CN106544168A - A kind of leatherware surface ballpoint pen oil abluent and preparation method thereof - Google Patents
A kind of leatherware surface ballpoint pen oil abluent and preparation method thereof Download PDFInfo
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- CN106544168A CN106544168A CN201610845717.5A CN201610845717A CN106544168A CN 106544168 A CN106544168 A CN 106544168A CN 201610845717 A CN201610845717 A CN 201610845717A CN 106544168 A CN106544168 A CN 106544168A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0031—Carpet, upholstery, fur or leather cleansers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
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Abstract
The present invention relates to a kind of leatherware surface ballpoint pen oil abluent and preparation method thereof.The present invention is according to basic components, it is added without cosurfactant, cosolvent, add anion surfactant AES, anion surfactant AES and nonionic surfactant AEO 9, the synergism of OP 10 are played, is changed the content of AES, is made cleaning agent formula, carry out the test of cleaning rate, cleaning rate is improved, cleaning rate is improved to 90% by 80%, and cleaning rate change is little after 8% when AES contents.
Description
Technical field
The present invention relates to a kind of abluent and preparation method thereof, especially a kind of leatherware abluent, specifically a kind of
It is adapted to the leatherware abluent of the ballpoint pen oil on removing leatherware surface.
Background technology
With the improvement of people's living standards, increasing people use leatherware product, for example leather sofa, skin chair, skin bed,
The real leather products such as suitcase, fur clothing, leather shoes, leather glove, corium cell-phone cover, automotive trim product.Leatherware uses long, can usually run into this
The situation of sample：Beautiful suitcase, fur clothing imprudence by ball stroke once or it is several under, leave together or a few road ball pens
Mark, and affect attractive in appearance.To remove this few road cut, people are frequently with following three kinds of methods：First, directly send Leather maintenance shop.2nd,
Cleaned using life general knowledge.3rd, special leather cleaning agent or nursing agent are bought.People will not be together or several mostly
The person's handwriting in road specially go Leather maintenance shop, purchase special caring agent, Selection utilization existence general knowledge cleaning ballpoint pen oil person's handwriting compared with
It is many, but easily make person's handwriting be extended to dizzy shape after processing, cause certain damage, affect attractive in appearance to leatherware product.In addition,
At some using the meeting room of skin chair, classroom, after several years, ballpoint pen oil is scribbled seriously, and which has been cleaned into a big problem.
The main component of ballpoint pen oil is organic dyestuff, the auxiliary agents such as benzyl alcohol, phenyl phenol, resin, phthalocyanine blue etc..Skin
Leather is made by Jing depilations and the not perishable animal skins of degeneration obtained by the physics such as tanning, chemical process, leather be by
Natural protein fibre is constituted in three dimensions close weave, and there is a kind of special grain layer on its surface, with natural grain
Stricture of vagina and gloss, comfortable feel.When ballpoint pen oil has been infected with the leatherware goods by made by leather, due to phthalocyanine blue dyestuff performance it is steady
The features such as fixed, bright in colour, strong coloring force, good fast light heat-resisting, solvent resistance, certain difficulty is brought to cleaning, according to inventor
It is known, there is no a kind of suitable abluent for removing ballpoint pen oil on leatherware available at present.
The content of the invention
The purpose of the present invention is the cleaning problem for ballpoint pen oil in leatherware goods, invents a kind of leatherware surface ball pen
Oily abluent.
The technical solution used in the present invention is：The present invention includes the surfactant containing AES.
Also include the cosurfactant containing miscellaneous oleyl alcohol.
Also include diethylene glycol monobutyl ether, the cosolvent of formal mixture.
Including following components（Measure in parts by weight）：
Surfactant：Anion surfactant fatty alcohol-polyoxyethylene ether AEO-9, zwitterionic surfactant octyl
The mixture 7-20% of phenol polyoxyethylene ether OP-10, polyoxyethylenated alcohol sodium sulfate AES；
Cosurfactant：Miscellaneous oleyl alcohol 0-3%；
Cosolvent：The mixture 0-10% of diethylene glycol monobutyl ether, formal；
Water solublity lanoline 0-2%；
Oleyl alcohol ether 0.5-2%；
Remaining is solvent：The mixture of water and ethanol.
