further with reference to embodiments
Describe in detail.It should be appreciated that specific embodiment described herein is not used to limit this only to explain the present invention
It is bright.
As shown in figure 1, a kind of system for processing the algae organic wastewater containing Algae toxins is embodiments provided, including
The algae organic waste containing Algae toxins Microcystin-RR and other algae Organic substances is filled with container 4, the container 4
Water, side is provided with anode 1 in the container 4, and interior opposite side is provided with negative electrode 3, and the anode 1 and negative electrode 3 pass through power line
External circuitses resistance 2 is connected with, the container 4 adopts pmma material, the upper end of the container 4 to be provided with gas collection by breather
Bag 6.
The upper end of the container 4 is additionally provided with changes the mouth of a river 5, changes on the mouth of a river 5 and is connected with lid.
The anode is made up of carbon brush, and negative electrode is the carbon cloth composition for scribbling platinum pt catalyst, and conductive material is titanium silk.
The embodiment of the present invention additionally provides a kind of algae method for processing organic wastewater for processing and containing Algae toxins, including following step
Suddenly：
S1, the algae organic wastewater containing Algae toxins Microcystin-RR and other algae Organic substances is placed in into installation
Have in the container of negative electrode and anode, and outer meeting resistance is provided between negative electrode and anode；
, in anodic oxidation Organic substance, the electronics of generation passes to negative electrode by external circuit, the proton in solution for S2, microorganism
Then by solution medium to movable cathode, last proton, electronics is combined with terminal electron acceptor in negative electrode, completes whole bio electricity
The electronic transfer process of chemistry, completes the removal of algae Organic substance.
The anode is made up of carbon brush, and negative electrode is the carbon cloth composition for scribbling platinum pt catalyst.
The container 4 adopts pmma material, and the upper end of the container 4 is provided with collection airbag 6 by breather.
Originally it is embodied as collecting airbag 6 and can collects algae organic wastewater and ferment in a reservoir produced gas, prevents from sending out
The lid loosening that the gases affect that ferment is produced is produced electricity and changed at water；It is containing Algae toxins Microcystin-RR to be placed in container
And the algae organic wastewater of other algae Organic substances, produced electricity from such waste water first, when resistance is 1000 Europe, produce
Voltage maintains 387mV.New raw material is selected for microbiological fuel cell, the range of application of microbiological fuel cell has been widened；
After testing, through 6 days, Microcystin Microcystin-RR degradation rates are 66%, and COD degradation rate is 37%；Through 12 days,
Microcystin Microcystin-RR degradation rates are 78%, and COD degradation rate is 53.40%.For Microcystin
The removal of Microcystin-RR have found a kind of new method.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (7)
1. a kind of system for processing the algae organic wastewater containing Algae toxins, including container (4), it is characterised in that the container (4)
It is interior filled with the algae organic wastewater containing Algae toxins Microcystin-RR and other algae Organic substances, the container (4)
Interior side is provided with anode (1), and interior opposite side is provided with negative electrode (3), and the anode (1) and negative electrode (3) are connected by power line
There is external circuitses resistance (2), the container (4) adopts pmma material, and the pmma material is polymethylacrylic acid
Formicester, container (4) upper end is provided with collection airbag (6) by breather.
2. the system that a kind of process as claimed in claim 1 contains the algae organic wastewater of Algae toxins, it is characterised in that the appearance
Device (4) upper end is additionally provided with changes the mouth of a river (5), changes on the mouth of a river (5) and is connected with lid.
3. the system that a kind of process as claimed in claim 1 contains the algae organic wastewater of Algae toxins, it is characterised in that the sun
Pole is made up of carbon brush, and negative electrode is the carbon cloth composition for scribbling platinum pt catalyst, and conductive material is titanium silk.
