CN106532194A - Metal-air battery system and vehicle - Google Patents

Metal-air battery system and vehicle Download PDF

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Publication number
CN106532194A
CN106532194A CN201611257263.6A CN201611257263A CN106532194A CN 106532194 A CN106532194 A CN 106532194A CN 201611257263 A CN201611257263 A CN 201611257263A CN 106532194 A CN106532194 A CN 106532194A
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CN
China
Prior art keywords
metal
electrolyte
air battery
air
liquid bath
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Granted
Application number
CN201611257263.6A
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Chinese (zh)
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CN106532194B (en
Inventor
柯浪
胡广来
汪云华
李富宇
冯育俊
田程
和晓才
徐俊毅
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Yunnan Chuangneng Feiyuan Metal Fuel Cell Co., Ltd.
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Yunnan Metallurgical Group Chong Neng Metal Fuel Cell Ltd By Share Ltd
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Priority to CN201611257263.6A priority Critical patent/CN106532194B/en
Publication of CN106532194A publication Critical patent/CN106532194A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/04Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode

Abstract

The invention discloses a metal-air battery system and a vehicle. The metal-air battery system comprises an electrolyte storage device, a metal-air battery device and an electrolyte distribution device, wherein an electrolyte storage space is limited in the electrolyte storage device; the metal-air battery device is arranged at the top of the electrolyte storage device and comprises a plurality of metal-air batteries which are connected in series; and the electrolyte distribution device is connected with the electrolyte storage device and the metal-air battery device separately and is used for providing the plurality of metal-air batteries with an electrolyte. The metal-air battery system disclosed by the embodiment of the invention has at least one of the advantages that the battery power is high, the structure is compact, heating of the electrolyte can be efficiently achieved, the problem that the batteries are difficulty to start is solved and battery module parts are not easily blocked by impurities generated in the discharging process.

Description

Metal-air battery system and vehicle
Technical field
The present invention relates to fuel cell field, in particular it relates to metal-air battery system and vehicle, more specifically, It is related to the metal fuel battery with aqueous solution as electrolyte, is related specifically to the aluminium-air cell of high-power output.
Background technology
Metal-air battery be a kind of oxygen with air as positive pole, metal or metal alloy as negative pole, it is neutral or Metal fuel battery of the alkaline aqueous solution for electrolyte.Metal-air battery is in running by consuming metal negative electrode and sky Oxygen in gas externally exports electric energy, is a kind of electrochmical power source.Through years of researches, the technology of metal-air battery gradually into It is ripe, for example, in aluminium-air cell, there are some low power products to realize commercialization.
However, current powerful metal-air battery still has much room for improvement.
The content of the invention
The application is the discovery of following facts and problem and understanding to be made based on inventor:
Current powerful metal-air battery generally existing such as battery structure is complicated, reliability is low, ambient temperature When low when start battery difficulty, high-rate battery discharge, the solid impurity that battery temperature is produced when easily too high, battery operated holds The problems such as easily blocking inside battery pipeline, therefore hinder the popularization and application of high-power metallic air cell.Inventor is through deep Enter research and many experiments find, this mainly due to current high-power metallic air cell structure design existing defects, So as to result in the need for arranging the supply that complicated electrolyte supply pipeline realizes electrolyte.And the longer electrolyte of complicated, flow process Feeding pipe, on the one hand can cause battery structure not compact, on the other hand, as metal-air battery is generally individually with certain Appropriate working temperature, therefore when the temperature of the surroundings is low, excessively complicated electrolyte supply pipeline is unfavorable for the insulation of electrolyte, So as to cause the difficulty in starting of battery during low temperature.Additionally, high-power metallic air cell is operationally, need to dissipate battery Heat is to prevent temperature too high, and the structure of complexity is also unsuitable for adding heat abstractor.Also, existing high-power metallic air electricity Pond, due to structure be related to it is excessively complicated, it is difficult to it is battery operated when the solid impurity that produces effectively filtered, and then easily make Into inside battery line clogging.
It is contemplated that at least solving one of technical problem in correlation technique to a certain extent.For this purpose, the present invention One purpose is to propose a kind of metal-air battery system.Embodiments in accordance with the present invention, the metal-air battery system bag Include:Electrolyte storage device, limits electrolyte memory space in the electrolyte storage device;Metal-air battery device, The metal-air battery device is arranged on the top of the electrolyte storage device, and the metal-air battery device bag Include multiple metal-air batteries of series connection;With electrolyte distributor, the electrolyte distributor respectively with the electrolyte Storage device is connected with the metal-air battery device, for supplying electrolyte to the plurality of metal-air battery.According to The above-mentioned metal-air battery system of the embodiment of the present invention has at least one of advantages below:The power of battery is big, compact conformation, The heating of electrolyte can be efficiently realized, is alleviated the difficult problem of start battery, the impurity of discharge process generation and is not easily blocked electricity Pond component parts etc..
Embodiments in accordance with the present invention, the electrolyte distributor include:Point liquid bath, described point of liquid bath are arranged on described Between metal-air battery device and the electrolyte storage device, and described point of liquid bath includes:Point liquid bath housing, described point Closing space is limited in liquid bath housing;Multiple points of liquid bath connectors, the plurality of point of liquid bath connector are arranged on described point of liquid The top of slot shell, and the plurality of point of liquid bath connector connected one to one with the plurality of metal-air battery respectively, For supplying the electrolyte in the metal-air battery;And point liquid bath inlet, described point of liquid bath inlet setting On described point of liquid bath housing, and electrolyte transfer pipeline, the electrolyte transfer pipeline is stored with the electrolyte respectively Device is connected with described point of liquid bath inlet, for supplying the electrolyte in described point of liquid bath thus, it is possible to easily real Evenly distributing and supplying for existing electrolyte, is conducive to simplifying electrolyte supply pipeline, makes the knot of the metal-air battery system Structure is compacter.
