CN106543880A - A kind of environmental protection coating material that can lift spectacle-frame comfort level and preparation method thereof - Google Patents
A kind of environmental protection coating material that can lift spectacle-frame comfort level and preparation method thereof Download PDFInfo
- Publication number
- CN106543880A CN106543880A CN201611136844.4A CN201611136844A CN106543880A CN 106543880 A CN106543880 A CN 106543880A CN 201611136844 A CN201611136844 A CN 201611136844A CN 106543880 A CN106543880 A CN 106543880A
- Authority
- CN
- China
- Prior art keywords
- parts
- spectacle
- frame
- environmental protection
- comfort level
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of environmental protection coating material that can lift spectacle-frame comfort level and preparation method thereof, is formulated by waterborne polyurethane resin, aqueous epoxy resins, rubber resin, fluorine carbon emulsion, organic siliconresin, cotton fibriia, nano titanium oxide, zinc stearate, levelling agent and solvent.The solvent of half is mixed with waterborne polyurethane resin, again aqueous epoxy resins, rubber resin, fluorine carbon emulsion, organic siliconresin, cotton fibriia, nano titanium oxide, zinc stearate and remaining solvent Hybrid Heating are dissolved, by two parts mixture mixing and stirring, obtain final product.Coating of the present invention has the advantages that adhesive force is strong, hardness is high, pliability good, absorption of perspiration and corrosion resistance are strong, it is sprayed on spectacle-frame to reach transparent bright, glossy, colour-fast and adeciduate effect, the service life of spectacle-frame can effectively be extended, its aesthetic property is improved.
Description
Technical field
The present invention relates to chemistry painting industry field, specifically a kind of environmental protection coating material that can lift spectacle-frame comfort level and its preparation
Method.
Background technology
At present, crowd quantity more and more higher of the China with different degrees of distant vision defect, wherein, more than 98% hypermetropia
Power defect belongs to light moderate visual impairment.And as the development of society, the rhythm of life of people are more and more faster, life stress is more next
It is bigger, cause people's extended sleep deficiency, excess eye-using, while also because people need to be worked and be lacked in the face of electronic product for a long time
The reasons such as few eye protection consciousness, the crowd of wearing spectacles is in the trend for constantly rising.
With the improvement of people's living standards, people are to the performance of glasses and attractive in appearance put forward higher requirement.In order to carry
The practicality and aesthetic property of high glasses, typically applies a coating to improve its practical and attractive in appearance effect outside eyeglass or picture frame.
At present, the spectacle-frame coating that people use can also effectively improve the absorption of perspiration and corrosion resistance of spectacle-frame, greatly prolong eye
The service life of picture frame.But the spectacle-frame coating for using at present depends on Italy and German import, expensive, greatly
Big limits its production and application.
Number of patent application discloses a kind of spectacle-frame coating and preparation method thereof for 201110374315.9, and the coating is by having
Machine bentonite, ink zinc stearate, colour carbon black, auxiliary agent FX540 and light base acrylic resin composition.The glasses for preparing
Coating has excellent heat-resisting and lower temperature resistance, while also having the advantages that nontoxic, safe.But, the spectacle-frame coating
Hardness is relatively low, and pliability is poor, sweat proof performance is low, long periods of wear be coated with the picture frame of above-mentioned coating easily occur tarnishing or
The phenomenon of pull-away, has a strong impact on the aesthetic property of spectacle-frame.
Therefore, research and develop out a kind of low price, the spectacle-frame that hardness and richness are high, flexibility and sweat proof performance are good
Coating is still the emphasis of current research.
The content of the invention
It is an object of the invention to provide a kind of environmental protection coating material that can lift spectacle-frame comfort level and preparation method thereof, to solve
The problem proposed in certainly above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme：
A kind of environmental protection coating material that can lift spectacle-frame comfort level, is prepared from by the raw material of following weight portion：The poly- ammonia of aqueouss
24～30 parts of ester resin, 20～24 parts of aqueous epoxy resins, 18～24 parts of rubber resin, 8～10 parts of fluorine carbon emulsion, organosilicon tree
6～8 parts of fat, 8～10 parts of cotton fibriia, 1～3 part of nano titanium oxide, 1～2 part of zinc stearate, 1～2 part of levelling agent, solvent
80～100 parts.
As further scheme of the invention：The levelling agent is silicone oil, polydimethylsiloxane, polyester modification siloxanes
Or acrylic compounds levelling agent.