Including following components：
| Raw material | W% |
| Acetylated lanolin | 0.5～2 |
| Glycerol | 1～5 |
| Propylene Glycol | 0.5～3 |
| Polyoxyethylenated alcohol sodium sulfate AES | 0～14 |
| Cosurfactant | 0～3 |
| AEO-9 | 3～8 |
| OP-10 | 1～4 |
| Oleyl alcohol ether | 0～2 |
| Ethanol | 30 |
| Cosolvent | 0～10 |
| Disodiumedetate | 0.5 |
| Sodium carboxymethyl cellulose | 1.5 |
| Defoamer | In right amount |
| Preservative | 0.1 |
| Citric acid | In right amount |
| Essence | 0.1%～0.2% |
| Water | In right amount |
The surfactant（Mass fraction）：AEO-9 5%；
OP-10：2%；
AES：8%.
The mass fraction of the miscellaneous oleyl alcohol is 2%.
The mass fraction of the cosolvent is 6%, the diethylene glycol monobutyl ether：Formal=1:0.1～0.6.
The Alcohols,fusel is normal propyl alcohol, isobutanol, isoamyl alcohol, active-amyl alcohol；
The cosurfactant：With miscellaneous oleyl alcohol as main constituent, specifically（Mass fraction）：Alcohols,fusel:span-40:Water=
80:5:15。
A kind of preparation method of leatherware surface ballpoint pen oil abluent, prepares according to following steps：By lanoline, glycerol,
Oleyl alcohol ether, Propylene Glycol heating for dissolving are stand-by, make A；
By AES heating for dissolving in water, B is made；
Cosurfactant aqueous solution C is made with miscellaneous oleyl alcohol, span-40, water；
Then A, B, C are added drop-wise in the aqueous solution containing AEO-9, OP-10 by metering under agitation, while adding ethanol, helping
Solvent, sodium carboxymethyl cellulose, sodium ethylene diamine tetracetate, the Deca defoamer after each component is added are subsequently adding citric acid tune
PH value, is eventually adding essence, preservative and is prepared from, and is formed by surfactant, cosurfactant, cosolvent, alcohol, water etc.
The emulsion of composition.
Described abluent, is cleaned using ultrasound wave, and leatherware cleaning agent soil removal efficiency is determined with mass analysis：By 0.08～
Ballpoint pen oil blue black between 0.20g is applied to certain massCorii Caprae seu Oviss surface predetermined portion, naturalness dries, and claims which
Quality is, Corii Caprae seu Oviss are placed in the ultrasonic washing unit for filling cleaning agent, and soak 5min, then ultrasonic wave concussion 3min,
Corii Caprae seu Oviss are taken out, is dried, is weighed.
Come off using the fractions to leathercraft are likely to result in ultrasound wave cleaning process, such as the material of leatherware flesh noodles layer takes off
Fall, so as to produce quality error, therefore in test, do controlled trial, under identical cleaning condition, circle is not coated with by another piece
The quality of pearl oil stain isCorii Caprae seu Oviss, be placed in the ultrasonic washing unit for filling cleaning agent, and soak 5min, then ultrasound wave
Concussion 3min, takes out Corii Caprae seu Oviss, dries, weigh。
Cleaning rate=
Part that the present invention does not relate to is same as the prior art or can be realized using prior art.
Beneficial effects of the present invention：
（1）The present invention is added without cosurfactant, cosolvent according to basic components, adds anion surfactant AES,
The synergism of anion surfactant AES and nonionic surfactant AEO-9, OP-10 is played, changes the content of AES,
Cleaning agent formula is made, the test of cleaning rate is carried out, cleaning rate is improved, cleaning rate is improved to 90% by 80%, when AES contents are 8%
Cleaning rate change later is little.
