CN106543623A - A kind of high temperature resistant vehicle line Masterbatch and its preparation method and application - Google Patents
A kind of high temperature resistant vehicle line Masterbatch and its preparation method and application Download PDFInfo
- Publication number
- CN106543623A CN106543623A CN201510607682.7A CN201510607682A CN106543623A CN 106543623 A CN106543623 A CN 106543623A CN 201510607682 A CN201510607682 A CN 201510607682A CN 106543623 A CN106543623 A CN 106543623A
- Authority
- CN
- China
- Prior art keywords
- high temperature
- temperature resistant
- parts
- vehicle line
- resistant vehicle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The present invention relates to electric wire macromolecular material, more particularly to a kind of preparation method of high temperature resistant vehicle line Masterbatch.A kind of high temperature resistant vehicle line Masterbatch that the present invention is provided, including following component by weight：40～60 parts of carrier；5～8 parts of dispersant；2～4 parts of antioxidant；Pigment 40～60.A kind of high temperature resistant vehicle line Masterbatch provided by the present invention, its dispersive property are good, and mechanical property increases, and does not affect the heat resistance of high temperature automotive line.
Description
Technical field
The present invention relates to wire cable material Masterbatch, more particularly to a kind of high temperature resistant vehicle line Masterbatch and preparation method thereof and
Using.
Background technology
Masterbatch is widely used in the resins such as polyethylene, polypropylene, nylon, PC, PVC, and daily plastic, electric wire
Deng product.Masterbatch according to the present invention, is mainly used in high temperature resistant vehicle line, and automobile electric wire extruded velocity is up to 1000M/Min,
Need color masterbatch that there is good dispersive property, the general wall thickness of automobile electric wire is relatively thin, much only 0.2mm or so, needs Masterbatch
With higher concentration, to reach certain coloring requirement.Very few not the reaching of Masterbatch addition in existing application technology colours requirement,
Addition is excessive to affect cable material combination property, therefore in the urgent need to a kind of new color masterbatch solves the technical problem.
The content of the invention
The shortcoming of prior art in view of the above, it is an object of the invention to provide a kind of degree of staining is high, scattered, temperature tolerance
The good Masterbatch of energy, for solving the problems of the prior art.
For achieving the above object and other related purposes, the present invention is adopted the following technical scheme that：
A first aspect of the present invention, there is provided a kind of high temperature resistant vehicle line Masterbatch, including following component by weight：
40～60 parts of carrier；5～8 parts of dispersant；2～4 parts of antioxidant；Pigment 40～60.
Preferably, the high temperature resistant vehicle line Masterbatch, including following component by weight：40～55 parts of carrier；
5～7 parts of dispersant；2～4 parts of antioxidant；Pigment 45～60.
Preferably, the high temperature resistant vehicle line Masterbatch, including following component by weight：40～50 parts of carrier；
5～7 parts of dispersant；2～4 parts of antioxidant；Pigment 45～60.
Preferably, the high temperature resistant vehicle line Masterbatch, including following component by weight：40～50 parts of carrier；
5～7 parts of dispersant；4 parts of antioxidant；Pigment 45～60.
Preferably, the carrier is maleic anhydride grafted polyethylene, the density of the maleic anhydride grafted polyethylene is 0.82～
0.96g/cm3, percent grafting are 1.0-2.0%, and melt index (190 DEG C × 2.16kg) is 1-10g/10min.
Preferably, the combination of the one or two kinds of during the dispersant selects polydimethylsiloxane or Tissuemat E.
The M of the polydimethylsiloxaneWScope is more than 1,000,000.The M of the Tissuemat EWScope is 1000-5000.
Preferably, the antioxidant is selected from the group of one or more in antioxidant 1010, irgasfos 168 and anti-oxidant DLTP
Close.
The chemical name of antioxidant 1010 is four (β-(3,5- di-tert-butyl-hydroxy phenyls) propanoic acid) pentaerythritol ester；Antioxidant
168 chemical name is three [2.4- di-tert-butyl-phenyls] phosphite ester；The chemical name of anti-oxidant DLTP is thio dipropyl
Sour dilauryl.
Preferably, combination of the antioxidant selected from three kinds of antioxidant 1010, irgasfos 168 and anti-oxidant DLTP, three's
Weight ratio is 2：1：1.
Preferably, the pigment from Rutile type titanium dioxide, blue or green blue, dark green, lemon yellow, WGP Huangs, permanent bordeaux,
The combination of one or more in everbright fast red, permanent violet.
Second aspect present invention, additionally provides the preparation method of the Masterbatch, comprises the steps：
(1) by raw material components by weight dispensing, 3～5min is then blended in high mixer.
