A kind of automatic open-close anti-explosion fire safety-door device and its method of work
Technical field
The invention belongs to fire equipment field, and in particular to a kind of automatic open-close anti-explosion fire safety-door device and its work
Method.
Background technology
Fire-proof and explosion-proof door is obtained in architectural engineering design for fire protection as a kind of fire separation facility attractive in appearance, easy to use
To being widely applied, it in addition to the effect with common door, within a certain period of time, together with framework can meet fire stability,
Integrality, with fire prevention, every cigarette, the specific function of stop high temperature, voluntarily can close and signal feedback function when there is fire.
At present, in petrochemical industry, power domain, it is fitted with the heating furnace that used, Industrial Boiler fire-proof and explosion-proof
Door, to the safety for ensureing body of heater.Conventional explosion proof door exposes problems with normal use:First, it is conventional anti-
The heat-proof quality of quick-fried door is poor, heat is distributed by the body of body of heater, while causing the temperature of body of heater to raise;Make heat
Amount is scattered and disappeared in road surrounding air by body of heater;Secondly, the sealing of conventional explosion proof door is poor, easily makes furnace gas take away heat
Amount, causes the loss of heat, makes the slatterning in vain of the energy in body of heater, reduces the efficiency of heating furnace.
In addition because fire-proof and explosion-proof door has fire performance, people's life has also gradually been entered into.Existing fire-proof and explosion-proof door exists
When fire occurs, flameproof effect can be generally played, but when the fiery face of the back of the body of the user in fire resistant doorsets, if accidentally touched anti-
Fiery explosion proof door back of the body fire face, because of heat-conduction effect, can cause user to scald.Conventional fire resistant doorsets are all as anti-using metal in addition
The main material of vent, quality are heavier, and inconvenience is brought during installation.Due to due to weight, so using
It is extremely inconvenient.
The content of the invention
In order to solve above-mentioned technical problem, the present invention provides a kind of automatic open-close anti-explosion fire safety-door device and its work
Method, including:Fixed mount 1, controller 2, alarm 3, lowering or hoisting gear 4, pressure sensor 5, protective plate 6, temperature sensor 7,
Dragging track 8;1 structure of the fixed mount is in " Jiong " shape, and 1 inside both sides of fixed mount are provided with dragging track 8,8 quantity of dragging track
For 2, dragging track 8 is screwed with fixed mount 1;8 top of the dragging track is provided with lowering or hoisting gear 4, wherein lowering or hoisting gear 4
Central upper portion is provided with controller 2, and controller 2 is threadedly coupled with fixed mount 1;The alarm 3 is located in one of dragging track 8
Upper end, alarm 3 are threadedly coupled with fixed mount 1;The protective plate 6 be located at two dragging tracks 8 between, protective plate 6 with slide
Track 8 is slidably connected;6 center of the protective plate is provided with pressure sensor 5 and temperature sensor 7;
The alarm 3, pressure sensor 5 and temperature sensor 7 are connected with the control of controller 2 by wire.
Further, the lowering or hoisting gear 4 includes:Power set 4-1, protective plate position sensor 4-2, Smoke Sensor
4-3, power transmission shaft 4-4, spring bearing 4-5, driven sprocket 4-6, support base 4-7, weight linear meter 4-8;Described power transmission shaft 4-4 one end sets
Dynamic device 4-1, the power transmission shaft 4-4 other ends are provided with driven sprocket 4-6, wherein power set 4-1 and power transmission shaft 4-4 and drive and connect
Connect;Support base 4-7 is disposed with the power transmission shaft 4-4, support base 4-7 quantity is 3,3 support base 4-7 equidistant arrangements,
Support seat 4-7 is fixedly connected with fixed mount 1;The spring bearing 4-5 through power transmission shaft 4-4 centers, spring bearing 4-5 with wherein
One support base 4-7 is fixedly connected;It is described to be disposed with protective plate location sensitive on the support base 4-7 at power transmission shaft 4-4 centers
Device 4-2 and Smoke Sensor 4-3;The weight linear meter 4-8 is located on front side of dragging track 8, and wherein weight linear meter 4-8 quantity is 2;
The power set 4-1, protective plate position sensor 4-2 and Smoke Sensor 4-3 pass through wire and controller 2 is controlled
It is connected.
