CN106519399A - Low-density nano composite material - Google Patents
Low-density nano composite material Download PDFInfo
- Publication number
- CN106519399A CN106519399A CN201611059904.7A CN201611059904A CN106519399A CN 106519399 A CN106519399 A CN 106519399A CN 201611059904 A CN201611059904 A CN 201611059904A CN 106519399 A CN106519399 A CN 106519399A
- Authority
- CN
- China
- Prior art keywords
- low
- composite material
- nano composite
- parts
- density
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/108—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond in a heterocyclic ring containing at least one carbon atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2451/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a low-density nano composite material, relating to the technical field of nano materials. The low-density nano composite material is prepared from the following raw materials: nano powder, a foaming agent, grafted polyolefin, low-density polyethylene, a coupling agent, a dispersing agent, an inorganic filler, a foaming agent and a toughener. The low-density nano composite material has the advantages of favorable properties and high stability. By adding the nano powder and other raw materials into the low-density polyethylene, the wear resistance of the nano composite material is enhanced under the under actions of the combination of the raw materials. The toughener increases the toughness of the nano composite material. Thus, the nano composite material has wide application range.
Description
Technical field
The present invention relates to technical field of nano material, and in particular to a kind of low-density nano composite material.
Background technology
Nano composite material be with matrixes such as resin, rubber, ceramics and metals as continuous phase, with the metal of nano-scale,
The modifying agent such as quasiconductor, rigid particles and other inorganic particulates, fiber, CNT is dispersion phase, by appropriate preparation side
Modifying agent uniformity is scattered in matrix material by method, forms a compound system containing nano-sized materials, because tool
There are the mechanical property more more excellent than conventional composite materials, barrier property, heat stability and fire resistance, be widely used in boat
The fields such as empty space flight, national defence, traffic, physical culture.
Nano composite material is to develop very rapid frontier in material science in recent years.Nano composite material it is special
Function is mainly derived from the small-size effect of particle and numerous Interface composites effects, as long as with a small amount of nano-particle by molten
Melt mixing or the mode of in-situ polymerization be added in polymer, can improve the mechanical performance of the polymer, barrier property and
Fire resistance, but, in prior art, obtained low-density nano composite material, although rigidity and fire resistance are improved,
But the mechanical performances such as wearability and toughness are poor.
The content of the invention
Not enough for prior art, the present invention provides a kind of low-density nano composite material, solves low in prior art
The technical problem of density nano composite material bad mechanical property.
To realize object above, technical scheme is achieved by the following technical programs：
A kind of low-density nano composite material, the low-density nano composite material are made up of the raw material of following weight portion：Nanometer
Powder body 15-25 parts, foaming agent 2-5 parts, graft polyolefin 2-3 parts, Low Density Polyethylene 70-85 parts, coupling agent 1-2 parts, dispersion
Agent 1-2 parts, inorganic filler 8-15 parts, foaming agent 1-2 parts, toughener 1-2 parts.
Preferably, the nano-powder is nano titanium oxide or nano silicon.
Preferably, the inorganic filler be Pulvis Talci, Calcium Carbonate, at least one in barium sulfate.
Preferably, the mean diameter of the inorganic filler is 0.5-10 μm.
Preferably, the graft polyolefin is maleic anhydride inoculated polypropylene.
Preferably, the density of the graft polyolefin be 0.88-0.90g/cm3, fusing point be 170-190 DEG C, 230 DEG C ×
Under the test condition of 2.16kg, melt flow rate (MFR) is 30-70g/10min, and percent grafting is 0.4-1.2%.
Preferably, the coupling agent is titanate esters or aluminium sesquioxide.
Preferably, the dispersant is glycerol monostearate.
Preferably, the foaming agent is APP or tripolycyanamide.
