CN106497685A - A kind of method that utilization carbide slag prepares household cleanser - Google Patents
A kind of method that utilization carbide slag prepares household cleanser Download PDFInfo
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- CN106497685A CN106497685A CN201610808234.8A CN201610808234A CN106497685A CN 106497685 A CN106497685 A CN 106497685A CN 201610808234 A CN201610808234 A CN 201610808234A CN 106497685 A CN106497685 A CN 106497685A
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- Prior art keywords
- carbide slag
- mixture
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- household cleanser
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of method that utilization carbide slag prepares household cleanser, methods described includes：(1) hydrated silica, sodium silicate, sodium pyrophosphate, sodium carboxymethyl cellulose and dodecylbenzene sodium sulfonate are mixed, obtains mixture 1；(2) mixture 1 is dissolved in after water and adds glycerol mix homogeneously, obtain mixture 2；(3) carbide slag is added in mixture 2, stir, obtain final product.The present invention prepares household cleanser using discarded carbide slag, and preparation process is simple, easily controllable and raw material sources extensively, greatly reduce preparation cost.Using clearance average out to more than 92% of the household cleanser prepared by the inventive method to various spots, 99% is reached as high as.
Description
Technical field
The present invention relates to a kind of method that utilization carbide slag prepares household cleanser, belongs to the recycling field of carbide slag.
Background technology
During " 12 ", fast development band of the Chinese calcium carbide industry in downstream industries such as polrvinyl chloride, BDOs
Under dynamic, self supporting carbide project of various places starts, and comparison is more, and carbide production capacity is again introduced into being skyrocketed through the phase.By 2015
End, more than 255 family of China carbide enterprise, production capacity reach 45,000,000 t/, produce 1.2t carbide slags (butt) by every 1t carbides
Calculate, 5019.6 ten thousand t/ carbide slags (butt) will be produced.Carbide slag belongs to trade waste, directly discharge to environmental hazard compared with
Greatly, it is necessary to which is reclaimed and carries out higher value application.
People such as cook in daily life, cooking and when having dinner, be easily stained with medicated clothing accidentally oil stain, laughable stain,
Tea stain and coffee stain etc.；In the wild as careless medicated clothing can be stained with careless stain, native stain during outing；Ink is splashed on medicated clothing easily accidentally
Produce ink blok；Milk stain is easily stained with child's medicated clothing of age of sucking；Bloodstain produced on different reason medicated clothings etc..For these
Common spot in life, is difficult to remove using detergent, liquid detergent that sells on the market etc., have impact on the attractive in appearance of medicated clothing, compels
It is essential and wants the household cleanser of high efficiency low cost thoroughly to remove.
Mainly there are production cement, non-burning brick, processed coating and Calcium Carbonate series of products etc. at present to the utilization of carbide slag, and sharp
The technology of household cleanser is prepared with carbide slag, and there is not been reported, prepares the larger high added value of demand hence with carbide slag
Household cleanser by with wide market prospect.
Content of the invention
An object of the present invention is to provide a kind of household cleanser of the composition of main utilization carbide slag；
The second object of the present invention is to provide a kind of method for preparing the household cleanser；
The third object of the present invention is to be applied to remove various spots by described household cleanser.
The above-mentioned purpose of the present invention is achieved through the following technical solutions：
A kind of method that utilization carbide slag prepares household cleanser, including：(1) by hydrated silica, sodium silicate, pyrophosphoric acid
The mixing of sodium, sodium carboxymethyl cellulose and dodecylbenzene sodium sulfonate, obtains mixture 1；(2) mixture 1 is dissolved in after water and is added again
Enter glycerol mix homogeneously, obtain mixture 2；(3) carbide slag is added in mixture 2, stir, obtain final product.
In parts by weight, the consumption of each composition is：20～40 parts of carbide slag, 0.5～3 part of hydrated silica, sodium silicate 2～
5 parts, 0.5～2 part of sodium carboxymethyl cellulose, 1～5 part of dodecylbenzene sodium sulfonate, 1～5 part of sodium pyrophosphate, 3～10 parts of glycerol,
30～50 parts of water；Preferably, the consumption of each composition is：25 parts of carbide slag, 2.5 parts of hydrated silica, 5 parts of sodium silicate, carboxymethyl are fine
Plain 1.5 parts of the sodium of dimension, 4 parts of dodecylbenzene sodium sulfonate, 5 parts of sodium pyrophosphate, 10 parts of glycerol, 47 parts of water.
