CN106541629B - Waterproof geotextile and preparation method thereof - Google Patents

Waterproof geotextile and preparation method thereof Download PDF

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Publication number
CN106541629B
CN106541629B CN201610910300.2A CN201610910300A CN106541629B CN 106541629 B CN106541629 B CN 106541629B CN 201610910300 A CN201610910300 A CN 201610910300A CN 106541629 B CN106541629 B CN 106541629B
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wefts
fiber
fibers
base layer
warps
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CN106541629A (en
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张伟
何红伟
王建军
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Nantong Shangshan Molding Technology Co., Ltd
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Nantong Shangshan Molding Technology Co ltd
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • B32B17/064—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/067—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B27/00—Layered products comprising a layer of synthetic resin
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
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    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
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    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention relates to a waterproof geotextile and a preparation method thereof, wherein the waterproof geotextile comprises a base layer and a bottom layer; the base layer is formed by weaving warps and wefts, and a plastic film is bonded on the surface of the base layer; the bottom layer comprises polyimide fibers, glass fibers and high-strength fibers, and the three fibers are interwoven together through needling and heat setting after opening, mixing, carding and lapping; the weight ratio of the polyimide fiber, the glass fiber and the high-strength fiber is 4: 4: 2. the geotextile has excellent mechanical properties, stronger tensile strength and deformation resistance, good corrosion resistance, and the geotextile plays roles of strengthening, seepage prevention and crack prevention in the reconstruction of the pavement, and can further prolong the service life of the pavement.