Preferably, the toughener be carboxy terminated nitrile rubber, neoprene, at least one in chlorosulfonated polyethylene
The present invention provides a kind of low-density nano composite material, and advantage is compared with prior art：
Obtained in of the invention, low-density nano composite material performance is good, and stability is high, and the present invention adds in Low Density Polyethylene
Nano-powder and other raw materials, be combineding with each other between raw material improves the anti-wear performance of nano composite material, while toughener
The toughness of nano composite material is increased again.
Low-density nano composite material of the present invention has function admirable, mechanical property preferably, with higher rigidity and tough
Property, and density is low, and product has more preferable practicality and wider use range.
Specific embodiment
To make purpose, technical scheme and the advantage of the embodiment of the present invention clearer, with reference to the embodiment of the present invention pair
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is a part of the invention
Embodiment, rather than the embodiment of whole.Based on the embodiment in the present invention, those of ordinary skill in the art are not making wound
The every other embodiment obtained under the premise of the property made work, belongs to the scope of protection of the invention.
Embodiment 1：
The present embodiment low-density nano composite material is made up of the raw material of following weight portion：15 parts of nano-powder, 2 parts of foaming agent,
2 parts of graft polyolefin, 70 parts of Low Density Polyethylene, 1 part of coupling agent, 1 part of dispersant, 8 parts of inorganic filler, 1 part of foaming agent, toughness reinforcing
1 part of agent；
Wherein, nano-powder is nano titanium oxide；
Inorganic filler is Pulvis Talci, and the mean diameter of inorganic filler is 0.5 μm；
Graft polyolefin is maleic anhydride inoculated polypropylene, and the density of graft polyolefin is 0.88g/cm3, and fusing point is 170 DEG C,
Under the test condition of 230 DEG C × 2.16kg, melt flow rate (MFR) is 30g/10min, and percent grafting is 0.4%；
Coupling agent is titanate esters；
Foaming agent is APP；
Toughener is carboxy terminated nitrile rubber.
The preparation method of the present embodiment low-density nano composite material, comprises the following steps：
S1, by the nano-powder of weight portion, foaming agent, graft polyolefin, Low Density Polyethylene, coupling agent, dispersant, inorganic fill out
Material, foaming agent and toughener mix homogeneously, obtain mixed material；
S2, by mixed material add double screw extruder in extruding pelletization, obtain final product acrylic resin, wherein double screw extruder spiral shell
Bar temperature is 220 DEG C, and screw speed is 120 r/min.
Embodiment 2
The present embodiment low-density nano composite material is made up of the raw material of following weight portion：25 parts of nano-powder, 5 parts of foaming agent,
3 parts of graft polyolefin, 85 parts of Low Density Polyethylene, 2 parts of coupling agent, 2 parts of dispersant, 15 parts of inorganic filler, 2 parts of foaming agent, increasing
Tough dose 2 parts；
Wherein, nano-powder is nano silicon；
Inorganic filler is Calcium Carbonate, and the mean diameter of inorganic filler is 10 μm；
Graft polyolefin is maleic anhydride inoculated polypropylene, and the density of graft polyolefin is 0.90g/cm3, and fusing point is 190 DEG C,
Under the test condition of 230 DEG C × 2.16kg, melt flow rate (MFR) is 70g/10min, and percent grafting is 1.2%；
Coupling agent is aluminium sesquioxide；
Dispersant is glycerol monostearate；
Foaming agent is tripolycyanamide；
Toughener is neoprene.
The preparation method of the present embodiment low-density nano composite material is with embodiment 1.
