CN106523801A - Glass fiber reinforced polyethylene water feed pipe - Google Patents

Glass fiber reinforced polyethylene water feed pipe Download PDF

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Publication number
CN106523801A
CN106523801A CN201610913563.9A CN201610913563A CN106523801A CN 106523801 A CN106523801 A CN 106523801A CN 201610913563 A CN201610913563 A CN 201610913563A CN 106523801 A CN106523801 A CN 106523801A
Authority
CN
China
Prior art keywords
layer
parts
feed pipe
coupling agent
glass fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610913563.9A
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Chinese (zh)
Inventor
刘俊峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Jie Lantech New Material Co Ltd
Anhui Glant New Material Co Ltd
Original Assignee
Anhui Jie Lantech New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Jie Lantech New Material Co Ltd filed Critical Anhui Jie Lantech New Material Co Ltd
Priority to CN201610913563.9A priority Critical patent/CN106523801A/en
Publication of CN106523801A publication Critical patent/CN106523801A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/12Rigid pipes of plastics with or without reinforcement
    • F16L9/121Rigid pipes of plastics with or without reinforcement with three layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D23/00Producing tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a general shape other than plane
    • B32B1/08Tubular products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/40Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

Abstract

The invention provides a glass fiber reinforced polyethylene water feed pipe. The glass fiber reinforced polyethylene water feed pipe comprises a pipe body. The pipe body is formed by combining an inner layer, a core layer and an outer layer. The inner layer and the outer layer are both made of HDPE materials. The material of the core layer is a pretreated glass fiber tape winding layer. An inner transition connecting layer is arranged between the inner layer and the core layer, and an outer transition connecting layer is arranged between the outer layer and the inner layer. The glass fiber reinforced HDPE is adopted, and due to the fact that the elasticity modulus of glass fiber is 60 MPa and is far larger than that of HDPE with the elasticity modulus being 0.8 MPa, glass fiber cloth is adopted as the inner layer, grafting is achieved through an inner and outer transition connecting layer coupling agent, and accordingly the anti-pressure ability of the HDPE water feed pipe can be achieved.

