CN106519754A - Anti-corrosion reflective coating - Google Patents
Anti-corrosion reflective coating Download PDFInfo
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- CN106519754A CN106519754A CN201610980426.7A CN201610980426A CN106519754A CN 106519754 A CN106519754 A CN 106519754A CN 201610980426 A CN201610980426 A CN 201610980426A CN 106519754 A CN106519754 A CN 106519754A
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- parts
- corrosion
- oxide
- reflecting coating
- absorbent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
Abstract
The invention relates to the technical field of coatings, in particular to an anti-corrosion reflective coating. The anti-corrosion reflective coating is prepared from, by weight, 25-30 parts of waterborne polyurethane resin, 20-25 parts of perchlorovinyl resin, 10-15 parts of hexafluorobutyl acrylate, 6-9 parts of nanometer talcum powder, 5-8 parts of lead powder, 8-12 parts of an ultraviolet light absorber, 2-5 parts of zinc oxide, 2-5 parts of ferric oxide, 3-6 parts of chromic oxide, 8-12 parts of organic pigment and 1-4 parts of a plant insect prevention bacteriostatic agent. The anti-corrosion reflective coating has the functions of absorbing ultraviolet light and generating light reflection color change and is good in durability and low in cost, and pure natural plant raw materials are applied as a corrosion inhibitor, so that the coating is non-toxic, environmentally friendly and safe to use.
Description
Technical field
A kind of the present invention relates to technical field of coatings, more particularly to corrosion-resistant reflecting coating.
Background technology
At present, the main raw material(s) used by reflectorized material includes resin, pigment, glass microballoon etc., any the same former material
Expect to the performance impact of light-reflecting product all it is critical that.Wherein, adhering resin must have good workability, splendid
Cementability, if the product of the unprotected layer in surface, it is also desirable to have water proofing property, washability, top layer resin to adhering resin
Requirement has good transparency, preferable refractive index, excellent weatherability and stability, must also have very between each layer resin
Good compatibility, optical characteristics requirement, use requirement and the manufacturing process that could so meet reflectorized material product are required；For
Pigment, then require high transparent, form and aspect stability, the compatibility good with resin；For glass microballoon, then require with high folding
Penetrate rate, high transparent, low devitrification rate, good circularity, good granularity concordance and dispersibility.But, the system of glass microballoon
Make complex procedures, it is relatively costly, and also existing reflecting coating is all to admix the medicament with antimildew function in liquid coating
The corrosion resistant purpose of aging resistance is realized, but these medicaments admixed in coating belong to pesticide type mostly, more or less have
Some toxicity, it is unfavorable to health, and price is costly.
The content of the invention
(1) technical problem to be solved
In order to solve the problems referred to above of prior art, the present invention provides one kind and can absorb ultraviolet and produce reflective discoloration
Function, using the corrosion-resistant reflecting coating of natural plants antibacterial insect prevention.
(2) technical scheme
In order to achieve the above object, the main technical schemes that the present invention is adopted include：
The corrosion-resistant reflecting coating of the present invention, by the material composition of following weight portion：
Waterborne polyurethane resin 25-30, superchlorinated polyvinyl chloride resin 20-25, hexafluorobutyl acrylate 10-15, nanomete talc powder
6-9, Hydrocerussitum (Ceruse) 5-8, UV absorbent 8-12, Zinc Oxide 2-5, ferrum oxide 2-5, chromium oxide 3-6, organic pigment 8-12, plant
Insect prevention antibacterial 1-4.
Further technical scheme is, the material composition of the corrosion-resistant reflecting coating of the present invention by following weight portion：
Waterborne polyurethane resin 27-29, superchlorinated polyvinyl chloride resin 22-24, hexafluorobutyl acrylate 12-14, nanomete talc powder
7-8, Hydrocerussitum (Ceruse) 6-7, UV absorbent 9-11, Zinc Oxide 3-4, ferrum oxide 3-4, chromium oxide 4-5, organic pigment 9-11, plant
Insect prevention antibacterial 2-3.
Further technical scheme is, the present invention corrosion-resistant reflecting coating by following weight portion material composition：
Waterborne polyurethane resin 28.5, superchlorinated polyvinyl chloride resin 23.2, hexafluorobutyl acrylate 13.8, nanomete talc powder 7.6,
Hydrocerussitum (Ceruse) 6.4, UV absorbent 10, Zinc Oxide 3.3, ferrum oxide 3.7, chromium oxide 4.1, organic pigment 10, botanical insect-proof are antibacterial
Agent 2.9.
Further technical scheme is, UV absorbent is oxybenzoic acid phenyl ester.
Further technical scheme is, organic pigment is quinacridone pigment.
