CN106504976A - The cleaning method of backflow board cavity - Google Patents

The cleaning method of backflow board cavity Download PDF

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Publication number
CN106504976A
CN106504976A CN201510565776.2A CN201510565776A CN106504976A CN 106504976 A CN106504976 A CN 106504976A CN 201510565776 A CN201510565776 A CN 201510565776A CN 106504976 A CN106504976 A CN 106504976A
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CN
China
Prior art keywords
formic acid
board cavity
backflow
purge gas
backflow board
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CN201510565776.2A
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Chinese (zh)
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CN106504976B (en
Inventor
蔡凤萍
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Semiconductor Manufacturing International Shanghai Corp
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Semiconductor Manufacturing International Shanghai Corp
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Publication of CN106504976A publication Critical patent/CN106504976A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02041Cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/08Cleaning containers, e.g. tanks
    • B08B9/0804Cleaning containers having tubular shape, e.g. casks, barrels, drums

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Abstract

The cleaning method of the backflow board cavity of the present invention, including:Backflow board cavity is provided, on the wall of the backflow board cavity, forms formic acid tin crystals;Purge gas are passed through in the backflow board cavity, the formic acid tin crystals is contacted with the purge gas and rises Huawei's gaseous state, and flow to outside the backflow board cavity, wherein with the purge gas, the temperature of the cleaning is more than or equal to the sublimation temperature of the formic acid tin crystals.In the present invention, formic acid stannum contact with purge gas so that formic acid stannum temperature raise and distil, gaseous formic acid stannum condenses into crystallization just as the air-flow of purge gas discharges cavity together in the exhaustor outside cavity.Formic acid flows through each region of cavity, thus can clean up the formic acid stannum in backflow board cavity.

