CN106524188A - Plasma liquid waste disposal system with energy-saving preheating system - Google Patents

Plasma liquid waste disposal system with energy-saving preheating system Download PDF

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Publication number
CN106524188A
CN106524188A CN201611146730.8A CN201611146730A CN106524188A CN 106524188 A CN106524188 A CN 106524188A CN 201611146730 A CN201611146730 A CN 201611146730A CN 106524188 A CN106524188 A CN 106524188A
Authority
CN
China
Prior art keywords
residual liquid
liquid
waste
plasma
residual
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611146730.8A
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Chinese (zh)
Inventor
陈伟
余德平
姚进
张金刚
沈剑虹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Sri Pathma Environmental Technology Co Ltd
Original Assignee
Jiangsu Sri Pathma Environmental Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Sri Pathma Environmental Technology Co Ltd filed Critical Jiangsu Sri Pathma Environmental Technology Co Ltd
Priority to CN201611146730.8A priority Critical patent/CN106524188A/en
Publication of CN106524188A publication Critical patent/CN106524188A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/04Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste liquors, e.g. sulfite liquors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2204/00Supplementary heating arrangements
    • F23G2204/20Supplementary heating arrangements using electric energy
    • F23G2204/201Plasma
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/10Waste heat recuperation reintroducing the heat in the same process, e.g. for predrying
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/10Liquid waste

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention relates to a plasma liquid waste disposal system with an energy-saving preheating system. The plasma liquid waste disposal system comprises a residual liquid barrel, a residual liquid conveying pump, a residual liquid conveying pipeline, a distributing device, a cracking device and a burning device, wherein the residual liquid barrel, the residual liquid conveying pump, the residual liquid conveying pipeline, the distributing device, the cracking device and the burning device are connected in sequence, a plasma generator is arranged on the upper end of the distributing device, a first residual liquid preheating loop is arranged on the residual liquid conveying pipeline, the burning device comprises a burning pipe and an outer protective layer, a waste heat recovery coil is arranged in the outer protective layer, and the first residual liquid preheating loop communicates with the waste heat recovery coil. According to the device, on the basis of an arc plasma cracking technique, a residual liquid preheating system is cleverly arranged, and liquid waste is preheated, so that the temperature of the liquid waste is continuously increased, the viscosity is reduced, and the liquidity is gradually increased; when the liquid waste reaches enough liquidity, the liquid waste flows to the next process, so that the effects of energy conservation and high efficiency are achieved, full cracking and burning are guaranteed, and the plasma liquid waste disposal system is an ideal choice for treating hazardous waste liquid and waste gas.