Further technical scheme is, botanical insect-proof antibacterial includes Folium Ilicis, Flos Caryophylli and Radix et Caulis Opuntiae Dillenii, Folium Ilicis, fourth
The weight ratio of fragrant and Radix et Caulis Opuntiae Dillenii is 2-3:1:1.
(3) beneficial effect
The invention has the beneficial effects as follows：The corrosion-resistant reflecting coating of the present invention, absorbs ultraviolet by UV absorbent
And reflective colour change function is produced, and the complicated technology for preparing glass microballoon is eliminated, durability is good, cheap, and reflecting power is strong.
And, corrosion inhibitor is done using the plant material of pure natural, compare pesticide, asepsis environment-protecting, using safety.
Specific embodiment
In order to preferably explain the present invention, in order to understand, by specific embodiment, the present invention is described in detail.
The corrosion-resistant reflecting coating of the present invention, by the material composition of following weight portion：
Waterborne polyurethane resin 25-30, superchlorinated polyvinyl chloride resin 20-25, hexafluorobutyl acrylate 10-15, nanomete talc powder
6-9, Hydrocerussitum (Ceruse) 5-8, UV absorbent 8-12, Zinc Oxide 2-5, ferrum oxide 2-5, chromium oxide 3-6, organic pigment 8-12, plant
Insect prevention antibacterial 1-4.
Preferably：Waterborne polyurethane resin 27-29, superchlorinated polyvinyl chloride resin 22-24, hexafluorobutyl acrylate 12-14, nanometer
Pulvis Talci 7-8, Hydrocerussitum (Ceruse) 6-7, UV absorbent 9-11, Zinc Oxide 3-4, ferrum oxide 3-4, chromium oxide 4-5, organic pigment 9-
11st, botanical insect-proof antibacterial 2-3.
Waterborne polyurethane resin can also be substituted with water-compatible amino resin, as paints adhesives.
UV absorbent is oxybenzoic acid phenyl ester, or ESCALOL 567, can inhale
Receive ultraviolet and produce reflective colour change function.
Organic pigment is quinacridone pigment, AZOpigments.
The preparation method of botanical insect-proof antibacterial is divided into following step：
S1：It is 2-3 by weight ratio:1:1 dry Folium Ilicis, Flos Caryophylli and Radix et Caulis Opuntiae Dillenii break into coarse powder, cross 25 mesh sieves；
S2：Folium Ilicis, Flos Caryophylli and ethanol that Radix et Caulis Opuntiae Dillenii coarse powder concentration is 85% are entered under 80-85 DEG C of temperature conditionss
Row reflux, extract, 2-3 hour, obtains concentrated solution；
S3：By the concentrated solution for obtaining by macroporous adsorbent resin separation and concentration, successively with water, 30% aquiferous ethanol,
40% aquiferous ethanol, 50% aquiferous ethanol, 60% aquiferous ethanol, 70% aquiferous ethanol carry out gradient elution, collect 3 times of posts respectively
Each position eluent of volume, collects and combines 40% aquiferous ethanol, 50% aquiferous ethanol, the eluting at each position of 60% aquiferous ethanol
The 1/5-1/4 that the eluent of merging is concentrated into original volume is obtained botanical insect-proof antibacterial by liquid.
Embodiment one
Take the material of following weight portion：Waterborne polyurethane resin 25, superchlorinated polyvinyl chloride resin 20, hexafluorobutyl acrylate 10,
Nanomete talc powder 6, Hydrocerussitum (Ceruse) 5, UV absorbent 8, Zinc Oxide 2, ferrum oxide 2, chromium oxide 3, the suppression of organic pigment 8, botanical insect-proof
Microbial inoculum 1.Above material mixing is uniformly obtained final product into corrosion-resistant reflecting coating.
The preparation method of the botanical insect-proof antibacterial is divided into following step：
S1：It is 2 by weight ratio:1:1 Folium Ilicis, Flos Caryophylli and Radix et Caulis Opuntiae Dillenii break into coarse powder, cross 25 mesh sieves；
S2：By dry Folium Ilicis, Flos Caryophylli and ethanol that Radix et Caulis Opuntiae Dillenii coarse powder concentration is 85% under 80 DEG C of temperature conditionss
Carry out reflux, extract, 3 hours, obtain concentrated solution；
S3：By the concentrated solution for obtaining by macroporous adsorbent resin separation and concentration, successively with water, 30% aquiferous ethanol,
40% aquiferous ethanol, 50% aquiferous ethanol, 60% aquiferous ethanol, 70% aquiferous ethanol carry out gradient elution, finally with 70% the third
Ketone eluting, respectively collect 3 times of column volumes each position eluent, collect and combine 40% aquiferous ethanol, 50% aquiferous ethanol, 60%
The eluent of merging is concentrated into the 1/5 of original volume and obtains botanical insect-proof antibacterial by the eluent at each position of aquiferous ethanol.