Description

The cleaning method of backflow board cavity
Technical field
A kind of the present invention relates to semiconductor device processing technology field, more particularly to cleaning of backflow board cavity Method.
Background technology
In order to carry out the encapsulation of chip (chip), on wafer (wafer), there must be projection (bump) shape Into wafer bumps (wafer bump) so as to the substrate connection with encapsulation.When making projection, first shape on wafer Into Underbump metallization layer (UBM) structure, on Underbump metallization layer, then form a stannum material.Stannum material is passed through Cross backflow solidify afterwards and form projection.In order to prevent the oxidation of the stannum material in reflux course or remove stannum material surface Stannum oxide, needs to be passed through nitrogen and formic acid in reflux course.However, formic acid can generate first with stannum oxide reaction Sour stannum, gaseous state formic acid stannum are sublimated to the cold as solid-state, are remained on the wall of backflow board cavity.Follow-up During projection is formed on wafer, formic acid stannum can come off in crystal column surface, form defect, affect wafer Performance.
Therefore, it is necessary to clean to the board cavity that flows back, prevent formic acid stannum from forming defect in crystal column surface. The cleaning of cavity is needed in prior art cavity is carried out lowering the temperature, begins to speak, cleans, then the operation such as heat up, And need to expend more manpower and materials, affect the production capacity of wafer bumps;Also, can be in return current machine when beginning to speak Outer boundry particle is introduced in platform cavity, so as to increased the granule risk of subsequent product.
Content of the invention
It is an object of the invention to, there is provided a kind of cleaning method of backflow board cavity, by the residual of formic acid stannum Thing is rejected to outside cavity, it is to avoid the defect that formic acid stannum is produced to crystal column surface, improves the production effect of wafer bumps Rate.
For solving above-mentioned technical problem, the present invention provides a kind of cleaning method of backflow board cavity, including;
One backflow board cavity is provided, on the wall of the backflow board cavity, is formed with formic acid tin crystals;
Purge gas, the formic acid tin crystals and the purge gas are passed through in the backflow board cavity Contact rises Huawei's gaseous state, and flow to outside the backflow board cavity, wherein with the purge gas, described clear Sublimation temperature of the temperature that washes more than or equal to the formic acid tin crystals.
Optionally, the purge gas are reducibility gas.
Optionally, the purge gas are formic acid gas.
Optionally, the temperature of the purge gas being passed through is 200 DEG C -300 DEG C.
Optionally, the time of the purge gas being passed through is more than or equal to 30min.
Optionally, the concentration of the purge gas being passed through is more than or equal to 10000ppm
Optionally, the flow of the purge gas being passed through is more than or equal to 30000sccm.
Optionally, the external exhaustor of the backflow board cavity, formic acid stannum gas are coagulated in the exhaustor China forms formic acid tin crystals, whether judges cleaning process by variable quantity of the formic acid tin crystals in the exhaustor Complete.
Optionally, a heater is additionally provided with outside the backflow board cavity, for heating the purge gas.
Optionally, the backflow board cavity includes preheating zone, heating zone, heat preservation zone and cooling area, is passed through After the purge gas, the temperature of the preheating zone, the heating zone, the heat preservation zone and the cooling area Degree is all higher than the sublimation temperature equal to the formic acid tin crystals..
Optionally, the concrete steps for forming formic acid tin crystals in the backflow board cavity include;
Wafer is provided, the wafer includes stannum material, the wafer is placed in the backflow board cavity;
Formic acid is passed through in the backflow board cavity, the formic acid reacts to form formic acid stannum with the stannum material, Formic acid stannum is sublimated on the wall of the backflow board cavity, forms formic acid tin crystals.
The cleaning method of the backflow board cavity of the present invention, is passed through purge gas, institute into backflow board cavity State the sublimation temperature of the temperature more than or equal to formic acid tin crystals of cleaning.Purge gas can flow to backflow board cavity Each place, formic acid tin crystals contact with purge gas so that the rising of formic acid stannum temperature and liter Huawei gaseous state, Gaseous formic acid stannum just discharges cavity together with the air-flow of purge gas, condenses in the exhaustor outside cavity Into crystallization.May determine that by the generating process crystallized in exhaustor whether the formic acid stannum residual in cavity cleans Totally.Formic acid tin crystals in backflow board cavity can be cleaned up by the present invention, and not in cavity Other impurities are introduced, so as to avoid defect being formed in crystal column surface.
Description of the drawings
Fig. 1 is the flow chart of the cleaning method of present invention backflow board cavity;
Fig. 2 is the structure chart in one embodiment of cleaning method of present invention backflow board cavity.