Further, the power set 4-1 includes:Self-locking motor 4-1-1, gearbox 4-1-2, shaft coupling 4-1-3, it is main
Movable sprocket 4-1-4;The self-locking motor 4-1-1 output shaft ends are connected with gearbox 4-1-2, gearbox 4-1-2 and self-locking motor
4-1-1 drive connections;The gearbox 4-1-2 output shaft ends are connected with shaft coupling 4-1-3, wherein the shaft coupling 4-1-3 other ends
It is fixedly connected with power transmission shaft 4-4;The drive sprocket 4-1-4 is located at shaft coupling 4-1-3 sides, shaft coupling 4-1-3 and power transmission shaft
4-4 is fixedly connected;
The self-locking motor 4-1-1 is connected with the control of controller 2 by wire.
Further, the protective plate 6 is molded by macromolecular material pressing mold, the constituent and manufacture process of protective plate 6
It is as follows:
First, 6 constituent of protective plate:
Count by weight, 140~285 parts of 1- (4- bromophenyls) piperidin-4-yl t-butyl carbamate, (5- amino -2- (4-
Isopropyl piperazine -1- bases) phenyl) 53~174 parts of methyl alcohol, 1- (4- (4,4,5,5- tetramethyl -1,3,2- diborane -2- bases)
Phenyl) 33~125 parts of piperidin-4-yl urethanes, [4- [[3- (3- azepine pyridines) -2- pyrazines] epoxide] phenyl] -1H- benzene
And 86~193 parts of imidazoles -2- bases ketone, 4- (4- (4,4,5,5- tetramethyl -1,3,2- diborane -2- bases) phenyl) piperidines -
57~181 parts of 1- carboxylate methyl esters, 81~197 parts of 5- amino-n- methoxyl group-n- methyl -2- pyridine carboxamides, concentration is 51ppm
(5- amino -2- (4- isopropyl piperazine -1- bases) phenyl) 92~161 parts of methyl alcohol of~69ppm, 6- (2- pyrimidines) -2,6- phenodiazines
Miscellaneous spiral shell [3.3] heptane -2- carboxylic acids 1,82~119 parts of 1- dimethylethyl esters, tetrahydrochysene -1H- thienos [3,4-c] pyrroles -5 (3h) -
72~133 parts of benzyl carboxylate, 94~213 parts of crosslinking agent, 2- acetyl group -4- methyl-n- phenethyl -4- amylenes acid amides 51~150
Part, 5- (1- ((2- (trimethyl silyl) ethyoxyl) methyl) iodo- 1H- imidazos [4, the 5-b] pyridine -2- bases of the chloro- 5- of -6-
Epoxide) 41~169 parts of -2- methyl toluates, 5- amino -2- (4- ethyl -1- piperazines) 38~144 parts of phenmethylol;
The crosslinking agent is 4- (4- bromophenyls) piperidines -1- carboxylate methyl esters, 4- (4- bromophenyls) piperidines -1- carboxylic acid isopropyls, piperazine
Any one in pyridine -4- base isopropyl carbamates;
2nd, the manufacture process of protective plate 6, comprises the steps of:
1st step:3100~4200 parts of the ultra-pure water that electrical conductivity is 4.87 μ S/cm~6.69 μ S/cm is added in a kettle., is started
Agitator in reactor, rotating speed are 94rpm~162rpm, start heat pump, make reactor temperature rise to 84 DEG C~124
℃;Sequentially add 1- (4- bromophenyls) piperidin-4-yl t-butyl carbamate, (5- amino -2- (4- isopropyl piperazine -1- bases)
Phenyl) methyl alcohol, 1- (4- (4,4,5,5- tetramethyl -1,3,2- diborane -2- bases) phenyl) piperidin-4-yl urethane
Ester, stirs to being completely dissolved, and it is 4.29~6.64 to adjust pH value, and agitator speed is adjusted to 140rpm~212rpm, and temperature is
145 DEG C~226 DEG C, esterification 18~28 hours;
2nd step:Take [4- [[3- (3- azepine pyridines) -2- pyrazines] epoxide] phenyl] -1H- benzimidazolyl-2 radicals-base ketone, 4- (4- (4,
4,5,5- tetramethyl -1,3,2- diborane -2- bases) phenyl) piperidines -1- carboxylate methyl esters are crushed, and powder diameter is 700~
1000 mesh;Add 5- amino-n- methoxyl group-n- methyl -2- pyridine carboxamides to be well mixed, be laid in pallet, tile thickness
For 10mm~18mm, adopt dosage for 5.5kGy~7.9kGy, energy for 7.6MeV~10.8MeV alpha ray irradiation 130~
240 minutes, and β x ray irradiation xs of Isodose 130~240 minutes;
3rd step:The mixed-powder of the 2nd steps of Jing process is dissolved in 51ppm~69ppm (5- amino -2- (4- isopropyl piperazine -1- bases)
Phenyl) in methyl alcohol, reactor is added, agitator speed is 162rpm~258rpm, and temperature is 142 DEG C~166 DEG C, starts vacuum
Pump makes the vacuum of reactor reach -0.42MPa~4.54MPa, keeps this state response 14~23 hours;Pressure release is simultaneously passed through radon
