CN106538549A - A kind of bactericidal composition containing benziothiazolinone and flumorph - Google Patents
A kind of bactericidal composition containing benziothiazolinone and flumorph Download PDFInfo
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- CN106538549A CN106538549A CN201610965997.3A CN201610965997A CN106538549A CN 106538549 A CN106538549 A CN 106538549A CN 201610965997 A CN201610965997 A CN 201610965997A CN 106538549 A CN106538549 A CN 106538549A
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- Prior art keywords
- flumorph
- benziothiazolinone
- bactericidal composition
- composition containing
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
Abstract
The invention discloses a kind of bactericidal composition containing benziothiazolinone and flumorph, containing effective ingredient benziothiazolinone and flumorph.The weight ratio of benziothiazolinone and flumorph is 1：20～20：1, percentage by weight is 5～90% in the composition for benziothiazolinone and flumorph weight summation.Benziothiazolinone and flumorph compositionss are needed to can be prepared as the one kind in aqueous suspension agent, micro-capsule suspension, aqueous emulsion, microemulsion, ultra low volume liquids, wettable powder, water dispersible granules according to practical application, for preventing and treating cucumber downy mildew.
Description
Technical field
The present invention relates to a kind of bactericidal composition containing benziothiazolinone and flumorph, it is effective with benziothiazolinone and flumorph to be
Composition, for preventing and treating cucumber downy mildew.
Background technology
The resistance problem of agricultural disease is a global problem, always the emphasis class of agricultural science and technology worker concern
Topic.With the continuity year in year out of disease chemical prevention, the increase of Pesticide use amount and not scientifical use pesticide, pathogenic bacteria
Resistance is increasingly serious, and the pathogenic bacteria species for producing resistance is on the increase.Meanwhile, the use pesticide of high intensity causes agricultural product pesticide
Exceeded, environmental pollution and the increase of peasant's drug cost etc. are remained, is unfavorable for agricultural sustainable development.Therefore, research and develop efficiently,
Low toxicity, the bactericide agricultural chemicals of environmental protection have positive effect to agricultural sustainable development.
Benziothiazolinone English name：Benziothiazolinone, chemical name：1,2 benzisothiazole-3-ketones.Thiophene is mould
Ketone is a kind of new, wide-spectrum bactericide, is mainly used in preventing and treating and treating cucumber downy mildew, pear scab, apple scab, Citrus
The various bacteria of anthrax, grapevine anthracnose etc., fungal disease, destroy pathogenic bacteria nuclear structures so as to lose cardia
And exhaustion is dead and disturbs the metabolism of pathogenic bacteria cell so as to physiologic derangement, pathogenic bacteria is ultimately resulted in dead.
Flumorph English name：Flumorph, chemical name：(E, Z) 4- [3- (3', 4'- Dimethoxyphenyl) -3- (4-
Fluorophenyl) acryloyl] morpholine.Flumorph is acryloyl morpholine series bactericidal agent, is had both with absorbability, protection and therapeutical effect,
The main biosynthesiss by suppressing pathogen ergosterol, suppress spore germination, its therapeutical effect and lasting period to be superior to alkene
Morpholide, can be used for various crop and prevents and treats the microbial disease of the ovum such as downy mildew, late blight.
The mixture of different pesticide species, is the common methods for preventing and treating agricultural pest.Screened by formulation of pesticide, filtered out
Rational formula, can effectively improve actual prevention effect, reduce dosage, and reduces cost delays the drug-fast generation of pest and disease damage,
It is the important means of agricultural synthesis improvement.The present inventor is had made intensive studies to the recipe determination of benziothiazolinone and flumorph, is sent out
Existing benziothiazolinone and flumorph carry out mixture and have obvious potentiation to cucumber downy mildew pathogenic bacteria in certain mixed ratio scope,
After further study, complete the present invention.
The compositionss application of benziothiazolinone and flumorph there is no report at present.
The content of the invention
Present invention solves the technical problem that be to provide it is a kind of efficiently, low toxicity and the lasting period it is long, can effectively prevent and treat agriculture funguses
A kind of compositionss containing benziothiazolinone and flumorph of sexually transmitted disease (STD) evil.
