CN106498276A - 10.9 grade atmospheric corrosion resistant cold-forging steel gren rods and its production method - Google Patents

10.9 grade atmospheric corrosion resistant cold-forging steel gren rods and its production method Download PDF

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Publication number
CN106498276A
CN106498276A CN201610833875.9A CN201610833875A CN106498276A CN 106498276 A CN106498276 A CN 106498276A CN 201610833875 A CN201610833875 A CN 201610833875A CN 106498276 A CN106498276 A CN 106498276A
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atmospheric corrosion
corrosion resistant
forging steel
cold
production method
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CN201610833875.9A
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Inventor
翟进坡
陈继林
陶晓燕
田新中
刘晓光
张治广
崔娟
郭明仪
张松琦
阮士朋
李永超
牛斌
沈家华
赵欣欣
王利军
张鹏
黄翠环
刘超
王宁涛
冯忠贤
回士旭
阎丽珍
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Xingtai Iron and Steel Co Ltd
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Xingtai Iron and Steel Co Ltd
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Priority to CN201610833875.9A priority Critical patent/CN106498276A/en
Publication of CN106498276A publication Critical patent/CN106498276A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention discloses a kind of 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod, its composition is by weight percentage:C 0.25~0.35%, Si 0.15~0.35%, Mn 0.60~0.90%, P≤0.030%, S≤0.030%, Cr 0.60~0.90%, Ni 0.20~0.50%, Cu 0.20~0.50%, remaining are iron and trace impurity.Optimization design of this gren rod by chemical composition, by adding the elements such as alloy Cu, Cr, make securing member in use by surface corrosion, self-assembling formation a kind of fine and close and with the compact amorphous metal film of matrix, make material that there is the effect of atmospheric corrosion resistance;By adding alloying element Ni, make that there is during material hot rolling good surface quality, follow-up drawing, cold-heading process surface do not have obvious cracking phenomena;There is mechanical property, the features such as corrosivity is good, processability is good.

Description

10.9 grade atmospheric corrosion resistant cold-forging steel gren rods and its production method
Technical field
The present invention relates to a kind of hot rolling wire and its production method, especially a kind of weather-proof bolt are rotten with 10.9 grades of resistance to air Erosion cold-forging steel gren rod and its production method.
Background technology
High intensity and long-life are always the direction of metal material research.High intensity connecting bolt is used for steel structure connection, In the design of steel construction, high-strength bolt play a part of connection, fastening and position, with building structure high stratification and The aspects such as the overlength of bridge, the requirement that high design stress and light weight are proposed to the bolt as connection parts.To this most Effective measures are the high intensities of bolting steel.
It is reported that, the weathering steel of the country such as the U.S., Canada, Japan, Europe is widely used, and at home, The range of application of weathering steel is simultaneously little, and domestic Ge great steel mills all proceed by the research of steel construction weather-resistant steel plate, mesh at present Front the most frequently used steel structure connection method is high strength exploitation.Atmospheric corrosion resistance high-strength bolt gren rod, be The elements such as a small amount of copper, chromium, nickel are added in steel, make steel form one layer of densification and and parent metal between rusty scale and matrix The good amorphous state spinel oxides film of adhesiveness, due to the presence of this layer of dense oxide film, prevents the oxygen in air Penetrate into steel substrate with water, corrosion is slow down to ferrous materials in-house development, so as to substantially increase the corrosion resistant of ferrous materials Corrosion energy.
There are some producers produce Tests for Weathering Steel at present both at home and abroad, but most for sheet material.Application No. 201310290465.0 Chinese patent application provides a kind of preparation side of the high intensity non-annealed cold-forging steel of atmospheric corrosion resistance Method, but which is primarily directed to a kind of 8.8 grades and exempts from atmospheric corrosion resistance wire rod of annealing.The China of Patent No. 201210122948.5 Patent provides a kind of weather-proof welding wire for submerged-arc welding of rail truck high corrosion resistant type and wire rod, and the patent is primarily directed to a kind of weldering Silk steel, although good welding performance but intensity are unable to reach the requirement of 10.9 grades of steel for fastener.