Description

Plasma liquid waste treatment system with energy-conservation preheating system
Technical field
The invention belongs to the process field of danger wastes, useless more particularly, to a kind of plasma with energy-conservation preheating system Liquid treating system.
Background technology
Substantial amounts of poisonous and hazardous waste liquid can be produced during commercial production, especially organic liquid waste, liquid waste processing is current The big event of the offal treatment in the fields such as chemical industry, medicine, pesticide and petrochemical field, discharging of waste liquid need to meet certain ring Guaranteed request.And in prior art, Jing is processed to waste liquid frequently with the mode burned, as existing burning in-furnace temperature has Limit, some Organic substances cannot be decomposed completely, and incomplete combustion can produce secondary pollution, and the flue gas for producing that burns is cooled down not in time Or the extremely toxic substance such as not low enough easy two English of temperature, serious destruction, people can be caused to human body and environment to need badly and find one Plant new method to dispose waste liquid, such as waste liquid is preheated before burning, reduce waste liquid viscosity, meet by preheating Certain mobility, the process of convenient operation below, improves the efficiency of burning or other processing modes.
The content of the invention
For the defect of prior art, the invention provides a kind of flexible structure, efficient energy-saving, beneficial to before waste liquid feeds plus The plasma liquid waste treatment system with energy-conservation preheating system of heat.
The technical solution used in the present invention is:
Plasma liquid waste treatment system with energy-conservation preheating system, comprising the residual liquid bucket, residual liquid delivery pump being sequentially connected, residual Liquid conveyance conduit, distributing device, cracker, incinerator, the upper end of the distributing device are provided with plasma generator, institute State on residual liquid conveyance conduit, be provided with the first residual liquid pre-add hot loop, the incinerator includes burning pipe and external protection, institute State in external protection, be provided with waste heat recovery coil pipe, the first residual liquid pre-add hot loop is connected with waste heat recovery coil pipe.
On the residual liquid conveyance conduit, the second residual liquid pre-add hot loop is additionally provided with, in the second residual liquid pre-add hot loop, It is provided with pipeline heater.
Between the residual liquid conveyance conduit and residual liquid bucket, circulating line is additionally provided with.
Cloth tray of the distributing device comprising the charging aperture and annular shape being connected, the residual liquid conveyance conduit and distributing device Charging aperture connection, some spray apertures through annulus are distributed with the annulus wall of the cloth tray.
Cracking is to being injected into from distributing device by the high-temperature electric arc plasma torch of plasma generator generation What residual liquid was cracked, there is cracking in toxic waste, form cracking gas at high temperature;Residual liquid is entered by the aperture on distributing device Enter, in the outlet high-temperature region of plasma arc, material can be heated in distributing device vaporization distributing device, rain in the injection of plasma arc Main reaction region is directly entered after plasma arc mixing, that is, is served mixing and is served and be brought rapidly up, reduce invalid hot injury, So that cracking energy consumption is low, cracking is abundant, meanwhile, residual liquid in distributing device serves the effect of cooling distributing device, prevents plasma High temperature failure feed zone.
The upper part of the incinerator, is provided with a gas supplementing opening, for supplementing air or vapor, for remaining high Temperature reaction, further removes the carbon and organic components in flue gas, and the temperature in incinerator is more than 1500 degrees Celsius, usually 200-3500℃.Gas supplementing opening is set in incineration area, according to material balance, oxygen or vapor is directly filled into into incineration area, is made Obtaining the atoms such as C, H of high temperature carries out reacting secondary restructuring in this region, directly generates the chemistry such as stable carbon dioxide, vapor Stablize nontoxic material, it is to avoid the generation of secondary pollution, reaction is more abundant, while so that the high temperature of plasma generation Heat concentrate on main reaction region for heating crack residual liquid, greatly reduce invalid heat.
After the incinerator, quenching apparatus, water washing device and alkaline cleaner are also sequentially provided with, for carrying out at tail gas Reason.The incinerator and quenching apparatus are arranged on same manometer tube, the manometer tube upper semisection be incineration area, the pressure Pipe lower semisection is chilling area, and chilling area carries out quick refrigeration to less than 200 DEG C to the flue gas after burning, it is to avoid the product of two English It is raw.Water washing device to tail gas in most acid ingredients carry out solution absorption, alkaline cleaner is further to the acid in tail gas Property composition carries out synthesis, treats in tail gas only surplus carbon dioxide and vapor, enters air, complete the process of high-risk waste liquid.