（2）The present invention is cleaned based on the resin of ballpoint pen oil, phthalocyanine blue etc. are difficult, is creatively prepared using miscellaneous oleyl alcohol and non-
Ionic surface active agent span 40 is made into cosurfactant.According to basic components, the amount of AES is 8%, is added without cosolvent,
Gradually cosurfactant being added in abluent, making cleaning agent formula, carry out the test of cleaning rate, cosurfactant changes
Become the surface activity and hydrophile-lipophile balance of surfactant, simultaneously participate in form micelle, adjust the polarity of water and oil, improve
Solvability of the abluent to ballpoint pen oil composition, as the addition cleaning rate of cosurfactant is gradually stepped up, cleaning rate
94% is brought up to by 90% or so, when its addition is more than 2.0%, the amplitude that its cleaning efficiency is improved is little.
(3) slightly solubility in the present invention based on the dyestuff in ballpoint pen oil, creatively adds diethylene glycol monobutyl ether, diformazan
The cosolvent that alcohol formal class is formulated, according to basic components, is 8% in the amount of AES, when cosurfactant is 2.0%, plus
Enter cosolvent, change the amount of cosolvent, make cleaning agent formula, with the increase of cosolvent, strengthen abluent stability and
Penetration, increases the dissolubility of the dyestuff in ballpoint pen oil, resinous principle, improves cleaning rate, carry out the test of cleaning rate, clearly
Wash rate to be improved to 98% by 94%, when the amount of cosolvent is more than 6%, cleaning rate is maximum, then improves the width that its content cleaning rate is improved
Degree is little.
（4）The present invention, according to basic components, leatherware goods cause epidermis face during cleaning, inevitably
Oils and fatss or oil film loss, be bonded together intracortical fiber and the composition of abluent so that corium is hardened, becomes fragile,
Different amounts of water solublity lanoline and oleyl alcohol, the cleaning rate of the leatherware goods after test cleaning, degree of purity, softness are added in formula
Degree, glossiness, appropriate water solublity lanoline, oleyl alcohol ether improve the pliability of the leatherware goods after cleaning, glossiness, cleaning
Rate is not affected.
Description of the drawings
Fig. 1 is impact schematic diagrams of the AES to cleaning rate.
Fig. 2 is impact schematic diagram of the cosurfactant to cleaning rate.
Impact schematic diagram of Fig. 3 cosolvents to cleaning rate.
Specific embodiment
With reference to embodiment, the present invention is further illustrated.
Embodiment one.
A kind of leatherware surface ballpoint pen oil abluent, is characterized in that the mass fraction of AEO-9 in the abluent is 5%, OP-
10 mass fraction is 8% for the mass fraction of 2%, AES, and Alcohols,fusel is the quality point of the cosurfactant that main component is prepared
For 0%, the mass fraction of cosolvent is 0 to number, and the mass fraction of water solublity lanoline is that 0-2%, the mass fraction of oleyl alcohol ether are
0.5-2%.The abluent being configured to, is cleaned using ultrasound wave, tests cleaning performance.Its cleaning rate is tested for 90.4%.
Embodiment two
A kind of leatherware surface ballpoint pen oil abluent, is characterized in that the mass fraction of AEO-9 in the abluent for 5%, OP-10's
It is 8% that mass fraction is the mass fraction of 2%, AES, and the mass fraction of miscellaneous oleyl alcohol is 2%, and the mass fraction of cosolvent is 0, water-soluble
Property lanoline mass fraction be 0-2%, oleyl alcohol ether mass fraction be 0.5-2%.The abluent being configured to is clear using ultrasound wave
Wash, test cleaning rate is 94.2%.
Embodiment three
A kind of leatherware surface ballpoint pen oil abluent, is characterized in that the mass fraction of AEO-9 in the abluent for 5%, OP-10's
It is 8% that mass fraction is the mass fraction of 2%, AES, and the mass fraction of cosurfactant is 2%, diethylene glycol monobutyl ether and diformazan
The mass fraction of the cosolvent of alcohol formal compounding is 6%, and the mass fraction of water solublity lanoline is 0-2%, the quality of oleyl alcohol ether
Fraction is 0.5-2%.The abluent being configured to, is cleaned using ultrasound wave, and test cleaning rate is 98.1%.