As further scheme of the invention：The solvent is ethylene glycol, n-butyl alcohol, ethylene glycol, tetramethylolmethane
In one kind.
A kind of preparation method of the described environmental protection coating material that can lift spectacle-frame comfort level, comprises the following steps that：
(1) waterborne polyurethane resin is dissolved by the solvent for taking half amount, obtains waterborne polyurethane resin solution；
(2) by aqueous epoxy resins, rubber resin, fluorine carbon emulsion, organic siliconresin, cotton fibriia, nanometer titanium dioxide
During titanium, zinc stearate add remaining solvent, 40～44 DEG C are slowly heated to, are stirred continuously uniformly to being completely dissolved, must mix
Liquid；
(3) epoxy acrylic resin solution is poured in mixed liquor, is slowly stirred uniformly, obtains final product.
Compared with prior art, the invention has the beneficial effects as follows：
The coating of the present invention has the advantages that adhesive force is strong, hardness is high, pliability good, absorption of perspiration and corrosion resistance are strong, should
For different types of spectacle-frame, so as to reach transparent bright, glossy, colour-fast and adeciduate effect, Ke Yiyou
Effect extends the service life of spectacle-frame, to improve the aesthetic property of spectacle-frame.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment obtained under the premise of creative work is not made by those of ordinary skill in the art, all
Belong to the scope of protection of the invention.
Embodiment 1
The environmental protection coating material of spectacle-frame comfort level can be lifted, is prepared from by the raw material of following weight portion：Aqueous polyurethane tree
24 parts of fat, 20 parts of aqueous epoxy resins, 18 parts of rubber resin, 8 parts of fluorine carbon emulsion, 6 parts of organic siliconresin, 8 parts of cotton fibriia are received
1 part of titanium dioxide of rice, 1 part of zinc stearate, 1 part of silicone oil, 80 parts of ethylene glycol.
Embodiment 2
The environmental protection coating material of spectacle-frame comfort level can be lifted, is prepared from by the raw material of following weight portion：Aqueous polyurethane tree
27 parts of fat, 22 parts of aqueous epoxy resins, 21 parts of rubber resin, 9 parts of fluorine carbon emulsion, 7 parts of organic siliconresin, 9 parts of cotton fibriia are received
2 parts of titanium dioxide of rice, 1.5 parts of zinc stearate, 1.5 parts of polydimethylsiloxane, 90 parts of ethylene glycol.
Embodiment 3
The environmental protection coating material of spectacle-frame comfort level can be lifted, is prepared from by the raw material of following weight portion：Aqueous polyurethane tree
30 parts of fat, 24 parts of aqueous epoxy resins, 24 parts of rubber resin, 10 parts of fluorine carbon emulsion, 8 parts of organic siliconresin, 10 parts of cotton fibriia,
3 parts of nano titanium oxide, 2 parts of zinc stearate, 2 parts of polyester modification siloxanes, 100 parts of tetramethylolmethane.
In the various embodiments described above, the preparation process of environmental protection coating material is as follows：
(1) waterborne polyurethane resin is dissolved by the solvent for taking half amount, obtains waterborne polyurethane resin solution；
(2) by aqueous epoxy resins, rubber resin, fluorine carbon emulsion, organic siliconresin, cotton fibriia, nanometer titanium dioxide
During titanium, zinc stearate add remaining solvent, 42 DEG C are slowly heated to, are stirred continuously uniformly to being completely dissolved, obtain mixed liquor；
(3) epoxy acrylic resin solution is poured in mixed liquor, is slowly stirred uniformly, obtains final product.
Comparative example 1
The environmental protection coating material of spectacle-frame comfort level can be lifted, is prepared from by the raw material of following weight portion：Aqueous polyurethane tree
27 parts of fat, 9 parts of fluorine carbon emulsion, 7 parts of organic siliconresin, 9 parts of cotton fibriia, 2 parts of nano titanium oxide, 1.5 parts of zinc stearate gather
1.5 parts of dimethyl siloxane, 90 parts of ethylene glycol.
Comparative example 2
The environmental protection coating material of spectacle-frame comfort level can be lifted, is prepared from by the raw material of following weight portion：Aqueous polyurethane tree
27 parts of fat, 22 parts of aqueous epoxy resins, 21 parts of rubber resin, 9 parts of cotton fibriia, 2 parts of nano titanium oxide, zinc stearate 1.5
Part, 1.5 parts of polydimethylsiloxane, 90 parts of ethylene glycol.