Embodiment 3
The present embodiment low-density nano composite material is made up of the raw material of following weight portion：20 parts of nano-powder, 3 parts of foaming agent,
3 parts of graft polyolefin, 78 parts of Low Density Polyethylene, 2 parts of coupling agent, 1 part of dispersant, 12 parts of inorganic filler, 2 parts of foaming agent, increasing
Tough dose 2 parts；
Wherein, nano-powder is nano titanium oxide；
Inorganic filler is barium sulfate, and the mean diameter of inorganic filler is 0.8 μm；
Graft polyolefin is maleic anhydride inoculated polypropylene, and the density of graft polyolefin is 0.89g/cm3, and fusing point is 180 DEG C,
Under the test condition of 230 DEG C × 2.16kg, melt flow rate (MFR) is 50g/10min, and percent grafting is 0.8%；
Coupling agent is titanate esters；
Foaming agent is tripolycyanamide；
Dispersant is glycerol monostearate；
Toughener is chlorosulfonated polyethylene.
The preparation method of the present embodiment low-density nano composite material is with embodiment 1.
Embodiment 4
The present embodiment low-density nano composite material is made up of the raw material of following weight portion：23 parts of nano-powder, 4 parts of foaming agent,
3 parts of graft polyolefin, 81 parts of Low Density Polyethylene, 2 parts of coupling agent, 1 part of dispersant, 14 parts of inorganic filler, 1 part of foaming agent, increasing
Tough dose 1 part；
Wherein, nano-powder is nano titanium oxide；
Inorganic filler is Pulvis Talci, and the mean diameter of inorganic filler is 0.9 μm；
Graft polyolefin is maleic anhydride inoculated polypropylene, and the density of graft polyolefin is 0.90g/cm3, and fusing point is 185 DEG C,
Under the test condition of 230 DEG C × 2.16kg, melt flow rate (MFR) is 60g/10min, and percent grafting is 1.1%；
Coupling agent is aluminium sesquioxide；
Foaming agent is APP；
Toughener is carboxy terminated nitrile rubber, neoprene, chlorosulfonated polyethylene are mixed.
The preparation method of the present embodiment low-density nano composite material is with embodiment 1.
Embodiment 5
The present embodiment low-density nano composite material is made up of the raw material of following weight portion：17 parts of nano-powder, 3 parts of foaming agent,
3 parts of graft polyolefin, 75 parts of Low Density Polyethylene, 1 part of coupling agent, 2 parts of dispersant, 10 parts of inorganic filler, 1 part of foaming agent, increasing
Tough dose 1 part；
Wherein, nano-powder is nano silicon；
Inorganic filler is Pulvis Talci, Calcium Carbonate, barium sulfate are mixed, and the mean diameter of inorganic filler is 0.6 μm；
Graft polyolefin is maleic anhydride inoculated polypropylene, and the density of graft polyolefin is 0.89g/cm3, and fusing point is 175 DEG C,
Under the test condition of 230 DEG C × 2.16kg, melt flow rate (MFR) is 40g/10min, and percent grafting is 0.5%；
Coupling agent is titanate esters；
Foaming agent is tripolycyanamide；
Dispersant is glycerol monostearate；
Toughener is neoprene.
The preparation method of the present embodiment low-density nano composite material is with embodiment 1.
Embodiment 6
The present embodiment low-density nano composite material is made up of the raw material of following weight portion：24 parts of nano-powder, 5 parts of foaming agent,
2 parts of graft polyolefin, 81 parts of Low Density Polyethylene, 2 parts of coupling agent, 2 parts of dispersant, 11 parts of inorganic filler, 1 part of foaming agent, increasing
Tough dose 2 parts；
Wherein, nano-powder is nano titanium oxide；
Inorganic filler is Pulvis Talci, and the mean diameter of inorganic filler is 0.7 μm；
Graft polyolefin is maleic anhydride inoculated polypropylene, and the density of graft polyolefin is 0.88g/cm3, and fusing point is 187 DEG C,
Under the test condition of 230 DEG C × 2.16kg, melt flow rate (MFR) is 65g/10min, and percent grafting is 1%；
Coupling agent is titanate esters；
Foaming agent is APP；
Toughener is carboxy terminated nitrile rubber.
The preparation method of the present embodiment low-density nano composite material is with embodiment 1.