Gas, makes reacting kettle inner pressure for 1.53MPa~2.45MPa, insulation standing 6~12 hours;Agitator speed is promoted to 195rpm
~283rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 6- (2- pyrimidines) -2,6- diaza spiroheptane -2- carboxylic acids
After 1,1- dimethylethyl esters, -5 (3h)-benzyl carboxylate of tetrahydrochysene -1H- thienos [3,4-c] pyrroles are completely dissolved, crosslinking agent is added
Stirring mixing so that the hydrophilic lipophilic balance of reactor solution is 6.36~9.56, and insulation stands 16~24 hours;
4th step:When agitator speed is 257rpm~378rpm, 2- acetyl group -4- methyl-n- phenethyl -4- are sequentially added
Amylene acid amides, 5- (1- ((2- (trimethyl silyl) ethyoxyl) methyl) iodo- 1H- imidazos [4,5-b] pyrroles of the chloro- 5- of -6-
Pyridine -2- base epoxides) -2- methyl toluates and 5- amino -2- (4- ethyl -1- piperazines) phenmethylol, reactor pressure is lifted,
1.87MPa~3.16MPa is reached, temperature is 231 DEG C~318 DEG C, polymerisation 26~48 hours;Will be anti-after the completion of reaction
Answer pressure in kettle to be down to 0MPa, be cooled to 26 DEG C~32 DEG C, discharge, enter molding press and can be prepared by protective plate 6.
Further, the invention also discloses the work of a kind of automatic open-close anti-explosion fire safety-door device and its method of work
Make method, the method includes following step:
1st step:After the device installation, power-on is now placed in the controller 2 inside the device and starts working, control
Self-locking motor 4-1-1 inside the control power set 4-1 of device 2 starts, and self-locking motor 4-1-1 drives drive sprocket 4-1-4 prevent
Backplate 6 is driven to initial position, and at the same time the protective plate position sensor 4-2 real-time monitorings inside lowering or hoisting gear 4 are anti-
The position of backplate 6;When protective plate position sensor 4-2 detects protective plate 6 moves to the initial value of its setting, protective plate position
Put inductor 4-2 and produce electric signal, transmit to controller 2, the control self-locking motor 4-1-1 of controller 2 stops operating and self-locking;
2nd step:When the temperature sensor 7 on protective plate 6 monitors that ambient temperature reaches the higher limit of its setting, or
Smoke Sensor 4-3 inside lowering or hoisting gear 4 detect smokescope higher than its setting value when, Smoke Sensor 4-3 and
Temperature sensor 7 produces electric signal, transmits to controller 2, and the control self-locking motor 4-1-1 of controller 2 starts, while alarm 3
Start, self-locking motor 4-1-1 drives protective plate 6 to block up door seal, at the same time the protection of protective plate position sensor 4-2 real-time monitorings
The position of plate 6, after door is blocked by protective plate 6 completely, protective plate position sensor 4-2 produces electric signal, transmits to controller
2, the control self-locking motor 4-1-1 of controller 2 stops operating and self-locking;
3rd step:When the temperature sensor 7 on protective plate 6 monitors that ambient temperature is reduced to the lower limit of its setting, or
Person be located at lowering or hoisting gear 4 inside Smoke Sensor 4-3 detect smokescope less than its setting value when, Smoke Sensor 4-3
Electric signal is produced with temperature sensor 7, is transmitted to controller 2, the control self-locking motor 4-1-1 of controller 2 starts, self-locking motor 4-
1-1 drive protective plates 6 are supervised in real time to initial position, at the same time the protective plate position sensor 4-2 inside lowering or hoisting gear 4
Survey the position of protective plate 6;When protective plate position sensor 4-2 detects protective plate 6 moves to the initial value of its setting, protection
Board position inductor 4-2 produces electric signal, transmits to controller 2, and the control self-locking motor 4-1-1 of controller 2 stops operating simultaneously certainly
Lock;
4th step:When door is blocked by protective plate 6 completely, now pressure sensor 5 is started working, real-time monitoring ambient pressure, pressure
Force snesor 5 produces electric signal, and transmits to controller 2, and monitoring information is fed back to user by controller 2.