Compared with prior art, the device of the present invention is based on using arc-plasma cracking technique, to residual liquid the present invention Preheating system is cleverly arranged that waste liquid is preheated, and waste liquid temperature is constantly raised, and viscosity is reduced, flowing Property is improved therewith, and after waste liquid reaches enough mobility, to next process, whole preheating process can pass through waste liquor stream Automated condtrol, processes convenient, efficient energy-saving, it is ensured that what is cracked and burn is abundant, and hazardous waste disposal ability is strong, Scope is wide, can complete nontoxic, the harmless treatment of nearly all type waste liquid, waste gas, can be towards chemical industry, medicine, pesticide, petrochemical industry Deng numerous areas, it is to avoid secondary pollution is produced, while avoiding the generation of two English, result can reach the U.S., Japan, Europe The environmental requirement of the multiple countries in continent, is to process dangerous waste liquid, the ideal chose of waste gas.
Description of the drawings
Structural representations of the Fig. 1 for the embodiment of the present invention 1;
Structural representations of the Fig. 2 for the embodiment of the present invention 2;
Distributing device structural representations of the Fig. 3 for the embodiment of the present invention.
Specific embodiment
Embodiment 1
As shown in figs. 1 and 3, the plasma liquid waste treatment system with energy-conservation preheating system, comprising the residual liquid bucket being sequentially connected 1st, residual liquid delivery pump 2, residual liquid conveyance conduit 3, distributing device 4, cracker 6, incinerator 7, the upper end of the distributing device 4, if Plasma generator 5 is equipped with, on the residual liquid conveyance conduit 3, the first residual liquid pre-add hot loop 3.1, the burning is provided with Device 7 is provided with waste heat recovery coil pipe 7.2 comprising pipe and external protection is burned in the external protection, and first residual liquid is pre- Heating circuit 3.1 is connected with waste heat recovery coil pipe 7.2.
The distributing device 4 includes the charging aperture 4.1 and circular cloth tray 4.2 being connected, the residual liquid conveyance conduit 3 It is connected with the charging aperture 4.1 of distributing device 4, some spray apertures through annulus on the annulus wall of the cloth tray 4.2, is distributed with 4.21。
The upper part of the incinerator 7, is provided with a gas supplementing opening 7.1.
After the incinerator 7, quenching apparatus, water washing device and alkaline cleaner are also sequentially provided with, for carrying out tail gas Process.The incinerator and quenching apparatus are arranged on same manometer tube, the manometer tube upper semisection be incineration area, the pressure Solenoid lower semisection is chilling area.
The pre-warmed operation principle of residual liquid is:
When burning does not also start, residual liquid directly can be got to by residual liquid conveyance conduit 3 by cloth by 2 strength of residual liquid delivery pump first Fed in device 4, crack then and burn, after starting to burn, the first residual liquid pre-add hot loop 3.1 on residual liquid conveyance conduit 3 Can start working, residual liquid be preheated by the heat for reclaiming, so that charging is easier, cracking also more thoroughly, is fired Burn more abundant;
Embodiment 2
As shown in Figures 2 and 3, on the basis of embodiment 1, on the residual liquid conveyance conduit 3, it is additionally provided with the second residual liquid and preheats back Road 3.2, in the second residual liquid pre-add hot loop 3.2, is provided with pipeline heater.The residual liquid conveyance conduit 3 and residual liquid bucket 1 it Between, it is additionally provided with circulating line 3.3.
The pre-warmed operation principle of residual liquid is:
When running into residual liquid viscosity and being very big, can first pass through residual liquid delivery pump 2 drive it is on residual liquid Jing residual liquids conveyance conduit 3 second residual Liquid pre-add hot loop 3.2 is squeezed in distributing device again after being preheated and completes charging, or, residual liquid delivery pump 2 can be first passed through Drive the second residual liquid pre-add hot loop 3.2 on residual liquid Jing residual liquids conveyance conduit 3 and coordinate circulating line 3.3 to preheat residual liquid bucket Residual liquid in 1, after residual liquid reaches uniform temperature or viscosity, closes the second residual liquid pre-add hot loop 3.2 and closed circuit 3.3, Squeezed into by residual liquid conveyance conduit 3 again and in distributing device 4, complete charging, cracked then and burned, after starting to burn, residual liquid is defeated Send the first residual liquid pre-add hot loop 3.1 on pipeline 3 start working, residual liquid is preheated by the heat for reclaiming.
The invention is not limited in aforesaid specific embodiment.The present invention is expanded to and any is disclosed in this manual New feature or any new combination, and the arbitrary new method that discloses or the step of process or any new combination.