Description

Waterproof geotextile and preparation method thereof
Technical Field
The invention belongs to the field of building materials, relates to a geotextile and a preparation method thereof, and particularly relates to a waterproof geotextile and a preparation method thereof.
Background
At present, geotechnique's cloth mainly is applied to big engineering of silt diameter small stress such as water conservancy, harbour, channel, railway, highway, and its main effect that plays includes 1: the isolation function is to isolate the building materials with different physical properties, so that the materials are not mixed, and the integrity of the materials is kept; 2: filtering, namely allowing water to pass through to intercept materials such as soil particles, fine sand and the like by utilizing the water permeability of the geotextile when the water flows into a coarse material soil layer from a fine material soil layer; 3: the stabilizing effect, the tensile anti-deformation capability of the soil body is enhanced, and the stability of the building structure is enhanced.
The existing common geotextile has a single structure and low tensile strength and deformation resistance, so that the service life of the geotextile is shortened, therefore, the technical personnel in the field need to provide a reinforced geotextile which can effectively improve the tensile strength and deformation resistance and prolong the service life of the geotextile.
Disclosure of Invention
The waterproof geotextile provided by the invention has the advantages of excellent mechanical property, stronger tensile strength and deformation resistance, good corrosion resistance, and effects of strengthening, preventing seepage and preventing reflection cracks in the improvement of the pavement, and can further prolong the service life of the pavement.
Specifically, the invention provides a waterproof geotextile, which comprises a base layer and a bottom layer; the base layer is formed by weaving warps and wefts, and a plastic film is bonded on the surface of the base layer; the bottom layer comprises polyimide fibers, glass fibers and high-strength fibers, and the three fibers are interwoven together through needling and heat setting after opening, mixing, carding and lapping; the weight ratio of the polyimide fiber, the glass fiber and the high-strength fiber is 4: 4: 2.
the high-strength fiber is prepared by mixing 10-20 parts of ultra-high molecular weight polyethylene powder with the molecular weight of 150-200 ten thousand, 1-4 parts of polyformaldehyde, 60-80 parts of paraffin oil, 0.5-3 parts of lignin and 0.5-2 parts of nano organic bentonite in a mixing kettle, heating and stirring at the temperature of 130-150 ℃ to obtain an expansion liquid, naturally cooling to form a gel block, taking out the gel block, crushing the gel block into granules on crushing equipment, removing part of solvent by using deoiling equipment, and inputting the granules into a screw extruder for melt spinning: the length-diameter ratio of the screw is 1: 40, the temperature of each section of the screw is 150-250 ℃, the extrusion speed of the screw is 200-250 revolutions per minute, the holes of a spinneret plate are 100-150, the aperture is 0.5-0.8 mm, the temperature of a spinning melt is controlled at 200-220 ℃, the drafting of a nozzle is 5-15 m per minute, then the pre-stretching and winding are carried out, and the high-strength fiber is obtained through extraction, drying and super-stretching processes; the parts are parts by weight.
Preferably, the high-strength fiber is prepared by mixing 15 parts of ultra-high molecular weight polyethylene powder with the molecular weight of 150-200 ten thousand, 3 parts of polyformaldehyde, 70 parts of paraffin oil, 2 parts of lignin and 1 part of nano organic bentonite in a mixing kettle, heating and stirring the mixture, heating the mixture at the temperature of 140 ℃ to obtain an expansion liquid, naturally cooling the mixture to form a gel block, taking out the gel block, crushing the gel block into granules on crushing equipment, removing part of solvent by using deoiling equipment, and inputting the granules into a screw extruder for melt spinning: the length-diameter ratio of the screw is 1: 40, the temperature of each section of the screw is 200 ℃, the extrusion speed of the screw is 220 r/min, 130 holes of a spinneret plate and the aperture is 0.6mm, the temperature of a spinneret melt is controlled at 210 ℃, a nozzle drafts 10 m/min, then the high-strength fiber is obtained by pre-stretching and winding, and then the high-strength fiber is obtained by extraction, drying and super-stretching processes.
Preferably, the high-strength fiber is prepared by mixing 10 parts of ultra-high molecular weight polyethylene powder with the molecular weight of 150-200 ten thousand, 1 part of polyformaldehyde, 60 parts of paraffin oil, 0.5 part of lignin and 0.5 part of nano organic bentonite in a mixing kettle, heating and stirring, heating to 130 ℃ to obtain an expansion liquid, naturally cooling to form a gel block, taking out the gel block, crushing the gel block into granules on a crushing device, removing part of solvent by using a deoiling device, and inputting the granules into a screw extruder for melt spinning: the length-diameter ratio of the screw is 1: 40, the temperature of each section of the screw is 150 ℃, the extrusion speed of the screw is 200 r/min, the holes of a spinneret plate are 100, the aperture is 0.5mm, the temperature of a spinneret melt is controlled at 200 ℃, a nozzle drafts 5 m/min, then the high-strength fiber is obtained by pre-stretching and winding, and then the high-strength fiber is obtained by extraction, drying and super-stretching processes.
Preferably, the high-strength fiber is prepared by mixing 20 parts of ultra-high molecular weight polyethylene powder with the molecular weight of 150-200 ten thousand, 4 parts of polyformaldehyde, 80 parts of paraffin oil, 3 parts of lignin and 2 parts of nano organic bentonite in a mixing kettle, heating and stirring, heating to the temperature of 150 ℃ to obtain an expansion liquid, naturally cooling to form a gel block, taking out the gel block, crushing the gel block into granules on a crushing device, removing part of solvent by using a deoiling device, and inputting the granules into a screw extruder for melt spinning: the length-diameter ratio of the screw is 1: 40, the temperature of each section of the screw is 250 ℃, the extrusion speed of the screw is 250 rpm, the hole diameter of a spinneret plate is 150, the hole diameter is 0.8mm, the temperature of a spinneret melt is controlled at 220 ℃, a nozzle drafts 15 m/min, then the high-strength fiber is obtained by pre-stretching and winding, and then the high-strength fiber is obtained by extraction, drying and super-stretching processes.
The base layer is woven by warps and wefts, the wefts comprise first wefts, second wefts and third wefts, the warps comprise first warps and second warps, and the first wefts, the second wefts and the third wefts are woven according to the proportion of 1:1 arrangement, the first warp and the second warp are in proportion of 2: 1, the first warp adopts polyamide fiber, the second warp adopts polyacrylonitrile fiber, the first weft adopts polyester fiber, the second weft adopts glass fiber, and the third weft adopts flax fiber.
In a particular embodiment of the invention, the plastic film is a waterproof breathable film, preferably a waterproof breathable polyurethane film.
The base layer and the bottom layer are bonded together through a bonding agent; preferably, the binder is a polyester powder.
Detailed Description
Example 1: waterproof geotextile
The geotextile comprises a base layer and a bottom layer; the base layer is formed by weaving warps and wefts, and a plastic film is bonded on the surface of the base layer; the bottom layer comprises polyimide fibers, glass fibers and high-strength fibers, and the three fibers are interwoven together through needling and heat setting after opening, mixing, carding and lapping; the weight ratio of the polyimide fiber, the glass fiber and the high-strength fiber is 4: 4: 2;