A kind of automatic open-close anti-explosion fire safety-door device disclosed by the invention and its method of work, have an advantage in that:
(1) the device protective plate adopts macromolecular material, light weight, protection against the tide, heat-resisting, cracking resistance, firm is unlikely to deform;
(2) installation cost is low, nonpoisonous and tasteless, environment friendly and pollution-free;
(3) the plant automation low degree, with various monitoring functions, can be automatically obtained folding.
(4) the device good sealing effect, can effectively completely cut off the poisonous, pernicious gas and smog, dust produced in fire
Deng impurity particle.
A kind of automatic open-close anti-explosion fire safety-door device of the present invention and its method of work, the device conduct oneself with dignity and
Low cost of manufacture, safety and environmental protection, it is easy to transport and installation;The plant automation degree is high, built-in multiple monitoring devices can and
When tackle emergency situations;The device performance is stable, and material is firm, can successfully manage scene of fire, effectively isolation fire and fire
The impurity particle such as the poisonous, pernicious gas produced in calamity and smog, dust.
Description of the drawings
Fig. 1 is a kind of heretofore described automatic open-close anti-explosion fire safety-door device and its method of work structural representation
Figure.
Fig. 2 is heretofore described lifting device structure schematic diagram.
Fig. 3 is heretofore described powerplant configuration schematic diagram.
Fig. 4 is that heretofore described protective plate fatigue strength changes over figure.
In figure 1 above~Fig. 3, fixed mount 1, controller 2, alarm 3, lowering or hoisting gear 4, power set 4-1, self-locking motor
4-1-1, gearbox 4-1-2, shaft coupling 4-1-3, drive sprocket 4-1-4, protective plate position sensor 4-2, Smoke Sensor 4-
3, power transmission shaft 4-4, spring bearing 4-5, driven sprocket 4-6, support base 4-7, weight linear meter 4-8, pressure sensor 5, protective plate 6,
Temperature sensor 7, dragging track 8.
Specific embodiment
With reference to the accompanying drawings and examples to the present invention provide a kind of automatic open-close anti-explosion fire safety-door device and its
Method of work is further described.
As shown in figure 1, being a kind of heretofore described automatic open-close anti-explosion fire safety-door device and its method of work
Structural representation.It is seen in fig. 1, that including:Fixed mount 1, controller 2, alarm 3, lowering or hoisting gear 4, pressure sensor 5 are prevented
Backplate 6, temperature sensor 7, dragging track 8;1 structure of the fixed mount is in " Jiong " shape, and 1 inside both sides of fixed mount are provided with slides rail
Road 8,8 quantity of dragging track are 2, and dragging track 8 is screwed with fixed mount 1;8 top of the dragging track is provided with lifting dress
4 are put, wherein 4 central upper portion of lowering or hoisting gear is provided with controller 2, and controller 2 is threadedly coupled with fixed mount 1;The alarm 3 is located at
8 upper end of one of dragging track, alarm 3 are threadedly coupled with fixed mount 1;The protective plate 6 positioned at two dragging tracks 8 it
Between, protective plate 6 is slidably connected with dragging track 8;6 center of the protective plate is provided with pressure sensor 5 and temperature sensor 7;
The alarm 3, pressure sensor 5 and temperature sensor 7 are connected with the control of controller 2 by wire.