Claims (4)

1. the plasma liquid waste treatment system with energy-conservation preheating system, it is characterised in that comprising the residual liquid bucket being sequentially connected, Residual liquid delivery pump, residual liquid conveyance conduit, distributing device, cracker, incinerator, the upper end of the distributing device, be provided with etc. from Daughter generator, on the residual liquid conveyance conduit, is provided with the first residual liquid pre-add hot loop, and the incinerator includes burning pipe And external protection, in the external protection, it is provided with waste heat recovery coil pipe, the first residual liquid pre-add hot loop and waste heat recovery Coil pipe is connected.
2. the plasma liquid waste treatment system with energy-conservation preheating system as claimed in claim 1, it is characterised in that described On residual liquid conveyance conduit, the second residual liquid pre-add hot loop is additionally provided with, in the second residual liquid pre-add hot loop, is provided with pipeline heating Device.
3. the plasma liquid waste treatment system with energy-conservation preheating system as claimed in claim 1, it is characterised in that described Between residual liquid conveyance conduit and residual liquid bucket, circulating line is additionally provided with.
4. the plasma liquid waste treatment system with energy-conservation preheating system as claimed in claim 1, it is characterised in that described After incinerator, quenching apparatus, water washing device and alkaline cleaner are also sequentially provided with, for carrying out vent gas treatment.
CN201611146730.8A 2016-12-13 2016-12-13 Plasma liquid waste disposal system with energy-saving preheating system Pending CN106524188A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201611146730.8A CN106524188A (en) 2016-12-13 2016-12-13 Plasma liquid waste disposal system with energy-saving preheating system

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110695056A (en) * 2019-10-20 2020-01-17 安徽航天环境工程有限公司 Oil sludge cracking treatment device
CN110695057A (en) * 2019-10-20 2020-01-17 安徽航天环境工程有限公司 Oil sludge cracking treatment method
CN110695055A (en) * 2019-10-20 2020-01-17 安徽航天环境工程有限公司 Red mud cracking treatment method
CN112923382A (en) * 2019-12-05 2021-06-08 核工业西南物理研究院 High-concentration organic waste liquid plasma cracking recombination system and method
CN114110624A (en) * 2021-11-29 2022-03-01 济南市琦泉热电有限责任公司 Waste oil and waste liquid incineration boiler for flue gas self-heating treatment

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08327040A (en) * 1995-06-01 1996-12-10 Fukuhara:Kk Waste liquid disposing apparatus
CN1342865A (en) * 2000-09-08 2002-04-03 浙江巨圣氟化学有限公司 Method for treating organic halide by plasma incineration and industrial device
CN103868079A (en) * 2014-04-08 2014-06-18 大连科林能源工程技术开发有限公司 High concentration saliferous organic waste liquor recycling chemical intermediate and waste heat utilizing boiler system
CN105889949A (en) * 2016-04-19 2016-08-24 山东聊城中盛蓝瑞化工有限公司 Organic wastewater incineration and gasification system and incineration and gasification method
CN106001064A (en) * 2016-06-17 2016-10-12 鞍山华融富瑞新能源科技有限公司 Ultra-low-temperature plasma organic waste recycling method and device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08327040A (en) * 1995-06-01 1996-12-10 Fukuhara:Kk Waste liquid disposing apparatus
CN1342865A (en) * 2000-09-08 2002-04-03 浙江巨圣氟化学有限公司 Method for treating organic halide by plasma incineration and industrial device
CN103868079A (en) * 2014-04-08 2014-06-18 大连科林能源工程技术开发有限公司 High concentration saliferous organic waste liquor recycling chemical intermediate and waste heat utilizing boiler system
CN105889949A (en) * 2016-04-19 2016-08-24 山东聊城中盛蓝瑞化工有限公司 Organic wastewater incineration and gasification system and incineration and gasification method
CN106001064A (en) * 2016-06-17 2016-10-12 鞍山华融富瑞新能源科技有限公司 Ultra-low-temperature plasma organic waste recycling method and device

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110695056A (en) * 2019-10-20 2020-01-17 安徽航天环境工程有限公司 Oil sludge cracking treatment device
CN110695057A (en) * 2019-10-20 2020-01-17 安徽航天环境工程有限公司 Oil sludge cracking treatment method
CN110695055A (en) * 2019-10-20 2020-01-17 安徽航天环境工程有限公司 Red mud cracking treatment method
CN110695056B (en) * 2019-10-20 2021-07-30 航天神禾(北京)环保有限公司 Oil sludge cracking treatment device
CN112923382A (en) * 2019-12-05 2021-06-08 核工业西南物理研究院 High-concentration organic waste liquid plasma cracking recombination system and method
CN114110624A (en) * 2021-11-29 2022-03-01 济南市琦泉热电有限责任公司 Waste oil and waste liquid incineration boiler for flue gas self-heating treatment

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Application publication date: 20170322

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