4. it is a kind of to process the algae method for processing organic wastewater containing Algae toxins, it is characterised in that to comprise the steps：
S1, the algae organic wastewater containing Algae toxins Microcystin-RR and other algae Organic substances is placed in the moon is installed
In the container of pole and anode, and outer meeting resistance is provided between negative electrode and anode；
, in anodic oxidation Organic substance, the electronics of generation passes to negative electrode by external circuit, and the proton in solution then leads to for S2, microorganism
Solution medium is crossed to movable cathode, last proton, electronics is combined with terminal electron acceptor in negative electrode, complete whole bio electrochemistry
Electronic transfer process, complete the removal of algae Organic substance.
5. a kind of process as claimed in claim 4 contains the algae method for processing organic wastewater of Algae toxins, it is characterised in that described
Anode is made up of carbon brush, and negative electrode is the carbon cloth composition for scribbling platinum pt catalyst.
6. a kind of process as claimed in claim 4 contains the algae method for processing organic wastewater of Algae toxins, it is characterised in that described
Container (4) adopts pmma material, and the container (4) upper end is provided with collection airbag (6) by breather.
7. a kind of process as claimed in claim 4 contains the algae method for processing organic wastewater of Algae toxins, it is characterised in that walked
Terminal electron acceptor in rapid S2 is air.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610839190.5A CN106565011A (en) | 2016-09-22 | 2016-09-22 | Method and system for treating Microcystin-containing algae organic wastewater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610839190.5A CN106565011A (en) | 2016-09-22 | 2016-09-22 | Method and system for treating Microcystin-containing algae organic wastewater |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106565011A true CN106565011A (en) | 2017-04-19 |
Family
ID=58531895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610839190.5A Pending CN106565011A (en) | 2016-09-22 | 2016-09-22 | Method and system for treating Microcystin-containing algae organic wastewater |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106565011A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060096915A1 (en) * | 2004-11-11 | 2006-05-11 | Hitachi Plant Engineering & Construction Co., Ltd. | Method and equipment for treating microcystin-containing water |
| CN103626299A (en) * | 2013-12-10 | 2014-03-12 | 环境保护部南京环境科学研究所 | Method for cooperatively controlling microcystis aeruginosa and purifying water quality by using Plagiognathops microlepis, hyriopsis cumingii, Bellamya aeruginosa and calamus |
| CN104112868A (en) * | 2014-06-11 | 2014-10-22 | 武汉大学 | Constructing method and device for single-chamber medium-free algae microbial fuel cell |
| CN105084554A (en) * | 2015-08-11 | 2015-11-25 | 北京大学深圳研究生院 | Method and device for removing microcystic toxins in water |
| CN206033362U (en) * | 2016-09-22 | 2017-03-22 | 中南大学 | Alga organic wastewater device |
-
2016
- 2016-09-22 CN CN201610839190.5A patent/CN106565011A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060096915A1 (en) * | 2004-11-11 | 2006-05-11 | Hitachi Plant Engineering & Construction Co., Ltd. | Method and equipment for treating microcystin-containing water |
| CN103626299A (en) * | 2013-12-10 | 2014-03-12 | 环境保护部南京环境科学研究所 | Method for cooperatively controlling microcystis aeruginosa and purifying water quality by using Plagiognathops microlepis, hyriopsis cumingii, Bellamya aeruginosa and calamus |
| CN104112868A (en) * | 2014-06-11 | 2014-10-22 | 武汉大学 | Constructing method and device for single-chamber medium-free algae microbial fuel cell |
| CN105084554A (en) * | 2015-08-11 | 2015-11-25 | 北京大学深圳研究生院 | Method and device for removing microcystic toxins in water |
| CN206033362U (en) * | 2016-09-22 | 2017-03-22 | 中南大学 | Alga organic wastewater device |
Non-Patent Citations (1)
| Title |
|---|
| 刘晓烨等: "《环境工程微生物学研究技术与方法》", 31 August 2011, 哈尔滨工业大学出版社, pages: 115 * |
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