CN106520227B - A kind of additive that can save heavy oil oil consumption - Google Patents

A kind of additive that can save heavy oil oil consumption Download PDF

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Publication number
CN106520227B
CN106520227B CN201610895992.8A CN201610895992A CN106520227B CN 106520227 B CN106520227 B CN 106520227B CN 201610895992 A CN201610895992 A CN 201610895992A CN 106520227 B CN106520227 B CN 106520227B
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Prior art keywords
additive
heavy oil
oil
mixed
save
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CN201610895992.8A
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CN106520227A (en
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郑宏军
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Zhoushan Yue Wei Xin Energy Technology Co Ltd
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Zhoushan Yue Wei Xin Energy Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1835Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom having at least two hydroxy substituted non condensed benzene rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/305Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/305Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C10L1/308Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond) organo tin compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/04Organic compounds
    • C10L2200/0407Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/0438Middle or heavy distillates, heating oil, gasoil, marine fuels, residua
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2300/00Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
    • C10L2300/20Mixture of two components

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Lubricants (AREA)

Abstract

A kind of additive that can save heavy oil oil consumption, belongs to fuel oil additive technical field.It includes the raw material of following weight percent:Cyclopentadiene tricarbonyl manganese 2~6%, 20~35%, 2,6 di-tert-butyl p-cresol 1~3% of ethylhexanoate salt, surfactant 10~23%, balance of solvent.A kind of above-mentioned additive that can save heavy oil oil consumption can rapidly change associated water molecules state and heavy oil merges completely, and from the efficiency of combustion that can significantly improve heavy oil, fractional energy savings is up to 25~46%.