(2) step (1) resulting material is packaged into into bag using the plasticizing pelletize of double-screw extruding pelletizing unit, drying.
Preferably, in the step (1), the concrete grammar of raw material mix homogeneously is：Jing plastic high-speed mixers machine is blended, rotating speed control
For 400～800rpm.
Preferably, in the step (2), double screw extruder temperature setting is：145-155 DEG C of one area of machine barrel, 2nd area of machine barrel
155-165 DEG C, 170-180 DEG C of 3rd area of machine barrel, 175-185 DEG C of 4th area of machine barrel, 190-200 DEG C of 5th area of machine barrel, head and mould
195-205℃。
The plastic high-speed mixer type GRH500Z, by Fuxin, vast Te Er rubber and plastics machines limited liability company system makes and twin-screw extrusion
Comminutor model C TE65 type, is manufactured by section times Long Keya (Nanjing) Machinery Co., Ltd., is the dress of routine in prior art
Put.
Preferably, in the step (2), dry temperature is 75-85 DEG C.
A third aspect of the present invention, there is provided application of the aforementioned high temperature resistant vehicle line in Masterbatch automobile electric wire cable production art.
Compared with prior art, beneficial effects of the present invention are：
A kind of high temperature resistant vehicle line Masterbatch provided by the present invention, its dispersive property are good, and mechanical property increases, not shadow
Ring the heat resistance of high temperature automotive line.
Specific embodiment
Embodiments of the present invention are illustrated below by way of specific instantiation, those skilled in the art can be by disclosed by this specification
Content understand easily the present invention other advantages and effect.The present invention can also be added by specific embodiments different in addition
To implement or apply, the every details in this specification can also be based on different viewpoints and application, in the essence without departing from the present invention
Various modifications and changes are carried out under god.
It should be clear that the not concrete process equipment for indicating or device adopt conventional equipment in the art or device in the following example；
All pressure values and scope are all referring to absolute pressure.
In addition, it is to be understood that one or more method and steps mentioned in the present invention do not repel before and after the combination step can be with
There is additive method step or additive method step can also be inserted between the step of these specifically mention, unless otherwise stated；
It should also be understood that the combination annexation between one or more the equipment/devices mentioned in the present invention is not repelled setting in the combination
Can also there is other equipment/device before and after standby/device or which can also be inserted between these two equipment/devices for specifically mentioning
His equipment/device, unless otherwise stated.And, unless otherwise stated, the numbering of various method steps only differentiates various method steps
Convenient tool, rather than to limit the ordering of various method steps or limiting enforceable scope of the invention, its relativeness
It is altered or modified, in the case of without essence change technology contents, when being also considered as enforceable category of the invention.
Embodiment 1
A kind of high temperature resistant vehicle line of the present embodiment redness master batch, its raw material components are as follows：Maleic anhydride grafted polyethylene
40 parts；5 parts of Tissuemat E；2 parts of antioxidant 1010；1 part of irgasfos 168；1 part of anti-oxidant DLTP；Face
60 parts of everbright fast red of material.The density of the maleic anhydride grafted polyethylene is 0.94g/cm3, and percent grafting is 2.0%, is melted
It is 1.8g/10min to melt index (190 DEG C × 2.16kg).The molecular weight of the Tissuemat E is 2000-3000.
Preparation method is：Above raw material components Jing plastic high-speed mixers machine is mixed into (rotating speed is controlled to 400～800rpm), twin screw
The high temperature resistant vehicle line redness master batch product of the present embodiment is obtained final product after the pelletize of extruding granulator retable drying；Wherein, double spiral shells
Bar extruder temperature is set to：150 ± 5 DEG C of one area of machine barrel, 160 ± 5 DEG C of 2nd area of machine barrel, 175 ± 5 DEG C of 3rd area of machine barrel, 4th area of machine barrel
180 ± 5 DEG C, 195 ± 5 DEG C of 5th area of machine barrel, 200 ± 5 DEG C of head and mould；Dry temperature control is at 75-85 DEG C.
Embodiment 2
A kind of preparation of high temperature resistant vehicle line yellow masterbatch of the present embodiment, its raw material components are as follows：Maleic anhydride is grafted poly- second
50 parts of alkene；6 parts of Tissuemat E；2 parts of antioxidant 1010；1 part of irgasfos 168；1 part of anti-oxidant DLTP；Vapour
Bar WGP is yellow 50 parts.The density of the maleic anhydride grafted polyethylene is 0.96g/cm3, percent grafting is 1.0%, and melting refers to
Number (190 DEG C × 2.16kg) is 1.0g/10min.The molecular weight of the Tissuemat E is 2000-3000.
The preparation method of the high temperature resistant vehicle line Masterbatch of the present embodiment is with embodiment 1.