To solve the above problems, the technical solution adopted in the present invention is：It is a kind of to contain benziothiazolinone and flumorph compositionss
And the ratio of weight and number of insecticides adjuvant, benziothiazolinone and flumorph is 1：20～20：1, benziothiazolinone and flumorph weight summation are in agriculture
Percentage by weight in drug composition is 5～90%.
A kind of described bactericidal composition containing benziothiazolinone and flumorph can be according to well known to a person skilled in the art side
Method, is configured to aqueous suspension agent, micro-capsule suspension, aqueous emulsion, microemulsion, ultra low volume liquids, wettable powder, water-dispersible grain
One kind in agent, for preventing and treating cucumber downy mildew.
A kind of described bactericidal composition containing benziothiazolinone and flumorph also has prepares helping needed for pesticidal preparations
Agent, auxiliary agent are solvent, emulsifying agent, wetting agent, stabilizer, dispersant, thickening agent, PH regulators, defoamer, antifreezing agent, filler
The mixing of one or more in agent etc., is known substance, is the various auxiliary agents commonly used in pesticidal preparations, according to different situations
Can be varied from, be not particularly limited.
Described a kind of bactericidal composition containing benziothiazolinone and flumorph, for preventing and treating cucumber downy mildew.
A kind of bactericidal composition containing benziothiazolinone and flumorph that the present invention is provided, is generally used using spray method,
Can also as needed using agriculturally apply other use technology.
One kind that the present invention is provided contains benziothiazolinone and flumorph compositionss have the advantages that：
1st, the bactericidal composition that the present invention is provided, shows obvious potentiation, compositionss in certain ratio range
The prevention effect of pathogenic bacteria is significantly improved than single dose, the using dosage of pesticide is reduced, is reduced times for spraying, reduce
Drug cost, reduces adverse effect of the pesticide to ecological environment.
2nd, the bactericidal composition that the present invention is provided, two kinds of active ingredient mechanism of action are not quite identical, can overcome long-term
Single to extend the service life of medicament using the shortcoming for easily producing resistance, the comprehensive control to pathogenic bacteria resistance has important meaning
Justice.
3rd, the bactericidal composition that the present invention is provided, drug effect play rapid, and the lasting period is long, and use cost is low, easy to use, save
Shi Shengli, its popularization and application have huge economic benefit and social benefit.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention are more short and sweet, present invention specific examples below
Illustrate, but the present invention is only limitted to absolutely not these embodiments.Described below is only the present invention preferably embodiment, is used only for
The description present invention, it is impossible to be interpreted as limiting the scope of the present invention.It should be pointed out that all in the spirit and principles in the present invention
Within any modification, equivalent and the improvement made etc., all should include within protection scope of the present invention.Therefore, originally
The protection domain of patent of invention should be defined by claims.
Amount described in embodiment is weight percentage.
Example of formulations case：The preparation method of present composition pesticidal preparations
Bactericidal composition described in embodiment 1 is aqueous suspension agent, and each component percentage amount is respectively：
Concrete operation step is：First other auxiliary agents are mixed, in cutter, shear-mixed is uniform, is subsequently adding benziothiazolinone
And flumorph, 2～3h is ground in ball crusher, a diameter is made in below 5mm, you can 32% benziothiazolinone flumorph water is obtained
Aqueous suspension formulations.
Bactericidal composition described in embodiment 2 is aqueous emulsion, and each component percentage amount is respectively：
Concrete operation step is：First benziothiazolinone and flumorph, trimethylbenzene, Sorbitan fatty acid ester are mixed,
Dissolving becomes uniform oil phase.Again part water and other auxiliary agents are mixed, dissolving becomes uniform water phase.Then anti-
Answer kettle high speed that oil phase is added water phase while stirring, slowly add water to and reach phase inversion point, carry out high speed shear afterwards, and add
Enter remaining water, shear about 30min, you can 21% benziothiazolinone flumorph water and milk agent formulation is obtained.
Bactericidal composition described in embodiment 3 is microemulsion, and each component percentage amount is respectively：
Concrete operation step is：First benziothiazolinone and flumorph are completely dissolved with fatty acid methyl ester, other are then added
Auxiliary agent, mix homogeneously are eventually adding water, after being sufficiently stirred for, you can 16% benziothiazolinone flumorph microemulsion formulation is obtained.