Specific embodiment
The cleaning method of the backflow board cavity of the present invention is retouched in more detail below in conjunction with schematic diagram State, which show the preferred embodiments of the present invention, it should be appreciated that those skilled in the art can change here The present invention of description, and still realize the advantageous effects of the present invention.Therefore, description below is appreciated that Widely known for those skilled in the art, and it is not intended as limitation of the present invention.
The core concept of the present invention is that, after backflow, the temperature of the board cavity that flows back is relatively low for stannum material Part, formic acid stannum can be sublimated to crystallize and be formed residual, the purge gas into backflow board cavity, purge gas Temperature of the temperature more than or equal to formic acid tin crystals distillation, purge gas can flow to each ground of backflow board cavity Side, formic acid tin crystals contact with purge gas so that the rising of formic acid stannum temperature and liter Huawei gaseous state, and with clear The air-flow of gas washing body discharges cavity together, crystallization of sublimating in the exhaustor outside cavity.By the generation for crystallizing Process may determine that whether the formic acid stannum residual in cavity cleans up.Formic acid tin crystals is white crystal, when When white crystal in exhaustor is not further added by, it is believed that the formic acid stannum in backflow board cavity has cleaned dry Only.The present invention can not introduce other impurities in cavity, will be dry for the formic acid stannum cleaning in backflow board cavity Only, so as to avoid crystal column surface formed defect.
The structural representation of the backflow board of the present invention is with reference to shown in Fig. 1, and the backflow below in conjunction with Fig. 2 The flow chart of the cleaning method of board is specifically described to the cleaning method of the present invention.
Execution step S1, there is provided backflow board, backflow board include the backflow board cavity for reflux course 20, the board cavity 20 that flows back include preheating zone (this be it will be appreciated by those skilled in the art that, in figure not Illustrate), heating zone (this be it will be appreciated by those skilled in the art that, not shown in figure), heat preservation zone 21, Cooling area 22, is formed with formic acid tin crystals on the wall of backflow board cavity 20.
In the present embodiment, the formic acid tin crystals on the wall of backflow board cavity 20 is wafer in solder reflow mistake Residual in journey, its detailed process is as follows:Wafer 10 is provided, 10 surface of wafer includes engagement pad, stannum material etc. Structure (not shown), stannum material are sn-ag alloy material, for being formed in the back-end process of wafer 10 Projection cube structure.Wafer 10 is placed in backflow board cavity 20, wafer 10 is placed in backflow board cavity 20 Heat preservation zone 21 in so that in reflux course, the temperature of wafer 10 is more stable.To the board cavity 20 that flows back Heated up so that the temperature of heat preservation zone 21 is maintained 200 DEG C -300 DEG C, nitrogen conduct is passed through in cavity Shielding gas prevents stannum material oxidized in reflux course, and stannum material is flowed back, and the time of reflux course is 15min-25min.Temperature in reflux course exceedes the fusing point of sn-ag alloy so that stannum material is molten into liquid gold Category, liquid metal in the presence of surface tension can become and connect torulose shape.However, due to stannum material The shape of bottom is fixed so that stannum material formed spherical so that stannum material formed wafer projection.Backflow During, as the oxygen of residual is difficult to avoid that in cavity, to form one layer of oxygen so as to aoxidize on stannum material surface Changing stannum, therefore, a small amount of formic acid gas being passed through while nitrogen is passed through, the concentration of the formic acid being passed through is 500ppm-1000ppm.Formic acid both had faintly acid, while have reproducibility again.Now, formic acid can be with The stannum oxide reaction on stannum material top layer, so that remove the oxide layer on stannum material surface so that the wafer bumps of formation Performance is more preferable.But, formic acid is reacted in heat preservation zone 21 with the stannum oxide of stannum material, and the formic acid stannum of generation is gas State, gaseous formic acid stannum flow to 22 other regions of grade of cooling area in cavity, when the temperature in the region relatively low (low In 200 DEG C) when.Gaseous formic acid stannum is sublimated to the cold and crystallizes into solid-state, therefore, in the cooling area of cavity The low region of 22 grade other temperature, formic acid stannum form crystallization and remain in cavity.
In the present invention, follow-up wafer is carried out in the backflow board cavity 20 for remaining formic acid tin crystals and flowed back During, formic acid tin crystals can come off and form residue in crystal column surface, form defect, affect wafer Performance.Additionally, in the present embodiment, illustrate so that the reflux course of wafer forms formic acid tin crystals as an example, It will be appreciated by persons skilled in the art that formic acid tin crystals can be residual to be formed in other technical process Stay in backflow board cavity, the present invention is without limitation.