As shown in Fig. 2 being heretofore described lifting device structure schematic diagram.Find out from Fig. 2 or Fig. 1, lifting dress
Putting 4 includes:Power set 4-1, protective plate position sensor 4-2, Smoke Sensor 4-3, power transmission shaft 4-4, spring bearing 4-5,
Driven sprocket 4-6, support base 4-7, weight linear meter 4-8;Described power transmission shaft 4-4 one end is provided with power set 4-1, and power transmission shaft 4-4 is another
One end is provided with driven sprocket 4-6, wherein power set 4-1 and power transmission shaft 4-4 drive connections;It is disposed with the power transmission shaft 4-4
Support base 4-7, support base 4-7 quantity is 3, and 3 support base 4-7 equidistant arrangements, support base 4-7 are fixedly connected with fixed mount 1;
The spring bearing 4-5 is fixedly connected through power transmission shaft 4-4 centers, spring bearing 4-5 with one of support base 4-7;Institute
Rheme is disposed with protective plate position sensor 4-2 and Smoke Sensor 4-3 on the support base 4-7 at power transmission shaft 4-4 centers;It is described
Weight linear meter 4-8 is located on front side of dragging track 8, and wherein weight linear meter 4-8 quantity is 2;
The power set 4-1, protective plate position sensor 4-2 and Smoke Sensor 4-3 pass through wire and controller 2 is controlled
It is connected.
As shown in figure 3, being heretofore described powerplant configuration schematic diagram.Find out from Fig. 3 or Fig. 1 or Fig. 2, move
Power apparatus 4-1 includes:Self-locking motor 4-1-1, gearbox 4-1-2, shaft coupling 4-1-3, drive sprocket 4-1-4;The self-locking electricity
Machine 4-1-1 output shaft ends are connected with gearbox 4-1-2, gearbox 4-1-2 and self-locking motor 4-1-1 drive connections;The speed change
Case 4-1-2 output shaft ends are connected with shaft coupling 4-1-3, and the wherein shaft coupling 4-1-3 other ends are fixedly connected with power transmission shaft 4-4;Institute
Drive sprocket 4-1-4 is stated positioned at shaft coupling 4-1-3 sides, shaft coupling 4-1-3 is fixedly connected with power transmission shaft 4-4;
The self-locking motor 4-1-1 is connected with the control of controller 2 by wire.
The course of work of a kind of automatic open-close anti-explosion fire safety-door device of the present invention and its method of work is:
1st step:After the device installation, power-on is now placed in the controller 2 inside the device and starts working, control
Self-locking motor 4-1-1 inside the control power set 4-1 of device 2 starts, and self-locking motor 4-1-1 drives drive sprocket 4-1-4 prevent
Backplate 6 is driven to initial position, and at the same time the protective plate position sensor 4-2 real-time monitorings inside lowering or hoisting gear 4 are anti-
The position of backplate 6;When protective plate position sensor 4-2 detects protective plate 6 moves to the initial value of its setting, protective plate position
Put inductor 4-2 and produce electric signal, transmit to controller 2, the control self-locking motor 4-1-1 of controller 2 stops operating and self-locking;
2nd step:When the temperature sensor 7 on protective plate 6 monitors that ambient temperature reaches the higher limit of its setting, or
Smoke Sensor 4-3 inside lowering or hoisting gear 4 detect smokescope higher than its setting value when, Smoke Sensor 4-3 and
Temperature sensor 7 produces electric signal, transmits to controller 2, and the control self-locking motor 4-1-1 of controller 2 starts, while alarm 3
Start, self-locking motor 4-1-1 drives protective plate 6 to block up door seal, at the same time the protection of protective plate position sensor 4-2 real-time monitorings
The position of plate 6, after door is blocked by protective plate 6 completely, protective plate position sensor 4-2 produces electric signal, transmits to controller
2, the control self-locking motor 4-1-1 of controller 2 stops operating and self-locking;
3rd step:When the temperature sensor 7 on protective plate 6 monitors that ambient temperature is reduced to the lower limit of its setting, or
Person be located at lowering or hoisting gear 4 inside Smoke Sensor 4-3 detect smokescope less than its setting value when, Smoke Sensor 4-3
Electric signal is produced with temperature sensor 7, is transmitted to controller 2, the control self-locking motor 4-1-1 of controller 2 starts, self-locking motor 4-
1-1 drive protective plates 6 are supervised in real time to initial position, at the same time the protective plate position sensor 4-2 inside lowering or hoisting gear 4
Survey the position of protective plate 6;When protective plate position sensor 4-2 detects protective plate 6 moves to the initial value of its setting, protection
Board position inductor 4-2 produces electric signal, transmits to controller 2, and the control self-locking motor 4-1-1 of controller 2 stops operating simultaneously certainly
Lock;
4th step:When door is blocked by protective plate 6 completely, now pressure sensor 5 is started working, real-time monitoring ambient pressure, pressure
Force snesor 5 produces electric signal, and transmits to controller 2, and monitoring information is fed back to user by controller 2.