the high-strength fiber is prepared by mixing 15 parts of ultra-high molecular weight polyethylene powder with the molecular weight of 150-: the length-diameter ratio of the screw is 1: 40, the temperature of each section of the screw is 200 ℃, the extrusion speed of the screw is 220 r/min, 130 holes of a spinneret plate and the aperture is 0.6mm, the temperature of a spinneret melt is controlled at 210 ℃, a nozzle drafts 10 m/min, then the high-strength fiber is obtained by pre-stretching and winding, and then the high-strength fiber is obtained by extraction, drying and super-stretching processes;
the base layer is woven by warps and wefts, the wefts comprise first wefts, second wefts and third wefts, the warps comprise first warps and second warps, and the first wefts, the second wefts and the third wefts are woven according to the proportion of 1:1 arrangement, the first warp and the second warp are in proportion of 2: 1, arranging the first warp yarns and the second warp yarns, wherein the first warp yarns are made of polyamide fibers, the second warp yarns are made of polyacrylonitrile fibers, the first weft yarns are made of polyester fibers, the second weft yarns are made of glass fibers, and the third weft yarns are made of flax fibers;
the base layer and the bottom layer are bonded together by polyester powder.
Example 2 a waterproof geotextile
The geotextile comprises a base layer and a bottom layer; the base layer is formed by weaving warps and wefts, and a plastic film is bonded on the surface of the base layer; the bottom layer comprises polyimide fibers, glass fibers and high-strength fibers, and the three fibers are interwoven together through needling and heat setting after opening, mixing, carding and lapping; the weight ratio of the polyimide fiber, the glass fiber and the high-strength fiber is 4: 4: 2;
the high-strength fiber is prepared by mixing 10 parts of ultra-high molecular weight polyethylene powder with the molecular weight of 150-: the length-diameter ratio of the screw is 1: 40, the temperature of each section of the screw is 150 ℃, the extrusion speed of the screw is 200 rpm, the holes of a spinneret plate are 100, the aperture is 0.5mm, the temperature of a spinneret melt is controlled at 200 ℃, a nozzle drafts 5 m/min, then the high-strength fiber is obtained by pre-stretching and winding, and then the high-strength fiber is obtained by extraction, drying and super-stretching processes;
the base layer is woven by warps and wefts, the wefts comprise first wefts, second wefts and third wefts, the warps comprise first warps and second warps, and the first wefts, the second wefts and the third wefts are woven according to the proportion of 1:1 arrangement, the first warp and the second warp are in proportion of 2: 1, arranging the first warp yarns and the second warp yarns, wherein the first warp yarns are made of polyamide fibers, the second warp yarns are made of polyacrylonitrile fibers, the first weft yarns are made of polyester fibers, the second weft yarns are made of glass fibers, and the third weft yarns are made of flax fibers;
the base layer and the bottom layer are bonded together by polyester powder.
Example 3 preparation of a waterproof geotextile
The geotextile comprises a base layer and a bottom layer; the base layer is formed by weaving warps and wefts, and a plastic film is bonded on the surface of the base layer; the bottom layer comprises polyimide fibers, glass fibers and high-strength fibers, and the three fibers are interwoven together through needling and heat setting after opening, mixing, carding and lapping; the weight ratio of the polyimide fiber, the glass fiber and the high-strength fiber is 4: 4: 2;
the high-strength fiber is prepared by mixing 20 parts of ultra-high molecular weight polyethylene powder with the molecular weight of 150-: the length-diameter ratio of the screw is 1: 40, the temperature of each section of the screw is 250 ℃, the extrusion speed of the screw is 250 rpm, the hole diameter of a spinneret plate is 150, the hole diameter is 0.8mm, the temperature of a spinneret melt is controlled at 220 ℃, a nozzle is drafted for 15 m/min, then the high-strength fiber is obtained by pre-stretching and winding, and then the high-strength fiber is obtained by extraction, drying and super-stretching processes;
the base layer is woven by warps and wefts, the wefts comprise first wefts, second wefts and third wefts, the warps comprise first warps and second warps, and the first wefts, the second wefts and the third wefts are woven according to the proportion of 1:1 arrangement, the first warp and the second warp are in proportion of 2: 1, arranging the first warp yarns and the second warp yarns, wherein the first warp yarns are made of polyamide fibers, the second warp yarns are made of polyacrylonitrile fibers, the first weft yarns are made of polyester fibers, the second weft yarns are made of glass fibers, and the third weft yarns are made of flax fibers;
the base layer and the bottom layer are bonded together by polyester powder.
Comparative example 1: (polyimide fiber omitted from the base layer)
The geotextile comprises a base layer and a bottom layer; the base layer is formed by weaving warps and wefts, and a plastic film is bonded on the surface of the base layer; the bottom layer comprises glass fibers and high-strength fibers, and the two fibers are interwoven together through needling and heat setting after opening, mixing, carding and lapping; the weight ratio of the glass fiber to the high-strength fiber is 4: 4: 2; the rest is the same as example 1.
Comparative example 2: (omitting polyoxymethylene)
The high-strength fiber is prepared by mixing 15 parts of ultra-high molecular weight polyethylene powder with the molecular weight of 150-: the length-diameter ratio of the screw is 1: 40, the temperature of each section of the screw is 200 ℃, the extrusion speed of the screw is 220 r/min, 130 holes of a spinneret plate and the aperture is 0.6mm, the temperature of a spinneret melt is controlled at 210 ℃, a nozzle drafts 10 m/min, then the high-strength fiber is obtained by pre-stretching and winding, and then the high-strength fiber is obtained by extraction, drying and super-stretching processes; the rest is the same as example 1.
COMPARATIVE EXAMPLE 3 (omitting third weft)
The base layer is woven by warps and wefts, the wefts comprise first wefts and second wefts, the warps comprise first warps and second warps, the first wefts and the second wefts are arranged in a ratio of 1:1, and the first warps and the second warps are arranged in a ratio of 2: 1, arranging the first warp yarns and the second warp yarns, wherein the first warp yarns are made of polyamide fibers, the second warp yarns are made of polyacrylonitrile fibers, the first weft yarns are made of polyester fibers, and the second weft yarns are made of glass fibers; the rest is the same as example 1.
Comparative example 4 (changing the ratio of the first meridian to the second meridian)
The base layer is woven by warps and wefts, the wefts comprise first wefts, second wefts and third wefts, the warps comprise first warps and second warps, and the first wefts, the second wefts and the third wefts are woven according to the proportion of 1:1, arranging the first warp and the second warp according to the proportion of 1:1, arranging the first warp yarns and the second warp yarns, wherein the first warp yarns are made of polyamide fibers, the second warp yarns are made of polyacrylonitrile fibers, the first weft yarns are made of polyester fibers, the second weft yarns are made of glass fibers, and the third weft yarns are made of flax fibers; the rest is the same as example 1.
Example 4: performance testing
The mechanical properties of the waterproof geotextiles prepared in examples 1 to 3 of the present invention and comparative examples 1 to 4 were measured, and the results are shown in table 1.
Table 1 mechanical properties of the waterproof geotextile of the present invention
Breaking strength (KN/m) CBR bursting strength (KN)
Example 1 67 7.9
Example 2 66 8.0
Example 3 67 7.8
Comparative example 1 36 4.6
Comparative example 2 42 5.0
Comparative example 3 38 5.2
Comparative example 4 37 5.6
The results in Table 1 show that the geotextiles prepared in examples 1-3 of the present invention have excellent mechanical properties, and
the mechanical properties of the ratios 1 to 4 are significantly reduced.