Execution step S2, by purge gas from the one end for the air inlet pipe 30 being connected with the backflow board cavity Backflow board cavity 20 is passed through, the temperature of the purge gas is more than or equal to the temperature of formic acid tin crystals distillation, So that formic acid tin crystals is contacted with the purge gas and temperature rising, and rise Huawei's gas.Need explanation It is that the purge gas can also have reproducibility so that during purge gas are passed through, purgative gas Body and formic acid tin crystals or the other impurities in cavity can also carry out the reaction of reproducibility so that clear in cavity That washed is more abundant.In the present embodiment, illustrated as a example by being passed through formic acid gas, using formic acid gas not Impurity is easily introduced, formic acid is entered in cavity from air inlet pipe 30.In 30 middle setting of air inlet pipe, one heater 40, The depth of formic acid is heated to the gaseous state formic acid that predetermined temperature is 200 DEG C -300 DEG C by heater 40 by formic acid, Gaseous state formic acid is passed through in cavity.The concentration of the formic acid being passed through is more than or equal to 10000ppm, the stream of the formic acid being passed through Amount is more than or equal to 30000sccm so that after being passed through the purge gas, preheating zone, heating zone, cooling area And the temperature of heat preservation zone is above the temperature of formic acid tin crystals distillation, and the total amount foot of the formic acid for causing to be passed through To remove all of formic acid stannum for being remained in cavity.Additionally, under the formic acid gas of the concentration and flow, The pressure and pressure flowed back in board cavity 20 can preferably be controlled so that purge gas and formic acid tin crystals That reacted is more abundant, and enables formic acid stannum gas to flow to the outside of backflow board cavity 20 faster.First After acid gas enter backflow board cavity 20, the formic acid tin crystals formic acid higher with temperature is contacted, formic acid stannum Heat rises Huawei's gaseous state, and gaseous formic acid stannum is flowed outside cavity together with the air-flow of formic acid.In the present embodiment In, the time of the formic acid being passed through is more than or equal to 30min, and the high temperature being continually fed into, the formic acid of high concentration can flow Through each place in cavity, so that the formic acid stannum of each place residual can distil in cavity For gaseous state, and with formic acid gas Liu Dao exhaustors 50 in.
It should be noted that in the cleaning method of the backflow board cavity of the present invention, also include step S3, In step s3, formic acid stannum is being sublimated to form knot with being formed in the exhaustor 50 being connected outside backflow board cavity Brilliant.It is understood that formic acid tin crystals is white, therefore, it can the variable quantity by formic acid tin crystals Judge whether cleaning process completes.When the crystallization that formic acid stannum is formed in exhaustor 50 is not further added by, can be with Judge that the residual of the formic acid stannum in now cavity is cleaned.Judge that the variable quantity of formic acid tin crystals can be adopted Method with directly observing.Certainly, in the present embodiment, it is also possible to which the composition of the gas at exhaustor 30 is entered Row detection, so that judge whether formic acid stannum cleans completely.
Additionally, adopting the formic acid gas of high-temperature, high-temperature, high flow capacity in the present embodiment as removal formic acid The carrier gas of tin crystals, certainly, can also adopt other carrier gas to remove formic acid tin crystals in the present invention.For example, Reducibility gas hydrogen.But, using formic acid as reducibility gas in reflux course, therefore, this The formic acid of bright employing, can not be in the case of introducing other impurities in backflow board cavity used as carrier gas, will Formic acid tin crystals in cavity is removed.
In sum, the cleaning method of backflow board cavity of the invention.The purgative gas into backflow board cavity Body, the temperature of purge gas are higher than the sublimation temperature of formic acid tin crystals.The purge gas being continually fed into can flow to Cavity each place, formic acid stannum contact with purge gas so that formic acid stannum temperature rising and distil, gaseous Formic acid stannum just discharges cavity together with the air-flow of purge gas, condenses into crystallization in the exhaustor outside cavity. May determine that by the generating process for crystallizing whether the formic acid stannum residual in cavity cleans up.The present invention can be with Formic acid stannum in backflow board cavity is cleaned up, and other impurities is not introduced in cavity, so as to keep away Exempt to form defect in crystal column surface.
Obviously, those skilled in the art can carry out various changes and modification without deviating from this to the present invention Bright spirit and scope.So, if the present invention these modification and modification belong to the claims in the present invention and Within the scope of its equivalent technologies, then the present invention is also intended to comprising these changes and modification.