Description

A kind of fiberglass reinforced polyethylene feed pipe
Technical field
The present invention relates to production of construction materials field, and in particular to a kind of fiberglass reinforced polyethylene feed pipe.
Background technology
PE (polyethylene) materials due to its intensity it is high, corrosion-resistant, it is nontoxic the features such as, be widely used in feed pipe manufacture neck Domain.Because it will not get rusty, therefore, it is substituting the preferable tubing of common ferrum feed pipe.PE feed pipes perform product national standard: GB/T 13663-2000《Feedwater polyethylene (PE) tubing》, China's plastic conduit have developed rapidly, and quality is being improved constantly.Its Middle polyethylene PE pipe is widely used in building water supply due to its own unique advantage, and construction drainage, buried drain pipe are built Heating, appendix is built, electrician protects sleeve pipe, industrial pipe, agricultural pipe etc. with telecommunication.Which is mainly used in urban water supply, city The field such as city's gas supply and field irrigation.
Existing market is that PE feed pipe highests nominal pressure is 1.6MPa, on long-distance sand transport and special applications, is existed The defect of low intensity.
The content of the invention
For above problems of the prior art, the invention provides a kind of fiberglass reinforced polyethylene feed pipe, carries The high anti-pressure ability of feed pipe.
The present invention is achieved by the following technical solutions:
A kind of fiberglass reinforced polyethylene feed pipe, includes body, the body by internal layer, sandwich layer and outer layer it is compound and HDPE material is into, internal layer and outer layer, the sandwich layer material is winding pretreated glass fiber belt layer, the internal layer and sandwich layer Between arrange in transition articulamentum, outer transition articulamentum is set between the outer layer and internal layer;
The parts by weight of raw materials of its middle tube body is:HDPE is that 90.6-99.4 parts, coupling agent 1.8-5.5 parts, glass fibre are 16.8-27.1 parts.
Further, the parts by weight of raw materials of inside and outside transition articulamentum is:Coupling agent 0.5-0.8 parts, dispersant 0.8-3.7 Part, age resister 0.3-0.5 parts, lubricant 0.5-0.8 parts.
Further, coupling agent is surface coupling agent, and surface coupling agent is titanate esters, Aluminate, silanes, grafting Malaysia One or more in anhydride and its derivant, vinyl silanes, esters of acrylic acid and its derivant.
Further, dispersant is poly- (methylacryoyloxyethyl ammonium chloride-hydroxyalkyl acrylate) copolymer.
Further, age resister is acrylic resin.
Further, lubricant is paraffin, Tissuemat E, polypropylene wax, stearic acid, Metallic stearates and ethylene The mixture of one or more in acrylic acid copolymer slaine.
Further, its preparation technology flow process is:
1) using single screw extrusion machine by internal layer extrusion molding,
2) it is wrapped in glass fiber tape densification leak free on internal layer by Wrapping formed machine again, being formed strengthens sandwich layer;
3) finally by complex extruder by original compound extruded outer layer;
Wherein between internal layer and sandwich layer, extrude transition inside and outside fine and close leak free HDPE between sandwich layer and outer layer simultaneously and connect Connect layer.
Beneficial effects of the present invention:The present invention adopts fiberglass reinforced HDPE, due to the elastic modelling quantity 60MPa of glass fibre, Much larger than the 0.8MPa of HDPE, therefore using glass fabric as internal layer and by the realization of inside and outside transition articulamentum coupling agent Grafting, you can realize the anti-pressure ability of HDPE feed pipes.
Description of the drawings
Fig. 1 is the sectional view of the present invention.
Wherein:1 is body;2 is internal layer;3 is sandwich layer;4 is outer layer;5 is interior transition articulamentum;6 is outer transition articulamentum.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, it is below in conjunction with drawings and Examples, right The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only to explain the present invention, and It is not used in the restriction present invention.
Embodiment 1
Refer to Fig. 1, a kind of fiberglass reinforced polyethylene feed pipe includes body 1, body is by internal layer 2, sandwich layer 3 and outer Layer 4 is composited, and sandwich layer 3 and outer layer 4 are HDPE material, and 2 material of internal layer is glass fabric, is set between internal layer 2 and sandwich layer 3 Interior transition articulamentum 5 is put, outer transition articulamentum 6 is set between outer layer 4 and internal layer 2;
Body 1 is included, the body is composited by internal layer 2, sandwich layer 3 and outer layer 4, and internal layer 2 and outer layer 4 are HDPE Material, the material of the sandwich layer 3 is winding pretreated glass fiber belt layer, arranges interior transition and connect between the internal layer 2 and sandwich layer 3 Layer 5 is connect, outer transition articulamentum 6 is set between the outer layer 4 and internal layer 2.
The parts by weight of raw materials of its middle tube body is:HDPE is 90.6 parts, 1.8 parts of coupling agent, glass fibre are 16.8 parts.Wherein The parts by weight of raw materials of inside and outside transition articulamentum is:0.5 part of coupling agent, poly- (methylacryoyloxyethyl ammonium chloride-acrylic acid hydroxyl Alkyl ester) 0.8 part of copolymer, 0.3 part of acrylic resin, 0.5 part of lubricant.
Coupling agent is surface coupling agent, surface coupling agent be titanate esters, Aluminate, silanes, grafted maleic anhydride and its One or more in derivant, vinyl silanes, esters of acrylic acid and its derivant.
Lubricant is common for paraffin, Tissuemat E, polypropylene wax, stearic acid, Metallic stearates and ethylene acrylic The mixture of one or more in poly- slaine.
Its preparation technology flow process is:Using single screw extrusion machine by internal layer extrusion molding, then by Wrapping formed machine by glass The densification of glass fiber band is leak free to be wrapped on internal layer, and being formed strengthens sandwich layer;To be combined originally finally by complex extruder and squeeze Go out outer layer;Wherein between internal layer and sandwich layer, extrude transition inside and outside fine and close leak free HDPE between sandwich layer and outer layer simultaneously and connect Connect layer.