Content of the invention
It is cold that the technical problem to be solved in the present invention is to provide 10.9 good grade atmospheric corrosion resistants of a kind of mechanical property, corrosivity Upsetting steel gren rod;Present invention also offers a kind of production method of 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod.
For solving above-mentioned technical problem, present component is by weight percentage:C 0.25~0.35%, Si 0.15~ 0.35%th, Mn 0.60~0.90%, P≤0.030%, S≤0.030%, Cr 0.60~0.90%, Ni 0.20~0.50%, Cu 0.20~0.50%, remaining is iron and trace impurity.
The inventive method includes heating, rolls and refrigerating work procedure, and the wire rod composition is as described above by weight percentage.
Heating process described in the inventive method:1050~1150 DEG C of heating-up temperature, 70~130min of temperature retention time.
Rolling process described in the inventive method:Enter 880~950 DEG C of final rolling temperature, 850~920 DEG C of laying temperature.
Refrigerating work procedure described in the inventive method:Wire rod phase transformation leading portion cooldown rate is 0.4~0.6 DEG C/s.
It is using the beneficial effect produced by above-mentioned technical proposal:The present invention is led to by the optimization design of chemical composition The elements such as addition alloy Cu, Cr are crossed, makes securing member in use by surface corrosion, a kind of fine and close and and base of self-assembling formation The compact amorphous metal film of body, makes material that there is the effect of atmospheric corrosion resistance;By adding alloying element Ni, material is made There is during hot rolling good surface quality, follow-up drawing, cold-heading process surface do not have obvious cracking phenomena;There is mechanical property Can, the features such as corrosivity is good, processability is good.
The inventive method is using works such as rational designing chemical composition, adjustment heating-up temperature, rolling temperature control, reduction cooling rates Skill is adjusted, and the gren rod microstructure of acquisition is made up of ferrite+bainite+a small amount of pearlite, and tensile strength 800~ 950MPa, reduction of area 35~50%, meet the processing request of user.The performance of the inventive method gained gren rod meets bolt The demand of mechanical property, while disclosure satisfy that material atmospheric corrosion resistance, corrosion resistance index I >=6.2 again;Presentation quality Excellent, processability is good.
Description of the drawings
The present invention is further detailed explanation with reference to the accompanying drawings and detailed description.
Fig. 1 is the metallograph of the present invention;
Fig. 2 is the polarization curve of the present invention.
Specific embodiment
Embodiment 1:This 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod is produced using following methods.
(1)Smelting, continuous casting working procedure:Smelting molten steel is simultaneously casting continuously to form steel billet, and its composition is by weight percentage:C 0.32%、Si 0.20%th, Mn 0.82%, P 0.020%, S 0.010%, Cr 0.81%, Ni 0.24%, Cu 0.25%, remaining is iron, corrosion resistance Index is I=6.4.
(2)Heating process:By heating steel billet to 1100 DEG C, temperature retention time 85min;Then water under high pressure dephosphorization, dephosphorization temperature For 1040 DEG C, it is desirable to dephosphorization hydraulic pressure at least 10MPa.
(3)Rolling process:Steel billet after by dephosphorization carries out rolling during 6+8 passages are thick, the pre- finish rolling of 4 passages, and 8 passage finish rolling are entered 895 DEG C of final rolling temperature, after finish rolling terminates, laying temperature is controlled at 880 DEG C.
(4)Refrigerating work procedure:Steyr not cooling line is entered, air-cooled line stay-warm case is adjusted and is opened quantity and blower fan aperture, tell After silk, wire rod phase transformation leading portion cooldown rate is controlled in 0.5 DEG C/s.