In order to reach more preferable effect, be passed through enough CO while carbide slag is added in step (3) in mixture 22；
Mixing time described in step (3) is preferably 15-25min.
Described carbide slag is the product that will be obtained through calcination processing after preheated for carbide slag slurries drying again；Preferably, institute
The calcination processing that states is to carry out calcination processing at a high temperature of 700-1200 DEG C；It is furthermore preferred that described calcination processing be
Calcination processing is carried out at a high temperature of 800-1000 DEG C, and most preferably, described calcination processing is forged at a high temperature of 900 DEG C
Burning process.
The household cleanser that the present invention is provided can effectively remove various spots, including oil stain, coffee stain, laughable stain, tea stain,
Soy sauce, native stain, milk stain, careless stain, bloodstain or ink blok；After measured, go can fabric oil stain using the household cleanser of the present invention
Except rate reaches as high as 99%.
Thus, invention further provides the household cleanser to be applied to remove spot, including：By described dirt
Stain remover is applied in spot, dries or uses clean water after drying；
The principle of the removal spot of household cleanser of the present invention is：Spot dissolving-absorption-removing.
Compared with prior art, the invention has the characteristics that：The present invention makes full use of discarded carbide slag to prepare spot
Remover, preparation process is simple, easily controllable and raw material sources extensively, greatly reduce preparation cost, are the height of carbide slag
Value had not only improve economic benefit but also beneficial to environmental protection using beneficial pathways are provided.Greasiness removal prepared by the present invention
Agent reaches as high as 99% to the clearance mean height of spot up to more than 92%.
Specific embodiment
Further describe the present invention with reference to specific embodiment, advantages of the present invention and feature will be with description and
Apparent.It should be understood that the embodiment is only exemplary, any restriction is not constituted to the scope of the present invention.This area
Technical staff should be understood that without departing from the spirit and scope of the invention can to the details of technical solution of the present invention and
Form is modified or is replaced, but these modifications or replacement each fall within protection scope of the present invention.
The preparation of carbide slag
Preparative Example 1
Again through 900 DEG C of calcination processing, carbide slag will be obtained after preheated for carbide slag slurries drying.
Preparative Example 2
Again through 1200 DEG C of calcination processing, carbide slag will be obtained after preheated for carbide slag slurries drying.
Preparative Example 3
Again through 700 DEG C of calcination processing, carbide slag will be obtained after preheated for carbide slag slurries drying.
Preparative Example 4
Again through 800 DEG C of calcination processing, carbide slag will be obtained after preheated for carbide slag slurries drying.
Preparative Example 5
Again through 1000 DEG C of calcination processing, carbide slag will be obtained after preheated for carbide slag slurries drying.
Embodiment 1
1st, the preparation of household cleanser
(1) by hydrated silica 2.5kg, sodium silicate 5kg, sodium carboxymethyl cellulose 1.5kg, sodium pyrophosphate 5kg and dodecane
Base benzene sulfonic acid sodium salt 4kg mix homogeneously, obtains mixture 1；
(2) glycerol 10kg mix homogeneously is added after mixture 1 being dissolved in 47kg water, obtains mixture 2；
(3) in mixture 2, add Preparative Example 1 to prepare carbide slag 25kg, is passed through foot while adding carbide slag
The CO of amount2, 20min is stirred, household cleanser is obtained final product.
2nd, household cleanser manufactured in the present embodiment is applied to remove the test of spot
(1), test method
By material to be tested uniform application at fabric oil stain, then dry or dry, finally washed away with clear water.
The white fabrics for polluting are measured using whiteness instrument, whiteness of the clearance after white fabrics greasiness removal
Calculated with the ratio of initial whiteness.
Clearance is defined as：
Wherein, initial whiteness refers to the whiteness of unpolluted white fabrics；Whiteness after greasiness removal refers to dirty
The whiteness of the white fabrics after processing through remover after stain pollution.
Whiteness：The degree of material superficial white is represented, is represented with the percentage rate of white amount.
(2), result of the test
After measured, using household cleanser manufactured in the present embodiment to fabric oil stain clearance up to 99%.
Embodiment 2
1st, the preparation of household cleanser
(1) by hydrated silica 3kg, sodium silicate 5kg, sodium carboxymethyl cellulose 2kg, sodium pyrophosphate 5kg and detergent alkylate
Sodium sulfonate 5kg mix homogeneously, obtains mixture 1；
(2) glycerol 10kg mix homogeneously is added after mixture 1 being dissolved in 30kg water, obtains mixture 2；
(3) in mixture 2, add Preparative Example 2 to prepare carbide slag 40kg, is passed through foot while adding carbide slag
The CO of amount2, 15min is stirred, household cleanser is obtained final product.