Bactericidal composition described in embodiment 4 is wettable powder, and each component percentage amount is respectively：
Concrete operation step is：Benziothiazolinone and flumorph, other auxiliary agents are sufficiently stirred in stirred tank, Jing comminution by gas stream
Mix homogeneously after machine crushing, you can 44% benziothiazolinone flumorph wettable powder formulation is obtained.
Bactericidal composition described in embodiment 5 is water dispersible granules, and each component percentage amount is respectively：
Concrete operation step is：To there are benziothiazolinone and flumorph, other auxiliary agent mix homogeneously, use micro jet powder
It is broken, pelletize, drying are carried out during fluidized-bed granulation dryer is added Jing after mediating, after screening, you can 60% benziothiazolinone fluorine is obtained
Morpholine water-dispersible grain agent formulation.
Bactericidal composition described in embodiment 6 is micro-capsule suspension, and each component percentage amount is respectively：
Concrete operation step is：By benziothiazolinone and flumorph, macromolecule cyst material, solvent mixing, dissolving is made uniformly
Oil phase, in a shear condition, oil phase is added to containing having in the aqueous phase solution of emulsifying agent, dispersant, adds Mannitol tune
Section pH value to 6.5, supply, and bi-material reacts in oil-water interfaces by surplus deionized water, forms high score ascus wall, you can
20% benziothiazolinone flumorph micro-capsule suspension is obtained.
Bactericidal composition described in embodiment 7 is ultra low volume liquids, and each component percentage amount is respectively：
Concrete operation step is：After benziothiazolinone and flumorph are dissolved with stirring solvent, other auxiliary agents are added, is fully stirred
Mix mix homogeneously, you can 4% benziothiazolinone flumorph ultra low volume liquids are obtained.
Bactericidal composition described in embodiment 8 is aqueous suspension agent, and each component percentage amount is respectively：
Concrete operation step is：First other auxiliary agents are mixed, in cutter, shear-mixed is uniform, is subsequently adding benziothiazolinone
And flumorph, 2～3h is ground in ball crusher, a diameter is made in below 5mm, you can 24% benziothiazolinone flumorph water is obtained
Aqueous suspension formulations.
Bactericidal composition described in embodiment 9 is microemulsion, and each component percentage amount is respectively：
Concrete operation step is：First benziothiazolinone and flumorph are completely dissolved with fatty acid methyl ester, other are then added
Auxiliary agent, mix homogeneously are eventually adding water, after being sufficiently stirred for, you can 22% benziothiazolinone flumorph microemulsion formulation is obtained.
Bactericidal composition described in embodiment 10 is aqueous emulsion, and each component percentage amount is respectively：
Concrete operation step is：First benziothiazolinone and flumorph, trimethylbenzene, Sorbitan fatty acid ester are mixed,
Dissolving becomes uniform oil phase.Again part water and other auxiliary agents are mixed, dissolving becomes uniform water phase.Then anti-
Answer kettle high speed that oil phase is added water phase while stirring, slowly add water to and reach phase inversion point, carry out high speed shear afterwards, and add
Enter remaining water, shear about 30min, you can 16% benziothiazolinone flumorph water and milk agent formulation is obtained.
Bactericidal composition described in embodiment 11 is water dispersible granules, and each component percentage amount is respectively：
Concrete operation step is：To there are benziothiazolinone and flumorph, other auxiliary agent mix homogeneously, use micro jet powder
It is broken, pelletize, drying are carried out during fluidized-bed granulation dryer is added Jing after mediating, after screening, you can 63% benziothiazolinone fluorine is obtained
Morpholine water-dispersible grain agent formulation.
In above dosage form, auxiliary agent is selected from described below：
Solvent can be solvent naphtha S-200, trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, Song Ji
One or more in oil, soybean oil, biodiesel, sec-Butyl Acetate, dimethyl carbonate, diesel oil, white oil, machine oil etc..
Emulsifying agent can be calcium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether, triphenoethyl benzene phenol polyoxypropylene gather
Oxygen ethylene block polymer, dibenzyl xenyl polyoxyethylene ether, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether,
Phenethyl phenol formaldehyde resin polyoxyethylene ether, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxypropylene polyoxy
Vinyl Ether, phenethyl phenol formaldehyde resin polyoxyethylene ether, Sorbitan fatty acid ester, sorbitan fatty acid ester polyoxy second
In alkene ether, natural fatty alcohol and ethylene oxide adduct, fatty acid and ethylene oxide condensate, polyoxyethylene fatty acid ester etc.