Comparative example one
A kind of leatherware surface ballpoint pen oil abluent, is characterized in that the mass fraction of AEO-9 in the abluent for 5%, OP-10's
It is 0% that mass fraction is the mass fraction of 2%, AES, and the mass fraction of cosurfactant is 0%, and the mass fraction of cosolvent is
0%.The abluent being configured to, is cleaned using ultrasound wave, and test cleaning rate is 80.3%.
According to basic components, cosurfactant, cosolvent are added without, change the content of AES, make cleaning agent formula,
Carry out the test of cleaning rate, test result such as Fig. 1 draws the addition anion surfactant AES in cleaning agent formula, its with
AEO-9, OP-10 surfactant synergism, improves cleaning rate, and when AES contents, after 8%, cleaning rate change is little.
Autogamy cosurfactant, its main component are miscellaneous oleyl alcohol, nonionic surfactant etc..According to basic components,
The amount of AES is 8%, is added without cosolvent, gradually adds cosurfactant in abluent, make cleaning agent formula, is carried out clear
The test of rate, test result such as Fig. 2 are washed, cosurfactant changes the surface activity and hydrophile-lipophile balance of surfactant
Property, simultaneously participate in form micelle, adjust the polarity of water and oil, improve solvability of the abluent to ballpoint pen oil composition, with
The addition cleaning rate for cosurfactant is gradually stepped up, when its addition is more than 2.0%, the amplitude that its cleaning efficiency is improved
Less.
According to basic components, it is 8% in the amount of AES, when cosurfactant is 2.0%, adds cosolvent, change cosolvent
Amount, make cleaning agent formula, carry out the test of cleaning rate, test result such as Fig. 3, with the increase of cosolvent, strengthens cleaning
The stability and penetration of agent, increases the dissolubility of the dyestuff in ballpoint pen oil, resinous principle, improves cleaning rate, by testing
As a result Fig. 3 can be seen that cleaning rate increases when the amount of cosolvent is more than 6%, but the amplitude for improving is little.
Fig. 1）、2）、3）It is three cases in test for us, AES played its anion surfactant and nonionic
The synergism of surfactant improves cleaning rate, and 2）With 3）It is creative in test to the addition of miscellaneous oleyl alcohol to help table respectively
Face activating agent plays the effect of cosurfactant, and diethylene glycol monobutyl ether, formal play its cosolvent for cosolvent
Effect in ballpoint pen oil the dye component of indissoluble, resinous principle etc. dissolving improve cleaning rate.
Impact of remaining auxiliary agent that the application is also inquired in addition to cleaning rate, is expressed as follows：
The pH value of general leatherware goods is between 5～7.5, and the composition such as phthalocyanine blue, resin in ballpoint pen oil, in acidity
Under the conditions of easy cleaning, therefore citric acid can be added in formula, adjust pH value to 6.5.Leatherware goods during cleaning, no
Can cause the oils and fatss or oil film loss in epidermis face with avoiding, be bonded together intracortical fiber and the composition of abluent, from
And make corium be hardened, become fragile, AES8%, cosurfactant 2%, cosolvent 6% are added in basic components, is added different amounts of
Water solublity lanoline and oleyl alcohol, the cleaning rate of the leatherware goods after test cleaning, degree of purity, pliability, glossiness, obtain table 2,
Appropriate water solublity lanoline, oleyl alcohol ether improve the pliability of the leatherware goods after cleaning, glossiness.In addition, also plus
Enter disodiumedetate chelating agen, essence, preservative, defoamer etc..
What is finally illustrated is：For the test of cleaning performance, because of the chemical composition in abluent, no matter using which kind of cleaning
Method, the fractions for having leathercraft during cleaning unavoidably come off or even infringement.We have attempted various methods,
Did experiment with towel, cotton, hairbrush etc., but due to the particularity of leatherware goods, the impact of its cleaning performance by cleaning meanss,
Cleaning way, even artificial operating condition impact it is larger, and in being difficult to accomplish to test cleaning condition homogeneity, so cleaning
Rate test is relatively inaccurate.In order to, under identical conditions, test cleaning rate, inspired by glasses are cleaned in optician's shop, therefore adopted
Cleaning performance is surveyed in ultrasound wave cleaning.When experiment condition is chosen, we are also when synthesis is manually wiped with cotton, towel
Between and dynamics in terms of, compareed with the cleaning condition of ultrasound wave and finally determine immersion 5min, then ultrasonic wave concussion 3min.