Embodiment two
Take the material of following weight portion：Waterborne polyurethane resin 28.5, superchlorinated polyvinyl chloride resin 23.2, hexafluorobutyl acrylate
13.8th, nanomete talc powder 7.6, Hydrocerussitum (Ceruse) 6.4, UV absorbent 10, Zinc Oxide 3.3, ferrum oxide 3.7, chromium oxide 4.1, organic
Pigment 10, botanical insect-proof antibacterial 2.9.
The preparation method of the botanical insect-proof antibacterial is divided into following step：
S1：It is 2.5 by weight ratio:1:1 Folium Ilicis, Flos Caryophylli and Radix et Caulis Opuntiae Dillenii break into coarse powder, cross 25 mesh sieves；
S2：By dry Folium Ilicis, Flos Caryophylli and ethanol that Radix et Caulis Opuntiae Dillenii coarse powder concentration is 85% under 83 DEG C of temperature conditionss
Carry out reflux, extract, 2.5 hours, obtain concentrated solution；
S3：By the concentrated solution for obtaining by macroporous adsorbent resin separation and concentration, successively with water, 30% aquiferous ethanol,
40% aquiferous ethanol, 50% aquiferous ethanol, 60% aquiferous ethanol, 70% aquiferous ethanol carry out gradient elution, finally with 70% the third
Ketone eluting, respectively collect 3 times of column volumes each position eluent, collect and combine 40% aquiferous ethanol, 50% aquiferous ethanol, 60%
The eluent of merging is concentrated into the 1/4 of original volume and obtains botanical insect-proof antibacterial by the eluent at each position of aquiferous ethanol.
Embodiment three
Take the material of following weight portion：Waterborne polyurethane resin 30, superchlorinated polyvinyl chloride resin 25, hexafluorobutyl acrylate 15,
Nanomete talc powder 9, Hydrocerussitum (Ceruse) 8, UV absorbent 12, Zinc Oxide 5, ferrum oxide 5, chromium oxide 6, organic pigment 12, botanical insect-proof
Antibacterial 4.Above material mixing is uniformly obtained final product into corrosion-resistant reflecting coating.
The preparation method of the botanical insect-proof antibacterial is divided into following step：
S1：It is 3 by weight ratio:1:1 Folium Ilicis, Flos Caryophylli and Radix et Caulis Opuntiae Dillenii break into coarse powder, cross 25 mesh sieves；
S2：By dry Folium Ilicis, Flos Caryophylli and ethanol that Radix et Caulis Opuntiae Dillenii coarse powder concentration is 85% under 85 DEG C of temperature conditionss
Carry out reflux, extract, 3 hours, obtain concentrated solution；
S3：By the concentrated solution for obtaining by macroporous adsorbent resin separation and concentration, successively with water, 30% aquiferous ethanol,
40% aquiferous ethanol, 50% aquiferous ethanol, 60% aquiferous ethanol, 70% aquiferous ethanol carry out gradient elution, finally with 70% the third
Ketone eluting, respectively collect 3 times of column volumes each position eluent, collect and combine 40% aquiferous ethanol, 50% aquiferous ethanol, 60%
The eluent of merging is concentrated into the 1/5 of original volume and obtains botanical insect-proof antibacterial by the eluent at each position of aquiferous ethanol.
Below by way of corresponding experiment, the invention will be further described：
The reflecting coating prepared using the present invention, carries out each side index and performance test with traditional reflecting coating, as a result
See the table below.
In sum, corrosion-resistant reflecting coating of the invention, can absorb ultraviolet and produce reflective colour change function, durable
Property is good, cheap, and, corrosion inhibitor is done using the plant material of pure natural, asepsis environment-protecting, using safety.
Claims (6)
1. a kind of corrosion-resistant reflecting coating, it is characterised in that it is by the material composition of following weight portion：
Waterborne polyurethane resin 25-30, superchlorinated polyvinyl chloride resin 20-25, hexafluorobutyl acrylate 10-15, nanomete talc powder 6-9,
Hydrocerussitum (Ceruse) 5-8, UV absorbent 8-12, Zinc Oxide 2-5, ferrum oxide 2-5, chromium oxide 3-6, organic pigment 8-12, botanical insect-proof
Antibacterial 1-4.