Embodiment 3
A kind of high temperature resistant vehicle line of the present embodiment blueness master batch, its raw material components are as follows：Maleic anhydride grafted polyethylene 50
Part；7 parts of Tissuemat E；2 parts of antioxidant 1010；1 part of irgasfos 168；1 part of anti-oxidant DLTP；Monastral blue is blue
45 parts.The density of the maleic anhydride grafted polyethylene is 0.82g/cm3, and percent grafting is 2.0%, melt index (190 DEG C ×
It is 2.16kg) 10g/10min.The molecular weight of the Tissuemat E is 2000-3000.
The preparation method of the high temperature resistant vehicle line Masterbatch of the present embodiment is with embodiment 1.
Embodiment 4
Obtained in embodiment 1～3, high temperature resistant vehicle line Masterbatch is added in CABLE MATERIALS in 2% ratio, is extruded into wall thickness 0.2mm
Automobile wire.
Additionally, also using using in prior art, color grain (contrasts Masterbatch Pu Liwan trade mark OnColorTM
CC10075093) same ratio addition is prepared from the automobile wire of same wall thickness.
It is compared, after testing, its technical parameter is as shown in table 1：
Table 1.
From all technical in table 1 can be seen that Masterbatch of the prior art it is added after can not reach high speed extrusion will
Ask, extrusion of wire surface is not smooth enough.
However, compared with the cable without high temperature resistant vehicle line Masterbatch of the present invention, and comparative example is compared, the present invention
A kind of high temperature resistant vehicle line Masterbatch be added in cable, with excellent physical and mechanical propertiess, ageing resistace and
The high speed extrusion performance of wire rod is not affected.
In sum, the present invention effectively overcomes various shortcoming of the prior art and has high industrial utilization.
The principle and its effect of above-described embodiment only illustrative present invention, it is of the invention not for limiting.It is any to be familiar with this skill
The personage of art all can carry out modifications and changes to above-described embodiment under the spirit and the scope without prejudice to the present invention.Therefore, such as
Those of ordinary skill in the art completed under without departing from disclosed spirit and technological thought all etc.
Effect modifications and changes, should be covered by the claim of the present invention.
Claims (10)
1. a kind of high temperature resistant vehicle line Masterbatch, including following component by weight：40～60 parts of carrier；Dispersant 5～
8 parts；2～4 parts of antioxidant；Pigment 40～60.
2. high temperature resistant vehicle line Masterbatch according to claim 1, it is characterised in that including by weight such as the following group
Point：40～55 parts of carrier；5～7 parts of dispersant；2～4 parts of antioxidant；Pigment 45～60.
3. high temperature resistant vehicle line Masterbatch according to claim 1, it is characterised in that including by weight such as the following group
Point：40～50 parts of carrier；5～7 parts of dispersant；2～4 parts of antioxidant；Pigment 45～60.
4. a kind of high temperature resistant vehicle line Masterbatch according to claim 1, it is characterised in that the carrier is maleic anhydride
Grafted polyethylene, the density of the maleic anhydride grafted polyethylene is 0.82～0.96g/cm3, melt index is
1-10g/10min。
5. a kind of high temperature resistant vehicle line Masterbatch according to claim 1, it is characterised in that the dispersant selects poly- two
The combination of the one or two kinds of in methylsiloxane or Tissuemat E.
6. a kind of high temperature resistant vehicle line Masterbatch according to claim 1, it is characterised in that the antioxidant is selected from antioxygen
The combination of one or more in agent 1010, irgasfos 168 and anti-oxidant DLTP.
7. a kind of high temperature resistant vehicle line Masterbatch according to claim 6, it is characterised in that the antioxidant is selected from antioxygen
Agent 1010, irgasfos 168 and the combination of three kinds of anti-oxidant DLTP, the weight ratio of three is 2：1：1.
8. a kind of high temperature resistant vehicle line Masterbatch according to claim 1, it is characterised in that the color material selects golden red
The combination of one or more in stone-type titanium dioxide, blue or green blue, dark green, lemon yellow, permanent bordeaux, permanent violet.
9. the preparation method of a kind of high temperature resistant vehicle line Masterbatch according to claim 1～8 any claim, including such as
Lower step：
(1) by each raw material components by weight dispensing, 3～5min is then blended in high mixer.
(2) step 1 resulting material is packaged into into bag using the plasticizing pelletize of double-screw extruding pelletizing unit, drying.
