CN106498432A - A kind of Hydrogen Energy air mixture production equipment and method - Google Patents
A kind of Hydrogen Energy air mixture production equipment and method Download PDFInfo
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- CN106498432A CN106498432A CN201710010309.2A CN201710010309A CN106498432A CN 106498432 A CN106498432 A CN 106498432A CN 201710010309 A CN201710010309 A CN 201710010309A CN 106498432 A CN106498432 A CN 106498432A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/14—Injection, e.g. in a reactor or a fuel stream during fuel production
- C10L2290/141—Injection, e.g. in a reactor or a fuel stream during fuel production of additive or catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Abstract
The invention discloses a kind of Hydrogen Energy air mixture production equipment and method, its structure includes electrolytic cell, one-level gas-liquid separation device, catalyst catalytic mixing device, two grades of gas-liquid separation devices and gas surge tank, the water inlet of one-level gas-liquid separation device is connected with water level regulation water tank by pipeline, the air inlet of one-level gas-liquid separation device is connected with heat exchanger by pipeline, and the air inlet of heat exchanger is connected with electrolytic cell by pipeline；The outlet of described one-level gas-liquid separation device is connected with catalyst catalytic mixing device by pipeline, the top exit of catalyst catalytic mixing device is connected with two grades of gas-liquid separation devices by pipeline, the top gas outlet of two grades of gas-liquid separation devices is connected with gas buffer tank by pipeline, and the gas outlet of gas buffer tank connects industrial combustion gas boiler by gas pipeline.Present invention reduces the consumption of electric energy, improve the heat in whole gas-making process and pass and change efficiency, the Hydrogen Energy mixed gas of generation are produced and used, it is to avoid the danger of gas memory leak.
Description
Technical field
The present invention relates to new forms of energy field of combustion technology, specifically a kind of Hydrogen Energy air mixture production equipment and side
Method.
Background technology
With the development of national economy, national year fuel consumption is more than 4.5 hundred million tons.Huge fuel consumption is not only to increasingly
Exhausted petroleum-based energy is exerted heavy pressures on, improper given off floating charcoal, hydrocarbon while great amount of fuel oil is burnt（HC）、
Carbon monoxide (CO), nitrogen oxides (NOX), sulfur dioxide（SO2）Originate etc. big and medium-sized cities major pollutants are become.In recent years,
Due to fossil-fuel-fired produced haze, contaminated air greatly destroys the ecological environment of the earth, has a strong impact on people's
Raw body health.Because there is an urgent demand of both energy-conservation and environmental protection, various improvement are all being studied by major country in the world
The technology of fuel combustion quality, most study is by adding various chemical raw materials in fuel, is carried out by main equipment
Fuel（Hydrogenation etc.）Reform, reach the purpose for lifting fuel quality, improving efficiency of combustion, reduce exhaust emissions.Hydrogen Energy is new generation
Record the regenerative resource of most environmental protection, but preparation, storage due to Hydrogen Energy, transport and the aspect such as safety applications also has many nothings
The problem that method is solved, it is difficult to be widely applied in civilian industry, while the oxyhydrogen generator of prior art includes electrolytic cell, setting
In gas outlet and the positive and negative electrode for being arranged on electrolyte bath of electrolytic cell upper end, but the caloric value due to positive and negative conductive electrode
Greatly, when hydrogen and oxygen is produced gas temperature is high, and atom is more enlivened, and stability is poor, the easy heap of bubble on electrode pad
Accumulate and prevent electric current from passing through, now, hydrogen atom is easily recombined with oxygen atom, form hydrone, cause to be electrolysed hydrogen and oxygen
The efficiency of gas reduces, and energy consumption is of a relatively high.
Content of the invention
The technical assignment of the present invention is to provide a kind of Hydrogen Energy air mixture production equipment and method for reducing power consumption.
The present invention technical assignment realize in the following manner, the Hydrogen Energy air mixture production equipment include electrolytic cell,
Heat exchanger, one-level gas-liquid separation device, catalyst catalytic mixing device, two grades of gas-liquid separation devices and gas surge tank, described
The water inlet of one-level gas-liquid separation device connected with water level regulation water tank by pipeline, the air inlet of one-level gas-liquid separation device
Connected with heat exchanger by pipeline, the air inlet of heat exchanger is exported with the hydrogen and oxygen gas mixture of electrolytic cell by pipeline and connected
Logical；The outlet of described one-level gas-liquid separation device is connected with catalyst catalytic mixing device by pipeline, and catalyst catalytic mixing is filled
The top exit that puts is connected with two grades of gas-liquid separation devices by pipeline, and the top gas outlet of two grades of gas-liquid separation devices is by pipe
Road is connected with gas buffer tank, and the gas outlet of gas buffer tank connects industrial combustion gas boiler by gas pipeline；
The water inlet of described heat exchanger is connected with cooling water tank by pipeline, and the cooling water inlet of cooling water tank passes through pipeline
Connect with the coolant outlet of heat exchanger.
The air inlet of described one-level gas-liquid separation device is connected with least one heat exchanger by pipeline；When there is two
Or during plural heat exchanger, coolant outlet and cooling water inlet between two or more heat exchangers lead to
Piping is connected, and the air inlet of each heat exchanger is connected with an electrolytic cell by pipeline.
