CN106558424A - 磺化氧化石墨烯/二氧化锰/聚吡咯复合材料的制备方法 - Google Patents
磺化氧化石墨烯/二氧化锰/聚吡咯复合材料的制备方法 Download PDFInfo
- Publication number
- CN106558424A CN106558424A CN201611039185.2A CN201611039185A CN106558424A CN 106558424 A CN106558424 A CN 106558424A CN 201611039185 A CN201611039185 A CN 201611039185A CN 106558424 A CN106558424 A CN 106558424A
- Authority
- CN
- China
- Prior art keywords
- manganese dioxide
- graphene oxide
- graphene
- solution
- mno
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 78
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 69
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 229920000128 polypyrrole Polymers 0.000 title claims abstract description 28
- 239000002131 composite material Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000084 colloidal system Substances 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 16
- 238000006277 sulfonation reaction Methods 0.000 claims abstract description 16
- 238000012695 Interfacial polymerization Methods 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
- 150000003233 pyrroles Chemical class 0.000 claims description 38
- 239000012286 potassium permanganate Substances 0.000 claims description 23
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 claims description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 16
- 229910052804 chromium Inorganic materials 0.000 claims description 16
- 239000011651 chromium Substances 0.000 claims description 16
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 16
- 239000003643 water by type Substances 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 229910052748 manganese Inorganic materials 0.000 claims description 11
- 239000011572 manganese Substances 0.000 claims description 11
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 10
- 239000004408 titanium dioxide Substances 0.000 claims description 9
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 235000010288 sodium nitrite Nutrition 0.000 claims description 8
- 229950000244 sulfanilic acid Drugs 0.000 claims description 8
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 claims 1
- 239000003205 fragrance Substances 0.000 claims 1
- 239000007772 electrode material Substances 0.000 abstract description 6
- 239000003990 capacitor Substances 0.000 abstract description 5
- ZAJAQTYSTDTMCU-UHFFFAOYSA-N 3-aminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1 ZAJAQTYSTDTMCU-UHFFFAOYSA-N 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 150000001336 alkenes Chemical class 0.000 description 8
- 229910002804 graphite Inorganic materials 0.000 description 7
- 239000010439 graphite Substances 0.000 description 7
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000012983 electrochemical energy storage Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- -1 manganese dioxide composites Graphite alkene Chemical class 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/46—Metal oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/48—Conductive polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Carbon And Carbon Compounds (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nanotechnology (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611039185.2A CN106558424B (zh) | 2016-11-24 | 2016-11-24 | 磺化氧化石墨烯/二氧化锰/聚吡咯复合材料的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611039185.2A CN106558424B (zh) | 2016-11-24 | 2016-11-24 | 磺化氧化石墨烯/二氧化锰/聚吡咯复合材料的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106558424A true CN106558424A (zh) | 2017-04-05 |
CN106558424B CN106558424B (zh) | 2018-05-08 |
Family
ID=58444466
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201611039185.2A Active CN106558424B (zh) | 2016-11-24 | 2016-11-24 | 磺化氧化石墨烯/二氧化锰/聚吡咯复合材料的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106558424B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115465924A (zh) * | 2022-09-19 | 2022-12-13 | 西安泰金工业电化学技术有限公司 | 一种PPy/GO/MnO2纳米复合电极、制备方法及应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120028127A1 (en) * | 2010-07-29 | 2012-02-02 | Nokia Corporation | Apparatus and associated methods |
CN105070527A (zh) * | 2015-08-27 | 2015-11-18 | 桂林理工大学 | 石墨烯/聚吡咯/二氧化锰三元复合电极材料的制备方法 |
-
2016
- 2016-11-24 CN CN201611039185.2A patent/CN106558424B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120028127A1 (en) * | 2010-07-29 | 2012-02-02 | Nokia Corporation | Apparatus and associated methods |