Description

A kind of additive that can save heavy oil oil consumption
Technical field
The invention belongs to fuel oil additive technical fields, and in particular to a kind of additive that can save heavy oil oil consumption.
Background technology
The increasingly exhaustion of natural resources, since the mankind develop oil product on a large scale, Energy-saving Projects also start therewith. With the progress of the development and science and technology of human history, the auxiliary product " heavy oil " of oil product is also referred to as " residual oil " and also has become Main fuel oil uses.And oil product or oil auxiliary product used as fuel oil be it is a kind of can not possibly secondary recovery or profit The energy.
Under the action of market economy, the booming demand caused to oil product of domestic and international coastal transport service is increasingly Greatly, price is higher and higher, most of to transport owner to save transportation cost, and the original diesel engine of ship is made into diesel oil weight The engine that oil can be used simultaneously.Although prodigious effort has been done to reducing transportation cost by carrier, effect is not very It is ideal.Presently with regard to country, it can accomplish that energy saving 5% or more just belongs to national major project.
In addition, there are also additive for heavy oil in the prior art, can be eliminated by using this additive described The unfavorable performance of heavy fuel.Although these additives play the role of improving fuel oil combustibility to a certain extent, There are the unconspicuous disadvantages of effects of energy saving and emission reduction.
Invention content
In view of the problems of the existing technology, it is an object of the invention to design, offer is a kind of to save adding for heavy oil oil consumption Add the technical solution of agent.
A kind of additive that can save heavy oil oil consumption, it is characterised in that include the raw material of following weight percent:
Cyclopentadiene tricarbonyl manganese 2~6%
Ethylhexanoate salt 20~35%
2,6-di-tert-butyl p-cresol 1~3%
Surfactant 10~23%
Balance of solvent
The solvent be mixed xylenes or kerosene, the mixed xylenes by ortho-xylene, paraxylene and Dimethylbenzene is by weight 1:2~4:3~5 are mixed to get.
A kind of additive that can save heavy oil oil consumption, it is characterised in that include the raw material of following weight percent:
Cyclopentadiene tricarbonyl manganese 3~5%
Ethylhexanoate salt 25~30%
2,6-di-tert-butyl p-cresol 2~3%
Surfactant 12~18%
Balance of solvent.
A kind of additive that can save heavy oil oil consumption, it is characterised in that the ethylhexanoate salt by isooctyl acid iron, Isooctyl acid tin and cobalt iso-octoate are by weight 1:2~3:4~6 are mixed to get.
A kind of additive that can save heavy oil oil consumption, it is characterised in that the surfactant is by levelling agent O- 25 and tween T-80 is by weight 2~4:1 is mixed to get.
A kind of above-mentioned additive that can save heavy oil oil consumption can rapidly change associated water molecules state and heavy oil is complete Fusion, from the efficiency of combustion that can significantly improve heavy oil, fractional energy savings is up to 25~46%.And it can effectively disperse the weight in heavy oil Matter ingredient improves mobile performance, prevents sediment from generating and being adhered in duct wall;Simultaneously dirt can be effectively reduced using additive The discharge of object is contaminated, SO is reduced2And CH discharges, comprehensive reducing come 40% or more;Smoke intensity and dark brown are also reduced simultaneously;In addition, additive Addition can also effectively clean oil line pipe, prevent weight well cuts and the exhaust system in combustion process corrosion, to pot Stove and engine have significant protective effect.
Specific implementation mode
It further illustrates the present invention with reference to embodiments.
Embodiment 1
Take cyclopentadiene tricarbonyl manganese 4kg, ethylhexanoate salt 25kg(Isooctyl acid iron 3.5kg, isooctyl acid tin 7.5kg and different pungent Sour cobalt 14kg), 2,6-di-tert-butyl p-cresol 2kg, surfactant 15kg(Levelling agent O-25 10kg and tween T-80 5kg), mixed xylenes 54kg(Ortho-xylene 9kg, paraxylene 18kg and meta-xylene 27kg)It is uniformly mixed to get to one Kind can save the additive of heavy oil oil consumption.
Embodiment 2
Take cyclopentadiene tricarbonyl manganese 2kg, ethylhexanoate salt 20kg(Isooctyl acid iron 2kg, isooctyl acid tin 6kg and cobalt iso-octoate 12kg), 2,6-di-tert-butyl p-cresol 1kg, surfactant 10kg(Levelling agent O-25 7.5kg and tween T-80 2.5kg)、 Mixed xylenes 67kg(Ortho-xylene 8.2kg, paraxylene 25kg and meta-xylene 33.8kg)It is uniformly mixed to get to one kind The additive of heavy oil oil consumption can be saved.
Embodiment 3
Take cyclopentadiene tricarbonyl manganese 6kg, ethylhexanoate salt 35kg(Isooctyl acid iron 3.8kg, isooctyl acid tin 8.4kg and different pungent Sour cobalt 22.8kg), 2,6-di-tert-butyl p-cresol 3kg, surfactant 23kg(Levelling agent O-25 12.8kg and tween T-80 4.6kg), mixed xylenes 33kg(Ortho-xylene 3.6kg, paraxylene 11.4kg and meta-xylene 18kg)It is uniformly mixed, i.e., Obtain a kind of additive that can save heavy oil oil consumption.
Embodiment 4
Take cyclopentadiene tricarbonyl manganese 3kg, ethylhexanoate salt 25kg(Isooctyl acid iron 2.5kg, isooctyl acid tin 7.5kg and different pungent Sour cobalt 15kg), 2,6-di-tert-butyl p-cresol 2kg, surfactant 12kg(Levelling agent O-25 9.6kg and tween T-80 2.4kg), kerosene 58kg is uniformly mixed to get to a kind of additive that can save heavy oil oil consumption.
Embodiment 5
Take cyclopentadiene tricarbonyl manganese 5kg, ethylhexanoate salt 30kg(Isooctyl acid iron 3kg, isooctyl acid tin 9kg and cobalt iso-octoate 18kg), 2,6-di-tert-butyl p-cresol 3kg, surfactant 18kg(Levelling agent O-25 14.4kg and tween T-80 3.6kg), kerosene 44kg is uniformly mixed to get to a kind of additive that can save heavy oil oil consumption.
Application examples 1
It takes the heavy-oil heating of 99.7kg to 50 DEG C respectively, is added in blender, stir, Example 1~5 is made respectively Standby additive 0.1kg, is added in above-mentioned heavy oil, and liquid fuel is prepared after 30~60 minutes in stirring.Liquid is taken respectively Fuel 5g is put into AC300 calorific value item detection instrument and detects calorific value, and compared with the heavy oil for additive is added, as a result such as table Shown in 1:
As seen from the results in Table 1, the heavy oil calorific value for adding the additive of the present invention is significantly larger than common heavy.
Application examples 2:The heavy oil of the addition present invention carries out combustion test in steam boiler
Boiler rated power:10T/h.
Establishing criteria and method:GB/T15320-2001 《Energy-conserving product assessment guidelines》、GB/T13234-1991《It starts an undertaking Energy saving calculation method》、GB/T10180-2003《Industrial Boiler Thermal Performance Test regulation》.
Measurement project is shown in Table 2, and the additive and 75% heavy oil that wherein embodiment 1 is 24.9% water, 0.1% embodiment 1 obtains are mixed Obtained compound heavy oil is closed, what the additive and 75% heavy oil that embodiment 2 is 24.9% water, 0.1% embodiment 2 obtains were mixed to get Compound heavy oil, the compound heavy oil that the additive and 75% heavy oil that embodiment 3 is 24.9% water, 0.1% embodiment 3 obtains are mixed to get, The compound heavy oil that the additive and 75% heavy oil that embodiment 4 is 24.9% water, 0.1% embodiment 4 obtains are mixed to get, embodiment 5 are The compound heavy oil that the additive and 75% heavy oil that 24.9% water, 0.1% embodiment 5 obtain are mixed to get.
Table 2:Blowdown flow rate detects
Heavy oil to being added to 1 additive of embodiment carries out saving energy test, the results are shown in Table 3.
Table 3:Saving energy test result
Application examples 3:The heavy oil and former 180 heavy oil for adding the additive of the present invention use Comparative result
A new sea 7 steamer uses contrast table
Explosion pressure and exhaust gas temperature comparison
Steamer introduction
Take turns Hull Number:A new sea 7, affiliated unit:One sea sea-freight Co., Ltd of Zhoushan;
Navigation route:Taizhou of Zhejiang power plant harbour-old man mountain harbour;
Quantity on probation:8 tons, usage time:On April 5, -2015 years on the 4th April in 2015;
Steamer size:Hull grows 96 meters;It is wide:15.8 meters.