Water level regulation controller and water level regulation pump are installed on the inlet channel of described water level regulation water tank；
Electrolyte circulating pump is installed on the pipeline that described heat exchanger is connected with electrolytic cell；
Cooling water circulating pump is installed on the pipeline that described heat exchanger is connected with cooling water tank；
The bottom liquid outlet of two grades of described gas-liquid separation devices is connected with catalyst catalytic mixing device by reflux line, described
Reflux line on connection valve is installed；The bottom of described catalyst catalytic mixing device is provided with catalyst and adds mouth；
Spark arrester is installed on the gas pipeline of described gas buffer tank connection.
Described electrolytic cell includes negative electrode end plate, positive electrode end plate, electrolytic zinc-coated steel sheet and insulative pin, and described negative electricity is extreme
Plate is connected with negative electrode, and positive electrode end plate is connected with positive electrode；It is connected between described negative electrode end plate and positive electrode end plate
The many insulative pins being parallel to each other, are uniformly configured with multiple electrolytic zinc-coated steel sheets in insulative pin；Configure on described positive electrode end plate
There is electrolyte inlet, on negative electrode end plate, be configured with electrolyte outlet.
The two ends of described insulative pin are linked together with negative electrode end plate, positive electrode end plate respectively by nut.
Described electrolytic zinc-coated steel sheet is circle, is uniformly provided with insulative pin hole corresponding with insulative pin quantity, absolutely on electrolytic zinc-coated steel sheet
Edge latch runs through insulative pin hole, is provided with an electrolyte flow hole on the circumference that two neighboring insulative pin hole is located；Adjacent
Felt pad is configured between two electrolytic zinc-coated steel sheets.
Described catalyst catalytic mixing device includes housing, is configured with gas outlet, the bottom configuration of housing at the top of housing
There is at least one catalyst to add mouth, in the lower housing portion inner chamber above catalyst interpolation mouth, be configured with taper aeration board, described exposure
Multiple solarization air caps are uniformly provided with gas plate.
Hydrogen Energy air mixture production method step is as follows：
Injecting the electrolyte in electrolytic cell and being electrolysed, electrolysate enters heat exchanger, 15-40 is cooled to through over-heat-exchanger
DEG C, aqueous vapor separation is carried out subsequently into one-level gas-liquid separation device, the mixed gas after aqueous vapor is separated pass through connecting pipe
The catalyst catalytic mixing device for being previously added liquid catalyst is entered, while gas catalyst is passed through to catalyst catalytic mixing device,
After catalyst catalytic mixing, mixed gas enter two grades of gas-liquid separation devices by pipeline and carry out gas-liquid separation, after gas-liquid separation
Mixed gas are transported to industrial combustion gas boiler combustion by spark arrester and gas pipeline；
KOH solution of the described electrolyte for mass percent concentration 25%, described electrolysate are gas-liquid mixture, i.e. hydrogen
The mixture of gas, oxygen, hydrogen ion, hydroxyl ion and electrolyte.
Ethanol solution of the described liquid catalyst for 92# gasoline, 95# gasoline or mass percent concentration more than 95%；Institute
The gas catalyst that states is coal gas or natural gas.
Multiple electrolytic zinc-coated steel sheets are configured with described electrolytic cell, are configured with felt pad, on electrolytic zinc-coated steel sheet between adjacent electrolytic zinc-coated steel sheet
Bubble and electrolyte mix, electrolytic cell is quickly taken out of by electrolyte circulating pump, after heat exchanger enter one
Level gas-liquid separation device is separated, and the time that bubble adsorbs on electrolytic zinc-coated steel sheet shortens, will not pile up between bubble；Electrolyte exists
Quickly flowed by electrolyte circulating pump between electrolytic cell, heat exchanger and one-level gas-liquid separation device, accelerate the electrolysis of water, with
When quick separating go out the mixed gas containing hydroxyl ion；
The liquid that two grades of described gas-liquid separation devices are stayed after carrying out gas-liquid separation, mixed by connecting valve inflow catalyst catalysis
Attach together and put recycling.
Compared to the prior art a kind of Hydrogen Energy air mixture production equipment and method of the present invention, greatly reduce electric energy
Consume, the heat biography that improve in whole gas-making process changes efficiency, and the mixed gas that produces are after knockout drum is separated
Catalyst catalytic mixing is entered, after the gas after catalytic mixing out enters two grades of gas-liquid separations, becomes comparatively safe incendivity
Gas, can be directly as the main fuel of the burning of Industrial Boiler.And the Hydrogen Energy mixed gas for producing need not be stored,
Produce and use, it is to avoid the danger that gas memory leak brings, whole system operate in low temperature（15-40℃）, low pressure（0.03--
0.09Mpa) under state, safety easy to control, simple to operate；The flame envelope temperature of the mixed gas burning produced with the apparatus and method
Degree is up to more than 1200 DEG C（Only 800 DEG C -900 DEG C of high-quality natural gas）, and only often make the consumed electric energy of 1 side's mixed gas
2.3 degree of electricity, greatly reduce energy resource consumption.
