CN106544553A - A kind of method of REINFORCED Al Si alloy piston high-temperature behavior - Google Patents
A kind of method of REINFORCED Al Si alloy piston high-temperature behavior Download PDFInfo
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- CN106544553A CN106544553A CN201610989691.1A CN201610989691A CN106544553A CN 106544553 A CN106544553 A CN 106544553A CN 201610989691 A CN201610989691 A CN 201610989691A CN 106544553 A CN106544553 A CN 106544553A
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- Prior art keywords
- alloy
- reinforced
- temperature
- piston
- temperature behavior
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Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
- C22C21/04—Modified aluminium-silicon alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/06—Making non-ferrous alloys with the use of special agents for refining or deoxidising
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F3/00—Pistons
- F02F3/0084—Pistons the pistons being constructed from specific materials
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2201/00—Metals
- F05C2201/90—Alloys not otherwise provided for
- F05C2201/903—Aluminium alloy, e.g. AlCuMgPb F34,37
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
Abstract
The invention discloses a kind of method of REINFORCED Al Si alloy piston high-temperature behavior, it is characterized in that, add Ni, Fe and Cr in its Al for adopting Si alloy, the alloy contains Si 12 14%, Cu 0.05 0.1%, Mg 0.3 1.2% by weight percentage, Ni 1.5 4%, Fe 0.4 1.4%, Cr 0.5 1.5%, Al surpluses.The present invention is by adding specific elemental constituent in Al Si alloys so that the high-temperature behavior of Al Si alloy pistons is greatly improved.
Description
Technical field
The present invention relates to technical field of alloy, more particularly to a kind of method of REINFORCED Al-Si alloy piston high-temperature behaviors.
Background technology
With the increasingly lifting of living standards of the people, effect of the automobile in people's lives also more and more higher.The core of automobile
Heart technology is electromotor, in fact the key of automotive performance.Piston-mode motor is the one kind in internal combustion engine, and which relies on piston to exist
Move reciprocatingly in cylinder, make gas working medium complete thermodynamic cycle, and the part chemical energy of fuel is converted into into the dynamic of mechanical energy
Power apparatus.
Piston is one of important part in electromotor, and its effect is subject to gaseous-pressure, and by piston pin by energy
Amount is passed to connecting rod and drives Crankshaft motion.When the engine operates, piston is direct more than 2000 DEG C of high-temperature fuel gas with transient temperature
Contact, even more than 400 DEG C of the temperature of top land, and temperature distributing disproportionation is even, while top land holds in working stroke
Very big gaseous-pressure, gasoline engine is received to reach 3MPa-5MPa, diesel engine is then up to 9MPa-15MPa, even more high.Additionally, living
Plug in the cylinder reciprocating linear velocity up to 6m/s-16m/s.As can be seen here, the work under bad environment of piston, while bearing
High pressure, the mechanical load of High Temperature And Velocity and thermic load.The high-temperature behavior enough to its material requirements of piston in the environment.
Al-Si alloys are most widely used in piston, with the rising of operating ambient temperature, Al-Si systems piston material
Intensity decline quickly, particularly after temperature is more than 300 DEG C, the downward trend of its intensity is particularly violent.
The content of the invention
It is an object of the invention to propose a kind of method of REINFORCED Al-Si alloy piston high-temperature behaviors, Al-Si can be lifted
The high-temperature behavior of piston.
It is that, up to this purpose, the present invention is employed the following technical solutions:
A kind of method of REINFORCED Al-Si alloy piston high-temperature behaviors, it is characterised in that in its Al-Si for adopting alloy
Addition Ni, Fe and Cr, the alloy contain Si 12-14%, Cu 0.05-0.1%, Mg 0.3-1.2% by weight percentage,
Ni 1.5-4%, Fe 0.4-1.4%, Cr 0.5-1.5%, Al surpluses.
Tensile strength UTS (350 DEG C) of the above-mentioned alloy at 350 DEG C is in 215MPa or so, the Al-Si with other Ni contents
Alloy compares, and the content of the present invention can obtain more δ-Al3CuNi phases.δ-Al3CuNi phases are in often ribbon shape
Looks, which forms block and γ-Al compared to ε-Al3Ni7Cu4Ni, with higher volume utilization, has in three kinds of nickel-rich phases
There is highest elevated temperature strength contribution rate.
In the alloy of the present invention, by adding Cr and Fe, α-Al (Fe, Cr) Si phases are formed, assisted and strengthened effect is played,
With the nickel-rich phase δ-Al as main hardening constituent3CuNi phases combine.Simultaneously as δ-Al3CuNi phase solid solutions Cr, Si and Fe
Pattern changes so that heat-resisting intermetallic compound net has encased α-Al crystal grain, so as to form the net of semi-enclosed closing
Shape eutectic cell, can prevent the sliding of crystal boundary well in high temperature, lift the high-temperature behavior of piston.
A small amount of Mg is individually added in Al-Si alloys and forms Mg2Si hardening constituents.During quenching, Mg2Si is incorporated in αsolidsolution,
Form dispersion phase precipitation after Ageing Treatment again so that the crystalline temperature battle array of αsolidsolution is distorted, and so as to reinforced alloys, significantly carries
High intensity, but alloy elongation percentage can decline.
Cu can improve the hardness and mechanical behavior under high temperature of aluminium alloy, and its solid solution effect can also improve the anti-tired of aluminium alloy
Labor intensity.But as the chemical potential of Cu is higher than Al, intercrystalline corrosion and stress corrosion are also easy to produce, reduce the corrosion resistance of aluminium alloy.