Embodiments in accordance with the present invention, the electrolyte distributor are further included:Driver element, the driver element It is arranged on the electrolyte transfer pipeline.Thus, it is possible to further improve the efficiency of electrolyte supply.
Embodiments in accordance with the present invention, the driver element are pump.Thus, advantageously reduce the metal-air battery system Equipment cost.
Embodiments in accordance with the present invention, described point of liquid bath inlet are arranged on the bottom of described point of liquid bath housing.
Embodiments in accordance with the present invention, the electrolyte distributor further include at least one following:Pipeline heating Unit, the pipeline heating unit are connected with the electrolyte transfer pipeline, for the electricity in the electrolyte transfer pipeline Solution liquid is heated;Filter element, the filter element are arranged on the electrolyte transfer pipeline, for the electrolyte Electrolyte in transfer pipeline is filtered.Thus, it is possible to realize carrying out height to supply to the electrolyte in metal-air battery The heating of effect, so as on the premise of pipeline heating unit energy resource consumption is saved, it is ensured that supply the electricity into metal-air battery Solution liquid has more suitable temperature.Filter element can effectively alleviate the solid impurity blocking of cell reaction generation in electrolyte The problem of pipeline.
Embodiments in accordance with the present invention, the electrolyte transfer pipeline is formed by metal material.Thus, it is easy to pipeline Heating unit is heated to the electrolyte in electrolyte transfer pipeline.
Embodiments in accordance with the present invention, the pipeline heating unit are included selected from least one of following:Resistive heater, Heat exchange fin, heat exchange coil and eddy heating for heating.Thus, it is possible to easily realize the heating to electrolyte, and it is not related to complexity Heating arrangement, is conducive to further reducing the volume of the metal-air battery system.
Embodiments in accordance with the present invention, the metal-air battery are further included:Metal-air battery housing, the gold Metal electrode and at least one air electrode are provided with category air cell housing;Metal-air battery electrolyte entrance, it is described Metal-air battery electrolyte entrance is arranged on the bottom of the metal-air battery housing, and metal-air battery electricity Solution liquid entrance is connected with described point of liquid bath connector;Metal-air battery electrolyte outlet, the metal-air battery electrolyte Outlet is arranged on the side wall of the metal-air battery housing;And electrolyte recovery pipe, the electrolyte recovery pipe It is connected with the metal-air battery electrolyte outlet.Thus, it is possible to utilize metal-air battery electrolyte outlet and electrolyte The radiating of the electrolyte that at least one of recovery pipe is discharged after further strengthening reacting.
Embodiments in accordance with the present invention, the metal-air battery electrolyte outlet is with the electrolyte recovery pipe extremely One of few formed by metal material.Thus, it is possible to further improve the heat-sinking capability of the metal-air battery.
Embodiments in accordance with the present invention, the metal-air battery electrolyte outlet is with the electrolyte recovery pipe extremely One of few formed by copper, rustless steel, nickel or ferrum.
Embodiments in accordance with the present invention, the metal-air battery electrolyte entrance with described point of liquid bath connector is It is detachably connected.
Embodiments in accordance with the present invention, the metal-air battery electrolyte entrance with described point of liquid bath connector is It is connected by screw thread.
Embodiments in accordance with the present invention, the metal-air battery include two air electrodes, the metal electrode It is arranged between described two air electrodes, and the metal-air battery is further included:Barriers, the barriers set Put on the side wall of the metal-air battery housing of side corresponding with the air electrode.
Embodiments in accordance with the present invention, the metal-air battery system are further included:Radiating subassembly, the radiating subassembly It is disposed adjacent with the metal-air battery device, to radiate to the metal-air battery device.Thus, may be used Further to put forward the structure for simplifying the metal-air battery system, radiating effect is improved.
Embodiments in accordance with the present invention, the radiating subassembly include fan.Thus, it is possible to reduce the metal-air battery system The equipment cost of system.
Embodiments in accordance with the present invention, the plurality of metal-air battery is along the length side of the metal-air battery device To be arrangeding in parallel, and the metal-air battery system is further included:Battery cover board, the battery cover board are arranged on described The top of multiple metal-air batteries, and the battery cover board is connected with least two metal electrodes, on the battery cover board Multiple through holes are provided with, the metal electrode passes through the through hole and is fixed on the battery cover board.Thus, needing more When changing metal electrode, multiple metal electrodes that can be easily to being fixed on battery cover board carry out unifying to change, such that it is able to Shorten servicing down times, improve the work efficiency of the metal-air battery system.
Embodiments in accordance with the present invention, the metal-air battery system are further included:Conducting strip, the conducting strip connect Connect the metal electrode and the air electrode of the two neighboring metal-air battery.Thus, it is possible to easily realize many Series connection between individual metal-air battery.
Embodiments in accordance with the present invention, the metal-air battery system are further included:Electrolyte accumulator tank, the electricity The solution liquid accumulator tank electrolyte recovery pipe and the electrolyte storage device respectively with the plurality of metal-air battery It is connected.Thus, it is possible to easily realize the recovery of electrolyte after reaction.