Description of the drawings
Structural representation of the accompanying drawing 1 for Hydrogen Energy air mixture production equipment.
Structural representation of the accompanying drawing 2 for electrolytic cell.
Structural representation of the accompanying drawing 3 for electrolytic zinc-coated steel sheet.
Structural representation of the accompanying drawing 4 for catalyst catalytic mixing device.
In figure：101st, electrolytic cell, 102, cooling water circulating pump, 103, heat exchanger, 104, cooling water inlet, 105, cooling
Water tank, 106, water level regulation controller, 107, water level regulation pump, 108, water level regulation water tank, 109, one-level gas-liquid separation device,
110th, catalyst catalytic mixing device, 111, two grades of gas-liquid separation devices, 112, gas buffer tank, 113, spark arrester, 114, connection
Valve, 115, positive electrode, 116, negative electrode, 117, hydrogen and oxygen gas mixture outlet, 118, catalyst add mouth, 119, cooling water goes out
Mouthful, 120, electrolyte circulating pump, 201, negative electrode end plate, 202, positive electrode end plate, 203, electrolytic zinc-coated steel sheet, 204, felt pad, 205,
Electrolyte inlet, 206, electrolyte outlet, 207, insulative pin, 208, nut, 301, electrolyte flow hole, 302, insulative pin
Hole, 401, aeration board, 402, solarization air cap, 403, gas outlet, 404, housing.
Specific embodiment
Embodiment 1：
Hydrogen Energy air mixture production equipment is assembled：
The Hydrogen Energy air mixture production equipment includes electrolytic cell 101, heat exchanger 103, one-level gas-liquid separation device 109, catalyst
110, two grades of gas-liquid separation devices 111 of catalytic mixing device and gas surge tank 112, described one-level gas-liquid separation device 109
Water inlet connected with water level regulation water tank 108 by pipeline, be provided with the inlet channel of water level regulation water tank 108 water level tune
Section controller 106 and water level regulation pump 107；The air inlet of one-level gas-liquid separation device 109 is by pipeline and a heat exchanger
103 connections, the air inlet of heat exchanger 103 are connected with the hydrogen and oxygen gas mixture outlet 117 of an electrolytic cell 101 by pipeline,
Electrolyte circulating pump 120 is installed on the pipeline that heat exchanger 103 is connected with electrolytic cell 101；The water inlet of heat exchanger 103 leads to
Piping is connected with cooling water tank 105, is provided with cooling water circulation on the pipeline that heat exchanger 103 is connected with cooling water tank 105
Pump 102；The cooling water inlet 104 of cooling water tank 105 is connected with the coolant outlet 119 of heat exchanger 103 by pipeline；Described
The outlet of one-level gas-liquid separation device 109 connected with catalyst catalytic mixing device 110 by pipeline, catalyst catalytic mixing device
110 include that housing 404, the top of housing 404 are configured with gas outlet 403, and the bottom of housing 404 is provided with a catalyst and adds mouth
118；Taper aeration board 401 is configured with 404 lower lumen of housing above catalyst interpolation mouth 118, on described aeration board 401
Multiple solarization air caps 402 are uniformly provided with.The top exit of catalyst catalytic mixing device 110 is by pipeline and two grades of gas-liquid separation devices
111 connections, the bottom liquid outlet of two grades of gas-liquid separation devices 111 are connected with catalyst catalytic mixing device 110 by reflux line,
Connection valve 114 is installed on described reflux line；The top gas outlet of two grades of gas-liquid separation devices 111 is by pipeline and gas
Body surge tank 112 is connected, and the gas outlet of gas buffer tank 112 connects industrial combustion gas boiler by gas pipeline；Gas buffer tank
Spark arrester 113 is installed on the gas pipeline of 112 connections.
Described electrolytic cell 101 includes negative electrode end plate 201, positive electrode end plate 202, electrolytic zinc-coated steel sheet 203 and insulative pin
207, described negative electrode end plate 201 is connected with negative electrode 116, and positive electrode end plate 202 is connected with positive electrode 115；Described is negative
The many insulative pins 207 being parallel to each other are connected between electrode end plate 201 and positive electrode end plate 202, in insulative pin 207
Even be configured with multiple electrolytic zinc-coated steel sheets 203, be configured with felt pad 204 between two neighboring electrolytic zinc-coated steel sheet 203；Described positive electrode end plate
Electrolyte inlet 205 is configured with 202, is configured with electrolyte outlet 206 on negative electrode end plate 201；Described insulative pin 207
Two ends linked together with negative electrode end plate 201, positive electrode end plate 202 by nut 208 respectively；Described electrolytic zinc-coated steel sheet 203
For circle, insulative pin hole 302 corresponding with 207 quantity of insulative pin on electrolytic zinc-coated steel sheet 203, is uniformly provided with, insulative pin 207 is passed through
Insulative pin hole 302 is worn, on the circumference that two neighboring insulative pin hole 302 is located, an electrolyte flow hole 301 is provided with.
