CN106554187A - A kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete - Google Patents

A kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete Download PDF

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Publication number
CN106554187A
CN106554187A CN201611113167.4A CN201611113167A CN106554187A CN 106554187 A CN106554187 A CN 106554187A CN 201611113167 A CN201611113167 A CN 201611113167A CN 106554187 A CN106554187 A CN 106554187A
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CN
China
Prior art keywords
concrete
flyash
phosphorus slag
cement
ceramsite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611113167.4A
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Chinese (zh)
Inventor
刘秋美
李彩玉
杨林
杨江红
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Guizhou Institute of Technology
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Guizhou Institute of Technology
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Publication date
Application filed by Guizhou Institute of Technology filed Critical Guizhou Institute of Technology
Priority to CN201611113167.4A priority Critical patent/CN106554187A/en
Publication of CN106554187A publication Critical patent/CN106554187A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials

Abstract

The invention discloses a kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, it is characterised in that per 1m3Each raw material dosage of haydite concrete is:Binder Materials 510kg, net duty of water 200kg, pottery sand 364kg, haydite 331kg, water reducer for cement mixing content 0.8~1.2%, the length for mixing 1.8%~2.2% are the polypropylene fibre of 15mm, in the Binder Materials, cement accounts for 40~60%, and phosphorus slag powder accounts for 20~30%, and flyash accounts for 20~40%.Phosphorus slag powder, flyash are replaced cement to mix in ceramsite concrete light-weight concrete as mixing material large dosage by the present invention, recycling, profit are useless completely, reduce water pollution and energy-saving green ecological product, so the present invention is to take full advantage of industrial solid castoff, greatly reduce production cost, environmental pollution is reduced, with notable Technological Economy meaning.

