CN106497397A - A kind of electric appliance magnetic shield coating - Google Patents

A kind of electric appliance magnetic shield coating Download PDF

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Publication number
CN106497397A
CN106497397A CN201611012004.7A CN201611012004A CN106497397A CN 106497397 A CN106497397 A CN 106497397A CN 201611012004 A CN201611012004 A CN 201611012004A CN 106497397 A CN106497397 A CN 106497397A
Authority
CN
China
Prior art keywords
electric appliance
magnetic shield
graphene fiber
coating
polypyrrole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611012004.7A
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Chinese (zh)
Inventor
缪建良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Changan Shuguang Glove Factory
Original Assignee
Wuxi Changan Shuguang Glove Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Changan Shuguang Glove Factory filed Critical Wuxi Changan Shuguang Glove Factory
Priority to CN201611012004.7A priority Critical patent/CN106497397A/en
Publication of CN106497397A publication Critical patent/CN106497397A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D179/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
    • C09D179/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/06Elements
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of electric appliance magnetic shield coating, including:Polypyrrole 40 60, firming agent 2 10, graphene fiber 10 30, Fe3O4Microwave absorption 5 15, and color dye 25;Wherein, the graphene fiber is graphene fiber beam, and the fibre bundle vertical distribution forms equidistant array, the Fe in polypyrrole3O4Microwave absorption is dispersed in the epoxy resin.The electric appliance magnetic shield coating coating of the present invention, while enabling to coating and possess excellent electric appliance magnetic shield coating property, but also with excellent heat dissipating.

Description

A kind of electric appliance magnetic shield coating
Technical field
A kind of the present invention relates to technical field of coatings, more particularly to electric appliance magnetic shield coating.
Background technology
With developing rapidly for electronic industry and telecommunications, electronics and electrical equipment are widely used.Existing Electrical equipment, all has various electric elements.These electric elements can produce electromagnetic radiation.Shell due to electronic equipment Body material is usually plastics, and therefore electromagnetic wave can be passed freely through, so as to cause electromagnetic pollution.Electromagnetism spoke for attenuation apparatus Penetrate and electromagnetic interference each other, need to metallize plastic casing or conducting.Wherein, electrically-conducting paint has into The advantages of shell shape that sheet is low, easily realizes automatization and adapts to complexity, most with prospects.
103059672 A of CN disclose a kind of electric appliance magnetic shield coating electrically-conducting paint, and which constitutes and mass ratio is: Acrylic resin modified 200-300 parts;Copper powder 150-200 parts;Silicon dioxide 20-30 parts;Titanate coupling agent 5-10 parts;Anti- heavy Agent 100-120 parts.The electric appliance magnetic shield coating electrically-conducting paint also includes inorganic filler 200-300 parts.The titanium dioxide Silicon is aerosil.Beneficial effects of the present invention are:Copper powder electrically-conducting paint has the silver-plated copper powder of double protective layers, its resistance to ring Border property, fire resistance are greatly improved, and electric conductivity is similar to silver.
103087574 A of CN disclose a kind of electric appliance magnetic shield paint filler, the electric appliance magnetic shield coating Filler is nucleocapsid structure, includes kernel, the first shell being coated on kernel and be coated in first shell from the inside to the outside successively Two shells;The kernel is permeability magnetic material, and first shell is silver or copper, and second shell is polyacetylene layer.Present invention also offers the electricity Preparation method and battery shielding coating using the electric appliance magnetic shield paint filler of the device with electromagnetic shielding paint filler.This The electric appliance magnetic shield paint filler that invention is provided has magnetic conduction, conductive dual-use function concurrently, while outer layer is conducting polymer, So that the electric appliance magnetic shield coating of the present invention has good dispersibility and electric appliance magnetic shield coating property.
Content of the invention
It is an object of the invention to proposing a kind of electric appliance magnetic shield coating, enable to coating and possess excellent electrical equipment While with electromagnetic shielding coating property, but also with excellent heat dissipating.
It is that the present invention is employed the following technical solutions up to this purpose:
A kind of electric appliance magnetic shield coating, including:Polypyrrole 40-60
Firming agent 2-10
Graphene fiber 10-30,
Xi Kefu alkali vitamin A1 esters 5-15, and
Color dye 2-5;Wherein,
The graphene fiber is graphene fiber beam, and, in polypyrrole, formation is equidistantly for the fibre bundle vertical distribution Array, the Xi Kefu alkali vitamin A1 esters microwave absorption is dispersed in the epoxy resin.
In the coating that the present invention is adopted, polypyrrole can form thin film when using, as polypyrrole possesses electromagnetic absorption spy Property, therefore which simultaneously works as the effect of film former and electromagnetic absorption.The polypyrrole Xi Kefu alkali internal with which is dispersed in Together, the electromagnetic interference that excessive for electric elements or other elements are produced absorbs vitamin A1 esters microwave absorption.
Absorbing material of the Xi Kefu alkali vitamin A1 esters for black, its weight only have the 1/10 of iron ball absorbing material.Xi Kefu The suction wave frequency bandwidth of alkali vitamin A1 esters, all effective to shortwave 8mm from long wave, which is complete by electromagnetic wave energy by ion displacement mode Portion is converted to heat energy, but the temperature of material itself is without rising.Therefore the present invention is using Xi Kefu alkali vitamin A1 esters and poly- pyrrole Cough up, graphene fiber is combined, and prevents spilling and the interference of electromagnetic wave well, while heat can be conducted, increase electrical equipment Heat dispersion.
The graphene fiber of the present invention is chopped fiber, and which not only possesses rigidity, while there is perfect two dimensional crystal structure, Its lattice is the hexagon surrounded by six carbon atom, and thickness is an atomic layer.Bonded by σ between carbon atom, in conjunction with Mode is sp2 hydridization, and these σ keys impart the extremely excellent mechanical property of Graphene and structural rigidity.The hardness ratio of Graphene Best iron and steel is strong 100 times, or even will also exceed diamond.In Graphene, each carbon atom has the p electricity of a non-bonding Son, these p electronics can be moved freely in crystal, and movement velocity is up to the 1/300 of the light velocity, imparts Graphene good Electric conductivity.Graphene is the transparent conductive material of a new generation.
Therefore the graphene conductive material using the present invention is together with film of poly pyrrole so that the coating electric appliance magnetic Shielding coating excellent effect.
Electric appliance magnetic shield coating of the present invention, which can be applicable to the surface of the electrical equipment such as household electrical appliance, computer, Change color and luster is played, is increased thermal diffusivity and is realized electric appliance magnetic shield coating function.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
Embodiment 1
A kind of electric appliance magnetic shield coating, including:Polypyrrole 40
Firming agent 2
Graphene fiber 10,
Xi Kefu alkali vitamin A1 esterses microwave absorption 5, and
Color dye 2;Wherein,
The graphene fiber is graphene fiber beam, and, in polypyrrole, formation is equidistantly for the fibre bundle vertical distribution Array, the Xi Kefu alkali vitamin A1 esters microwave absorption is dispersed in the epoxy resin.
Embodiment 2
A kind of electric appliance magnetic shield coating, including:Polypyrrole 60
Firming agent 10
Graphene fiber 30,
Xi Kefu alkali vitamin A1 esterses microwave absorption 15, and
Color dye 5;Wherein,
The graphene fiber is graphene fiber beam, and, in polypyrrole, formation is equidistantly for the fibre bundle vertical distribution Array, the Xi Kefu alkali vitamin A1 esters microwave absorption is dispersed in the epoxy resin.
Embodiment 3
A kind of electric appliance magnetic shield coating, including:Polypyrrole 50
Firming agent 5
Graphene fiber 20,
Xi Kefu alkali vitamin A1 esterses microwave absorption 10, and
Color dye 3;Wherein,
The graphene fiber is graphene fiber beam, and, in polypyrrole, formation is equidistantly for the fibre bundle vertical distribution Array, the Xi Kefu alkali vitamin A1 esters microwave absorption is dispersed in the epoxy resin.