One or more.
Wetting agent can be sodium butylnaphthalenesulfonate, sodium lauryl sulphate, aliphatic alcohol polyethenoxy (6-7) ether, sulfonation amber
One or more in amber dioctyl phthalate sodium salt, Morwet EFW, alkylnaphthalene sulfonate etc..
Disintegrating agent can be compound sodium nitrophenolate, sodium bicarbonate, magnesium chloride, aluminum chloride, Sodium Chloride, carbamide, ammonium sulfate, bentonite
One or more in.
Dispersant can be polycarboxylate, the formaldehyde condensation products of methyl naphthalene sulfonic acid sodium, sodium lignin sulfonate, lignin sulfonic acid
Calcium, to methoxyl group fatty acyl anilinesulfonic acid, desaccharide and be classified sodium lignin sulfonate, naphthalene sulfonic acid condensate sodium salt, alkylnaphthalene
One or more in sulfonic acid condensation polymer sodium salt, APES formaldehyde condensation product sulphuric acid etc..
Thickening agent can be one or more in xanthan gum, aluminium-magnesium silicate, bentonite, white carbon etc..
During pH adjusting agent can be ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc.
One or more.
Stabilizer can be dibutyl phthalate, hexamethylene diisocyanate, epoxy soybean oil, epoxy chloropropionate
One or more in alkane, Butylated hydroxyanisole, dibenzylatiooluene, propylgallate, tert-butylhydroquinone etc..
Defoamer can be one or more in silicone compound, methanol, silicone oil, azone etc..
Antifreezing agent can be one or more in glycerol, ethylene glycol, Propylene Glycol, Sorbitol, Polyethylene Glycol etc..
Carrier can be Kaolin, kieselguhr, bentonite, white carbon, precipitated calcium carbonate, attapulgite, clay, Talcum
One or more in powder, quartz sand, starch, APG, carbamide, potassium chloride, ammonium chloride etc..
Slow releasing agent can be polyvinyl alcohol, one or two in arabic gum.
Binding agent can be Polyethylene Glycol, one or two in industrial gelatine.
Assays Example case
Cucumber downy mildew test adopted field spray method dispenser (having water membrane to be advisable with blade surface), in 2016 5
Carry out within 11st spraying treatment the moon, spray apparatus adopts hand sprayer (liquid capacity about 2.0L), every 10 days sprays once, even
Continuous spray 2 times.
Investigation method
0 grade：Disease-free spot
1 grade：Lesion area accounts for less than the 5% of whole leaf area；
3 grades：Lesion area accounts for the 6%-15% of whole leaf area；
5 grades：Lesion area accounts for the 16%-25% of whole leaf area；
7 grades：Lesion area accounts for the 26%-50% of whole leaf area；
9 grades：Lesion area accounts for more than the 50% of whole leaf area.
According to survey data, the disease index and prevention effect of each process are calculated.
Disease index presses formula calculating, and result of calculation retains 2 significant digits：
When carrying out drug combination toxicity test, this test calculates the coefficient of synergism (SR) of mixture using Wadley methods, evaluates
The synergy type of mixture.
Wadley methods：The potentiation of pharmacy mix, i.e. SR are evaluated according to coefficient of synergism (SR)<0.5 is antagonism,
0.5≤SR≤1.5 be summation action, SR>1.5 is synergistic function.Coefficient of synergism (SR) is calculated by formula (1), (2)：
In formula：
X1------------- mixture EC50Theoretical value, unit are milligrams per liter (mg/L)；
PA--- --- --- --- in-mixture A percentage composition, unit be percentage rate (%)；
PB--- --- --- --- in-mixture B percentage composition, unit be percentage rate (%)；
The EC of A in A--------------- mixtures50Value, unit are milligrams per liter (mg/L)；
The EC of B in B--------------- mixtures50Value, unit are milligrams per liter (mg/L).
In formula：
The coefficient of synergism of SR------------- mixtures；
The EC of X1-------------- mixtures50Theoretical value, unit are milligrams per liter (mg/L)；
The EC of X2-------------- mixtures50Measured value, unit are milligrams per liter (mg/L).
Synergy of 1 benziothiazolinone of table with flumorph to cucumber downy mildew pathogenic bacteria is determined
As can be seen from Table 1, benziothiazolinone and flumorph are 1：20～20：Compound in the range of 1, to cucumber downy mildew pathogenic bacteria
Show as potentiation.