Embodiments in accordance with the present invention, the electrolyte accumulator tank are arranged on the metal-air battery device and the electricity Between solution liquid storage device.Thus, it is possible to further save the space that the metal-air battery system takes.
In another aspect of this invention, the present invention proposes a kind of vehicle.Embodiments in accordance with the present invention, the vehicle include Foregoing metal-air battery system.Thus, the vehicle has what foregoing metal-air battery system had Whole features and advantage, will not be described here.
Description of the drawings:
Fig. 1 shows the structural representation of metal-air battery system according to an embodiment of the invention;
Fig. 2 shows the structural representation of metal-air battery system in accordance with another embodiment of the present invention;
Fig. 3 shows the Longitudinal cross section schematic of the part-structure of metal-air battery according to an embodiment of the invention;
Fig. 4 shows the Longitudinal cross section schematic of metal-air battery part-structure in accordance with another embodiment of the present invention;
Fig. 5 shows the part-structure schematic diagram of metal-air battery device according to an embodiment of the invention;
Fig. 6 shows the part-structure schematic diagram of metal-air battery device in accordance with another embodiment of the present invention;
Fig. 7 shows the Longitudinal cross section schematic of the part-structure of metal-air battery according to an embodiment of the invention;
Fig. 8 shows the side diagram of the part-structure of metal-air battery in accordance with another embodiment of the present invention;
Fig. 9 shows the Longitudinal cross section schematic of the part-structure of metal-air battery according to an embodiment of the invention;
Figure 10 shows the side view of the part-structure of metal-air battery system according to an embodiment of the invention;
Figure 11 shows the bottom view of the part-structure of electrolyte distributor according to an embodiment of the invention;
Figure 12 shows the side view of the part-structure of metal-air battery system according to an embodiment of the invention;
Figure 13 shows the side view of the part-structure of metal-air battery system in accordance with another embodiment of the present invention;
Figure 14 shows the side view of the part-structure of the metal-air battery system according to another embodiment of the invention;
Figure 15 shows the side view of the part-structure of metal-air battery device according to an embodiment of the invention;
Figure 16 shows the side view of the part-structure of metal-air battery device in accordance with another embodiment of the present invention; And
Figure 17 shows the top view of the part-structure of metal-air battery device in accordance with another embodiment of the present invention.
Specific embodiment
Embodiments of the invention are described below in detail, the example of the embodiment is shown in the drawings, wherein from start to finish Same or similar label represents same or similar element or the element with same or like function.Below with reference to attached The embodiment of figure description is exemplary, it is intended to for explaining the present invention, and be not considered as limiting the invention.
In describing the invention, it is to be understood that term " on ", the orientation of the instruction such as D score or position relationship be base In orientation shown in the drawings or position relationship, it is for only for ease of the description present invention and simplifies description, rather than indicate or imply The device or element of indication must have specific orientation, with specific azimuth configuration and operation, therefore it is not intended that to this The restriction of invention.
In one aspect of the invention, the present invention proposes a kind of metal-air battery system.Enforcement of the invention Example, with reference to Fig. 1, the metal-air battery system includes:Electrolyte storage device 100, metal-air battery device 200 and electricity Solution liquid distributor 300.Specifically, electrolyte memory space 110 is limited in electrolyte storage device 100, for storing electricity Solution liquid.Metal-air battery device 200 is arranged on the top of electrolyte storage device 100, and metal-air battery device 200 includes Multiple metal-air batteries 210 of series connection.Thus, it is possible to increase the power of the metal-air battery system.Electrolyte distribution dress Put 300 to be connected with electrolyte storage device 100 and metal-air battery device 200 respectively, for multiple metal-air batteries 210 supply electrolyte.The metal-air battery system using upper (metal-air battery device 200), in (electrolyte distributor 300) structure design of (electrolyte storage device 100) under, can effectively simplify the electrolyte supply pipeline needed for the system, So as to the structure for advantageously allowing the battery system is compacter, while the solid impurity of cell reaction generation effectively can be alleviated Blocking pipeline.Above-mentioned metal-air battery system according to embodiments of the present invention has at least one of advantages below:Battery work( Rate is big, compact conformation, the heating that can efficiently realize electrolyte, alleviate the difficult problem of start battery, discharge process and produce Impurity is not easily blocked battery component part etc..
Below according to the specific embodiment of the present invention, each device and part of the metal-air battery system are carried out Describe in detail.Understand for convenience, first below the workflow of the metal-air battery system is briefly described:Electrolysis Storage in liquid storage device 100 has appropriate electrolyte, and when the metal-air battery system is started working, electrolyte is by electricity Solution liquid distributor 300 is supplied into metal-air battery device 200, and electrolyte is filled with multiple metal-air batteries 210 Afterwards, air electrode and metal electrode turn on and occur electrode reaction, start outwardly energy supply.When the metal-air battery system When needing to quit work, stop in metal-air battery device 200 supplying electrolyte, in metal-air battery device 200 Electrolyte is sent back in electrolyte storage device 100, to be subsequently circulated utilization.Now in multiple air cells 210 Electroless liquid, the electrical connection between air electrode and metal electrode disconnect, and electrode reaction stops.When needing to be again started up this it is During system, electrolyte is supplied in metal-air battery device 200 again, repeat said process.Thus, electrolyte can be in battery Realize circulating in the course of work, and then on the one hand can take the solid impurity produced in discharge process and heat out of battery Cavity, it is unobstructed so as to ensure inside battery runner, on the other hand, can also be by the circulation of electrolyte so that all metals are empty The electrolyte temperature of gas inside battery is consistent.