2nd, household cleanser manufactured in the present embodiment is applied to remove the test of spot
(1), test method
By material to be tested uniform application at fabric oil stain, then dry or dry, finally washed away with clear water.
The white fabrics for polluting are measured using whiteness instrument, whiteness of the clearance after white fabrics greasiness removal
Calculated with the ratio of initial whiteness.
Clearance is defined as：
Wherein, initial whiteness refers to the whiteness of unpolluted white fabrics；Whiteness after greasiness removal refers to dirty
The whiteness of the white fabrics after processing through remover after stain pollution.
Whiteness：The degree of material superficial white is represented, is represented with the percentage rate of white amount.
(2), result of the test
After measured, using household cleanser manufactured in the present embodiment to fabric oil stain clearance up to 92%.
Embodiment 3
1st, the preparation of household cleanser
(1) by hydrated silica 2kg, sodium silicate 4kg, sodium carboxymethyl cellulose 1.5kg, sodium pyrophosphate 3.5kg and dodecane
Base benzene sulfonic acid sodium salt 3kg mixes, and obtains mixture 1；
(2) glycerol 10kg mix homogeneously is added after mixture 1 being dissolved in 50kg water, obtains mixture 2；
(3) in mixture 2, add Preparative Example 3 to prepare carbide slag 25kg, is passed through foot while adding carbide slag
The CO of amount2, 20min is stirred, household cleanser is obtained final product.
2nd, household cleanser manufactured in the present embodiment is applied to remove the test of spot
(1), test method
By material to be tested uniform application at fabric oil stain, then dry or dry, finally washed away with clear water.
The white fabrics for polluting are measured using whiteness instrument, whiteness of the clearance after white fabrics greasiness removal
Calculated with the ratio of initial whiteness.
Clearance is defined as：
Wherein, initial whiteness refers to the whiteness of unpolluted white fabrics；Whiteness after greasiness removal refers to dirty
The whiteness of the white fabrics after processing through remover after stain pollution.
Whiteness：The degree of material superficial white is represented, is represented with the percentage rate of white amount.
(2), result of the test
After measured, using household cleanser manufactured in the present embodiment to fabric oil stain clearance up to 93%.
Embodiment 4
1st, the preparation of household cleanser
(1) by hydrated silica 3kg, sodium silicate 5kg, sodium carboxymethyl cellulose 2kg, sodium pyrophosphate 5kg and detergent alkylate
Sodium sulfonate 5kg mix homogeneously, obtains mixture 1；
(2) glycerol 3kg mix homogeneously is added after mixture 1 being dissolved in 50kg water, obtains mixture 2；
(3) in mixture 2, add Preparative Example 4 to prepare carbide slag 27kg, is passed through foot while adding carbide slag
The CO of amount2, 15min is stirred, household cleanser is obtained final product.
2nd, household cleanser manufactured in the present embodiment is applied to remove the test of spot
(1), test method
By material to be tested uniform application at fabric oil stain, then dry or dry, finally washed away with clear water.
The white fabrics for polluting are measured using whiteness instrument, whiteness of the clearance after white fabrics greasiness removal
Calculated with the ratio of initial whiteness.
Clearance is defined as：
Wherein, initial whiteness refers to the whiteness of unpolluted white fabrics；Whiteness after greasiness removal refers to dirty
The whiteness of the white fabrics after processing through remover after stain pollution.
Whiteness：The degree of material superficial white is represented, is represented with the percentage rate of white amount.
(2), result of the test
After measured, using household cleanser manufactured in the present embodiment to fabric oil stain clearance up to 97%.
Embodiment 5
1st, the preparation of household cleanser
(1) by hydrated silica 3kg, sodium silicate 5kg, sodium carboxymethyl cellulose 2kg, sodium pyrophosphate 5kg and detergent alkylate
Sodium sulfonate 5kg mix homogeneously, obtains mixture 1；
(2) glycerol 10kg mix homogeneously is added after mixture 1 being dissolved in 50kg water, obtains mixture 2；
(3) in mixture 2, add Preparative Example 5 to prepare carbide slag 20kg, is passed through foot while adding carbide slag
The CO of amount2, 20min is stirred, household cleanser is obtained final product.