Embodiment 2
The parts by weight of raw materials of (pipe structure is with embodiment 1) its middle tube body is:HDPE is 91.2 parts, 2.1 parts of coupling agent, glass Glass fiber is 17.2 parts.The parts by weight of raw materials of wherein inside and outside transition articulamentum is:0.6 part of coupling agent, poly- (methacryloxypropyl Ethyl ammonium chloride-hydroxyalkyl acrylate) copolymer 1 .4 parts, 0.3 part of acrylic resin, 0.57 part of lubricant.
Coupling agent is surface coupling agent, surface coupling agent be titanate esters, Aluminate, silanes, grafted maleic anhydride and its One or more in derivant, vinyl silanes, esters of acrylic acid and its derivant.
Lubricant is common for paraffin, Tissuemat E, polypropylene wax, stearic acid, Metallic stearates and ethylene acrylic The mixture of one or more in poly- slaine.
Its preparation technology flow process is:Using single screw extrusion machine by internal layer extrusion molding, then by Wrapping formed machine by glass The densification of glass fiber band is leak free to be wrapped on internal layer, and being formed strengthens sandwich layer;To be combined originally finally by complex extruder and squeeze Go out outer layer;Wherein between internal layer and sandwich layer, extrude transition inside and outside fine and close leak free HDPE between sandwich layer and outer layer simultaneously and connect Connect layer.
Embodiment 3
The parts by weight of raw materials of (pipe structure is with embodiment 1) its middle tube body is:HDPE is 93.5 parts, coupling agent 3.7, glass Fiber is 20.5 parts.The parts by weight of raw materials of wherein inside and outside transition articulamentum is:0.6 part of coupling agent, poly- (methacryloxypropyl second Ammonium chloride-hydroxyalkyl acrylate) 2.9 parts of copolymer, 0.4 part of acrylic resin, 0.63 part of lubricant.
Coupling agent is surface coupling agent, surface coupling agent be titanate esters, Aluminate, silanes, grafted maleic anhydride and its One or more in derivant, vinyl silanes, esters of acrylic acid and its derivant.
Lubricant is common for paraffin, Tissuemat E, polypropylene wax, stearic acid, Metallic stearates and ethylene acrylic The mixture of one or more in poly- slaine.
Its preparation technology flow process is:Using single screw extrusion machine by internal layer extrusion molding, then by Wrapping formed machine by glass The densification of glass fiber band is leak free to be wrapped on internal layer, and being formed strengthens sandwich layer;To be combined originally finally by complex extruder and squeeze Go out outer layer;Wherein between internal layer and sandwich layer, extrude transition inside and outside fine and close leak free HDPE between sandwich layer and outer layer simultaneously and connect Connect layer.
Embodiment 4
The parts by weight of raw materials of (pipe structure is with embodiment 1) its middle tube body is:HDPE is 95.8 parts, 4.3 parts of coupling agent, glass Glass fiber is 22.4 parts.The parts by weight of raw materials of wherein inside and outside transition articulamentum is:0.7 part of coupling agent, poly- (methacryloxypropyl Ethyl ammonium chloride-hydroxyalkyl acrylate) 3.2 parts of copolymer, 0.4 part of acrylic resin, 0.69 part of lubricant.
Coupling agent is surface coupling agent, surface coupling agent be titanate esters, Aluminate, silanes, grafted maleic anhydride and its One or more in derivant, vinyl silanes, esters of acrylic acid and its derivant.
Lubricant is common for paraffin, Tissuemat E, polypropylene wax, stearic acid, Metallic stearates and ethylene acrylic The mixture of one or more in poly- slaine.
Its preparation technology flow process is:Using single screw extrusion machine by internal layer extrusion molding, then by Wrapping formed machine by glass The densification of glass fiber band is leak free to be wrapped on internal layer, and being formed strengthens sandwich layer;To be combined originally finally by complex extruder and squeeze Go out outer layer;Wherein between internal layer and sandwich layer, extrude transition inside and outside fine and close leak free HDPE between sandwich layer and outer layer simultaneously and connect Connect layer.
Embodiment 5
The parts by weight of raw materials of (pipe structure is with embodiment 1) its middle tube body is:HDPE is 99.4 parts, 5.5 parts of coupling agent, glass Glass fiber is 27.1 parts.The parts by weight of raw materials of wherein inside and outside transition articulamentum is:0.8 part of coupling agent, poly- (methacryloxypropyl Ethyl ammonium chloride-hydroxyalkyl acrylate) 3.7 parts of copolymer, 0.5 part of acrylic resin, 0.8 part of lubricant.
Coupling agent is surface coupling agent, surface coupling agent be titanate esters, Aluminate, silanes, grafted maleic anhydride and its One or more in derivant, vinyl silanes, esters of acrylic acid and its derivant.
Lubricant is common for paraffin, Tissuemat E, polypropylene wax, stearic acid, Metallic stearates and ethylene acrylic The mixture of one or more in poly- slaine.
Its preparation technology flow process is:Using single screw extrusion machine by internal layer extrusion molding, then by Wrapping formed machine by glass The densification of glass fiber band is leak free to be wrapped on internal layer, and being formed strengthens sandwich layer;To be combined originally finally by complex extruder and squeeze Go out outer layer;Wherein between internal layer and sandwich layer, extrude transition inside and outside fine and close leak free HDPE between sandwich layer and outer layer simultaneously and connect Connect layer.
The present invention adopts fiberglass reinforced HDPE, due to the elastic modelling quantity 60MPa of glass fibre, much larger than HDPE's 0.8MPa, therefore using glass fabric as internal layer and by the realization grafting of inside and outside transition articulamentum coupling agent, you can realize The anti-pressure ability of HDPE feed pipes.
Presently preferred embodiments of the present invention is the foregoing is only, not to limit the present invention, all essences in the present invention Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.