It should be noted that in the present invention, the particular type of above-mentioned metal-air battery system is not particularly limited, only It is that previously described dependence oxygen and metal electrode carry out electrode reaction to want its energy supply principle.For example, can be empty for zinc Pneumoelectric pond, and for example, can be aluminium-air cell.
Embodiments in accordance with the present invention, with reference to Fig. 2, metal-air battery device 200 includes multiple metal-air batteries 210, multiple metal-air batteries 210 can be arranged in parallel along the length direction of metal-air battery device.In other words, Multiple metal-air batteries 210 are vertically disposed in metal-air battery device 200, and multiple metal-air batteries 210 can With along same linear array.Thus, be conducive to saving the space of metal-air battery device 200.
Electrolyte distributor 300 includes:Divide liquid bath 310 and electrolyte transfer pipeline 320.Liquid bath 310 is divided to be arranged on Between metal-air battery device 200 and electrolyte storage device 100, for the electricity that will be stored in electrolyte storage device 100 Solution liquid is allocated first, then is supplied uniformly across into multiple metal-air batteries 210.Specifically, liquid bath 310 is divided to include a point liquid Slot shell 1, multiple points of liquid bath connectors 2 and point liquid bath inlet 3.Divide in liquid bath housing and limit closing space, for reality The distribution of existing electrolyte.Multiple points of liquid bath connectors 2 are arranged on a point top for liquid bath housing 1, and multiple points of liquid bath connectors Connect one to one with multiple metal-air batteries 210 respectively.In other words, in metal-air battery system of the invention In, the quantity of metal-air battery 210 is equal with the quantity of point liquid bath connector 2, and each metal-air battery 210 with One point of liquid bath connector 2 is connected, and each point of liquid bath connector 2 also corresponds to one metal-air battery 210 of connection.Divide liquid bath Inlet 3 is arranged on point liquid bath housing, for example, and a point liquid bath inlet 3 can be arranged on a point bottom for liquid bath housing 1, is electrolysed One end of liquid transfer pipeline 320 is connected with a point liquid bath inlet 3, and the other end is connected with electrolyte storage device 100.Thus, may be used Easily to realize evenly distributing and supplying for electrolyte, be conducive to simplifying electrolyte supply pipeline, make the metal-air electricity The structure of cell system is compacter.
Embodiments in accordance with the present invention, electrolyte distributor 300 can further include with lower unit at least it One:Driver element 330, pipeline heating unit 340 and filter element 350.Embodiments in accordance with the present invention, driver element 330 Can be arranged on electrolyte transfer pipeline 320.Thus, it is possible to further improve the efficiency of electrolyte supply.For example, according to this The specific embodiment of invention, driver element 330 can be pump.Thus, advantageously reduce the equipment of the metal-air battery system Cost.
Pipeline heating unit is connected with electrolyte transfer pipeline 320, for the electrolyte in electrolyte transfer pipeline 320 Heated.Inventor is through further investigation discovery, current high-power metallic air cell, two in generally existing low temperature environment The problem of secondary difficulty in starting.And this mainly due to most metal-air batteries operationally, suitable electrolyte operating temperature For 45~55 degrees Celsius.Said temperature is higher than the ambient temperature under most times.Therefore, when electrolyte can not reach it is above-mentioned During appropriate working temperature, need, using electrolyte heating unit, to heat electrolyte.And existing high-power metallic air Battery is complex due to electrolyte supply pipeline, therefore when heating to electrolyte, usually using to the storage of whole electrolyte The mode heated by electrolyte in cryopreservation device.The mode of heating not only causes heating unit to need to expend larger energy, And the tube side due to electrolyte in pipeline is longer, therefore heats are not good.Due to present invention employs it is foregoing upper, In, under structure design, therefore can be used for heating the pipeline heating unit 340 of electrolyte and be arranged on electrolyte transfer pipeline On 320.Thus, it is possible to have pointedly heat to the electrolyte into multiple metal-air batteries 210 will be supplied, On the one hand can reduce for heating the energy expended required for electrolyte, the effect of electrolyte heating on the other hand, can be improved Rate.Be heated to preference temperature the direct Jing electrolyte distributor of electrolyte 300 be allocated by enter metal-air electricity Electrode reaction is carried out in pond 210, so as to avoid heated electrolyte in course of conveying temperature drop and affect battery Work.Embodiments in accordance with the present invention, electrolyte transfer pipeline can be formed by metal material.Thus, it is easy to pipeline to add Hot cell is heated to the electrolyte in electrolyte transfer pipeline.Thus, it is possible to further improve the efficiency of heating.According to this Inventive embodiment, pipeline heating unit 340 can be included selected from least one of following:Resistive heater, heat exchange fin, change Hot coil and eddy heating for heating.For example, pipeline heating unit 340 can include external heat power supply, and to be arranged on electrolyte defeated Send the resistive heater inside pipeline 320.Thus, it is possible to easily realize the heating to electrolyte, and it is not related to adding for complexity Heat structure, is conducive to further reducing the volume of the metal-air battery system.