Hydrogen Energy air mixture production method step is as follows：
By electrolyte（The KOH solution of mass percent concentration 25%）It is electrolysed in injection electrolytic cell 101, electrolysate is entered
Heat exchanger 103, is cooled to 15 DEG C through over-heat-exchanger 103, carries out aqueous vapor point subsequently into one-level gas-liquid separation device 109
From the mixed gas after aqueous vapor is separated enter the catalyst catalytic mixing device for being previously added 92# gasoline by connecting pipe
110, while being passed through coal gas to catalyst catalytic mixing device 110（It is passed through hydrogen ion of the amount of coal gas by electrolysis production out
Determine with the amount of hydroxyl ion, the normal condition consumption of gas is percent by volume 3-5%）, after catalyst catalytic mixing, knot
Symphysis is into C6H18O2And CH3-OH-CH2-CH2Admixture of gas, mixed gas enter two grades of gas-liquid separation devices 111 by pipeline
Gas-liquid separation is carried out, the mixed gas after gas-liquid separation are transported to the combustion of industrial combustion gas boiler by spark arrester 113 and gas pipeline
Burn；
Described electrolysate is the mixed of gas-liquid mixture, i.e. hydrogen, oxygen, hydrogen ion, hydroxyl ion and electrolyte
Compound.
Multiple electrolytic zinc-coated steel sheets 203 are configured with described electrolytic cell 101, are configured with felt pad between adjacent electrolytic zinc-coated steel sheet 203
204, the bubble and electrolyte on electrolytic zinc-coated steel sheet 203 is mixed, and quickly takes electrolytic cell 101 out of by electrolyte circulating pump 120,
Separated by entering one-level gas-liquid separation device 109 after heat exchanger 103, the time that bubble adsorbs on electrolytic zinc-coated steel sheet 203 shortens,
Will not pile up between bubble；Electrolyte leads between electrolytic cell 101, heat exchanger 103 and one-level gas-liquid separation device 109
120 quick flowing of electrolyte circulating pump is crossed, accelerates the electrolysis of water, while quick separating goes out the mixed gas containing hydroxyl ion；
The liquid that described two grades of gas-liquid separation devices 111 are stayed after carrying out gas-liquid separation, flows into catalyst by connecting valve 114
Catalytic mixing device 110 is recycled.
Embodiment 2：
Hydrogen Energy air mixture production equipment is assembled：
The Hydrogen Energy air mixture production equipment includes electrolytic cell 101, heat exchanger 103, one-level gas-liquid separation device 109, catalyst
110, two grades of gas-liquid separation devices 111 of catalytic mixing device and gas surge tank 112, described one-level gas-liquid separation device 109
Water inlet connected with water level regulation water tank 108 by pipeline, be provided with the inlet channel of water level regulation water tank 108 water level tune
Section controller 106 and water level regulation pump 107；The air inlet of one-level gas-liquid separation device 109 is by pipeline and two heat exchangers
103 connections, the coolant outlet and cooling water inlet between two heat exchangers 103 is by pipeline communication, each heat exchanger
103 air inlet connect by the hydrogen and oxygen gas mixture outlet 117 of pipeline and an electrolytic cell 101, heat exchanger 103 and is electrolysed
Electrolyte circulating pump 120 is installed on the pipeline of the connection of groove 101；The water inlet of heat exchanger 103 is by pipeline and cooling water tank
105 connections, are provided with cooling water circulating pump 102 with cooling water tank 105 on the pipeline that heat exchanger 103 is connected；Cooling water tank 105
Cooling water inlet 104 connected with the coolant outlet 119 of heat exchanger 103 by pipeline；Described one-level gas-liquid separation dress
Put 109 outlet to connect with catalyst catalytic mixing device 110 by pipeline, catalyst catalytic mixing device 110 includes housing 404,
The top of housing 404 is configured with gas outlet 403, and the bottom of housing 404 is provided with two catalyst and adds mouth 118；Catalyst adds mouth
Taper aeration board 401 is configured with 404 lower lumen of housing above in the of 118, is uniformly provided with multiple exposures on described aeration board 401
Pore 402.The top exit of catalyst catalytic mixing device 110 is connected with two grades of gas-liquid separation devices 111 by pipeline, two grades of gas
The bottom liquid outlet of liquid separating apparatus 111 is connected with catalyst catalytic mixing device 110 by reflux line, described reflux line
On be provided with connection valve 114；The top gas outlet of two grades of gas-liquid separation devices 111 is connected with gas buffer tank 112 by pipeline
Logical, the gas outlet of gas buffer tank 112 connects industrial combustion gas boiler by gas pipeline；The combustion gas of the connection of gas buffer tank 112
Spark arrester 113 is installed on pipeline.
Described electrolytic cell 101 includes negative electrode end plate 201, positive electrode end plate 202, electrolytic zinc-coated steel sheet 203 and insulative pin
207, described negative electrode end plate 201 is connected with negative electrode 116, and positive electrode end plate 202 is connected with positive electrode 115；Described is negative
The many insulative pins 207 being parallel to each other are connected between electrode end plate 201 and positive electrode end plate 202, in insulative pin 207
Even be configured with multiple electrolytic zinc-coated steel sheets 203, be configured with felt pad 204 between two neighboring electrolytic zinc-coated steel sheet 203；Described positive electrode end plate
Electrolyte inlet 205 is configured with 202, is configured with electrolyte outlet 206 on negative electrode end plate 201；Described insulative pin 207
Two ends linked together with negative electrode end plate 201, positive electrode end plate 202 by nut 208 respectively；Described electrolytic zinc-coated steel sheet 203
For circle, insulative pin hole 302 corresponding with 207 quantity of insulative pin on electrolytic zinc-coated steel sheet 203, is uniformly provided with, insulative pin 207 is passed through
Insulative pin hole 302 is worn, on the circumference that two neighboring insulative pin hole 302 is located, an electrolyte flow hole 301 is provided with.