Claims (7)

1. a kind of fiberglass reinforced polyethylene feed pipe, it is characterised in that:Include body, the body is by internal layer, sandwich layer and outer Layer is composited, and internal layer and outer layer are HDPE material, and the sandwich layer material is winding pretreated glass fiber belt layer, described interior Transition articulamentum in arranging between layer and sandwich layer, arranges outer transition articulamentum between the outer layer and internal layer;
The parts by weight of raw materials of its middle tube body is:HDPE be 90.6-99.4 parts, coupling agent 1.8-5.5 parts, glass fibre be 16.8- 27.1 parts.
2. a kind of fiberglass reinforced polyethylene feed pipe according to claim 1, it is characterised in that:Inside and outside transition articulamentum Parts by weight of raw materials be:Coupling agent 0.5-0.8 parts, dispersant 0.8-3.7 parts, age resister 0.3-0.5 parts, lubricant 0.5-0.8 parts.
3. a kind of fiberglass reinforced polyethylene feed pipe according to claim 1 and 2, it is characterised in that:Coupling agent is surface Coupling agent, surface coupling agent be titanate esters, Aluminate, silanes, grafted maleic anhydride and its derivant, vinyl silanes, third One or more in olefin(e) acid esters and its derivant.
4. a kind of fiberglass reinforced polyethylene feed pipe according to claim 1, it is characterised in that:Dispersant is poly- (methyl Acrylyl oxy-ethyl ammonium chloride-hydroxyalkyl acrylate) copolymer.
5. a kind of fiberglass reinforced polyethylene feed pipe according to claim 1, it is characterised in that:Age resister is polypropylene Resin.
6. a kind of fiberglass reinforced polyethylene feed pipe according to claim 1, it is characterised in that:Lubricant is stone One or more in wax, Tissuemat E, polypropylene wax, stearic acid, Metallic stearates and ethylene-acrylic acid copolymer slaine Mixture.
7. a kind of fiberglass reinforced polyethylene feed pipe according to claim 1, it is characterised in that:Its preparation technology flow process For:
1) using single screw extrusion machine by internal layer extrusion molding,
2) it is wrapped in glass fiber tape densification leak free on internal layer by Wrapping formed machine again, being formed strengthens sandwich layer;
3) finally by complex extruder by original compound extruded outer layer;
Wherein between internal layer and sandwich layer, transition connection inside and outside fine and close leak free HDPE between sandwich layer and outer layer, is extruded simultaneously Layer.
CN201610913563.9A 2016-10-19 2016-10-19 Glass fiber reinforced polyethylene water feed pipe Pending CN106523801A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610913563.9A CN106523801A (en) 2016-10-19 2016-10-19 Glass fiber reinforced polyethylene water feed pipe