A kind of automatic open-close anti-explosion fire safety-door device of the present invention and its method of work, the device conduct oneself with dignity and
Low cost of manufacture, safety and environmental protection, it is easy to transport and installation;The plant automation degree is high, built-in multiple monitoring devices can and
When tackle emergency situations;The device performance is stable, and material is firm, can successfully manage scene of fire, effectively isolation fire and fire
The impurity particle such as the poisonous, pernicious gas produced in calamity and smog, dust.
The embodiment of the manufacture process of protective plate of the present invention 6 is the following is, embodiment is to further illustrate this
Bright content, but should not be construed as limiting the invention.Without departing from the spirit and substance of the case in the present invention, to the present invention
Modification and replacement that method, step or condition are made, belong to the scope of the present invention.
If not specializing, the conventional meanses that technological means used is well known to those skilled in the art in embodiment.
Embodiment 1
Protective plate 6 of the present invention is manufactured according to following steps, and is counted by weight:
1st step:3100 parts of the ultra-pure water that electrical conductivity is 4.87 μ S/cm is added in a kettle., starts agitator in reactor, turn
Speed is 94rpm, starts heat pump, makes reactor temperature rise to 84 DEG C;Sequentially add 1- (4- bromophenyls) piperidin-4-yl ammonia
140 parts of base t-butyl formate, (5- amino -2- (4- isopropyl piperazine -1- bases) phenyl) 53 parts of methyl alcohol, 1- (4- (4,4,5,5- tetra-
Methyl isophthalic acid, 3,2- diborane -2- bases) phenyl) 33 parts of piperidin-4-yl urethanes, stirs to being completely dissolved, adjusts pH
It is worth for 4.29, agitator speed is adjusted to into 140rpm, temperature is 145 DEG C, esterification 18 hours;
2nd step:Take [4- [[3- (3- azepine pyridines) -2- pyrazines] epoxide] phenyl] -1H- benzimidazolyl-2 radicals -86 parts of base ketone, 4-
(4- (4,4,5,5- tetramethyl -1,3,2- diborane -2- bases) phenyl) 57 parts of piperidines -1- carboxylate methyl esters are crushed, powder
Particle diameter is 700 mesh;Add 81 parts of 5- amino-n- methoxyl group-n- methyl -2- pyridine carboxamides to be well mixed, be laid in pallet,
Tiling thickness is 10mm, adopts dosage for 5.5kGy, the alpha ray irradiation 130 minutes that energy is 7.6MeV, and Isodose
β x ray irradiation xs 130 minutes;
3rd step:The mixed-powder of the 2nd steps of Jing process is dissolved in 51ppm (5- amino -2- (4- isopropyl piperazine -1- bases) phenyl) first
In 92 parts of alcohol, reactor is added, agitator speed is 162rpm, and temperature is 142 DEG C, and starting vavuum pump makes the vacuum of reactor
- 0.42MPa is reached, this state response is kept 14 hours;Pressure release is simultaneously passed through radon gas, makes reacting kettle inner pressure for 1.53MPa, insulation
Stand 6 hours;Agitator speed is promoted to 195rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 6- (2- pyrimidines) -2,6-
82 parts of diaza spiroheptane -2- carboxylic acid 1,1- dimethylethyl esters, -5 (3h)-carboxylic of tetrahydrochysene -1H- thienos [3,4-c] pyrroles
After 72 parts of acid benzyl ester is completely dissolved, the stirring mixing of 94 parts of crosslinking agent is added so that the hydrophilic lipophilic balance of reactor solution is
6.36, insulation stands 16 hours;
4th step:When agitator speed is 257rpm, 2- acetyl group -4- methyl-n- phenethyl -4- amylene acid amides is sequentially added
51 parts, 5- (1- ((2- (trimethyl silyl) ethyoxyl) methyl) iodo- 1H- imidazos [4,5-b] pyridine -2- of the chloro- 5- of -6-
Base epoxide) 41 parts of -2- methyl toluates and 5- amino -2- (4- ethyl -1- piperazines) 38 parts of phenmethylol, lift reactor pressure
Power so as to reach 1.87MPa, temperature is 231 DEG C, polymerisation 26 hours;Reacting kettle inner pressure is down to after the completion of reaction
0MPa, is cooled to 26 DEG C, discharging, enters molding press and can be prepared by protective plate 6.