Hydrogen Energy air mixture production method step is as follows：
By electrolyte（The KOH solution of mass percent concentration 25%）It is electrolysed in injection electrolytic cell 101, electrolysate is entered
Heat exchanger 103, is cooled to 28 DEG C through over-heat-exchanger 103, carries out aqueous vapor point subsequently into one-level gas-liquid separation device 109
From the mixed gas after aqueous vapor is separated enter the catalyst catalytic mixing device for being previously added 95# gasoline by connecting pipe
110, while being passed through coal gas to catalyst catalytic mixing device 110（It is passed through hydrogen ion of the amount of coal gas by electrolysis production out
Determine with the amount of hydroxyl ion, the normal condition consumption of gas is percent by volume 3-5%）, after catalyst catalytic mixing, mix
Closing gas carries out gas-liquid separation by pipeline two grades of gas-liquid separation devices 111 of entrance, and the mixed gas after gas-liquid separation are by resistance
Firearm 113 and gas pipeline are transported to industrial combustion gas boiler combustion；
Described electrolysate is the mixed of gas-liquid mixture, i.e. hydrogen, oxygen, hydrogen ion, hydroxyl ion and electrolyte
Compound.
Multiple electrolytic zinc-coated steel sheets 203 are configured with described electrolytic cell 101, are configured with felt pad between adjacent electrolytic zinc-coated steel sheet 203
204, the bubble and electrolyte on electrolytic zinc-coated steel sheet 203 is mixed, and quickly takes electrolytic cell 101 out of by electrolyte circulating pump 120,
Separated by entering one-level gas-liquid separation device 109 after heat exchanger 103, the time that bubble adsorbs on electrolytic zinc-coated steel sheet 203 shortens,
Will not pile up between bubble；Electrolyte leads between electrolytic cell 101, heat exchanger 103 and one-level gas-liquid separation device 109
120 quick flowing of electrolyte circulating pump is crossed, accelerates the electrolysis of water, while quick separating goes out the mixed gas containing hydroxyl ion；
The liquid that described two grades of gas-liquid separation devices 111 are stayed after carrying out gas-liquid separation, flows into catalyst by connecting valve 114
Catalytic mixing device 110 is recycled.
Embodiment 3：
Hydrogen Energy air mixture production equipment is assembled：
The Hydrogen Energy air mixture production equipment includes electrolytic cell 101, heat exchanger 103, one-level gas-liquid separation device 109, catalyst
110, two grades of gas-liquid separation devices 111 of catalytic mixing device and gas surge tank 112, described one-level gas-liquid separation device 109
Water inlet connected with water level regulation water tank 108 by pipeline, be provided with the inlet channel of water level regulation water tank 108 water level tune
Section controller 106 and water level regulation pump 107；The air inlet of one-level gas-liquid separation device 109 is by pipeline and three heat exchangers
103 connections, the coolant outlet and cooling water inlet between three heat exchangers 103 is by pipeline communication, each heat exchanger
103 air inlet connect by the hydrogen and oxygen gas mixture outlet 117 of pipeline and an electrolytic cell 101, heat exchanger 103 and is electrolysed
Electrolyte circulating pump 120 is installed on the pipeline of the connection of groove 101；The water inlet of heat exchanger 103 is by pipeline and cooling water tank
105 connections, are provided with cooling water circulating pump 102 with cooling water tank 105 on the pipeline that heat exchanger 103 is connected；Cooling water tank 105
Cooling water inlet 104 connected with the coolant outlet 119 of heat exchanger 103 by pipeline；Described one-level gas-liquid separation dress
Put 109 outlet to connect with catalyst catalytic mixing device 110 by pipeline, catalyst catalytic mixing device 110 includes housing 404,
The top of housing 404 is configured with gas outlet 403, and the bottom of housing 404 is provided with three catalyst and adds mouth 118；Catalyst adds mouth
Taper aeration board 401 is configured with 404 lower lumen of housing above in the of 118, is uniformly provided with multiple exposures on described aeration board 401
Pore 402.The top exit of catalyst catalytic mixing device 110 is connected with two grades of gas-liquid separation devices 111 by pipeline, two grades of gas
The bottom liquid outlet of liquid separating apparatus 111 is connected with catalyst catalytic mixing device 110 by reflux line, described reflux line
On be provided with connection valve 114；The top gas outlet of two grades of gas-liquid separation devices 111 is connected with gas buffer tank 112 by pipeline
Logical, the gas outlet of gas buffer tank 112 connects industrial combustion gas boiler by gas pipeline；The combustion gas of the connection of gas buffer tank 112
Spark arrester 113 is installed on pipeline.