In sum, obtained in the present invention, low-density nano composite material performance is good, and stability is high, and the present invention is in low-density
Add nano-powder and other raw materials in polyethylene, be combineding with each other between raw material improves the wearability of nano composite material
Can, while toughener increased the toughness of nano composite material again.
Low-density nano composite material of the present invention has function admirable, mechanical property preferably, with higher rigidity and tough
Property, and density is low, and product has more preferable practicality and wider use range.
It should be noted that above example is only to illustrate technical scheme, rather than a limitation；Although ginseng
The present invention is described in detail according to previous embodiment, it will be understood by those within the art that：Which still can be with
Technical scheme described in foregoing embodiments is modified, or equivalent is carried out to which part technical characteristic；And
These modifications are replaced, and do not make the essence of appropriate technical solution depart from the spirit and model of various embodiments of the present invention technical scheme
Enclose.
Claims (10)
1. a kind of low-density nano composite material, it is characterised in that the low-density nano composite material is by following weight portion
Raw material is made：Nano-powder 15-25 parts, foaming agent 2-5 parts, graft polyolefin 2-3 parts, Low Density Polyethylene 70-85 parts, coupling
Agent 1-2 parts, dispersant 1-2 parts, inorganic filler 8-15 parts, foaming agent 1-2 parts, toughener 1-2 parts.
2. low-density nano composite material according to claim 1, it is characterised in that：The nano-powder is nano-silica
Change titanium or nano silicon.
3. low-density nano composite material according to claim 1, it is characterised in that：The inorganic filler be Pulvis Talci,
At least one in Calcium Carbonate, barium sulfate.
4. low-density nano composite material according to claim 3, it is characterised in that：The mean diameter of the inorganic filler
For 0.5-10 μm.
5. low-density nano composite material according to claim 1, it is characterised in that：The graft polyolefin is maleic acid
Acid anhydride graft polypropylene.
6. low-density nano composite material according to claim 1 or 5, it is characterised in that：The graft polyolefin it is close
Spend for 0.88-0.90g/cm3, fusing point is 170-190 DEG C, and under the test condition of 230 DEG C × 2.16kg, melt flow rate (MFR) is
30-70g/10min, percent grafting are 0.4-1.2%.
7. low-density nano composite material according to claim 1, it is characterised in that：The coupling agent is titanate esters or three
Al 2 O.
8. low-density nano composite material according to claim 1, it is characterised in that：The dispersant is that stearic acid list is sweet
Grease.
9. low-density nano composite material according to claim 1, it is characterised in that：The foaming agent be APP or
Tripolycyanamide.
10. low-density nano composite material according to claim 1, it is characterised in that：The toughener is carboxyl butyronitrile
At least one in rubber, neoprene, chlorosulfonated polyethylene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611059904.7A CN106519399A (en) | 2016-11-28 | 2016-11-28 | Low-density nano composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611059904.7A CN106519399A (en) | 2016-11-28 | 2016-11-28 | Low-density nano composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106519399A true CN106519399A (en) | 2017-03-22 |
Family
ID=58357379
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611059904.7A Withdrawn CN106519399A (en) | 2016-11-28 | 2016-11-28 | Low-density nano composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106519399A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370006A (en) * | 2018-10-08 | 2019-02-22 | 南京聚隆科技股份有限公司 | A kind of high apparent mass blow molding fretting map car duct material and preparation method thereof |
| CN109370005A (en) * | 2018-10-08 | 2019-02-22 | 南京聚隆科技股份有限公司 | One kind can silk-screen blow molding fretting map tool box and preparation method thereof |