Implement leading case in field：The present composition is used to prevent and treat cucumber downy mildew field test
Test site is located at Huizhou Zhong Kai Shi Zhen villages, is compared with 5% benziothiazolinone SC, 20% flumorph WP
Medicine, example of formulations medicament adopt nebulization, test to set 13 chemicals treatment altogether, and each processes 4 repetitions, 7 days after dispenser,
Respectively investigate a prevention effect within 15 days, record diseased plant number, count cucumber downy mildew sickness rate, calculate preventive effect, result of the test such as table 2
It is shown.
2 benziothiazolinone of table and flumorph combination preventing and treating cucumber downy mildew field test results
As can be seen from Table 2, example of formulations 1-11, the effect of benziothiazolinone and flumorph compounding to cucumber downy mildew preventing and treating
Process better than each control single dose.Illustrate that benziothiazolinone and flumorph compounding can reduce cucumber downy mildew sickness rate, reduce pesticide
Using dosage, reduces impact of the pesticide to environment, reduces drug cost.
Claims (6)
1. the weight ratio of a kind of bactericidal composition containing benziothiazolinone and flumorph, effective ingredient benziothiazolinone and flumorph is 1：20
～20：1.
2. the weight ratio of the bactericidal composition containing benziothiazolinone and flumorph, benziothiazolinone and flumorph according to claim 1
It is 1：10～10：1.
3. the bactericidal composition containing benziothiazolinone and flumorph according to claim 1, benziothiazolinone and flumorph weight it is total
Percentage by weight is 5～90% in the composition.
4. the bactericidal composition containing benziothiazolinone and flumorph according to claim 3, benziothiazolinone and flumorph weight it is total
Percentage by weight is 10～70% in the composition.
5. the bactericidal composition containing benziothiazolinone and flumorph according to claim 1, can be prepared as aqueous suspension agent, micro-
One kind in capsule suspension, aqueous emulsion, microemulsion, ultra low volume liquids, wettable powder, water dispersible granules.
6. according to a kind of bactericidal composition containing benziothiazolinone and flumorph described in claim 1, in preventing and treating Fructus Cucumidis sativi downy mildew
Application in disease.
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| CN201610965997.3A CN106538549A (en) | 2016-10-31 | 2016-10-31 | A kind of bactericidal composition containing benziothiazolinone and flumorph |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107006476A (en) * | 2017-05-10 | 2017-08-04 | 广东中迅农科股份有限公司 | A kind of composition pesticide containing imazalil and benziothiazolinone |
| CN108812684A (en) * | 2018-09-28 | 2018-11-16 | 陕西西大华特科技实业有限公司 | A kind of combination germicide containing benziothiazolinone and pyrimorph |
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| CN103300018A (en) * | 2012-08-13 | 2013-09-18 | 江苏辉丰农化股份有限公司 | Synergic sterilization composition containing benziothiazolinone and dimethomorph |
| CN103704234A (en) * | 2014-01-07 | 2014-04-09 | 中国农业科学院植物保护研究所 | Composite for preventing and controlling agricultural bacterial disease |
| AU2012387919B2 (en) * | 2012-08-13 | 2016-05-19 | Adama Huifeng (Jiangsu) Ltd. | Synergistic fungicide composition |
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- 2016-10-31 CN CN201610965997.3A patent/CN106538549A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103300018A (en) * | 2012-08-13 | 2013-09-18 | 江苏辉丰农化股份有限公司 | Synergic sterilization composition containing benziothiazolinone and dimethomorph |
| AU2012387919B2 (en) * | 2012-08-13 | 2016-05-19 | Adama Huifeng (Jiangsu) Ltd. | Synergistic fungicide composition |
| CN103704234A (en) * | 2014-01-07 | 2014-04-09 | 中国农业科学院植物保护研究所 | Composite for preventing and controlling agricultural bacterial disease |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107006476A (en) * | 2017-05-10 | 2017-08-04 | 广东中迅农科股份有限公司 | A kind of composition pesticide containing imazalil and benziothiazolinone |
| CN108812684A (en) * | 2018-09-28 | 2018-11-16 | 陕西西大华特科技实业有限公司 | A kind of combination germicide containing benziothiazolinone and pyrimorph |
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