Described electrolytic cell 101 includes negative electrode end plate 201, positive electrode end plate 202, electrolytic zinc-coated steel sheet 203 and insulative pin
207, described negative electrode end plate 201 is connected with negative electrode 116, and positive electrode end plate 202 is connected with positive electrode 115；Described is negative
The many insulative pins 207 being parallel to each other are connected between electrode end plate 201 and positive electrode end plate 202, in insulative pin 207
Even be configured with multiple electrolytic zinc-coated steel sheets 203, be configured with felt pad 204 between two neighboring electrolytic zinc-coated steel sheet 203；Described positive electrode end plate
Electrolyte inlet 205 is configured with 202, is configured with electrolyte outlet 206 on negative electrode end plate 201；Described insulative pin 207
Two ends linked together with negative electrode end plate 201, positive electrode end plate 202 by nut 208 respectively；Described electrolytic zinc-coated steel sheet 203
For circle, insulative pin hole 302 corresponding with 207 quantity of insulative pin on electrolytic zinc-coated steel sheet 203, is uniformly provided with, insulative pin 207 is passed through
Insulative pin hole 302 is worn, on the circumference that two neighboring insulative pin hole 302 is located, an electrolyte flow hole 301 is provided with.
Hydrogen Energy air mixture production method step is as follows：
By electrolyte（The KOH solution of mass percent concentration 25%）It is electrolysed in injection electrolytic cell 101, electrolysate is entered
Heat exchanger 103, is cooled to 40 DEG C through over-heat-exchanger 103, carries out aqueous vapor point subsequently into one-level gas-liquid separation device 109
From the ethanol that the mixed gas after aqueous vapor is separated are previously added mass percent concentration 97% by connecting pipe entrance is molten
The catalyst catalytic mixing device 110 of liquid, while be passed through natural gas to catalyst catalytic mixing device 110（Be passed through the amount of natural gas by
The amount of electrolysis production hydrogen ion out and hydroxyl ion determines that the normal condition consumption of gas is percent by volume 3-
5%）, after catalyst catalytic mixing, mixed gas enter two grades of gas-liquid separation devices 111 by pipeline and carry out gas-liquid separation, gas-liquid
Mixed gas after separating are transported to industrial combustion gas boiler combustion by spark arrester 113 and gas pipeline；
Described electrolysate is the mixed of gas-liquid mixture, i.e. hydrogen, oxygen, hydrogen ion, hydroxyl ion and electrolyte
Compound.
Multiple electrolytic zinc-coated steel sheets 203 are configured with described electrolytic cell 101, are configured with felt pad between adjacent electrolytic zinc-coated steel sheet 203
204, the bubble and electrolyte on electrolytic zinc-coated steel sheet 203 is mixed, and quickly takes electrolytic cell 101 out of by electrolyte circulating pump 120,
Separated by entering one-level gas-liquid separation device 109 after heat exchanger 103, the time that bubble adsorbs on electrolytic zinc-coated steel sheet 203 shortens,
Will not pile up between bubble；Electrolyte leads between electrolytic cell 101, heat exchanger 103 and one-level gas-liquid separation device 109
120 quick flowing of electrolyte circulating pump is crossed, accelerates the electrolysis of water, while quick separating goes out the mixed gas containing hydroxyl ion；
The liquid that described two grades of gas-liquid separation devices 111 are stayed after carrying out gas-liquid separation, flows into catalyst by connecting valve 114
Catalytic mixing device 110 is recycled.
By specific embodiment above, the those skilled in the art can readily realize the present invention.But should
Work as understanding, the present invention is not limited to above-mentioned several specific embodiments.On the basis of disclosed embodiment, the technology
The technical staff in field can be combined different technical characteristics, so as to realize different technical schemes.
Claims (10)
1. a kind of Hydrogen Energy air mixture production equipment, is catalyzed including electrolytic cell, heat exchanger, one-level gas-liquid separation device, catalyst
Mixing arrangement, two grades of gas-liquid separation devices and gas surge tank, it is characterised in that the water inlet of described one-level gas-liquid separation device
Mouth is connected with water level regulation water tank by pipeline, and the air inlet of one-level gas-liquid separation device is connected with heat exchanger by pipeline,
The air inlet of heat exchanger is by pipeline and the hydrogen and oxygen gas mixture outlet of electrolytic cell；Described one-level gas-liquid separation device
Outlet connected with catalyst catalytic mixing device by pipeline, the top exit of catalyst catalytic mixing device is by pipeline and two grades
Gas-liquid separation device is connected, and the top gas outlet of two grades of gas-liquid separation devices is connected with gas buffer tank by pipeline, and gas delays
The gas outlet for rushing tank connects industrial combustion gas boiler by gas pipeline；
The water inlet of described heat exchanger is connected with cooling water tank by pipeline, and the cooling water inlet of cooling water tank passes through pipeline
Connect with the coolant outlet of heat exchanger.
2. a kind of Hydrogen Energy air mixture production equipment according to claim 1, it is characterised in that described one-level gas-liquid point
Air inlet from device is connected with least one heat exchanger by pipeline；When there is two or more heat exchangers,
Coolant outlet and cooling water inlet between two or more heat exchangers is by pipeline communication, each heat exchanger
Air inlet connected with an electrolytic cell by pipeline.
