CN106504832B - A kind of preparation method of the cable of working stability - Google Patents

A kind of preparation method of the cable of working stability Download PDF

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Publication number
CN106504832B
CN106504832B CN201611158881.5A CN201611158881A CN106504832B CN 106504832 B CN106504832 B CN 106504832B CN 201611158881 A CN201611158881 A CN 201611158881A CN 106504832 B CN106504832 B CN 106504832B
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cable
core
oversheath
blank
working stability
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CN106504832A (en
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王小宁
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SHANGHAI PUDONG WIRE AND CABLE (GROUP) CO Ltd
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Suzhou Tong Ming Machinery Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/22Sheathing; Armouring; Screening; Applying other protective layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/0016Apparatus or processes specially adapted for manufacturing conductors or cables for heat treatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06Insulating conductors or cables

Abstract

The present invention relates to a kind of preparation method of the cable of working stability, including (i) dispensing:(ii) melting:(iii) alloy solution is subjected to continuous casting and rolling;(iv) wire drawing;(v) forge;(vi) quench;(vii) blank is made by twisting core, core outer wrapping insulating barrier, insulating barrier outer surface electroplated zinc nickel alloy coating, is made as conductor by both threads core is twisted, will an at least conductor as cable core;(viii) screen layer and oversheath will be wrapped up outside cable core successively, equal preset clearance between cable core, screen layer and oversheath, screen layer is wrapped with zinc-coated wire armor;Described outermost oversheath is the corrosion-resistant mud polyolefin sheath layer of fire-retardant Halogen;(ix) vacuumize:The gap reserved between cable core, screen layer and oversheath is vacuumized;(x) coating is coated.The overall Corrosion Protection and structural strength of the cable are uniformly substantially improved, and ensure that cable normal work under circumstances, and extend cable service life.