Embodiments in accordance with the present invention, filter element 350 can be arranged on electrolyte transfer pipeline 320, for electricity Electrolyte in solution liquid transfer pipeline 320 is filtered, such that it is able to effectively alleviate the solid that cell reaction is generated in electrolyte The problem of impurity blocking pipeline.It should be noted that in the present invention, the particular type of filter element 350 and the position of setting Put and be not particularly limited, those skilled in the art can be selected according to practical situation.For example, when driver element 330 is water During pump, filter element 350 can be added before driver element 330, in other words, the electricity in electrolyte storage device 100 Solution liquid can first pass around filter element 350 and remove solid impurity, then supply to electrolyte through driver element 330 again and convey Pipeline 320.Thus, it is possible to extend the service life of driver element 330.Or, it is defeated that filter element 350 can be arranged on electrolyte Send between pipeline 320 and driver element 330, or be arranged between electrolyte transfer pipeline 320 and point liquid bath 310.As long as crossing Filter unit 350 can be filtered to electrolyte before electrolyte supply to metal-air battery device 200 in advance. As metal-air battery system structure of the present invention is more compact, the electrolyte transfer pipeline of complexity is not related to, because This electrolyte storage device 100 and electrolyte distributor 300 can realize cleaning with relatively simple.Thus, mistake As long as filter unit 350 can prevent solid impurity from entering metal-air battery device 200.
Embodiments in accordance with the present invention, with reference to Fig. 3 and Fig. 4, metal-air battery 210 can further include following Part:Metal-air battery housing 10, metal-air battery electrolyte entrance 20, metal-air battery electrolyte outlet 30, electricity Solution liquid recovery pipe 40, metal electrode 50, at least one air electrode 60 and barriers 70.Specifically, metal-air battery Metal electrode 50 and at least one air electrode 60 are provided with housing 10, to realize the electrode of the metal-air battery 210 Reaction.For example, according to a particular embodiment of the invention, metal-air battery 210 can include two air electrodes 60 and Individual metal electrode 50, metal electrode 50 are arranged between two air electrodes 60.Thus, it is possible to improve air electrode with air Contact area, improves the performance of the metal-air battery.It will be appreciated to those of skill in the art that as air electrode 60 is needed To contact with external environment, the electrode reaction on air electrode is completed using oxygen.Therefore, when multiple metal-air batteries 210 When being arranged in order along same straight line, can have on the side wall of 60 side of air electrode in metal-air battery housing 10 and resistance is set Spacing body 70, to prevent from contacting between the air cell of adjacent two metal-air battery 210, and causes short circuit.Metal-air Battery electrolyte entrance 20 can be arranged on the bottom of metal-air battery housing 10, and be connected with a point liquid bath connector 2, with Just electrolyte is supplied into metal-air battery housing 10.Metal-air battery electrolyte outlet 30 is arranged on metal-air battery On the side wall of housing 10, electrolyte recovery pipe 40 is connected with metal-air battery electrolyte outlet 30, wherein, metal-air electricity At least one of pond electrolyte outlet 30 and electrolyte recovery pipe 40 are formed by metal material.Reacted electrolyte by Metal-air battery electrolyte outlet 30 discharges metal-air battery housing 10, and is back to electricity by electrolyte recovery pipe 40 In solution liquid storage device 100.The metal-air battery electrolyte outlet and/or electrolyte recovery pipe that metal is formed can enter one The radiating of the electrolyte that step is discharged after strengthening reaction, so as to be conducive to improving the performance of the metal-air battery system.Metal is empty At least one of pneumoelectric pond electrolyte outlet and electrolyte recovery pipe can be by including but not limited to copper, rustless steel, nickel or What ferrum was formed.Above-mentioned metal has preferable heat conductivility, and will not form galvanic element, will not be to the metal-air battery 210 Impact.According to a particular embodiment of the invention, metal-air battery electrolyte entrance 20 with a point liquid bath connector 2 can be It is detachably connected, for example, it may be connected by screw thread.Thus, be conducive to dismantling the metal-air battery with And safeguard.
As metal-air battery needs consumption metal electrode to carry out negative reaction, it is therefore desirable to regularly replace metal electricity Pole.And in metal-air battery system according to embodiments of the present invention, with multiple metal-air batteries, it is therefore desirable to periodically right Multiple metal electrodes are changed.The operation of replacing electrode for convenience, improve production efficiency, embodiments in accordance with the present invention, With reference to Fig. 5 and Fig. 6, metal-air battery device 200 can further include battery cover board 220.Battery cover board 220 is arranged It is connected with least two metal electrodes 50 at the top of multiple metal-air batteries, and battery cover board.In other words, the battery Cover plate 220 can cover multiple metal-air batteries 210, and the metal electrode 50 of multiple metal-air batteries 210 can be fixed On same battery cover board 220.Thus, when needing to change metal electrode 50, can easily to being fixed on battery cover board Multiple metal electrodes 50 on 220 carry out unifying to change, and such that it is able to shorten servicing down times, improve the metal-air battery The work efficiency of system.Specifically, multiple through holes can be provided with battery cover board 220, metal electrode 50 can be provided with and wear The conductor portion of through hole is crossed, and is fixed on battery cover board 220 by contact screw 80.Thus, it is easy to simplify and changes metal electrode Operation.Embodiments in accordance with the present invention, metal-air battery device 200 can further include conducting strip 230, so as to even The metal electrode 50 and air electrode 60 of two neighboring metal-air battery 210 are connect, is realized between multiple metal-air batteries 210 Series connection.Embodiments in accordance with the present invention, conducting strip 230 can be the bonding jumper with certain length, one end of conducting strip 230 Be connected with the metal electrode 50 of a metal-air battery, the other end and be disposed adjacent with the metal-air battery another gold Air electrode 60 in category air cell is connected.Conducting strip can be by part and metals such as foregoing contact screw 80A Electrode or air electrode are connected.For example, with reference to Fig. 5 and Fig. 6, conducting strip can including horizontal part 230A, kink 2360B with And vertical component effect 230C, horizontal part 230A are fixed on battery cover board 220, and it is connected with metal electrode 50 by contact screw 80; Connected by kink 230B between vertical component effect 230C and horizontal part 230A, and by between horizontal part 230A and vertical component effect 230C Stagger certain distance, so that vertical component effect 230C can be with next metal-air battery (with the metal electricity for being connected to horizontal part 91 Another adjacent metal-air battery of extremely affiliated metal-air battery) in air electrode 60 be connected.