3. a kind of Hydrogen Energy air mixture production equipment according to claim 1, it is characterised in that described water level regulation water
Water level regulation controller and water level regulation pump are installed on the inlet channel of case；
Electrolyte circulating pump is installed on the pipeline that described heat exchanger is connected with electrolytic cell；
Cooling water circulating pump is installed on the pipeline that described heat exchanger is connected with cooling water tank；
The bottom liquid outlet of two grades of described gas-liquid separation devices is connected with catalyst catalytic mixing device by reflux line, described
Reflux line on connection valve is installed；The bottom of described catalyst catalytic mixing device is provided with catalyst and adds mouth；
Spark arrester is installed on the gas pipeline of described gas buffer tank connection.
4. a kind of Hydrogen Energy air mixture production equipment according to claim 1,2 or 3, it is characterised in that described electrolysis
Groove includes that negative electrode end plate, positive electrode end plate, electrolytic zinc-coated steel sheet and insulative pin, described negative electrode end plate are connected with negative electrode, just
Electrode end plate is connected with positive electrode；The many insulation being parallel to each other are connected between described negative electrode end plate and positive electrode end plate
Latch, is uniformly configured with multiple electrolytic zinc-coated steel sheets in insulative pin；Electrolyte inlet, negative electrode are configured with described positive electrode end plate
Electrolyte outlet is configured with end plate.
5. a kind of Hydrogen Energy air mixture production equipment according to claim 4, it is characterised in that described insulative pin
Two ends are linked together with negative electrode end plate, positive electrode end plate respectively by nut.
6. a kind of Hydrogen Energy air mixture production equipment according to claim 4, it is characterised in that described electrolytic zinc-coated steel sheet is circle
Shape, is uniformly provided with insulative pin hole corresponding with insulative pin quantity on electrolytic zinc-coated steel sheet, insulative pin runs through insulative pin hole, adjacent
An electrolyte flow hole is provided with the circumference at two insulative pin holes place；Insulation is configured between two neighboring electrolytic zinc-coated steel sheet
Pad.
7. a kind of Hydrogen Energy air mixture production equipment according to claim 1 or 3, it is characterised in that described catalyst is urged
Changing mixing arrangement includes housing, is configured with gas outlet at the top of housing, and the bottom of housing is configured with least one catalyst and adds mouth,
Taper aeration board is configured with lower housing portion inner chamber above catalyst interpolation mouth, multiple aerations on described aeration board, are uniformly provided with
Hole.
8. a kind of Hydrogen Energy air mixture production method, it is characterised in that the method step is as follows：
Injecting the electrolyte in electrolytic cell and being electrolysed, electrolysate enters heat exchanger, 15-40 is cooled to through over-heat-exchanger
DEG C, aqueous vapor separation is carried out subsequently into one-level gas-liquid separation device, the mixed gas after aqueous vapor is separated pass through connecting pipe
The catalyst catalytic mixing device for being previously added liquid catalyst is entered, while gas catalyst is passed through to catalyst catalytic mixing device,
After catalyst catalytic mixing, mixed gas enter two grades of gas-liquid separation devices by pipeline and carry out gas-liquid separation, after gas-liquid separation
Mixed gas are transported to industrial combustion gas boiler combustion by spark arrester and gas pipeline；
KOH solution of the described electrolyte for mass percent concentration 25%, described electrolysate are gas-liquid mixture, i.e. hydrogen
The mixture of gas, oxygen, hydrogen ion, hydroxyl ion and electrolyte.
9. a kind of Hydrogen Energy air mixture production method according to claim 8, it is characterised in that described liquid catalyst is
The ethanol solution of 92# gasoline, 95# gasoline or mass percent concentration more than 95%；Described gas catalyst is coal gas or natural
Gas.