Comparative example 3
The environmental protection coating material of spectacle-frame comfort level can be lifted, is prepared from by the raw material of following weight portion：Aqueous polyurethane tree
27 parts of fat, 22 parts of aqueous epoxy resins, 21 parts of rubber resin, 9 parts of fluorine carbon emulsion, 7 parts of organic siliconresin, nano titanium oxide 2
Part, 1.5 parts of polydimethylsiloxane, 90 parts of ethylene glycol.
The performance detection test of test example one, spectacle-frame coating paint film
1st, test material
Embodiment 1, embodiment 2, embodiment 3, comparative example 1, comparative example 2 and comparative example 3 prepare spectacle-frame coating.
2nd, test method
By embodiment 1, embodiment 2, embodiment 3, comparative example 1, comparative example 2 and comparative example 3 prepare spectacle-frame coating according to
Spraying process is prepared into paint film, and the outward appearance, transparency, glossiness, adhesive force, hardness, pliability and richness to paint film is surveyed
It is fixed, wherein：Using tri- angle type vancometers of MN268, glossiness is detected that crevice projection angle is 600；Adhesive force is using a stroke lattice
Method is detected；Hardness is detected with reference to the method for GB/T6739-2006；Pliability is entered with reference to the method for GB/T1731-93
Row detection；Transparency and richness are detected by the way of expert opinion.
Evaluation methodology is：5 is very good；4 is preferable；3 is good；2 is general；1 is poor；0 is very poor, if slightly above 4, it is masked as 4+；
Slightly below 4, it is masked as 4-。
3rd, result of the test
Result of the test is as shown in table 1.
The performance detection test of 1 spectacle-frame coating of table
As shown in Table 1, the outward appearance of paint film prepared by the embodiment of the present invention 1～3, transparency, glossiness and richness are good, and
And its adhesive force, hardness and pliability are high, the paint film property that wherein prepared by embodiment 2 is optimal.And paint prepared by comparative example 1～3
The paint that the outward appearance of film, transparency, glossiness, adhesive force, hardness, pliability and richness are prepared than the embodiment of the present invention 1～3
Film is poor, illustrates that the formula collocation of the spectacle-frame coating of present invention offer is reasonable, can effectively improve glossiness, adhesive force, hard
The performance of the aspect such as degree and pliability.
The corrosion-resistant testing experiment of test example two, spectacle-frame coating paint film
1st, test material
Embodiment 1, embodiment 2, embodiment 3, comparative example 1, comparative example 2 and comparative example 3 prepare spectacle-frame coating.
2nd, test method
By embodiment 1, embodiment 2, embodiment 3, comparative example 1, comparative example 2 and comparative example 3 prepare spectacle-frame coating according to
Spraying process is prepared into paint film, carries out absorption of perspiration, resistant to acetone, resistance to acids and bases and humidity resistance to paint film and is measured, wherein resistance to
Antiperspirant is measured with reference to the method for EU criteria I5012870, and resistant to acetone is dipped in acetone using Cotton swab and directly tested, acidproof
With reference to the method for GB/T 1771-2007, alkalescence is detected that humidity resistance is measured with reference to the method for GB/T1740-2007.
3rd, result of the test
Result of the test is as shown in table 2.
The corrosion-resistant testing experiment of 2 spectacle-frame coating paint film of table
As shown in Table 2, the present invention prepare the embodiment of the present invention 1～3 prepare paint film have preferable absorption of perspiration, resistance to third
Ketone, acid and alkali-resistance and humidity resistance, can effectively extend the service life of spectacle-frame, and paint film prepared by comparative example 1～3
Absorption of perspiration, resistant to acetone, acid and alkali-resistance and humidity resistance are poor, illustrate that the formula collocation of the spectacle-frame coating of present invention offer is closed
Reason, can effectively improve the absorption of perspiration and corrosion resistance of coating.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Claims (4)
1. a kind of environmental protection coating material that can lift spectacle-frame comfort level, it is characterised in that be prepared from by the raw material of following weight portion：
24～30 parts of waterborne polyurethane resin, 20～24 parts of aqueous epoxy resins, 18～24 parts of rubber resin, 8～10 parts of fluorine carbon emulsion,
6～8 parts of organic siliconresin, 8～10 parts of cotton fibriia, 1～3 part of nano titanium oxide, 1～2 part of zinc stearate, levelling agent 1～2
Part, 80～100 parts of solvent.