In the present invention, while adding Cu and Mg, W hardening constituent (Al are formed in aluminium alloyxMg5Si4Cu4), compare Mg2Si
And CuAl2Phase, the reinforcing effect of W phases preferably, can significantly promote the raising of alloy mechanical property.But Cu and Mg is in Al-Si alloys
In total amount it is very few, reinforcing effect is just little, but total amount is too high, causes the plasticity of alloy to be deteriorated again.Therefore the present invention selects Cu
0.5-2.5%, Mg 0.3-1.2%.
Used as optimal technical scheme, the alloy of the present invention is rotten preferably through P-Sr composite inoculatings technique.
The present invention is by adding specific elemental constituent in Al-Si alloys so that the high-temperature behavior of Al-Si alloy pistons
It is greatly improved.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
Embodiment 1
A kind of method of REINFORCED Al-Si alloy piston high-temperature behaviors, it is characterised in that in its Al-Si for adopting alloy
Addition Ni, Fe and Cr, the alloy contain Si 12%, Cu 0.05%, Mg0.3%, Ni 1.5%, Fe by weight percentage
0.4%, Cr 0.5%, Al surplus.
1 said method of embodiment, by adding special component in the alloy so that high temperature (350 DEG C) Tensile strength is big
Width is improved.
Embodiment 2
A kind of method of REINFORCED Al-Si alloy piston high-temperature behaviors, it is characterised in that in its Al-Si for adopting alloy
Addition Ni, Fe and Cr, the alloy contain Si 13%, Cu 0.08%, Mg0.8%, Ni 2.6%, Fe by weight percentage
0.9%, Cr 0.9%, Al surplus.
Said method, by adding special component in the alloy so that high temperature (350 DEG C) Tensile strength is greatly improved.
Embodiment 3
A kind of method of REINFORCED Al-Si alloy piston high-temperature behaviors, it is characterised in that in its Al-Si for adopting alloy
Addition Ni, Fe and Cr, the alloy contain Si 14%, Cu 0.1%, Mg 1.2%, Ni 4%, Fe by weight percentage
1.4%, Cr 1.5%, Al surplus.
Said method, by adding special component in the alloy so that high temperature (350 DEG C) Tensile strength is greatly improved.
Claims (2)
1. a kind of method of REINFORCED Al-Si alloy piston high-temperature behaviors, it is characterised in that add in its Al-Si for adopting alloy
Plus Ni, Fe and Cr, the alloy is by weight percentage containing Si 12-14%, Cu 0.05-0.1%, Mg 0.3-1.2%, Ni
1.5-4%, Fe 0.4-1.4%, Cr 0.5-1.5%, Al surpluses.
2. the method for REINFORCED Al-Si alloy piston high-temperature behaviors according to claim 1, it is characterised in that the alloy
Through P-Sr composite inoculatings.
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CN201610989691.1A CN106544553A (en) | 2016-11-10 | 2016-11-10 | A kind of method of REINFORCED Al Si alloy piston high-temperature behavior |
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CN201610989691.1A CN106544553A (en) | 2016-11-10 | 2016-11-10 | A kind of method of REINFORCED Al Si alloy piston high-temperature behavior |
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CN201610989691.1A Pending CN106544553A (en) | 2016-11-10 | 2016-11-10 | A kind of method of REINFORCED Al Si alloy piston high-temperature behavior |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112375942A (en) * | 2020-10-26 | 2021-02-19 | 宁波德业粉末冶金有限公司 | Combined type intelligence bumper shock absorber piston |
Citations (6)
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US20040170523A1 (en) * | 2003-01-23 | 2004-09-02 | Hubert Koch | Casting alloy |
CN1609248A (en) * | 2003-10-17 | 2005-04-27 | 株式会社丰田中央研究所 | Aluminum alloys for casting, aluminum alloy castings and manufacturing method thereof |
CN102560206A (en) * | 2012-02-27 | 2012-07-11 | 安徽省恒泰动力科技有限公司 | Rare-earth aluminum alloy piston material and preparation method thereof |
CN103328668A (en) * | 2011-01-27 | 2013-09-25 | 日本轻金属株式会社 | High electric resistance aluminum alloy |
US20160138137A1 (en) * | 2014-11-19 | 2016-05-19 | Hyundai Motor Company | Aluminum alloy for engine piston of automobile and method for producing the same |
-
2016
- 2016-11-10 CN CN201610989691.1A patent/CN106544553A/en active Pending
Patent Citations (6)
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US20040170523A1 (en) * | 2003-01-23 | 2004-09-02 | Hubert Koch | Casting alloy |
CN1450185A (en) * | 2003-05-07 | 2003-10-22 | 东华大学 | Hypereutectoid alpax with eutectic structure and technological method thereof |
CN1609248A (en) * | 2003-10-17 | 2005-04-27 | 株式会社丰田中央研究所 | Aluminum alloys for casting, aluminum alloy castings and manufacturing method thereof |
CN103328668A (en) * | 2011-01-27 | 2013-09-25 | 日本轻金属株式会社 | High electric resistance aluminum alloy |
CN102560206A (en) * | 2012-02-27 | 2012-07-11 | 安徽省恒泰动力科技有限公司 | Rare-earth aluminum alloy piston material and preparation method thereof |
US20160138137A1 (en) * | 2014-11-19 | 2016-05-19 | Hyundai Motor Company | Aluminum alloy for engine piston of automobile and method for producing the same |
Non-Patent Citations (1)
Title |
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李云国: "《Al-Si-Cu-Ni-Mg系活塞合金高温强化相的研究》", 《中国优秀硕士学位论文全文数据库(工程科技1辑)》 * |
Cited By (1)
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CN112375942A (en) * | 2020-10-26 | 2021-02-19 | 宁波德业粉末冶金有限公司 | Combined type intelligence bumper shock absorber piston |
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Application publication date: 20170329 |