Claims (4)

1. The waterproof geotextile is characterized by comprising a base layer and a bottom layer; the base layer is formed by weaving warps and wefts, and a plastic film is bonded on the surface of the base layer; the bottom layer comprises polyimide fibers, glass fibers and high-strength fibers, and the three fibers are interwoven together through needling and heat setting after opening, mixing, carding and lapping; the weight ratio of the polyimide fiber, the glass fiber and the high-strength fiber is 4: 4: 2;
the high-strength fiber is prepared by mixing 10-20 parts of ultra-high molecular weight polyethylene powder with the molecular weight of 150-200 ten thousand, 1-4 parts of polyformaldehyde, 60-80 parts of paraffin oil, 0.5-3 parts of lignin and 0.5-2 parts of nano organic bentonite in a mixing kettle, heating and stirring at the temperature of 130-150 ℃ to obtain an expansion liquid, naturally cooling to form a gel block, taking out the gel block, crushing the gel block into granules on crushing equipment, removing part of solvent by using deoiling equipment, and inputting the granules into a screw extruder for melt spinning: the length-diameter ratio of the screw is 1: 40, the temperature of each section of the screw is 150-250 ℃, the extrusion speed of the screw is 200-250 revolutions per minute, the holes of a spinneret plate are 100-150, the aperture is 0.5-0.8 mm, the temperature of a spinning melt is controlled at 200-220 ℃, the drafting of a nozzle is 5-15 m per minute, then the pre-stretching and winding are carried out, and the high-strength fiber is obtained through extraction, drying and super-stretching processes;
the base layer is woven by warps and wefts, the wefts comprise first wefts, second wefts and third wefts, the warps comprise first warps and second warps, and the first wefts, the second wefts and the third wefts are woven according to the proportion of 1:1 arrangement, the first warp and the second warp are in proportion of 2: 1, the first warp adopts polyamide fiber, the second warp adopts polyacrylonitrile fiber, the first weft adopts polyester fiber, the second weft adopts glass fiber, and the third weft adopts flax fiber.
2. The waterproof geotextile of claim 1, wherein the plastic film is a waterproof breathable film.
3. The waterproof geotextile of claim 1, wherein the base layer and the bottom layer are bonded together by an adhesive.
4. The waterproof geotextile of claim 3, wherein the binder is a polyester powder.
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CN203449688U (en) * 2013-07-27 2014-02-26 江阴市璜塘水利工程有限公司 Composite geotextile

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CN101775666A (en) * 2010-01-22 2010-07-14 东华大学 Preparation method of high-strength high-modulus polyethylene fiber
CN203331508U (en) * 2013-07-08 2013-12-11 周勤华 High-intensity combination geotextile
CN203449688U (en) * 2013-07-27 2014-02-26 江阴市璜塘水利工程有限公司 Composite geotextile

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