2. corrosion-resistant reflecting coating as claimed in claim 1, it is characterised in that it is by the material composition of following weight portion
's：
Waterborne polyurethane resin 27-29, superchlorinated polyvinyl chloride resin 22-24, hexafluorobutyl acrylate 12-14, nanomete talc powder 7-8,
Hydrocerussitum (Ceruse) 6-7, UV absorbent 9-11, Zinc Oxide 3-4, ferrum oxide 3-4, chromium oxide 4-5, organic pigment 9-11, botanical insect-proof
Antibacterial 2-3.
3. corrosion-resistant reflecting coating as claimed in claim 1 or 2, it is characterised in that it is by the material group of following weight portion
Into：
Waterborne polyurethane resin 28.5, superchlorinated polyvinyl chloride resin 23.2, hexafluorobutyl acrylate 13.8, nanomete talc powder 7.6, Hydrocerussitum (Ceruse)
6.4th, UV absorbent 10, Zinc Oxide 3.3, ferrum oxide 3.7, chromium oxide 4.1, organic pigment 10, botanical insect-proof antibacterial
2.9。
4. corrosion-resistant reflecting coating as claimed in claim 1 or 2, it is characterised in that：
The UV absorbent is oxybenzoic acid phenyl ester.
5. corrosion-resistant reflecting coating as claimed in claim 1 or 2, it is characterised in that：
The organic pigment is quinacridone pigment.
6. corrosion-resistant reflecting coating as claimed in claim 1 or 2, it is characterised in that：
The botanical insect-proof antibacterial includes Folium Ilicis, Flos Caryophylli and Radix et Caulis Opuntiae Dillenii, and the weight ratio of Folium Ilicis, Flos Caryophylli and Radix et Caulis Opuntiae Dillenii is 2-
3:1:1。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610980426.7A CN106519754A (en) | 2016-11-08 | 2016-11-08 | Anti-corrosion reflective coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610980426.7A CN106519754A (en) | 2016-11-08 | 2016-11-08 | Anti-corrosion reflective coating |
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| Publication Number | Publication Date |
|---|---|
| CN106519754A true CN106519754A (en) | 2017-03-22 |
Family
ID=58349949
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|---|---|---|---|
| CN201610980426.7A Pending CN106519754A (en) | 2016-11-08 | 2016-11-08 | Anti-corrosion reflective coating |
Country Status (1)
| Country | Link |
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| CN (1) | CN106519754A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108047910A (en) * | 2017-12-12 | 2018-05-18 | 广东韩亚薄膜科技有限公司 | Anti-ultraviolet water paint and preparation method and application |
| CN108192064A (en) * | 2017-12-18 | 2018-06-22 | 苏州浩洋聚氨酯科技有限公司 | A kind of modified polyurethane synthetic material |
| CN110564191A (en) * | 2019-10-29 | 2019-12-13 | 天津宝丽杰涂料有限公司 | coating capable of preventing mold from breeding and spreading |
| CN111580202A (en) * | 2020-05-25 | 2020-08-25 | 合肥路明反光材料有限公司 | High-brightness folding-resistant reflective cloth |
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| CN103122574A (en) * | 2011-11-18 | 2013-05-29 | 大连得达科技发展有限公司 | Method for manufacturing reflective clothing |
| CN103756505A (en) * | 2013-12-26 | 2014-04-30 | 苏州市邦成电子科技有限公司 | Reflective coating |
| CN103865391A (en) * | 2014-03-19 | 2014-06-18 | 湖州百胜涂料有限公司 | Environment-friendly reflective coating |
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| CN105368203A (en) * | 2015-11-12 | 2016-03-02 | 合肥安奎思成套设备有限公司 | Anti-aging reflective coating |
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2016
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| CN103122574A (en) * | 2011-11-18 | 2013-05-29 | 大连得达科技发展有限公司 | Method for manufacturing reflective clothing |
| CN103756505A (en) * | 2013-12-26 | 2014-04-30 | 苏州市邦成电子科技有限公司 | Reflective coating |
| CN103865391A (en) * | 2014-03-19 | 2014-06-18 | 湖州百胜涂料有限公司 | Environment-friendly reflective coating |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108047910A (en) * | 2017-12-12 | 2018-05-18 | 广东韩亚薄膜科技有限公司 | Anti-ultraviolet water paint and preparation method and application |
| CN108192064A (en) * | 2017-12-18 | 2018-06-22 | 苏州浩洋聚氨酯科技有限公司 | A kind of modified polyurethane synthetic material |
| CN110564191A (en) * | 2019-10-29 | 2019-12-13 | 天津宝丽杰涂料有限公司 | coating capable of preventing mold from breeding and spreading |
| CN111580202A (en) * | 2020-05-25 | 2020-08-25 | 合肥路明反光材料有限公司 | High-brightness folding-resistant reflective cloth |
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