10. a kind of Hydrogen Energy air mixture production method according to claim 8, it is characterised in that in described electrolytic cell
Multiple electrolytic zinc-coated steel sheets are configured with, felt pad between adjacent electrolytic zinc-coated steel sheet, is configured with, the bubble and electrolyte on electrolytic zinc-coated steel sheet is blended in one
Rise, electrolytic cell is quickly taken out of by electrolyte circulating pump, one-level gas-liquid separation device is entered after heat exchanger and is separated, bubble
The time that adsorbs on electrolytic zinc-coated steel sheet shortens, and will not pile up between bubble；Electrolyte is in electrolytic cell, heat exchanger and one-level gas
Quickly flowed by electrolyte circulating pump between liquid separating apparatus, accelerate water electrolysis, while quick separating go out containing hydrogen-oxygen from
The mixed gas of son；
The liquid that two grades of described gas-liquid separation devices are stayed after carrying out gas-liquid separation, mixed by connecting valve inflow catalyst catalysis
Attach together and put recycling.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108452753A (en) * | 2018-04-16 | 2018-08-28 | 凯里天宇燃能科技有限公司 | Alcohol solution combustion gas reaction unit and gas supply system |
| CN111850597A (en) * | 2020-06-15 | 2020-10-30 | 中船重工（邯郸）派瑞特种气体有限公司 | Electrochemical fluorination external circulation electrolysis system |
| CN112206883A (en) * | 2020-09-27 | 2021-01-12 | 广州怡润贸易有限公司 | Paper shredder capable of completely breaking paper and preventing hand from being injured when cleaning |
| CN113341848A (en) * | 2021-07-01 | 2021-09-03 | 白玉林 | Water agent hydrogen and oxygen generation control circuit |
| WO2023097943A1 (en) * | 2021-12-03 | 2023-06-08 | 上海源晗能源技术有限公司 | Nitrogen-free combustion and carbon dioxide capture and utilization process for gas-fired boiler |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06173053A (en) * | 1992-12-07 | 1994-06-21 | Ishikawajima Harima Heavy Ind Co Ltd | Hydrogen producing device |
| US5505824A (en) * | 1995-01-06 | 1996-04-09 | United Technologies Corporation | Propellant generator and method of generating propellants |
| CN1384224A (en) * | 2001-05-08 | 2002-12-11 | 谢宏凯 | Hydrogen energy generator |
| JP2003328172A (en) * | 2002-05-13 | 2003-11-19 | Toshiba Corp | Hydrogen utilization system |
| CN101928953A (en) * | 2009-10-27 | 2010-12-29 | 上海高企新能源科技有限公司 | Water electrolysis hydrogen producing process by cooling filtering method |
| CN104674292A (en) * | 2014-12-08 | 2015-06-03 | 鹤山市嘉德环保科技有限公司 | Water molecule low-voltage electrochemical separation device and water molecule low-voltage electrochemical separation method |
| CN104818496A (en) * | 2014-01-30 | 2015-08-05 | 泱能（厦门）商贸有限公司 | Manufacturing device of oxygen-containing gaseous fuel |
| CN204943491U (en) * | 2015-07-28 | 2016-01-06 | 石祥 | A kind of for providing the system of hydrogen and oxygen gas mixture to combustion apparatus |
| CN206359623U (en) * | 2017-01-06 | 2017-07-28 | 山东格瑞斯新能源科技有限公司 | A kind of Hydrogen Energy air mixture production equipment |
-
2017
- 2017-01-06 CN CN201710010309.2A patent/CN106498432B/en not_active Expired - Fee Related
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06173053A (en) * | 1992-12-07 | 1994-06-21 | Ishikawajima Harima Heavy Ind Co Ltd | Hydrogen producing device |
| US5505824A (en) * | 1995-01-06 | 1996-04-09 | United Technologies Corporation | Propellant generator and method of generating propellants |
| CN1384224A (en) * | 2001-05-08 | 2002-12-11 | 谢宏凯 | Hydrogen energy generator |
| JP2003328172A (en) * | 2002-05-13 | 2003-11-19 | Toshiba Corp | Hydrogen utilization system |
| CN101928953A (en) * | 2009-10-27 | 2010-12-29 | 上海高企新能源科技有限公司 | Water electrolysis hydrogen producing process by cooling filtering method |
| CN104818496A (en) * | 2014-01-30 | 2015-08-05 | 泱能（厦门）商贸有限公司 | Manufacturing device of oxygen-containing gaseous fuel |
| CN104674292A (en) * | 2014-12-08 | 2015-06-03 | 鹤山市嘉德环保科技有限公司 | Water molecule low-voltage electrochemical separation device and water molecule low-voltage electrochemical separation method |
| CN204943491U (en) * | 2015-07-28 | 2016-01-06 | 石祥 | A kind of for providing the system of hydrogen and oxygen gas mixture to combustion apparatus |
| CN206359623U (en) * | 2017-01-06 | 2017-07-28 | 山东格瑞斯新能源科技有限公司 | A kind of Hydrogen Energy air mixture production equipment |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108452753A (en) * | 2018-04-16 | 2018-08-28 | 凯里天宇燃能科技有限公司 | Alcohol solution combustion gas reaction unit and gas supply system |
| CN111850597A (en) * | 2020-06-15 | 2020-10-30 | 中船重工（邯郸）派瑞特种气体有限公司 | Electrochemical fluorination external circulation electrolysis system |
| CN111850597B (en) * | 2020-06-15 | 2022-08-05 | 中船(邯郸)派瑞特种气体股份有限公司 | Electrochemical fluorination external circulation electrolysis system |
| CN112206883A (en) * | 2020-09-27 | 2021-01-12 | 广州怡润贸易有限公司 | Paper shredder capable of completely breaking paper and preventing hand from being injured when cleaning |
| CN113341848A (en) * | 2021-07-01 | 2021-09-03 | 白玉林 | Water agent hydrogen and oxygen generation control circuit |
| CN113341848B (en) * | 2021-07-01 | 2024-03-29 | 白玉林 | Control circuit for generating hydrogen and oxygen in water aqua |
| WO2023097943A1 (en) * | 2021-12-03 | 2023-06-08 | 上海源晗能源技术有限公司 | Nitrogen-free combustion and carbon dioxide capture and utilization process for gas-fired boiler |
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|---|---|
| CN106498432B (en) | 2018-09-25 |
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