The cold-forging steel gren rod of the present embodiment gained Φ 18mm specifications, tensile strength 885MPa, reduction of area 48%;Metallographic Figure is shown in Fig. 1, and as seen from the figure, its microstructure is made up of ferrite+bainite+a small amount of pearlite;Polarization curve is shown in Fig. 2, by Knowable to figure, its fine corrosion resistance.Deep processing is carried out through certain high-strength bolt processing factory:Pickling-phosphatization-be drawn to 17.2mm- spheroidizings-be drawn to 17mm- cold-headings, make hexagon socket head cap screw;Gained bolt presentation quality is excellent, existing without cracking As processability is good, and 100% is qualified.
Embodiment 2:This 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod is produced using following methods.
(1)Smelting, continuous casting working procedure:Smelting molten steel is simultaneously casting continuously to form steel billet, and its composition is by weight percentage:C 0.28%、Si 0.22%th, Mn 0.80%, P 0.021%, S 0.013%, Cr 0.83%, Ni 0.26%, Cu 0.26%, remaining is iron, corrosion resistance Index is I=6.6.
(2)Heating process:By heating steel billet to 1080 DEG C, temperature retention time 90min;Then water under high pressure dephosphorization, dephosphorization temperature For 1020 DEG C, it is desirable to dephosphorization hydraulic pressure at least 10MPa.
(3)Rolling process:Steel billet after by dephosphorization carries out rolling during 6+8 passages are thick, the pre- finish rolling of 4 passages, and 8 passage finish rolling are entered 905 DEG C of final rolling temperature, after finish rolling terminates, laying temperature is controlled at 890 DEG C.
(4)Refrigerating work procedure:Steyr not cooling line is entered, air-cooled line stay-warm case is adjusted and is opened quantity and blower fan aperture, tell After silk, wire rod phase transformation leading portion cooldown rate is controlled in 0.45 DEG C/s.
The cold-forging steel gren rod of the present embodiment gained Φ 20mm specifications, tensile strength 860MPa, reduction of area 45%.Through certain Fastening parts of automobiles factory carries out deep processing:Pickling-phosphatization-be drawn to 18.7mm- spheroidizings-be drawn to 18.3mm- are cold Upsetting, makes T-bolt;Gained bolt presentation quality is excellent, and without cracking phenomena, processability is good, and 100% is qualified.
Embodiment 3:This 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod is produced using following methods.
(1)Smelting, continuous casting working procedure:Smelting molten steel is simultaneously casting continuously to form steel billet, and its composition is by weight percentage:C 0.30%、Si 0.15%th, Mn 0.85%, P 0.022%, S 0.012%, Cr 0.79%, Ni 0.35%, Cu 0.50%, remaining be iron, corrosion resistance Index is I=6.4.
(2)Heating process:By heating steel billet to 1100 DEG C, temperature retention time 100min;Then water under high pressure dephosphorization, dephosphorization temperature For 1040 DEG C, it is desirable to dephosphorization hydraulic pressure at least 10MPa.
(3)Rolling process:Steel billet after by dephosphorization carries out rolling during 6+8 passages are thick, the pre- finish rolling of 4 passages, and 8 passage finish rolling are entered 900 DEG C of final rolling temperature, after finish rolling terminates, laying temperature is controlled at 860 DEG C.
(4)Refrigerating work procedure:Steyr not cooling line is entered, air-cooled line stay-warm case is adjusted and is opened quantity and blower fan aperture, tell After silk, wire rod phase transformation leading portion cooldown rate is controlled in 0.55 DEG C/s.
The cold-forging steel gren rod of the present embodiment gained Φ 16mm specifications, tensile strength 890MPa, reduction of area 43%.Through certain Fastening parts of automobiles factory carries out deep processing, pickling-phosphatization-be drawn to 15.3mm- simplify anneal-to be drawn to 14.80mm- cold Upsetting, makes big hex bolts;Gained bolt presentation quality is excellent, and without cracking phenomena, processability is good, and 100% is qualified.