Claims (2)

1. a kind of additive that can save heavy oil oil consumption, it is characterised in that comprise the following raw materials by weight percent:
Cyclopentadiene tricarbonyl manganese 2~6%
Ethylhexanoate salt 20~35%
2,6-di-tert-butyl p-cresol 1~3%
Surfactant 10~23%
Balance of solvent
The solvent is mixed xylenes or kerosene, and the mixed xylenes is by ortho-xylene, paraxylene and diformazan Benzene is by weight 1:2~4:3~5 are mixed to get;The ethylhexanoate salt is by isooctyl acid iron, isooctyl acid tin and cobalt iso-octoate by weight Measure ratio 1:2~3:4~6 are mixed to get;The surfactant is by levelling agent O-25 and tween T-80 by weight 2~4:1 It is mixed to get.
2. a kind of additive that can save heavy oil oil consumption as described in claim 1, it is characterised in that by following weight percent Raw material composition:
Cyclopentadiene tricarbonyl manganese 3~5%
Ethylhexanoate salt 25~30%
2,6-di-tert-butyl p-cresol 2~3%
Surfactant 12~18%
Balance of solvent.
CN201610895992.8A 2016-10-14 2016-10-14 A kind of additive that can save heavy oil oil consumption Expired - Fee Related CN106520227B (en)

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Application Number Priority Date Filing Date Title
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CN106520227B true CN106520227B (en) 2018-08-31

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Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10251675A (en) * 1997-03-13 1998-09-22 Lion Corp Fuel oil additive and fuel oil composition
CN1169927C (en) * 2002-09-26 2004-10-06 武汉理工大学 Multifunctional heavy oil and fuel oil additive, preparation and use thereof in preparing emulsified oil
CN101845339B (en) * 2010-06-13 2013-04-10 杭州祺和化工有限公司 Addition agent for improving performance of heavy oil
CN103509616A (en) * 2013-09-29 2014-01-15 开封大学 Multicomponent composite diesel oil heavy oil additive
CN103666607B (en) * 2013-12-02 2015-08-19 车春玲 A kind of heavy fuel oil (HFO) catalytic combustion additive and preparation and application
CN105733707A (en) * 2014-12-10 2016-07-06 余翔 Oil-saving additive for diesel

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