Claims (1)

1. a kind of electric appliance magnetic shield coating, including:Polypyrrole 40-60
Firming agent 2-10
Graphene fiber 10-30,
Xi Kefu alkali vitamin A1 esters 5-15, and
Color dye 2-5;Wherein,
The graphene fiber is graphene fiber beam, and the fibre bundle vertical distribution forms equidistant battle array in polypyrrole Row, the Xi Kefu alkali vitamin A1 esters microwave absorption are dispersed in the epoxy resin.
CN201611012004.7A 2016-11-17 2016-11-17 A kind of electric appliance magnetic shield coating Pending CN106497397A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611012004.7A CN106497397A (en) 2016-11-17 2016-11-17 A kind of electric appliance magnetic shield coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611012004.7A CN106497397A (en) 2016-11-17 2016-11-17 A kind of electric appliance magnetic shield coating

Publications (1)

Publication Number Publication Date
CN106497397A true CN106497397A (en) 2017-03-15

Family

ID=58324736

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611012004.7A Pending CN106497397A (en) 2016-11-17 2016-11-17 A kind of electric appliance magnetic shield coating

Country Status (1)

Country Link
CN (1) CN106497397A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106010118A (en) * 2016-06-27 2016-10-12 北京理工大学珠海学院 Epoxy resin paint with antistatic property and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106010118A (en) * 2016-06-27 2016-10-12 北京理工大学珠海学院 Epoxy resin paint with antistatic property and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨子立: "《浅谈电磁污染与电磁兼容技术》", 《黑龙江环境通报》 *

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Application publication date: 20170315