Embodiment 4:This 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod is produced using following methods.
(1)Smelting, continuous casting working procedure:Smelting molten steel is simultaneously casting continuously to form steel billet, and its composition is by weight percentage:C 0.35%、Si 0.23%th, Mn 0.90%, P 0.025%, S 0.015%, Cr 0.60%, Ni 0.39%, Cu 0.20%, remaining be iron, corrosion resistance Index is I=6.9.
(2)Heating process:By heating steel billet to 1090 DEG C, temperature retention time 130min;Then water under high pressure dephosphorization, dephosphorization temperature For 1030 DEG C, it is desirable to dephosphorization hydraulic pressure at least 10MPa.
(3)Rolling process:Steel billet after by dephosphorization carries out rolling during 6+8 passages are thick, the pre- finish rolling of 4 passages, and 8 passage finish rolling are entered 950 DEG C of final rolling temperature, after finish rolling terminates, laying temperature is controlled at 920 DEG C.
(4)Refrigerating work procedure:Steyr not cooling line is entered, air-cooled line stay-warm case is adjusted and is opened quantity and blower fan aperture, tell After silk, wire rod phase transformation leading portion cooldown rate is controlled in 0.56 DEG C/s.
The cold-forging steel gren rod of the present embodiment gained Φ 14mm specifications, tensile strength 900MPa, reduction of area 42%.Through certain Fastening parts of automobiles factory carries out deep processing, and pickling-phosphatization-be drawn to 13mm- simplifies 12.6mm- cold-headings of annealing-be drawn to, Make T-bolt;Gained bolt presentation quality is excellent, and without cracking phenomena, processability is good, and 100% is qualified.
Embodiment 5:This 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod is produced using following methods.
(1)Smelting, continuous casting working procedure:Smelting molten steel is simultaneously casting continuously to form steel billet, and its composition is by weight percentage:C 0.30%、Si 0.25%th, Mn 0.75%, P 0.030%, S 0.018%, Cr 0.72%, Ni 0.50%, Cu 0.32%, remaining be iron, corrosion resistance Index is I=7.0.
(2)Heating process:By heating steel billet to 1150 DEG C, temperature retention time 80min;Then water under high pressure dephosphorization, dephosphorization temperature For 1040 DEG C, it is desirable to dephosphorization hydraulic pressure at least 10MPa.
(3)Rolling process:Steel billet after by dephosphorization carries out rolling during 6+8 passages are thick, the pre- finish rolling of 4 passages, and 8 passage finish rolling are entered 910 DEG C of final rolling temperature, after finish rolling terminates, laying temperature is controlled at 900 DEG C.
(4)Refrigerating work procedure:Steyr not cooling line is entered, air-cooled line stay-warm case is adjusted and is opened quantity and blower fan aperture, tell After silk, wire rod phase transformation leading portion cooldown rate is controlled in 0.40 DEG C/s.
The cold-forging steel gren rod of the present embodiment gained Φ 24mm specifications, tensile strength 860MPa, reduction of area 48%.Through certain Fastening parts of automobiles factory carries out deep processing, pickling-phosphatization-be drawn to 22.7mm- simplify anneal-to be drawn to 22.3mm- cold Upsetting, makes big hex bolts;Gained bolt presentation quality is excellent, and without cracking phenomena, processability is good, and 100% is qualified.
Embodiment 6:This 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod is produced using following methods.
(1)Smelting, continuous casting working procedure:Smelting molten steel is simultaneously casting continuously to form steel billet, and its composition is by weight percentage:C 0.25%、Si 0.35%th, Mn 0.60%, P 0.027%, S 0.030%, Cr 0.90%, Ni 0.20%, Cu 0.45%, remaining is iron, corrosion resistance Index is I=7.0.
(2)Heating process:By heating steel billet to 1050 DEG C, temperature retention time 70min;Then water under high pressure dephosphorization, dephosphorization temperature For 1000 DEG C, it is desirable to dephosphorization hydraulic pressure at least 10MPa.