2. the environmental protection coating material that spectacle-frame comfort level can be lifted according to claim 1, it is characterised in that the levelling agent is
Silicone oil, polydimethylsiloxane, polyester modification siloxanes or acrylic compounds levelling agent.
3. the environmental protection coating material that spectacle-frame comfort level can be lifted according to claim 1, it is characterised in that the solvent is second
One kind in glycol, n-butyl alcohol, ethylene glycol, tetramethylolmethane.
4. a kind of preparation method of the environmental protection coating material that can lift spectacle-frame comfort level as claimed in claim 1, it is characterised in that
Comprise the following steps that：
(1) waterborne polyurethane resin is dissolved by the solvent for taking half amount, obtains waterborne polyurethane resin solution；
(2) by aqueous epoxy resins, rubber resin, it is fluorine carbon emulsion, organic siliconresin, cotton fibriia, nano titanium oxide, hard
During fat acid zinc adds remaining solvent, 40～44 DEG C are slowly heated to, are stirred continuously uniformly to being completely dissolved, obtain mixed liquor；
(3) epoxy acrylic resin solution is poured in mixed liquor, is slowly stirred uniformly, obtains final product.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611136844.4A CN106543880B (en) | 2016-12-12 | 2016-12-12 | A kind of environmental protection coating material and preparation method thereof that can promote spectacle-frame comfort level |
| CN201811070560.9A CN109354991B (en) | 2016-12-12 | 2016-12-12 | Preparation method of environment-friendly coating capable of improving comfort of glasses frame |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611136844.4A CN106543880B (en) | 2016-12-12 | 2016-12-12 | A kind of environmental protection coating material and preparation method thereof that can promote spectacle-frame comfort level |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811070560.9A Division CN109354991B (en) | 2016-12-12 | 2016-12-12 | Preparation method of environment-friendly coating capable of improving comfort of glasses frame |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106543880A true CN106543880A (en) | 2017-03-29 |
| CN106543880B CN106543880B (en) | 2018-12-18 |
Family
ID=58397708
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811070560.9A Expired - Fee Related CN109354991B (en) | 2016-12-12 | 2016-12-12 | Preparation method of environment-friendly coating capable of improving comfort of glasses frame |
| CN201611136844.4A Active CN106543880B (en) | 2016-12-12 | 2016-12-12 | A kind of environmental protection coating material and preparation method thereof that can promote spectacle-frame comfort level |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811070560.9A Expired - Fee Related CN109354991B (en) | 2016-12-12 | 2016-12-12 | Preparation method of environment-friendly coating capable of improving comfort of glasses frame |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN109354991B (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101608089A (en) * | 2009-07-29 | 2009-12-23 | 袁泉利 | Waterborne epoxy coating for non-bilged compartments |
| CN102002288A (en) * | 2010-10-15 | 2011-04-06 | 上海富臣化工有限公司 | Water-based environment friendly metallic paint and preparation method thereof |
| CN102051098A (en) * | 2010-11-26 | 2011-05-11 | 山东大学 | Environment-friendly photocatalytic water-based paint and preparation method thereof |
| CN104710883A (en) * | 2015-03-23 | 2015-06-17 | 苏州市神龙门窗有限公司 | Transparent coating for glass window and door and preparation method of transparent coating |
| WO2015125816A1 (en) * | 2014-02-19 | 2015-08-27 | 東亞合成株式会社 | Water-based paint composition and coating process using same, and coating film and product obtained using coating process |
| CN105505163A (en) * | 2015-12-03 | 2016-04-20 | 韩登鹤 | Protective coating for frames of glasses |
| CN105647350A (en) * | 2016-01-27 | 2016-06-08 | 中山永辉化工股份有限公司 | Glasses frame coating and preparation method thereof |
| CN105670493A (en) * | 2016-04-15 | 2016-06-15 | 武汉赫斯特涂层材料股份有限公司 | Waterborne UV organosilicone-polyurethane anti-corrosion paint and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05230421A (en) * | 1991-03-01 | 1993-09-07 | Sigma:Kk | Method for treating metallic material with resin-japanese lacquer mixture |
| CN1055944C (en) * | 1993-12-28 | 2000-08-30 | 大金工业株式会社 | Coating composition and coated article |
| US7739314B2 (en) * | 2005-08-15 | 2010-06-15 | Google Inc. | Scalable user clustering based on set similarity |
-
2016
- 2016-12-12 CN CN201811070560.9A patent/CN109354991B/en not_active Expired - Fee Related