| CN109880546A (en) * | 2019-03-14 | 2019-06-14 | 南亚新材料科技股份有限公司 | Barium sulfate filler slurry of polymolecularity applied to copper-clad plate and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102791782A (en) * | 2010-03-08 | 2012-11-21 | 旭化成化学株式会社 | Foam composition, method for producing same, and foam |
| CN103374167A (en) * | 2012-04-27 | 2013-10-30 | 东北林业大学 | High-filling calcium carbonate/polyethylene bacteriostatic foam material and preparation method thereof |
| CN103613836A (en) * | 2013-11-21 | 2014-03-05 | 安徽爱乐门窗系统工程有限公司 | Foaming material with modifying filler |
-
2016
- 2016-11-28 CN CN201611059904.7A patent/CN106519399A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102791782A (en) * | 2010-03-08 | 2012-11-21 | 旭化成化学株式会社 | Foam composition, method for producing same, and foam |
| CN103374167A (en) * | 2012-04-27 | 2013-10-30 | 东北林业大学 | High-filling calcium carbonate/polyethylene bacteriostatic foam material and preparation method thereof |
| CN103613836A (en) * | 2013-11-21 | 2014-03-05 | 安徽爱乐门窗系统工程有限公司 | Foaming material with modifying filler |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370006A (en) * | 2018-10-08 | 2019-02-22 | 南京聚隆科技股份有限公司 | A kind of high apparent mass blow molding fretting map car duct material and preparation method thereof |
| CN109370005A (en) * | 2018-10-08 | 2019-02-22 | 南京聚隆科技股份有限公司 | One kind can silk-screen blow molding fretting map tool box and preparation method thereof |
| CN109880546A (en) * | 2019-03-14 | 2019-06-14 | 南亚新材料科技股份有限公司 | Barium sulfate filler slurry of polymolecularity applied to copper-clad plate and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Yu et al. | Fabrication of PLA/CNC/CNT conductive composites for high electromagnetic interference shielding based on Pickering emulsions method | |
| CN102532685B (en) | Nano talcpowder modified polypropylene composite material and preparation method thereof | |
| CN102585348A (en) | Toughened conducting material and preparation method for toughened conducting material | |
| US20110193008A1 (en) | Method for producing a phase-change material composition | |
| Zaman et al. | Morphology, mechanical, and crystallization behaviors of micro-and nano-ZnO filled polypropylene composites | |
| WO2013111862A1 (en) | Method for producing master batch for conductive resin, and master batch | |
| CN106519399A (en) | Low-density nano composite material | |
| CN106519390B (en) | Polyolefin graphene nanocomposite material and preparation method thereof | |
| CN101309957A (en) | A polymer composition with uniformly distributed nano-sized inorganic particles | |
| CN103087389A (en) | High-heat-conductivity high-toughness composite material and preparation method thereof | |
| JP2015510685A (en) | Resin composition for electromagnetic shielding containing composite carbon material | |
| TW201602237A (en) | Electrically conductive polyamide moulding materials | |
| TW201637269A (en) | A cathode for a Li/S battery | |
| CN105063794B (en) | The method for promoting the dispersed phase in incompatible polymer blend to form stable fibers | |
| JP2017145414A (en) | Method for producing conductive resin composition | |
| CN102453404A (en) | Novel polyethylene powder coating | |
| JP7055871B2 (en) | Conductive concentrated resin composition, conductive polyamide resin composition, its manufacturing method and molded product | |
| US8961846B2 (en) | Solid-state shear pulverization/melt-mixing methods and related polymer-carbon nanotube composites | |
| CN103436976A (en) | Method for preparing polyolefin-based complex fiber through modified nano-particles | |
| CN104356585A (en) | High-performance continuous carbon fiber reinforced ABS composite material and preparation method thereof | |
| KR101621126B1 (en) | Polymer pellet for extrusion, polymer composites and method for preparing them | |
| WO2013157621A1 (en) | Masterbatch for electrically conductive resin, and electrically conductive resin | |
| WO2014185243A1 (en) | Fiber-reinforced resin composition | |
| CN104356642A (en) | Preparation method of nucleator-carried glass-fiber-reinforced polyamide composite material | |
| JP5564090B2 (en) | Manufacturing method of resin composite material and resin composite material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170322 |