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Application Number Priority Date Filing Date Title
CN201610913563.9A CN106523801A (en) 2016-10-19 2016-10-19 Glass fiber reinforced polyethylene water feed pipe

Publications (1)

Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111022786A (en) * 2019-12-30 2020-04-17 安徽杰蓝特新材料有限公司 Glass fiber reinforced PE water supply pipe and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0276989A (en) * 1988-02-29 1990-03-16 Inst Fr Petrole Composite material hardly deformed in longitudinal direction even when it is subject to effect of internal pressure
JPH10329247A (en) * 1997-06-02 1998-12-15 Toray Ind Inc Composite material tubular member
US6039084A (en) * 1997-06-13 2000-03-21 Teleflex, Inc. Expanded fluoropolymer tubular structure, hose assembly and method for making same
CN2627320Y (en) * 2003-07-24 2004-07-21 新疆永昌复合材料股份有限公司 Glass fiber reinforcement steel-plastic high pressure multiple tube
CN103527862A (en) * 2013-09-27 2014-01-22 漯河君叁材料高科有限公司 Glass fiber reinforced polyethylene composite material pipe and manufacturing method thereof
CN204477521U (en) * 2014-12-25 2015-07-15 浙江伟星新型建材股份有限公司 A kind of high abrasion reinforced composite pipe material
CN105647177A (en) * 2016-02-04 2016-06-08 南通瑞隆新材料有限公司 Preparation method of ABS-toughened polyamide

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0276989A (en) * 1988-02-29 1990-03-16 Inst Fr Petrole Composite material hardly deformed in longitudinal direction even when it is subject to effect of internal pressure
JPH10329247A (en) * 1997-06-02 1998-12-15 Toray Ind Inc Composite material tubular member
US6039084A (en) * 1997-06-13 2000-03-21 Teleflex, Inc. Expanded fluoropolymer tubular structure, hose assembly and method for making same
CN2627320Y (en) * 2003-07-24 2004-07-21 新疆永昌复合材料股份有限公司 Glass fiber reinforcement steel-plastic high pressure multiple tube
CN103527862A (en) * 2013-09-27 2014-01-22 漯河君叁材料高科有限公司 Glass fiber reinforced polyethylene composite material pipe and manufacturing method thereof
CN204477521U (en) * 2014-12-25 2015-07-15 浙江伟星新型建材股份有限公司 A kind of high abrasion reinforced composite pipe material
CN105647177A (en) * 2016-02-04 2016-06-08 南通瑞隆新材料有限公司 Preparation method of ABS-toughened polyamide

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111022786A (en) * 2019-12-30 2020-04-17 安徽杰蓝特新材料有限公司 Glass fiber reinforced PE water supply pipe and preparation method thereof

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Application publication date: 20170322