(3)Rolling process:Steel billet after by dephosphorization carries out rolling during 6+8 passages are thick, the pre- finish rolling of 4 passages, and 8 passage finish rolling are entered 880 DEG C of final rolling temperature, after finish rolling terminates, laying temperature is controlled at 850 DEG C.
(4)Refrigerating work procedure:Steyr not cooling line is entered, air-cooled line stay-warm case is adjusted and is opened quantity and blower fan aperture, tell After silk, wire rod phase transformation leading portion cooldown rate is controlled in 0.6 DEG C/s.
The cold-forging steel gren rod of the present embodiment gained Φ 18mm specifications, tensile strength 885MPa, reduction of area 45%.Through certain High-strength bolt processing factory carries out deep processing:Pickling-phosphatization-be drawn to 17.2mm- spheroidizings-be drawn to 17mm- are cold Upsetting, makes hexagon socket head cap screw;Gained bolt presentation quality is excellent, and without cracking phenomena, processability is good, and 100% is qualified.

Claims (5)

1. a kind of 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod, it is characterised in that its composition is by weight percentage:C 0.25~0.35%, Si 0.15~0.35%, Mn 0.60~0.90%, P≤0.030%, S≤0.030%, Cr 0.60~0.90%, Ni 0.20~0.50%, Cu 0.20~0.50%, remaining are iron and trace impurity.
2. a kind of production method of 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod, which includes heating, rolls and refrigerating work procedure, It is characterized in that:The wire rod composition is by weight percentage:C 0.25~0.35%, Si 0.15~0.35%, Mn 0.60~ 0.90%th, P≤0.030%, S≤0.030%, Cr 0.60~0.90%, Ni 0.20~0.50%, Cu 0.20~0.50%, remaining is Iron and trace impurity.
3. the production method of 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod according to claim 2, it is characterised in that The heating process:1050~1150 DEG C of heating-up temperature, 70~130min of temperature retention time.
4. the production method of 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod according to claim 2, it is characterised in that The rolling process:Enter 880~950 DEG C of final rolling temperature, 850~920 DEG C of laying temperature.
5. the production method of 10.9 grade atmospheric corrosion resistant cold-forging steel gren rod according to claim 2, it is characterised in that The refrigerating work procedure:Wire rod phase transformation leading portion cooldown rate is 0.4~0.6 DEG C/s.
CN201610833875.9A 2016-09-20 2016-09-20 10.9 grade atmospheric corrosion resistant cold-forging steel gren rods and its production method Pending CN106498276A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107058880A (en) * 2017-03-28 2017-08-18 邢台钢铁有限责任公司 A kind of automobile daming piston bar steel and its production method
CN109023112A (en) * 2018-09-28 2018-12-18 邢台钢铁有限责任公司 High-strength weather-resistant cold-forging steel and preparation method thereof
CN109234509A (en) * 2018-10-31 2019-01-18 首钢集团有限公司 600Mpa grades of weather-proof bolting steel self-corrosion matching process of electric power pylon
CN109290367A (en) * 2018-09-25 2019-02-01 湖南华菱湘潭钢铁有限公司 A kind of milling method of corrosion-resistant cold-forging steel
CN109465566A (en) * 2018-11-21 2019-03-15 首钢集团有限公司 Improve production method of the high-strength weathering gas shield welding wire with wire rod with circle performance
CN109957728A (en) * 2017-12-14 2019-07-02 鞍钢股份有限公司 Weather-resistant cold heading steel wire rod for 800 MPa-level fastener and production method thereof