Description

A kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete
Technical field
The present invention relates to a kind of ceramsite concrete light-weight concrete, and in particular to a kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete.
Background technology
Phosphorus slag is a kind of solid slag produced during Yellow Phosphorous Plant extracts yellow phosphorus;Flyash is by coal-burning power plant's chimney The solid emission of collection;All it is the larger industrial solid castoff of discharge, all containing substantial amounts of SiO2And Al2O3, with potential The hydraulicity, in concrete can a large amount of recycles, reducing energy consumption, reduce cement consumption, improve concrete performance, protection ring The aspects such as border play actively significant effect.Ardealite is to prepare phosphoric acid using Wet Processes of Phosphoric Acid sulphuric acid and rock phosphate in powder reaction The side-product for obtaining.The trade waste resources such as extensive effectively utilizes phosphorus slag, flyash, reduce environmental pollution, give full play to The effect of trade waste and reduce the consumption of cement to reduce the production cost of concrete, be to need what is further solved to ask Topic.
The content of the invention
To solve the above problems, the invention provides a kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, using cement, Phosphorus slag, flyash as composite gelled material, haydite and pottery sand as light aggregate, by adding water reducer and polypropylene fibre Further improve the performances such as its mechanical property, water absorption and coefficient of softing, prepare insulation, sound insulation, environmental protection it is light Matter concrete.Environmental conservation and building energy conservation be nation-building it is new society key link, phosphorus slag flyash-haydite concrete Compared with normal concrete with from heavy and light, heat-insulated, sound insulation and heat insulation effect, under the requirement for meeting design strength, general deadweight drop It is low by 30%~40%, with significant economical, societal benefits and environmental benefit.
For achieving the above object, the technical scheme taken of the present invention is:
A kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, per 1m3Each raw material dosage of haydite concrete is:Gelling material Material 510kg, net duty of water 200kg, pottery sand 364kg, haydite 331kg, water reducer are the 0.8~1.2% of cement mixing content, mix Polypropylene fibre of 1.8%~2.2% length for 15mm, in the Binder Materials, cement accounts for 40~60%, and phosphorus slag powder accounts for 20 ~30%, flyash accounts for 20~40%.
Preferably, the water reducer accounts for the 1.0% of Binder Materials.
Preferably, the volume of polypropylene fibre is 2.0%.
Preferably, the cement adopts composite Portland cement, and strength grade is 42.5, and apparent density is 3100kg/m.
Preferably, the fineness of phosphorus slag powder is more than 350m2/ kg, apparent density are 2850kg/m3
Preferably, 18~45 μm of the diameter of the polypropylene fibre, cross sectional shape are Y shape, and burning-point is 590 DEG C, density 0.91gcm3, extension at break degree 5~15%, 260~680MPa of tensile strength, 4~9GPa of elastic modelling quantity, hydroscopicity < 0.1%.
The invention has the advantages that:
Compared with prior art, phosphorus slag powder, flyash are replaced cement to mix pottery as mixing material large dosage by the present invention In grain lightweight concrete, complete recycling, profit are useless, reduce water pollution and energy-saving green ecological product, so this Bright is to take full advantage of industrial solid castoff, greatly reduces production cost, reduces environmental pollution.
Phosphorus slag that the present invention is prepared, lytag lightweight concrete, can be used as roofing and non-bearing wall body, and it is big across Degree bridge and the medium engineering of skyscraper.Not only turn waste into wealth, turn harm into good, and mitigate environmental pollution, save a large amount of soils, With notable Technological Economy meaning.
Specific embodiment
In order that objects and advantages of the present invention become more apparent, with reference to embodiments the present invention is carried out further Describe in detail.It should be appreciated that specific embodiment described herein is not used to limit this only to explain the present invention It is bright.
Raw material used in following examples is:
Cement:Composite Portland cement, strength grade are 42.5, and apparent density is 3100kg/m3
Phosphorus slag powder:Fineness is more than 350m2/ kg, apparent density are 2850kg/m3, less than cement 3100kgm~3, mixed It can be the weight for reducing concrete phosphorus slag powder part to be mixed in coagulating soil and substitutes cement, but a small amount of due to containing in phosphorus slag powder P2O5Cement setting time can be extended with F, so volume is general no more than 40%.
Flyash:Apparent density be 2420kgm~3, less than phosphorus slag powder 2850kgm~3With cement 3100kgm ~3, it is the lighting for being very beneficial for increasing concrete that flyash is mixed in concrete.Although doping quantity of fly ash is bigger, mix The more of soil weight reduction are coagulated, but volume is excessive, also results in mechanical performance of concrete etc. and drastically declines, while also needing to ensure Certain curing age.
Water reducer:The high-performance polycarboxylic acids water reducing agent of outstanding person's new material company limited production of Guizhou section, weak yellow liquid subtract Water rate is 25%~30%.
Polypropylene fibre:Outsourcing, the production of Tai'an modern plastics company limited, fibre length 15mm, 18~45 μ of diameter M, cross sectional shape is Y shape, and burning-point is 590 DEG C, density 0.91gcm3, extension at break degree 5~15%, tensile strength 260~ 680MPa, 4~9GPa of elastic modelling quantity, hydroscopicity < 0.1%.
Embodiment 1
A kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, per 1m3Each raw material dosage of haydite concrete is:Gelling material Material 510kg, net duty of water 200kg, pottery sand 364kg, haydite 331kg, water reducer are the 0.8~1.2% of cement mixing content, mix Polypropylene fibre of 1.8%~2.2% length for 15mm, in the Binder Materials, cement accounts for 40~60%, and phosphorus slag powder accounts for 20 ~30%, flyash accounts for 20~40%.
Embodiment 2
A kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, per 1m3Each raw material dosage of haydite concrete is:Gelling material Material 510kg, net duty of water 200kg, pottery sand 364kg, haydite 331kg, water reducer are the 1.0% of cement mixing content, mix 2.0% length The polypropylene fibre for 15mm is spent, cement accounts for 40~60% in the Binder Materials, and phosphorus slag powder accounts for 20~30%, and flyash accounts for 20 ~40%.
Prepare the technique of lightweight concrete mainly include prewetting haydite, haydite, pottery sand to mix with Binder Materials, and pour into Type.Detailed process flow is
Pre-wetted treatment is carried out to lightweight aggregate, that is, a certain amount of haydite is weighed in bucket, to add water and do not had haydite up to water, soak Open fire is filtered off after 1d, nature is spread out and is dried to saturated dry surface.Then first with forced stirrer by the lightweight aggregate prewetted and glue Gel material after stir about 1min, adds water and continues stirring 2min together.Then pour into place in mould and vibrate on a vibration table 0.5min, it is closely knit to use trowel smooth out surface afterwards, precuring 24h in the curing box under standard conditions is put into, in examination body surface after form removal Bread wraps up in one layer of preservative film, continues to be placed in curing box to conserve to regulation age and takes out.
Phosphorus slag, flyash and ceramsite concrete light-weight concrete have high-strength light, insulation, antidetonation, cracking resistance, good endurance, Fire resistance is good, alkali resistant aggregate reaction is good, is mainly used in roofing and non-bearing wall body, and Longspan Bridge and skyscraper In.Phosphorus slag, flyash and ceramsite concrete light-weight concrete can use the trade waste resources such as phosphorus slag, flyash with large-scale recovery, The production cost of lightweight concrete is reduced, with significant economical, societal benefits and environmental benefit.
The present invention is satisfied by JGJ 51~2002 using indexs such as the intensity and density for measuring《Lightweight aggregate concrete technology is advised Journey》Standard requirement, the analysis by test and to result, per 1m3In haydite concrete:Binder Materials 510kg, net duty of water 200kg, pottery sand 364kg, haydite 331kg, water reducer for cement mixing content 1.0% mix the polypropylene that 2.0% length is 15mm fine During dimension, the rupture strength of ceramsite concrete light-weight concrete, comprcssive strength, water absorption rate and shrinkage value reach optimum.Using these most Good volume prepare 1100kgm~3Lightweight concrete, its heat conductivity be 0.26W/ (mK)~1, lead with good It is hot.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (6)