The crosslinking agent is 4- (4- bromophenyls) piperidines -1- carboxylate methyl esters.
Embodiment 2
Protective plate 6 of the present invention is manufactured according to following steps, and is counted by weight:
1st step:4200 parts of the ultra-pure water that electrical conductivity is 6.69 μ S/cm is added in a kettle., starts agitator in reactor, turn
Speed is 162rpm, starts heat pump, makes reactor temperature rise to 124 DEG C;Sequentially add 1- (4- bromophenyls) piperidin-4-yl
285 parts of t-butyl carbamate, (5- amino -2- (4- isopropyl piperazine -1- bases) phenyl) 174 parts of methyl alcohol, 1- (4- (4,4,5,
5- tetramethyl -1,3,2- diborane -2- bases) phenyl) 125 parts of piperidin-4-yl urethanes, stir to being completely dissolved,
It is 6.64 to adjust pH value, and agitator speed is adjusted to 212rpm, and temperature is 226 DEG C, esterification 28 hours;
2nd step:Take [4- [[3- (3- azepine pyridines) -2- pyrazines] epoxide] phenyl] -1H- benzimidazolyl-2 radicals -193 parts of base ketone, 4-
(4- (4,4,5,5- tetramethyl -1,3,2- diborane -2- bases) phenyl) 181 parts of piperidines -1- carboxylate methyl esters are crushed, powder
Particle diameter is 1000 mesh;Add 197 parts of 5- amino-n- methoxyl group-n- methyl -2- pyridine carboxamides to be well mixed, be laid in pallet
Interior, tiling thickness is 18mm, adopt dosage for 7.9kGy, energy for 10.8MeV alpha ray irradiation 240 minutes, and agent on an equal basis
The β x ray irradiation xs of amount 240 minutes;
3rd step:The mixed-powder of the 2nd steps of Jing process is dissolved in 69ppm (5- amino -2- (4- isopropyl piperazine -1- bases) phenyl) first
In 161 parts of alcohol, reactor is added, agitator speed is 258rpm, and temperature is 166 DEG C, and starting vavuum pump makes the vacuum of reactor
Degree reaches 4.54MPa, keeps this state response 23 hours;Pressure release is simultaneously passed through radon gas, makes reacting kettle inner pressure for 2.45MPa, guarantor
Temperature stands 12 hours;Agitator speed is promoted to 283rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 6- (2- pyrimidines)-
119 parts of 2,6- diaza spiroheptane -2- carboxylic acid 1,1- dimethylethyl esters, tetrahydrochysene -1H- thienos [3,4-c] pyrroles -5
(3h), after -133 parts of benzyl carboxylate is completely dissolved, 213 parts of stirring mixing of crosslinking agent are added so that the hydrophilic and oleophilic of reactor solution
Equilibrium valve is 9.56, and insulation stands 124 hours;
4th step:When agitator speed is 378rpm, 2- acetyl group -4- methyl-n- phenethyl -4- amylene acid amides is sequentially added
150 parts, 5- (1- ((2- (trimethyl silyl) ethyoxyl) methyl) iodo- 1H- imidazos [4,5-b] pyridine -2- of the chloro- 5- of -6-
Base epoxide) 169 parts of -2- methyl toluates and 5- amino -2- (4- ethyl -1- piperazines) 144 parts of phenmethylol, lift reactor
Pressure so as to reach 3.16MPa, temperature is 318 DEG C, polymerisation 48 hours;Reacting kettle inner pressure is down to after the completion of reaction
0MPa, is cooled to 32 DEG C, discharging, enters molding press and can be prepared by protective plate 6.
The crosslinking agent is piperidin-4-yl isopropyl carbamate.