Embodiments in accordance with the present invention, with reference to Fig. 7~Fig. 9, metal-air battery and battery cover board can also with Lower structure:10 bottom of metal-air battery housing is provided with metal-air battery electrolyte entrance 20, metal-air battery electrolysis Liquid outlet 30 is arranged on the side wall on 10 top of metal-air battery housing, and electrolyte recovery pipe 40 is arranged on metal-air electricity It is connected on the side wall of pond housing 10 and with metal-air battery electrolyte outlet 30.Metal-air battery housing 10 and air electrode The 60 side walls being connected are provided with air vent, so that air electrode 60 can touch outside air.To prevent disposed at air vent from exposing Air electrode 60 and setting adjacent thereto another metal-air battery 210 in air electrode 60 contact, barriers 70 Across the middle part of air vent, while the air electrode 60 for preventing two adjacent metal-air batteries 210 contacts, may be used also To provide certain support as air electrode 60.Can be connected by air electrode conducting strip 90 between two air electrodes 60, And the connection of air electrode 60 and external circuit is realized by air electrode conducting strip 90 by contact screw 80B.Two air electrodes 60 could be arranged to respectively close to two side walls relative in metal-air battery housing 10, air electrode conducting strip 90 and company The contact screw 80B for connecing air electrode conducting strip can be fixed in metal-air battery housing 10 and two with air electrode On adjacent side wall of individual side wall.The conducting strip of foregoing connection air electrode and aluminium electrode (metal electrode 50) 230 vertical component effect can be extended on the side wall with 90 side of air electrode conducting strip, and by contact screw and air electricity Pole conducting strip 90 is fixedly connected.Metal-air battery electrolyte outlet 30 and the electrolyte recovery pipe 40 that is attached thereto can be with It is arranged on the side wall with 90 opposite side of air electrode conducting strip.
Embodiments in accordance with the present invention, electrolyte storage device 100, metal-air battery device 200 and electrolyte point Can be configured so that with device 300 respectively independently detachable.Specifically, with reference to Figure 10, electrolyte storage device 100 can be by Electrolyte tank 120 and the electrolyte case lid 130 being disposed thereon are constituted.Electrolyte distributor 300 can be integrated in electrolysis In liquid case lid 130.Electrolyte case lid 130 is opened, electrolyte tank 120 can be cleaned.Can arrange in electrolyte tank 120 Electrolyte supply mouth, so that the addition (not shown) of electrolyte is realized when electrolyte case lid is not opened.Metal-air electricity Pool device 200 can be fixed on electrolyte case lid 130 by battery bracket 240.Electrolyte case lid 130 and battery bracket 240 can also be arranged to what is be detachably connected.Thus, it is possible to the easily electrolyte distribution to being integrated on electrolyte tank lid Device 300 is cleaned or is keeped in repair.Specifically, with reference to Figure 11, can have inside point liquid bath 310 of electrolyte distributor 300 There are multiple dividing plates 11, multiple and 210 one-to-one semiclosed chamber of metal-air battery to be internally formed in a point liquid bath 310 12.The top of multiple dividing plates 11 is connected with the top of point liquid bath 310, and the bottom of dividing plate 11 is not connected with the bottom of point liquid bath 310 Connect.Thus, electrolyte can be unified from the bottom of point liquid bath 310 to enter in point liquid bath by electrolyte supply pipeline 320, with point The rising of electrolyte level in liquid bath 310, the electrolyte in point liquid bath 310 are here divided evenly over multiple semi-enclosed chambers In, multiple metal-air electrodes 210 are subsequently entered, being evenly supplied for electrolyte is realized.Embodiments in accordance with the present invention, the metal Air battery system can further include electrolyte accumulator tank 360.Electrolyte accumulator tank 360 respectively with multiple metal-airs The electrolyte recovery pipe 40 of battery is connected with electrolyte storage device 100.Thus, it is possible to the electrolyte for reclaiming is oriented to electrolysis In liquid storage device away from driver element 330 one end, to increase circulation path of the electrolyte in electrolyte storage device, more Be conducive to battery cooling and the sedimentation of solid impurity.Embodiments in accordance with the present invention, electrolyte accumulator tank 360 can be arranged on gold Between category air battery device 200 and electrolyte storage device 100.For example, electrolyte accumulator tank 360 can be arranged on electrolyte The bottom of case lid 130, it is adjacent with point liquid bath 310.In other words, liquid bath 310 is divided to be arranged on the one of 130 bottom of electrolyte case lid Side, electrolyte accumulator tank 360 are arranged on the opposite side of 130 bottom of electrolyte case lid.Due at the top of point liquid bath 310 with multiple metals The metal-air battery electrolyte entrance 20 of air cell 210 is connected, and electrolyte recovery pipe 40 can be arranged to it is vertical to Under shed (refers to Figure 10), therefore, electrolyte accumulator tank and point liquid bath are arranged on into the bottom of electrolyte case lid 130, are conducive to Realize that point liquid bath and electrolyte accumulator tank are connected nearby with multiple electrolyte recovery pipes 40.Thus, it is possible to further save should The space that metal-air battery system takes.