CN105070527A (zh) * | 2015-08-27 | 2015-11-18 | 桂林理工大学 | 石墨烯/聚吡咯/二氧化锰三元复合电极材料的制备方法 |
Non-Patent Citations (1)
Title |
---|
肖毓秀: "印制式石墨烯基微型超级电容器的研究", 《中国优秀硕士学位论文全文数据库工程科技II辑》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115465924A (zh) * | 2022-09-19 | 2022-12-13 | 西安泰金工业电化学技术有限公司 | 一种PPy/GO/MnO2纳米复合电极、制备方法及应用 |
CN115465924B (zh) * | 2022-09-19 | 2024-03-26 | 西安泰金新能科技股份有限公司 | 一种PPy/GO/MnO2纳米复合电极、制备方法及应用 |
Also Published As
Publication number | Publication date |
---|---|
CN106558424B (zh) | 2018-05-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105070527B (zh) | 石墨烯/聚吡咯/二氧化锰三元复合电极材料的制备方法 | |
Wei et al. | All pseudocapacitive MXene-MnO2 flexible asymmetric supercapacitor | |
Fan et al. | Fe3O4@ carbon nanosheets for all-solid-state supercapacitor electrodes | |
Kang et al. | Investigating metal-organic framework as a new pseudo-capacitive material for supercapacitors | |
Hu et al. | High-capacitance mechanism for Ti3C2 T x MXene by in situ electrochemical Raman spectroscopy investigation | |
Wang et al. | Three-dimensional macroporous carbon/Fe3O4-doped porous carbon nanorods for high-performance supercapacitor | |
Patil et al. | Fern-like rGO/BiVO4 hybrid nanostructures for high-energy symmetric supercapacitor | |
Ren et al. | Functionalization of biomass carbonaceous aerogels: selective preparation of MnO2@ CA composites for supercapacitors | |
Li et al. | Facile synthesis of MnO2/CNTs composite for supercapacitor electrodes with long cycle stability | |
Saravanakumar et al. | Interconnected V2O5 nanoporous network for high-performance supercapacitors | |
Kong et al. | Three-dimensional NiCo2O4@ polypyrrole coaxial nanowire arrays on carbon textiles for high-performance flexible asymmetric solid-state supercapacitor | |
Wu et al. | Preparation of novel three-dimensional NiO/ultrathin derived graphene hybrid for supercapacitor applications | |
Li et al. | Carbon/MnO2 double-walled nanotube arrays with fast ion and electron transmission for high-performance supercapacitors | |
Rafique et al. | Highly uniform anodically deposited film of MnO2 nanoflakes on carbon fibers for flexible and wearable fiber-shaped supercapacitors | |
Yang et al. | Facile synthesis of nitrogen-doped graphene–ultrathin MnO2 sheet composites and their electrochemical performances | |
Chen et al. | Microwave–hydrothermal crystallization of polymorphic MnO2 for electrochemical energy storage | |
Yang et al. | High-performance all-solid-state supercapacitor based on the assembly of graphene and manganese (II) phosphate nanosheets | |
Nonaka et al. | Crumpled graphene decorated with manganese ferrite nanoparticles for hydrogen peroxide sensing and electrochemical supercapacitors | |
CN106531472B (zh) | 一种聚吡咯/石墨烯/锰氧化物复合材料的制备方法 | |
Abuzeid et al. | Facile, cost-effective and eco-friendly green synthesis method of MnO2 as storage electrode materials for supercapacitors | |
Xue et al. | Zeolitic imidazolate frameworks (ZIFs)-derived NixCo3− xO4/CNTs nanocomposites with enhanced electrochemical performance for supercapacitor | |
Chen et al. | Preparation of polyaniline onto dl-tartaric acid assembled MXene surface as an electrode material for supercapacitors | |
JP2014501028A (ja) | 複合電極材及びその製造方法、並びに応用 | |
Chen et al. | Simple synthesis of flower-like manganese dioxide nanostructures on cellulose nanocrystals for high-performance supercapacitors and wearable electrodes | |
CN104021948B (zh) | 纳米纤维状三维氢氧化镍/碳纳米管复合材料及其制备方法和应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20170405 Assignee: Guilin Qi Hong Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044172 Denomination of invention: Preparation method of sulfonated graphene oxide/manganese dioxide/polypyrrole composite material Granted publication date: 20180508 License type: Common License Record date: 20231024 |
|
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20170405 Assignee: Sales and Operation Department of Qiyue Paper Products in Xixiangtang District, Nanning Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044309 Denomination of invention: Preparation method of sulfonated graphene oxide/manganese dioxide/polypyrrole composite material Granted publication date: 20180508 License type: Common License Record date: 20231027 |
|
EE01 | Entry into force of recordation of patent licensing contract |