- 2016-12-12 CN CN201611136844.4A patent/CN106543880B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101608089A (en) * | 2009-07-29 | 2009-12-23 | 袁泉利 | Waterborne epoxy coating for non-bilged compartments |
| CN102002288A (en) * | 2010-10-15 | 2011-04-06 | 上海富臣化工有限公司 | Water-based environment friendly metallic paint and preparation method thereof |
| CN102051098A (en) * | 2010-11-26 | 2011-05-11 | 山东大学 | Environment-friendly photocatalytic water-based paint and preparation method thereof |
| WO2015125816A1 (en) * | 2014-02-19 | 2015-08-27 | 東亞合成株式会社 | Water-based paint composition and coating process using same, and coating film and product obtained using coating process |
| CN104710883A (en) * | 2015-03-23 | 2015-06-17 | 苏州市神龙门窗有限公司 | Transparent coating for glass window and door and preparation method of transparent coating |
| CN105505163A (en) * | 2015-12-03 | 2016-04-20 | 韩登鹤 | Protective coating for frames of glasses |
| CN105647350A (en) * | 2016-01-27 | 2016-06-08 | 中山永辉化工股份有限公司 | Glasses frame coating and preparation method thereof |
| CN105670493A (en) * | 2016-04-15 | 2016-06-15 | 武汉赫斯特涂层材料股份有限公司 | Waterborne UV organosilicone-polyurethane anti-corrosion paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109354991B (en) | 2021-02-09 |
| CN106543880B (en) | 2018-12-18 |
| CN109354991A (en) | 2019-02-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103627306B (en) | Mist surface hand feeling scratch-resistant coating paint and preparation method thereof | |
| CN103669021B (en) | A kind of low energy consumption ecological artificial leather manufacture method | |
| CN102051115B (en) | Ultraviolet light curing colored paint and preparation method thereof | |
| CN103509422A (en) | Hydrophobic and oleophobic coating composition | |
| CN105647350B (en) | A kind of spectacle-frame coating and preparation method thereof | |
| CN105419606B (en) | A kind of aqueous polyurethane delustering agent and preparation method thereof | |
| CN103726330A (en) | High temperature-resistant super black and misty processing agent used for synthetic leather | |
| CN109535985A (en) | Electronic product plastic shell two-component finishing coat, preparation method and application method | |
| CN106118230A (en) | A kind of ink being applied on ultrawhite safety glass and preparation method thereof | |
| CN106519950A (en) | Rubber paint for windshield and preparation method thereof | |
| CN106752514A (en) | A kind of environmental protection coating material for spectacle-frame and preparation method thereof | |
| CN109385193A (en) | A kind of good aqueous plastic coating and preparation method thereof of adhesion | |
| CN107312402A (en) | A kind of high performance capacitors aluminum housing coating fluorocarbon coating and preparation method thereof | |
| CN102168378A (en) | Non-yellowing anti-graffiti resin for synthetic leather as well as preparation method of the resin | |
| CN104004419A (en) | Fluorocarbon stone simulation paint, multi-color painted surface and preparing methods of fluorocarbon stone simulation paint and multi-color painted surface | |
| CN109456700A (en) | A kind of high-elastic sand face texture paint of exterior wall and preparation method | |
| CN106543880B (en) | A kind of environmental protection coating material and preparation method thereof that can promote spectacle-frame comfort level | |
| WO2017107710A1 (en) | Water-based high-gloss polishing oil for leather synthesis and preparation method therefor | |
| CN104389193A (en) | Jean-pollution-preventing PVC artificial leather and preparation method thereof | |
| CN104087106B (en) | The preparation method of a kind of light resistance water paint and adhesive | |
| CN110066583A (en) | Modified alkyd resin coating and preparation method thereof | |
| CN108148489A (en) | A kind of oil rub resistance self-healing coatings and preparation method thereof, application | |
| CN107418417A (en) | A kind of polyurethane Brilliant white paint | |
| TW201441321A (en) | Gold ink composition | |
| CN105462402A (en) | Acrylic primer paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20181012 Address after: No. 1, Chengyang street, Xushui District, Baoding, Hebei Applicant after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: 450000 D502, 1 tower, 96 Ruida Road, Zhengzhou high tech Industrial Development Zone, Henan. Applicant before: Zhengzhou Information Technology Co., Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20200929 Granted publication date: 20181218 |
|
| PD01 | Discharge of preservation of patent | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210902 Granted publication date: 20181218 |