Embodiments in accordance with the present invention, with reference to Figure 12~Figure 14, metal-air battery system can further include scattered Hot component 250.Radiating subassembly 250 can be arranged on the side wall of metal-air battery housing.For example, can be solid by radiating subassembly It is scheduled on battery bracket 240.Radiating subassembly can include multiple fans.Thus, it is possible to reduce the metal-air battery system Equipment cost, further puies forward the structure for simplifying the metal-air battery system, improves radiating effect.
With reference to Figure 15~Figure 17, in metal-air battery device, multiple metal-air batteries 210 can be along metal-air The length direction of cell apparatus 200 be arranged in parallel.Multiple metal-air batteries 210 have the side wall of air cell 60 towards metal The width of air battery device 200 is arranged, and the air electrode 60 of two neighboring metal-air battery 210 is oppositely arranged. In the metal-air battery device, 40 side of electrolyte recovery pipe of multiple metal-air batteries is arranged in metal-air battery dress 200 the same side is put, in multiple metal-air batteries 210, the contact screw 80B being connected with air electrode is arranged in the same side. Embodiments in accordance with the present invention, can have multiple battery cover boards, can fix on battery cover board in metal-air battery device There are multiple metal electrodes.Fixed gold on the number of metal-air battery, the number of battery cover board and same battery cover board The number of category electrode is not particularly limited, and those skilled in the art can be designed according to practical situation.For example, in order to set The simplicity of meter, on each battery cover board, the quantity of fixed metal electrode can be with equal, to realize the batch of battery cover board Production.For example, 5 metal electrodes can be fixed on each battery cover board, it is understood, therefore, that metal-air battery The number of the metal-air battery included in device, can be 5 multiple.For example, when metal-air battery device include 5 it is electric During the cover plate of pond, then there are in the metal-air battery device 25 metal-air batteries.For preferably self-contained battery cover plate, also Press strip 22 can be set at the top of battery cover board.
In another aspect of this invention, the present invention proposes a kind of vehicle.Embodiments in accordance with the present invention, the vehicle include Foregoing metal-air battery system.Thus, the vehicle has what foregoing metal-air battery system had Whole features and advantage, will not be described here.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show Example ", or the description of " some examples " etc. mean specific features with reference to the embodiment or example description, structure, material or spy Point is contained at least one embodiment or example of the present invention.In this manual, to the schematic representation of above-mentioned term not Identical embodiment or example must be directed to.And, the specific features of description, structure, material or feature can be with office Combined in one or more embodiments or example in an appropriate manner.Additionally, in the case of not conflicting, the skill of this area The feature of the different embodiments or example described in this specification and different embodiments or example can be tied by art personnel Close and combine.
Although embodiments of the invention have been shown and described above, it is to be understood that above-described embodiment is example Property, it is impossible to limitation of the present invention is interpreted as, one of ordinary skill in the art within the scope of the invention can be to above-mentioned Embodiment is changed, changes, replacing and modification.

Claims (14)

1. a kind of metal-air battery system, it is characterised in that include:
Electrolyte storage device, limits electrolyte memory space in the electrolyte storage device;
Metal-air battery device, the metal-air battery device are arranged on the top of the electrolyte storage device, and The metal-air battery device includes the multiple metal-air batteries connected;With
Electrolyte distributor, the electrolyte distributor are electric with the electrolyte storage device and the metal-air respectively Pool device is connected, for supplying electrolyte to the plurality of metal-air battery.
2. metal-air battery system according to claim 1, it is characterised in that the electrolyte distributor includes:
Liquid bath, described point of liquid bath is divided to be arranged between the metal-air battery device and the electrolyte storage device, and Described point of liquid bath includes:
Divide liquid bath housing, in described point of liquid bath housing, limit closing space;
Multiple points of liquid bath connectors, the plurality of point of liquid bath connector are arranged on the top of described point of liquid bath housing, and described Multiple points of liquid bath connectors are connected one to one with the plurality of metal-air battery respectively, for the metal-air battery It is middle to supply the electrolyte;And
Liquid bath inlet, described point of liquid bath inlet is divided to be arranged on described point of liquid bath housing, and
Electrolyte transfer pipeline, the electrolyte transfer pipeline respectively with the electrolyte storage device and described point of liquid bath feed liquor Mouth is connected, for supplying the electrolyte in described point of liquid bath,
Optionally, described point of liquid bath inlet is arranged on the bottom for dividing liquid bath housing.
3. metal-air battery system according to claim 2, it is characterised in that the electrolyte distributor is further Including at least one following:
Driver element, the driver element are arranged on the electrolyte transfer pipeline,
Optionally, the driver element is pump;
Pipeline heating unit, the pipeline heating unit are connected with the electrolyte transfer pipeline, for defeated to the electrolyte The electrolyte in pipeline is sent to be heated;
Filter element, the filter element are arranged on the electrolyte transfer pipeline, for the electrolyte transfer pipeline In electrolyte filtered.