Claims (11)

1. a kind of backflow board cavity cleaning method, it is characterised in that include:
One backflow board cavity is provided, on the wall of the backflow board cavity, is formed with formic acid tin crystals;
Purge gas are passed through in the backflow board cavity, the formic acid tin crystals is contacted with the purge gas and rises Huawei's gaseous state, and flow to outside the backflow board cavity, wherein with the purge gas, the temperature of the cleaning is more than or equal to the sublimation temperature of the formic acid tin crystals.
2. as claimed in claim 1 backflow board cavity cleaning method, it is characterised in that the purge gas be reducibility gas.
3. as claimed in claim 2 backflow board cavity cleaning method, it is characterised in that the purge gas be formic acid gas.
4. as claimed in claim 1 backflow board cavity cleaning method, it is characterised in that the temperature of the purge gas being passed through be 200 DEG C -300 DEG C.
5. as claimed in claim 1 backflow board cavity cleaning method, it is characterised in that the time of the purge gas being passed through be more than or equal to 30min.
6. as claimed in claim 1 backflow board cavity cleaning method, it is characterised in that the concentration of the purge gas being passed through be more than or equal to 10000ppm.
7. as claimed in claim 1 backflow board cavity cleaning method, it is characterised in that the flow of the purge gas being passed through be more than or equal to 30000sccm.
8. as described in any one in claim 1-7 backflow board cavity cleaning method, it is characterized in that, the external exhaustor of board cavity that flows back, formic acid stannum gas sublimates to form formic acid tin crystals in the exhaustor, judges whether cleaning process completes by variable quantity of the formic acid tin crystals in the exhaustor.
9. as described in any one in claim 1-7 backflow board cavity cleaning method, it is characterised in that be additionally provided with a heater outside the backflow board cavity, for heating the purge gas.
10. as claimed in claim 1 backflow board cavity cleaning method, it is characterized in that, the backflow board cavity includes preheating zone, heating zone, heat preservation zone and cooling area, after being passed through the purge gas, the temperature of the preheating zone, the heating zone, the heat preservation zone and the cooling area is all higher than the sublimation temperature equal to the formic acid tin crystals.
The cleaning method of 11. backflow board cavitys as claimed in claim 1, it is characterised in that the concrete steps for forming formic acid tin crystals in the backflow board cavity include:
Wafer is provided, the wafer includes stannum material, the wafer is placed in the backflow board cavity;
Formic acid is passed through in the backflow board cavity, the formic acid reacts to form formic acid stannum with the stannum material, formic acid stannum is sublimated on the wall of the backflow board cavity, forms formic acid tin crystals.
CN201510565776.2A 2015-09-07 2015-09-07 The cleaning method of reflux board cavity Active CN106504976B (en)

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CN106504976B CN106504976B (en) 2019-05-03

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114234630A (en) * 2022-02-24 2022-03-25 泰姆瑞(北京)精密技术有限公司 Online type partition vacuum furnace with cleaning function and welding method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5913127A (en) * 1995-06-29 1999-06-15 Micron Technology, Inc. Method to thermally form hemispherical grain (HSG) silicon to enhance capacitance for application in high density DRAMS
CN101160647A (en) * 2004-06-10 2008-04-09 塞米吉尔公司 Serial thermal processor arrangement
CN104259153A (en) * 2014-07-24 2015-01-07 上海华力微电子有限公司 Furnace tube cleaning process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5913127A (en) * 1995-06-29 1999-06-15 Micron Technology, Inc. Method to thermally form hemispherical grain (HSG) silicon to enhance capacitance for application in high density DRAMS
CN101160647A (en) * 2004-06-10 2008-04-09 塞米吉尔公司 Serial thermal processor arrangement
CN104259153A (en) * 2014-07-24 2015-01-07 上海华力微电子有限公司 Furnace tube cleaning process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114234630A (en) * 2022-02-24 2022-03-25 泰姆瑞(北京)精密技术有限公司 Online type partition vacuum furnace with cleaning function and welding method thereof

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