Description

A kind of preparation method of the cable of working stability
Technical field
The present invention relates to a kind of preparation method of the cable of working stability, belong to power cable technical field.
Background technology
At present, with the development of science and technology, either industry or the daily life of the mankind, towards electrified side To development, then in industry and power domain, its status is also gradually increased cable.Cable have power cable, control cable, Compensating cable, shielded cable, high-temperature cable, computer cable, signal cable, coaxial cable, fire-resisting cable, cable for ship, aluminium Alloy cable etc..Cable is typically by several or the cable of at least two similar ropes being twisted of several groups of every group of wires, Mutually insulated between every group of wire, and be often twisted into around a center, whole outside is surrounded by the coating of high-insulation, is used for Connect circuit, electrical equipment etc..
With the appearance of haze phenomenon in recent years, the variation of air ambient, no matter overhead cable or buried cable by To certain influence, the harmful substance in air ambient increases, and overhead cable is in surface meeting in such air for a long time There are some mottlings that are corroded, the life-span for shortening cable largely, while the sewage for the formation for passing through rainfall, flow into To underground, there is also certain corrosivity to buried cable.So the corrosion-resistant needs of cable are further strengthened.
The content of the invention
The technical problem to be solved in the present invention is, in view of the shortcomings of the prior art, proposing a kind of work of corrosion resistance and good The preparation method of stable cable.
The present invention is to solve the technical scheme that above-mentioned technical problem proposes to be:A kind of preparation side of the cable of working stability Method, comprise the following steps:
(i) dispensing:The mass percent of each composition is in raw material:C:0.05-0.15%, Fe:1.25-1.56%, Mn: 0.42- 0.73%, S:≤ 0.020%, P:≤ 0.030%, Cr:0.13-0.26%, Ni:1.35-1.63%, Zn:1.75- 1.96%th, Cu:7.95-8.46%, Mo:0.03-0.06%, Ti:1.47-1.69%, Pd:0.02-0.05%, Pt:0.21- 0.33%th, Au:0.41-0.62%, W:0.05-0.15%, Nd:0.03-0.06%, Ce:0.03-0.07%, Eu:0.01- 0.04%th, Lu:0.02-0.03%, surplus Ag;
(ii) melting:The cable raw material of working stability is heated into melting, it is specific as follows:
A, added raw materials into by the mass percent of each composition in the cable of predetermined working stability in smelting furnace, by smelting furnace Temperature bring up to 1650 degrees Celsius to 1680 degrees Celsius, raw material is smelted to form alloy solution;
B, alloy solution obtained in the previous step is cooled down, uses water cooling with 26-28 DEG C/s cooldown rate by alloy Solution water is cooled to room temperature;
C, the alloy after previous step is cooled down carries out secondary smelting in smelting furnace, and the temperature in smelting furnace is brought up into 1500 takes the photograph For family name's degree to 1550 degrees Celsius, alloy forms alloy solution by secondary smelting;
(iii) alloy solution is subjected to continuous casting and rolling;
(iv) wire drawing:By the blank wire drawing after continuous casting and rolling;
(v) forge:The blank after wire drawing is forged into refining using the mode forged;
Blank is heated to 750-800 DEG C first, forged 25 minutes;
Then use water cooling with 16-19 DEG C/s cooling rate by blank water cooling to room temperature;
Blank is heated to 650-680 DEG C again, forged 25 minutes;
Use again water cooling with 11-15 DEG C/s cooling rate by blank water cooling to 350-370 DEG C, be then air-cooled to room temperature;
(vi) quench:Raw material after wire drawing is put into glowing furnace to be quenched, hardening media is vacuum quenching oil, control quenching Temperature is 600-650 DEG C, is taken out after quenching and is air-cooled to room temperature;
(vii) blank is made by twisting core, core outer wrapping insulating barrier, insulating barrier outer surface electroplated zinc nickel alloy coating will Both threads core is twisted to be made as conductor, will an at least conductor as cable core;
(viii) screen layer and oversheath will be wrapped up outside cable core successively, equal preset clearance between cable core, screen layer and oversheath, Screen layer is wrapped with zinc-coated wire armor;Described oversheath is the corrosion-resistant mud polyolefin sheath layer of fire-retardant Halogen;
(ix) vacuumize:The gap reserved between cable core, screen layer and oversheath is vacuumized;
(x) coating is coated, is specially:
A, the uniform dip-coating of the polyethylene glycol polyelectrolyte aqueous solution is dipped in surface of outer sheath with glass bar, be placed in 80- afterwards 0.5-1 hours in 90 DEG C of baking oven, obtain the oversheath coated with polyethylene glycol polyelectrolyte;