1. a kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, it is characterised in that per 1m3Each raw material dosage of haydite concrete For:Binder Materials 510kg, net duty of water 200kg, pottery sand 364kg, haydite 331kg, water reducer for cement mixing content 0.8~ 1.2%, the length for mixing 1.8%~2.2% is the polypropylene fibre of 15mm, and in the Binder Materials, cement accounts for 40~60%, phosphorus Ground-slag accounts for 20~30%, and flyash accounts for 20~40%.
2. as claimed in claim 1 a kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, it is characterised in that the water reducer Account for the 1.0% of Binder Materials.
3. as claimed in claim 1 a kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, it is characterised in that polypropylene fibre Volume be 1.8%~2.0%.
4. as claimed in claim 1 a kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, it is characterised in that the cement is adopted With composite Portland cement, strength grade is 42.5, and apparent density is 3100kg/m.
5. as claimed in claim 1 a kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, it is characterised in that phosphorus slag powder it is thin Degree is more than 350m2/ kg, apparent density are 2850kg/m3
6. as claimed in claim 1 a kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete, it is characterised in that the polypropylene 18~45 μm of the diameter of fiber, cross sectional shape is Y shape, and burning-point is 590 DEG C, density 0.91gcm3, extension at break degree 5~ 15%, 260~680MPa of tensile strength, 4~9GPa of elastic modelling quantity, hydroscopicity < 0.1%.
CN201611113167.4A 2016-12-06 2016-12-06 A kind of phosphorus slag, flyash and ceramsite concrete light-weight concrete Pending CN106554187A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117348A (en) * 2017-12-22 2018-06-05 中建西部建设贵州有限公司 A kind of phosphorus slag base environment-friendly type construction material and preparation method thereof
CN112962814A (en) * 2021-02-05 2021-06-15 方圆建设集团有限公司 Novel steel pipe heat-insulation composite hollow wall and production process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1530501A (en) * 2003-03-10 2004-09-22 张英保 Light cast-in-situs concrete wallboard
CN103951350A (en) * 2014-04-25 2014-07-30 中南大学 Lightweight aggregate concrete for heat preservation of structures
CN105084833A (en) * 2015-08-06 2015-11-25 重庆科技学院 High-strength thermal insulation full lightweight concrete and preparation method and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1530501A (en) * 2003-03-10 2004-09-22 张英保 Light cast-in-situs concrete wallboard
CN103951350A (en) * 2014-04-25 2014-07-30 中南大学 Lightweight aggregate concrete for heat preservation of structures
CN105084833A (en) * 2015-08-06 2015-11-25 重庆科技学院 High-strength thermal insulation full lightweight concrete and preparation method and application thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
应小洋: "泵送轻骨料混凝土的研究", 《浙江建筑》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117348A (en) * 2017-12-22 2018-06-05 中建西部建设贵州有限公司 A kind of phosphorus slag base environment-friendly type construction material and preparation method thereof
CN108117348B (en) * 2017-12-22 2019-11-22 中建西部建设贵州有限公司 A kind of phosphorus slag base environment-friendly type construction material and preparation method thereof
CN112962814A (en) * 2021-02-05 2021-06-15 方圆建设集团有限公司 Novel steel pipe heat-insulation composite hollow wall and production process thereof

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