The ultrasound wave cleaning condition of selection to the cleansing power on the leatherware surface that has ball pen oil stain with using cotton, towel or hairbrush etc.
Manually dip abluent wipe repeatedly leatherware surface ball pen 3～15min of oil stain or so cleansing power it is close.To reduce cleaning
Infringement of the agent to leatherware, adds water solublity lanoline, oleyl alcohol ether in formula.
Claims (10)
1. a kind of leatherware surface ballpoint pen oil abluent, it is characterised in that include the surfactant containing AES.
2. a kind of leatherware surface ballpoint pen oil abluent according to claim 1, it is characterised in that also include containing miscellaneous
The cosurfactant of oleyl alcohol.
3. a kind of leatherware surface ballpoint pen oil abluent according to claim 2, it is characterised in that also include diethylene glycol
The cosolvent of monobutyl ether, formal mixture.
4. a kind of leatherware surface ballpoint pen oil abluent according to claim 1, it is characterised in that including following components
（Measure in parts by weight）：
Surfactant：Anion surfactant fatty alcohol-polyoxyethylene ether AEO-9, zwitterionic surfactant octyl
The mixture 7-20% of phenol polyoxyethylene ether OP-10, polyoxyethylenated alcohol sodium sulfate AES；
Cosurfactant：Miscellaneous oleyl alcohol 0-3%；
Cosolvent：The mixture 0-10% of diethylene glycol monobutyl ether, formal；
Water solublity lanoline 0-2%；
Oleyl alcohol ether 0.5-2%；
Remaining is solvent：The mixture of water and ethanol.
5. a kind of leatherware surface ballpoint pen oil abluent according to claim 4, it is characterised in that including following components：
6. a kind of leatherware surface ballpoint pen oil abluent according to claim 4 or 5, it is characterised in that
The surfactant（Mass fraction）：AEO-9 5%；
OP-10：2%；
AES：8%.
7. a kind of leatherware surface ballpoint pen oil abluent according to claim 6, it is characterised in that the matter of the miscellaneous oleyl alcohol
Amount fraction is 2%.
8. a kind of leatherware surface ballpoint pen oil abluent according to claim 7, it is characterised in that the matter of the cosolvent
Amount fraction is 6%, the diethylene glycol monobutyl ether：Formal=1:0.1～0.6.
9. a kind of leatherware surface ballpoint pen oil abluent according to claim 7, it is characterised in that the Alcohols,fusel is for just
Propanol, isobutanol, isoamyl alcohol, active-amyl alcohol；
The cosurfactant：With miscellaneous oleyl alcohol as main constituent, specifically（Mass fraction）：Alcohols,fusel:span-40:Water=
80:5:15。
10. a kind of preparation method of leatherware surface ballpoint pen oil abluent, it is characterised in that prepare according to following steps：By sheep
Hair fat, glycerol, oleyl alcohol ether, Propylene Glycol heating for dissolving are stand-by, make A；
By AES heating for dissolving in water, B is made；
Cosurfactant aqueous solution C is made with miscellaneous oleyl alcohol, span-40, water；
Then A, B, C are added drop-wise in the aqueous solution containing AEO-9, OP-10 by metering under agitation, while adding ethanol, helping
Solvent, sodium carboxymethyl cellulose, sodium ethylene diamine tetracetate, the Deca defoamer after each component is added are subsequently adding citric acid tune
PH value, is eventually adding essence, preservative and is prepared from.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108315106A (en) * | 2018-02-02 | 2018-07-24 | 北京正雅皮具护理有限公司 | Luxury goods leatherware cleaning |
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| CN103666873A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Pre-washing spotting agent for clothing |
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| CN103897875A (en) * | 2012-12-25 | 2014-07-02 | 青岛海芬海洋生物科技有限公司 | Enzyme-containing clothes pre-washing agent and preparing method thereof |
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| CN108315106A (en) * | 2018-02-02 | 2018-07-24 | 北京正雅皮具护理有限公司 | Luxury goods leatherware cleaning |
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