B, electroplate:In the surface of outer sheath electroplated zinc nickel alloy coating coated with polyethylene glycol polyelectrolyte, admiro Thickness of coating is 70 ± 30 μm, and the cable of working stability is made.
The improvement of above-mentioned technical proposal is:The step (i) in the cable raw material of middle working stability each composition quality percentage Than for:C:0.05%th, Fe:1.25%th, Mn:0.42%th, S:≤ 0.020%, P:≤ 0.030%, Cr:0.13%th, Ni: 1.35%th, Zn:1.75%th, Cu:7.95%th, Mo:0.03%th, Ti:1.47%th, Pd:0.02%th, Pt:0.21%th, Au: 0.41%th, W:0.05%th, Nd:0.03%th, Ce:0.03%th, Eu:0.01%th, Lu:0.02%, surplus Ag.
The improvement of above-mentioned technical proposal is:The step (i) in the cable raw material of middle working stability each composition quality percentage Than for:C:0.15%th, Fe:1.56%th, Mn:0.73%th, S:≤ 0.020%, P:≤ 0.030%, Cr:0.26%th, Ni: 1.63%th, Zn:1.96%th, Cu:8.46%th, Mo:0.06%th, Ti:1.69%th, Pd:0.05%th, Pt:0.33%th, Au: 0.62%th, W:0.15%th, Nd:0.06%th, Ce:0.07%th, Eu:0.04%th, Lu:0.03%, surplus Ag.
It is of the invention to be using the beneficial effect of above-mentioned technical proposal:
(1) cable of working stability of the invention strengthens the heat-resisting and resistance to of cable due to containing Zn, Ni and W in raw material Corrosive nature;
(2) cable of working stability of the invention alleviates the matter of cable due to containing Ti, Al and rare earth element in raw material Amount, adds structural strength and decay resistance;
(3) cable of the working stability of invention in raw material melting due to having carried out secondary smelting so that raw material melting is more Add thoroughly, can effectively remove the impurity in raw material, improve product quality;
(4) present invention to the blank after wire drawing by carrying out forging processing so that the hair training physical property finally given is more It is good, it is more durable;By repeatedly forging, the heating when forging also acts the effect of tempering, further improves blank Material performance;
(5) present invention can repair the raw material after wire drawing due to being laterally and longitudinally recessed by the quenching carried out to raw material Caused by face crack, raw material superficial layer can be made to produce the residual stress opposite with working stress, part can be offset during stand under load Working stress, the intensity of raw material is added, substantially prolongs service life;
(6) preparation method of the cable of working stability of the invention, it is not dispensing therein, is heat-treated and vacuumizes work Skill so that the heat-and corrosion-resistant and structural strength of cable all greatly promote, and ensure that cable normal work under circumstances, and And extend cable service life;
(7) preparation method of the cable of working stability of the invention, in the poly- electrolysis of the surface of oversheath coating polyethylene glycol Matter, pass through the homogeneous conductive of electrolyte so that coating attachment is more uniform in plating, so as to improve subsequent plating operations Quality so that zn-ni alloy depositses cover even closer uniform, and effectively prevent coating from coming off.
Embodiment
Embodiment 1
The preparation method of the cable of the working stability of the present embodiment, comprises the following steps:
(i) dispensing:The mass percent of each composition is in raw material:C:0.05%th, Fe:1.25%th, Mn:0.42%th, S:≤ 0.020%th, P:≤ 0.030%, Cr:0.13%th, Ni:1.35%th, Zn:1.75%th, Cu:7.95%th, Mo:0.03%th, Ti: 1.47%th, Pd:0.02%th, Pt:0.21%th, Au:0.41%th, W:0.05%th, Nd:0.03%th, Ce:0.03%th, Eu:0.01%th, Lu:0.02%, surplus Ag;
(ii) melting:The cable raw material of working stability is heated into melting, it is specific as follows:
A, added raw materials into by the mass percent of each composition in the cable of predetermined working stability in smelting furnace, by smelting furnace Temperature bring up to 1650 degrees Celsius to 1680 degrees Celsius, raw material is smelted to form alloy solution;
B, alloy solution obtained in the previous step is cooled down, uses water cooling with 26-28 DEG C/s cooldown rate by alloy Solution water is cooled to room temperature;
C, the alloy after previous step is cooled down carries out secondary smelting in smelting furnace, and the temperature in smelting furnace is brought up into 1500 takes the photograph For family name's degree to 1550 degrees Celsius, alloy forms alloy solution by secondary smelting;
(iii) alloy solution is subjected to continuous casting and rolling;
(iv) wire drawing:By the blank wire drawing after continuous casting and rolling;
(v) forge:The blank after wire drawing is forged into refining using the mode forged;
Blank is heated to 750-800 DEG C first, forged 25 minutes;
Then use water cooling with 16-19 DEG C/s cooling rate by blank water cooling to room temperature;
Blank is heated to 650-680 DEG C again, forged 25 minutes;