Embodiment 3
Protective plate 6 of the present invention is manufactured according to following steps, and is counted by weight:
1st step:3650 parts of the ultra-pure water that electrical conductivity is 5.78 μ S/cm is added in a kettle., starts agitator in reactor, turn
Speed is 128rpm, starts heat pump, makes reactor temperature rise to 104 DEG C;Sequentially add 1- (4- bromophenyls) piperidin-4-yl
212 parts of t-butyl carbamate, (5- amino -2- (4- isopropyl piperazine -1- bases) phenyl) 113 parts of methyl alcohol, 1- (4- (4,4,5,
5- tetramethyl -1,3,2- diborane -2- bases) phenyl) 79 parts of piperidin-4-yl urethanes, stirs to being completely dissolved, adjusts
Section pH value is 5.46, and agitator speed is adjusted to 172rpm, and temperature is 185 DEG C, esterification 23 hours;
2nd step:Take [4- [[3- (3- azepine pyridines) -2- pyrazines] epoxide] phenyl] -1H- benzimidazolyl-2 radicals -139 parts of base ketone, 4-
(4- (4,4,5,5- tetramethyl -1,3,2- diborane -2- bases) phenyl) 119 parts of piperidines -1- carboxylate methyl esters are crushed, powder
Particle diameter is 850 mesh;Add 139 parts of 5- amino-n- methoxyl group-n- methyl -2- pyridine carboxamides to be well mixed, be laid in pallet
Interior, tiling thickness is 14mm, adopt dosage for 6.7kGy, energy for 8.8MeV alpha ray irradiation 175 minutes, and agent on an equal basis
The β x ray irradiation xs of amount 175 minutes;
3rd step:The mixed-powder of the 2nd steps of Jing process is dissolved in 60ppm (5- amino -2- (4- isopropyl piperazine -1- bases) phenyl) first
In 126 parts of alcohol, reactor is added, agitator speed is 212rpm, and temperature is 154 DEG C, and starting vavuum pump makes the vacuum of reactor
Degree reaches 2.06MPa, keeps this state response 19 hours;Pressure release is simultaneously passed through radon gas, makes reacting kettle inner pressure for 1.99MPa, guarantor
Temperature stands 9 hours;Agitator speed is promoted to 240rpm, simultaneous reactions kettle pressure release to 0MPa;6- (2- pyrimidines) -2 is sequentially added,
100 parts of 6- diaza spiroheptane -2- carboxylic acid 1,1- dimethylethyl esters, tetrahydrochysene -1H- thienos [3,4-c] pyrroles -5
(3h), after -102 parts of benzyl carboxylate is completely dissolved, 153 parts of stirring mixing of crosslinking agent are added so that the hydrophilic and oleophilic of reactor solution
Equilibrium valve is 7.96, and insulation stands 20 hours;
4th step:When agitator speed is 317rpm, 2- acetyl group -4- methyl-n- phenethyl -4- amylene acid amides is sequentially added
76 parts, 5- (1- ((2- (trimethyl silyl) ethyoxyl) methyl) iodo- 1H- imidazos [4,5-b] pyridine -2- of the chloro- 5- of -6-
Base epoxide) 106 parts of -2- methyl toluates and 5- amino -2- (4- ethyl -1- piperazines) 88 parts of phenmethylol, lift reactor
Pressure so as to reach 2.52MPa, temperature is 274 DEG C, polymerisation 37 hours;Reacting kettle inner pressure is down to after the completion of reaction
0MPa, is cooled to 28 DEG C, discharging, enters molding press and can be prepared by protective plate 6.
The crosslinking agent is 4- (4- bromophenyls) piperidines -1- carboxylic acid isopropyls.
Reference examples
Reference examples are the protective plate of commercially available certain brand.
Embodiment 4
Protective plate described in the protective plate 6 that embodiment 1~3 is prepared and reference examples carries out using effect contrast.To the two
Compression strength, Unit Weight, heat distortion temperature, corrosion rate are counted, as a result as shown in table 1.
As seen from Table 1, protective plate of the present invention 6, its compression strength, Unit Weight, heat distortion temperature, corrosion rate
The product of prior art production is superior to etc. index.
Additionally, as shown in figure 4, being the statistics that 6 fatigue of materials intensity of protective plate of the present invention changes with use time.
Find out in figure, protective plate 6 used by embodiment 1~3, its fatigue of materials intensity is significantly better than existing product with use time intensity of variation
Product.