4. metal-air battery system according to claim 2, it is characterised in that the electrolyte transfer pipeline is by gold Category material is formed.
5. metal-air battery system according to claim 3, it is characterised in that the pipeline heating unit includes being selected from It is at least one of following:Resistive heater, heat exchange fin, heat exchange coil and eddy heating for heating.
6. metal-air battery system according to claim 2, it is characterised in that the metal-air battery is further wrapped Include:
Metal-air battery housing, is provided with metal electrode and at least one air electrode in the metal-air battery housing;
Metal-air battery electrolyte entrance, the metal-air battery electrolyte entrance are arranged on the metal-air battery shell The bottom of body, and the metal-air battery electrolyte entrance is connected with described point of liquid bath connector;
Metal-air battery electrolyte outlet, the metal-air battery electrolyte outlet are arranged on the metal-air battery shell On the side wall of body;And
Electrolyte recovery pipe, the electrolyte recovery pipe are connected with the metal-air battery electrolyte outlet.
7. metal-air battery system according to claim 6, it is characterised in that the metal-air battery electrolyte goes out Mouthful it is to be formed by metal material with least one of the electrolyte recovery pipe;
Optionally, at least one of the metal-air battery electrolyte outlet and described electrolyte recovery pipe are by copper, no What rust steel, nickel or ferrum were formed.
8. according to the metal-air battery system described in claim 6, it is characterised in that the metal-air battery electrolyte entrance It is detachably connected with described point of liquid bath connector;
Optionally, the metal-air battery electrolyte entrance is connected by screw thread with described point of liquid bath connector.
9. the metal-air battery system described in claim 6, it is characterised in that the metal-air battery is included described in two Air electrode, the metal electrode are arranged between described two air electrodes, and the metal-air battery is further wrapped Include:
Barriers, the barriers are arranged on the side of the metal-air battery housing of side corresponding with the air electrode On wall.
10. profit requires the metal-air battery system described in 6, it is characterised in that further include:
Radiating subassembly, the radiating subassembly are disposed adjacent with the metal-air battery device, so as to empty to the metal Pneumoelectric pool device is radiated;
Optionally, the radiating subassembly includes fan.
11. profits require the metal-air battery system described in 6, it is characterised in that the plurality of metal-air battery is along the gold The length direction of category air battery device be arranged in parallel, and the metal-air battery device is further included:
Battery cover board, the battery cover board are arranged on the top of the plurality of metal-air battery, and the battery cover board with At least two metal electrodes are connected, and multiple through holes are provided with the battery cover board, and the metal electrode passes through the through hole simultaneously And be fixed on the battery cover board.
12. profits require the metal-air battery system described in 6, it is characterised in that the metal-air battery device is further wrapped Include:
Conducting strip, the conducting strip connect the metal electrode and the air electricity of the two neighboring metal-air battery Pole.
Metal-air battery system described in 13. claim 6, it is characterised in that the metal-air battery system is further Including:
Electrolyte accumulator tank, the electrolyte accumulator tank electrolyte recovery tube respectively with the plurality of metal-air battery Road is connected with the electrolyte storage device;
Optionally, the electrolyte accumulator tank be arranged on the metal-air battery device and the electrolyte storage device it Between.
14. a kind of vehicles, it is characterised in that including the metal-air battery system described in any one of claim 1~13.
CN201611257263.6A 2016-12-30 2016-12-30 Metal-air battery system and vehicle Active CN106532194B (en)

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CN109904566A (en) * 2017-12-11 2019-06-18 中国科学院大连化学物理研究所 A kind of metal-air batteries system
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CN103855446A (en) * 2012-11-29 2014-06-11 中国科学院大连化学物理研究所 Electrolyte storage box for metal-air cell system
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Publication number Priority date Publication date Assignee Title
CN107492603A (en) * 2017-07-20 2017-12-19 新材料与产业技术北京研究院 Aluminum air battery system
CN109904566A (en) * 2017-12-11 2019-06-18 中国科学院大连化学物理研究所 A kind of metal-air batteries system
RU2710024C1 (en) * 2018-10-29 2019-12-24 Федеральное государственное казенное военное образовательное учреждение высшего образования "ВОЕННАЯ АКАДЕМИЯ МАТЕРИАЛЬНО-ТЕХНИЧЕСКОГО ОБЕСПЕЧЕНИЯ имени генерала армии А.В. Хрулева" Metal-water battery
RU192241U1 (en) * 2019-04-24 2019-09-10 Общество с ограниченной ответственностью "АЛ Технолоджис" METAL-AIR BATTERY WITH PACK INSTALLATION AND REMOVAL DEVICE
CN112542598A (en) * 2020-12-24 2021-03-23 郑州佛光发电设备有限公司 System and method for heating metal air battery electrolyte by using self-oxygen production mode
CN112542598B (en) * 2020-12-24 2021-11-12 郑州佛光发电设备有限公司 System and method for heating metal air battery electrolyte by using self-oxygen production mode
CN113328115A (en) * 2021-05-20 2021-08-31 湖北劲铝新源电池科技有限公司 Metal-air battery system and vehicle
CN113328115B (en) * 2021-05-20 2022-05-31 湖北劲铝新源电池科技有限公司 Metal-air battery system and vehicle

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