Use again water cooling with 11-15 DEG C/s cooling rate by blank water cooling to 350-370 DEG C, be then air-cooled to room temperature;
(vi) quench:Raw material after wire drawing is put into glowing furnace to be quenched, hardening media is vacuum quenching oil, control quenching Temperature is 600-650 DEG C, is taken out after quenching and is air-cooled to room temperature;
(vii) blank is made by twisting core, core outer wrapping insulating barrier, insulating barrier outer surface electroplated zinc nickel alloy coating will Both threads core is twisted to be made as conductor, will an at least conductor as cable core;
(viii) screen layer and oversheath will be wrapped up outside cable core successively, equal preset clearance between cable core, screen layer and oversheath, Screen layer is wrapped with zinc-coated wire armor;Described oversheath is the corrosion-resistant mud polyolefin sheath layer of fire-retardant Halogen;
(ix) vacuumize:The gap reserved between cable core, screen layer and oversheath is vacuumized;
(x) coating is coated, is specially:
A, the uniform dip-coating of the polyethylene glycol polyelectrolyte aqueous solution is dipped in surface of outer sheath with glass bar, be placed in 80- afterwards 0.5-1 hours in 90 DEG C of baking oven, obtain the oversheath coated with polyethylene glycol polyelectrolyte;
B, electroplate:In the surface of outer sheath electroplated zinc nickel alloy coating coated with polyethylene glycol polyelectrolyte, admiro Thickness of coating is 70 ± 30 μm, and the cable of working stability is made.
Embodiment 2
The preparation method of the cable of the working stability of the present embodiment, comprises the following steps:
(i) dispensing:The mass percent of each composition is in raw material:C:0.15%th, Fe:1.56%th, Mn:0.73%th, S:≤ 0.020%th, P:≤ 0.030%, Cr:0.26%th, Ni:1.63%th, Zn:1.96%th, Cu:8.46%th, Mo:0.06%th, Ti: 1.69%th, Pd:0.05%th, Pt:0.33%th, Au:0.62%th, W:0.15%th, Nd:0.06%th, Ce:0.07%th, Eu:0.04%th, Lu:0.03%, surplus Ag;
(ii) melting:The cable raw material of working stability is heated into melting, it is specific as follows:
A, added raw materials into by the mass percent of each composition in the cable of predetermined working stability in smelting furnace, by smelting furnace Temperature bring up to 1650 degrees Celsius to 1680 degrees Celsius, raw material is smelted to form alloy solution;
B, alloy solution obtained in the previous step is cooled down, uses water cooling with 26-28 DEG C/s cooldown rate by alloy Solution water is cooled to room temperature;
C, the alloy after previous step is cooled down carries out secondary smelting in smelting furnace, and the temperature in smelting furnace is brought up into 1500 takes the photograph For family name's degree to 1550 degrees Celsius, alloy forms alloy solution by secondary smelting;
(iii) alloy solution is subjected to continuous casting and rolling;
(iv) wire drawing:By the blank wire drawing after continuous casting and rolling;
(v) forge:The blank after wire drawing is forged into refining using the mode forged;
Blank is heated to 750-800 DEG C first, forged 25 minutes;
Then use water cooling with 16-19 DEG C/s cooling rate by blank water cooling to room temperature;
Blank is heated to 650-680 DEG C again, forged 25 minutes;
Use again water cooling with 11-15 DEG C/s cooling rate by blank water cooling to 350-370 DEG C, be then air-cooled to room temperature;
(vi) quench:Raw material after wire drawing is put into glowing furnace to be quenched, hardening media is vacuum quenching oil, control quenching Temperature is 600-650 DEG C, is taken out after quenching and is air-cooled to room temperature;
(vii) blank is made by twisting core, core outer wrapping insulating barrier, insulating barrier outer surface electroplated zinc nickel alloy coating will Both threads core is twisted to be made as conductor, will an at least conductor as cable core;
(viii) screen layer and oversheath will be wrapped up outside cable core successively, equal preset clearance between cable core, screen layer and oversheath, Screen layer is wrapped with zinc-coated wire armor;Described oversheath is the corrosion-resistant mud polyolefin sheath layer of fire-retardant Halogen;
(ix) vacuumize:The gap reserved between cable core, screen layer and oversheath is vacuumized;
(x) coating is coated, is specially:
A, the uniform dip-coating of the polyethylene glycol polyelectrolyte aqueous solution is dipped in surface of outer sheath with glass bar, be placed in 80- afterwards 0.5-1 hours in 90 DEG C of baking oven, obtain the oversheath coated with polyethylene glycol polyelectrolyte;
B, electroplate:In the surface of outer sheath electroplated zinc nickel alloy coating coated with polyethylene glycol polyelectrolyte, admiro Thickness of coating is 70 ± 30 μm, and the cable of working stability is made.
The present invention is not limited to above-described embodiment.All technical schemes formed using equivalent substitution, all falling within the present invention will The protection domain asked.