CN114875332A (en) * 2022-05-30 2022-08-09 湖南华菱湘潭钢铁有限公司 Production method of annealing-free wire rod for high-strength alloy welding wire of 80 kilograms or more

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101603155A (en) * 2008-06-11 2009-12-16 中国第一汽车集团公司 Microalloy non quenched and tempered steel for automobile axle head
CN101812644A (en) * 2010-03-19 2010-08-25 江苏省沙钢钢铁研究院有限公司 Non-quenched and tempered cold forging steel for high-strength fastener and manufacturing method thereof
CN102321851A (en) * 2011-10-14 2012-01-18 江苏省沙钢钢铁研究院有限公司 10.9-grade boron-containing spheroidizing-free cold heading steel wire rod and manufacturing method thereof
CN102899470A (en) * 2012-11-05 2013-01-30 南京钢铁股份有限公司 Method for controlling decarburization on surfaces of medium-carbon cold forging steel wires
CN103205641A (en) * 2013-02-04 2013-07-17 繁昌县琪鑫铸造有限公司 Preparation method for high-strength foundation bolt
CN105714195A (en) * 2016-03-08 2016-06-29 邢台钢铁有限责任公司 Atmospheric-corrosion-resistant cold heading steel hot rolled wire rod and production method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101603155A (en) * 2008-06-11 2009-12-16 中国第一汽车集团公司 Microalloy non quenched and tempered steel for automobile axle head
CN101812644A (en) * 2010-03-19 2010-08-25 江苏省沙钢钢铁研究院有限公司 Non-quenched and tempered cold forging steel for high-strength fastener and manufacturing method thereof
CN102321851A (en) * 2011-10-14 2012-01-18 江苏省沙钢钢铁研究院有限公司 10.9-grade boron-containing spheroidizing-free cold heading steel wire rod and manufacturing method thereof
CN102899470A (en) * 2012-11-05 2013-01-30 南京钢铁股份有限公司 Method for controlling decarburization on surfaces of medium-carbon cold forging steel wires
CN103205641A (en) * 2013-02-04 2013-07-17 繁昌县琪鑫铸造有限公司 Preparation method for high-strength foundation bolt
CN105714195A (en) * 2016-03-08 2016-06-29 邢台钢铁有限责任公司 Atmospheric-corrosion-resistant cold heading steel hot rolled wire rod and production method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
国家质量技术监督局: "《紧固件机械性能 螺栓、螺钉和螺柱(GB/T 3098.1-2000)》", 1 February 2001 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107058880A (en) * 2017-03-28 2017-08-18 邢台钢铁有限责任公司 A kind of automobile daming piston bar steel and its production method
CN107058880B (en) * 2017-03-28 2018-10-23 邢台钢铁有限责任公司 A kind of automobile daming piston bar steel and its production method
CN109957728A (en) * 2017-12-14 2019-07-02 鞍钢股份有限公司 Weather-resistant cold heading steel wire rod for 800 MPa-level fastener and production method thereof
CN109957728B (en) * 2017-12-14 2021-02-23 鞍钢股份有限公司 Weather-resistant cold heading steel wire rod for 800 MPa-level fastener and production method thereof
CN109290367A (en) * 2018-09-25 2019-02-01 湖南华菱湘潭钢铁有限公司 A kind of milling method of corrosion-resistant cold-forging steel
CN109023112A (en) * 2018-09-28 2018-12-18 邢台钢铁有限责任公司 High-strength weather-resistant cold-forging steel and preparation method thereof
CN109234509A (en) * 2018-10-31 2019-01-18 首钢集团有限公司 600Mpa grades of weather-proof bolting steel self-corrosion matching process of electric power pylon
CN109465566A (en) * 2018-11-21 2019-03-15 首钢集团有限公司 Improve production method of the high-strength weathering gas shield welding wire with wire rod with circle performance
CN109465566B (en) * 2018-11-21 2021-05-25 首钢集团有限公司 Production method for improving same-circle performance of wire rod for high-strength weather-resistant gas-shielded welding wire
CN114875332A (en) * 2022-05-30 2022-08-09 湖南华菱湘潭钢铁有限公司 Production method of annealing-free wire rod for high-strength alloy welding wire of 80 kilograms or more

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Application publication date: 20170315