10. the high temperature resistant vehicle line Masterbatch according to claim 1～8 any claim is in automobile electric wire cable production art
In application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510607682.7A CN106543623A (en) | 2015-09-22 | 2015-09-22 | A kind of high temperature resistant vehicle line Masterbatch and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510607682.7A CN106543623A (en) | 2015-09-22 | 2015-09-22 | A kind of high temperature resistant vehicle line Masterbatch and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106543623A true CN106543623A (en) | 2017-03-29 |
Family
ID=58364868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510607682.7A Pending CN106543623A (en) | 2015-09-22 | 2015-09-22 | A kind of high temperature resistant vehicle line Masterbatch and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106543623A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108314826A (en) * | 2018-03-12 | 2018-07-24 | 宁波色母粒有限公司 | The polyolefin cobalt blue master batch and preparation method thereof of resistance to strong acid corrosion |
| CN113637280A (en) * | 2021-10-18 | 2021-11-12 | 北京能之光科技有限公司 | Silver ion antibacterial compatilizer master batch suitable for inorganic filler modified PP |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
| CN102070820A (en) * | 2010-12-01 | 2011-05-25 | 浙江七色鹿色母粒有限公司 | Polyethylene of raised temperature resistance (PE-RT) master batch and preparation method thereof |
| CN102250399A (en) * | 2011-06-01 | 2011-11-23 | 广州市波斯塑胶颜料有限公司 | Polyolefin masterbatch and preparation method thereof |
-
2015
- 2015-09-22 CN CN201510607682.7A patent/CN106543623A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
| CN102070820A (en) * | 2010-12-01 | 2011-05-25 | 浙江七色鹿色母粒有限公司 | Polyethylene of raised temperature resistance (PE-RT) master batch and preparation method thereof |
| CN102250399A (en) * | 2011-06-01 | 2011-11-23 | 广州市波斯塑胶颜料有限公司 | Polyolefin masterbatch and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108314826A (en) * | 2018-03-12 | 2018-07-24 | 宁波色母粒有限公司 | The polyolefin cobalt blue master batch and preparation method thereof of resistance to strong acid corrosion |
| CN113637280A (en) * | 2021-10-18 | 2021-11-12 | 北京能之光科技有限公司 | Silver ion antibacterial compatilizer master batch suitable for inorganic filler modified PP |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102964808B (en) | Environment-friendly thermoplastic polyurethane (TPU) film and preparation method thereof | |
| CN105644074A (en) | High strength wood-plastic coated coextruded composite material and preparation method thereof | |
| CN101798417B (en) | Anti-termite and coloring functional master batch for plastic and preparation method thereof | |
| CN107936430A (en) | High fluidity polyvinyl alcohol that thermoplastification is modified, cast film materials and preparation method thereof | |
| CN104479349B (en) | A kind of flame-proof composite material for 3D printing and preparation method thereof | |
| CN107936431A (en) | Polyvinyl alcohol water solubility casting films and preparation method thereof | |
| CN102875881B (en) | Preparation method of special color master batch for ultrahigh-molecular-weight polyethylene spinning | |
| EP3802037A1 (en) | Method for the manufacture of a colored polymer composition | |
| CN102585324A (en) | Polyethylene composition for improving yellow index and lustrousness and preparation method thereof | |
| CN108794867A (en) | Polyethylene film masterbatch, blown film polyethylene composition and preparation method thereof | |
| CN102558675A (en) | Polypropylene material with high melt strength and preparation method thereof | |
| CN106496740A (en) | A kind of antistatic PET color master batch | |
| CN108690315A (en) | A kind of Heat resistance ABS material of matt and preparation method thereof | |
| CN106543623A (en) | A kind of high temperature resistant vehicle line Masterbatch and its preparation method and application | |
| CN103772883A (en) | ABS/PBT material used by extrusion process and preparation method for ABS/PBT material | |
| CN109096777A (en) | A kind of Masterbatch and production method | |
| CN1243051C (en) | Coloring agglomerate for polyethylene packing film and its prepn process | |
| CN106751035A (en) | A kind of fold resistant is turned white PP composite material and preparation method thereof | |
| CN109608837A (en) | A kind of polyester-polyolefin film and preparation method thereof | |
| CN105111662A (en) | Nanometer calcium carbonate foamed and toughened polystyrene master batch and preparation method thereof | |
| CN107805353A (en) | A kind of high-performance ABS color master batch and its preparation technology and application | |
| CN107540935B (en) | Polypropylene reclaimed material composition and preparation method thereof | |
| CN104119635A (en) | ABS / PA6 material for extrusion technology and preparation method thereof | |
| CN104119636A (en) | High gloss glass fiber reinforced ABS/PC material for extrusion process and preparation method thereof | |
| CN106800779A (en) | A kind of preparation technology of the sheet material of polyphenylene sulfide reinforcing material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170329 |
|
| RJ01 | Rejection of invention patent application after publication |