Claims (3)

  1. A kind of 1. preparation method of the cable of working stability, it is characterised in that:Comprise the following steps:
    (i) dispensing:The mass percent of each composition is in raw material:C:0.05-0.15%、Fe:1.25-1.56% 、Mn:0.42- 0.73%、S:≤0.020%、P:≤0.030%、Cr:0.13-0.26%、Ni:1.35-1.63%、Zn:1.75-1.96%、Cu: 7.95-8.46%、Mo:0.03-0.06%、Ti:1.47-1.69%、Pd:0.02-0.05%、Pt:0.21-0.33%、Au:0.41- 0.62%、W:0.05-0.15%、Nd:0.03-0.06%、Ce:0.03-0.07%、Eu:0.01-0.04%、Lu:0.02-0.03%, Surplus is Ag;
    (ii) melting:The cable raw material of working stability is heated into melting, it is specific as follows:
    A, added raw materials into by the mass percent of each composition in the cable of predetermined working stability in smelting furnace, by the temperature in smelting furnace Degree brings up to 1650 degrees Celsius to 1680 degrees Celsius, and raw material is smelted to form alloy solution;
    B, alloy solution obtained in the previous step is cooled down, uses water cooling with 26-28 DEG C/s cooldown rate by alloy solution Water cooling is to room temperature;
    C, the alloy after previous step is cooled down carries out secondary smelting in smelting furnace, and the temperature in smelting furnace is brought up into 1500 degrees Celsius To 1550 degrees Celsius, alloy forms alloy solution by secondary smelting;
    (iii) alloy solution is subjected to continuous casting and rolling;
    (iv) wire drawing:By the blank wire drawing after continuous casting and rolling;
    (v) forge:The blank after wire drawing is forged into refining using the mode forged;
    Blank is heated to 750-800 DEG C first, forged 25 minutes;
    Then use water cooling with 16-19 DEG C/s cooling rate by blank water cooling to room temperature;
    Blank is heated to 650-680 DEG C again, forged 25 minutes;
    Use again water cooling with 11-15 DEG C/s cooling rate by blank water cooling to 350-370 DEG C, be then air-cooled to room temperature;
    (vi) quench:Raw material after wire drawing is put into glowing furnace to be quenched, hardening media is vacuum quenching oil, controls hardening heat Taken out for 600-650 DEG C, after quenching and be air-cooled to room temperature;
    (vii) blank is made by twisting core, core outer wrapping insulating barrier, insulating barrier outer surface electroplated zinc nickel alloy coating, by two Root core is twisted to be made as conductor, will an at least conductor as cable core;
    (viii) screen layer and oversheath will be wrapped up outside cable core successively, equal preset clearance between cable core, screen layer and oversheath, shielding Layer is wrapped with zinc-coated wire armor;Described oversheath is the corrosion-resistant mud polyolefin sheath layer of fire-retardant Halogen;
    (ix) vacuumize:The gap reserved between cable core, screen layer and oversheath is vacuumized;
    (x) coating is coated, is specially:
    A, the uniform dip-coating of the polyethylene glycol polyelectrolyte aqueous solution is dipped in surface of outer sheath with glass bar, be placed in 80-90 DEG C afterwards Baking oven in 0.5-1 hours, obtain the oversheath coated with polyethylene glycol polyelectrolyte;
    B, electroplate:In the surface of outer sheath electroplated zinc nickel alloy coating coated with polyethylene glycol polyelectrolyte, zn-ni alloy depositses Thickness is 70 ± 30 μm, and the cable of working stability is made.
  2. 2. the preparation method of the cable of working stability as claimed in claim 1, it is characterised in that:(i) middle work is steady for the step The mass percent of each composition is in fixed cable raw material:C:0.05%、Fe:1.25% 、Mn:0.42%、S:≤0.020%、P:≤ 0.030%、Cr:0.13%、Ni:1.35%、Zn:1.75%、Cu:7.95%、Mo:0.03%、Ti:1.47%、Pd:0.02%、Pt: 0.21%、Au:0.41%、W:0.05%、Nd:0.03%、Ce:0.03%、Eu:0.01%、Lu:0.02%, surplus Ag.
  3. 3. the preparation method of the cable of working stability as claimed in claim 1, it is characterised in that:(i) middle work is steady for the step The mass percent of each composition is in fixed cable raw material:C:0.15%、Fe:1.56% 、Mn:0.73%、S:≤0.020%、P:≤ 0.030%、Cr:0.26%、Ni:1.63%、Zn:1.96%、Cu:8.46%、Mo:0.06%、Ti:1.69%、Pd:0.05%、Pt: 0.33%、Au:0.62%、W:0.15%、Nd:0.06%、Ce:0.07%、Eu:0.04%、Lu:0.03%, surplus Ag.
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CN106531342B (en) * 2016-12-15 2018-11-16 苏州卫优知识产权运营有限公司 A kind of preparation method of high-strength alloy cable
CN108053944A (en) * 2017-12-13 2018-05-18 苏州浩焱精密模具有限公司 A kind of processing technology of corrosion proof cable
CN109065264A (en) * 2018-08-06 2018-12-21 镇江市南方工矿器材有限公司 A kind of processing technology of cutoff instrument anti-explosion cable
CN109979677A (en) * 2019-03-25 2019-07-05 扬州亚光电缆有限公司 The preparation method of modified polyether ether ketone composite material cable

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JP4143086B2 (en) * 2005-12-20 2008-09-03 日立電線株式会社 Extra-fine copper alloy wire, extra-fine copper alloy twisted wire, and manufacturing method thereof
CN102013283A (en) * 2010-12-04 2011-04-13 江苏南瑞淮胜电缆有限公司 Super heat-resistant and high-strength aluminium alloy cable steel reinforced (AACSR) and preparing method thereof
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