2nd, household cleanser manufactured in the present embodiment is applied to remove the test of spot
(1), test method
By material to be tested uniform application at fabric oil stain, then dry or dry, finally washed away with clear water.
The white fabrics for polluting are measured using whiteness instrument, whiteness of the clearance after white fabrics greasiness removal
Calculated with the ratio of initial whiteness.
Clearance is defined as：
Wherein, initial whiteness refers to the whiteness of unpolluted white fabrics；Whiteness after greasiness removal refers to dirty
The whiteness of the white fabrics after processing through remover after stain pollution.
Whiteness：The degree of material superficial white is represented, is represented with the percentage rate of white amount.
(2), result of the test
After measured, using household cleanser manufactured in the present embodiment to fabric oil stain clearance up to 96%.
Claims (6)
1. a kind of method that utilization carbide slag prepares household cleanser, it is characterised in that include：(1) by hydrated silica, silicic acid
The mixing of sodium, sodium pyrophosphate, sodium carboxymethyl cellulose and dodecylbenzene sodium sulfonate, obtains mixture 1；(2) mixture 1 is dissolved in
Glycerol mix homogeneously is added after water, obtains mixture 2；(3) carbide slag is added in mixture 2, stir, obtain final product.
2. in accordance with the method for claim 1, it is characterised in that in parts by weight, the consumption of each composition is：Carbide slag 20
～40 parts, hydrated silica 0.5-3 parts, 2～5 parts of sodium silicate, 0.5～2 part of sodium carboxymethyl cellulose, dodecylbenzene sodium sulfonate 1
～5 parts, 1～5 part of sodium pyrophosphate, 3～10 parts of glycerol, 30～50 parts of water.
3. in accordance with the method for claim 1, it is characterised in that described carbide slag be by preheated for carbide slag slurries drying after
The product for obtaining through calcination processing again.
4. in accordance with the method for claim 3, it is characterised in that described calcination processing is at a high temperature of 700-1200 DEG C
Carry out calcination processing.
5. in accordance with the method for claim 1, it is characterised in that while adding carbide slag in mixture 2 in step (3)
It is passed through enough CO2.
6. in accordance with the method for claim 1, it is characterised in that the mixing time described in step (3) is 15-25min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610808234.8A CN106497685A (en) | 2016-09-08 | 2016-09-08 | A kind of method that utilization carbide slag prepares household cleanser |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610808234.8A CN106497685A (en) | 2016-09-08 | 2016-09-08 | A kind of method that utilization carbide slag prepares household cleanser |
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| CN106497685A true CN106497685A (en) | 2017-03-15 |
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| CN201610808234.8A Pending CN106497685A (en) | 2016-09-08 | 2016-09-08 | A kind of method that utilization carbide slag prepares household cleanser |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109030379A (en) * | 2018-07-06 | 2018-12-18 | 上海建科检验有限公司 | A kind of test method of interior wall coating spot-resistant performance |
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|---|---|---|---|---|
| CN1075505A (en) * | 1992-02-19 | 1993-08-25 | 黄丁义 | Cleaning soil-removing agent |
| CN1134976A (en) * | 1995-09-15 | 1996-11-06 | 武汉食品工业学院 | Method for prodn. of cleanser by using waste argil |
| CN101880604A (en) * | 2010-06-28 | 2010-11-10 | 黄山学院 | Clothes blot remover and preparation method thereof |
-
2016
- 2016-09-08 CN CN201610808234.8A patent/CN106497685A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075505A (en) * | 1992-02-19 | 1993-08-25 | 黄丁义 | Cleaning soil-removing agent |
| CN1134976A (en) * | 1995-09-15 | 1996-11-06 | 武汉食品工业学院 | Method for prodn. of cleanser by using waste argil |
| CN101880604A (en) * | 2010-06-28 | 2010-11-10 | 黄山学院 | Clothes blot remover and preparation method thereof |
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| Title |
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| 战佳宇等: "《固体废物协同处置与综合利用》", 31 December 2014, 中国建材工业出版社 * |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109030379A (en) * | 2018-07-06 | 2018-12-18 | 上海建科检验有限公司 | A kind of test method of interior wall coating spot-resistant performance |
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Address after: 102200 Beijing City, Changping District science and Technology Park Chang Huai Lu No. 155 Applicant after: Shenwu science and technology group Limited by Share Ltd Address before: 102200 Beijing City, Changping District science and Technology Park Chang Huai Lu No. 155 Applicant before: Beijing Shenwu Environment Energy Technology Group Co., Ltd. |