CN106497246A - A kind of enhanced chloro-sulfonated polyethylene anti-corrosive coating of modified zinc oxide antibacterial and mouldproof - Google Patents
A kind of enhanced chloro-sulfonated polyethylene anti-corrosive coating of modified zinc oxide antibacterial and mouldproof Download PDFInfo
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- CN106497246A CN106497246A CN201611010899.0A CN201611010899A CN106497246A CN 106497246 A CN106497246 A CN 106497246A CN 201611010899 A CN201611010899 A CN 201611010899A CN 106497246 A CN106497246 A CN 106497246A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
- C09D123/32—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
- C09D123/34—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur by chlorosulfonation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of enhanced chloro-sulfonated polyethylene anti-corrosive coating of modified zinc oxide antibacterial and mouldproof, is prepared by the raw materials in：Chlorosulfonated polyethylene latex 60 65, polychloroprene latex 35 40, polyoxyethylene aliphatic alcohol ether 78, appropriate deionized water, silane coupler KH5602.5 3, lanthana 23, cerium sesquioxide 1.5 2, concentration for 65wt% salpeter solution is appropriate, concentration is the ammonium bicarbonate soln of 50wt%, Rutile type titanium dioxide 10 12, aluminium triphosphate 23, Oleum Cinnamomi 56, barium metaborate 34, zinc nitrate 34, hexamethylenetetramine 34, stearic acid 45, appropriate dehydrated alcohol.The full aqueouss of composite anti-corrosion coating that the present invention makes, environmentally friendly, each component cooperative effect is good, and film forming is short for drying time, and flintiness is good, and anti-corrosion is weather-proof, and film adhesive is good, can be used for yard piping, metal machinery equipment, the anti-corrosion of chemical industry equipment.
Description
Technical field
The present invention relates to technical field, more particularly to a kind of enhanced chlorosulfonated polyethylene of modified zinc oxide antibacterial and mouldproof is anti-
Rotten coating.
Background technology
Corrosion and corrosion protection is the industry distinct issues such as chemical industry, light industry, metallurgy, electric power, weaving, printing and dyeing, ship processed, building.
Cause damage because of corrosion every year huge, anticorrosive work is particularly important, chloro-sulfonated polyethylene anti-corrosive coating, with excellent
Good rotproofness, particularly splendid pliability are used widely, along with inexpensive, once once deep by people in the industry
The favor of scholar.With developing rapidly for modern industry level, propose to anticorrosive paint that higher, tightened up to bear environment rotten
The ability of erosion.The antiseptic property of the chlorosulfonated polythylene coatings of conventional formulation production is typically extremely difficult to require.Conventional chlorine sulphur
It is mostly solvent type to change polyethylene anti-corrosion coating, not only causes the waste of a large amount of solvents, and solvent for use is poisonous, Yi Hui
Send out, to environment, do not meet environmental requirement, and water paint has technique cleaning, advanced technology, low emission, mental retardation
Consumption, safe and harmless advantage, therefore, research hydrophilic chlorosulfonated polyethylene anticorrosive coating has great social benefit and economy
Benefit.
《The development of water chlorosulfonated polyethylene anti-corrosion coatings》With chlorosulfonated polyethylene latex and water-base epoxy tree in one text
Fat is compounded, and makes water-based anticorrosive paint by evaporating kettle removed under reduced pressure solvent, and the coating property that makes is excellent, strong adaptability, is applied
Nonpoisonous and tasteless during brush, nonflammable, production process is simple, easy construction.Due to the interpolation of aqueous epoxy resins, painting is improve
Corrosion Protection is reduced while the adhesive force of material, it is impossible to be effectively improved the combination property of chlorosulfonated polyethylene, Gu need
Further modification is carried out to hydrophilic chlorosulfonated polyethylene coating, to meet the demand of industry development.
Content of the invention
The object of the invention is exactly the defect in order to make up prior art, there is provided a kind of modified zinc oxide antibacterial and mouldproof is enhanced
Chloro-sulfonated polyethylene anti-corrosive coating.
The present invention is achieved by the following technical solutions：
A kind of enhanced chloro-sulfonated polyethylene anti-corrosive coating of modified zinc oxide antibacterial and mouldproof, is prepared by the raw materials in：
Chlorosulfonated polyethylene latex 60-65, polychloroprene latex 35-40, polyoxyethylene aliphatic alcohol ether 7-8, appropriate deionized water, silane coupled
Agent KH5602.5-3, lanthana 2-3, cerium sesquioxide 1.5-2, concentration for 65wt% salpeter solution is appropriate, concentration is 50wt%
Ammonium bicarbonate soln, Rutile type titanium dioxide 10-12, aluminium triphosphate 2-3, Oleum Cinnamomi 5-6, barium metaborate 3-4, zinc nitrate
3-4, hexamethylenetetramine 3-4, stearic acid 4-5, appropriate dehydrated alcohol.
A kind of enhanced chloro-sulfonated polyethylene anti-corrosive coating of modified zinc oxide antibacterial and mouldproof according to claims 1,
It is prepared from by following concrete grammar：
（1）Chlorosulfonated polyethylene latex is mixed with polychloroprene latex, in input emulsator, is subsequently adding, polyoxyethylene fatty alcohol
Ether and the deionized water of total amount equivalent, stir to form primary emulsion with the speed of 200-300 turn/part, then are sent to rotate
In vaporizer, vacuum be 0.01-0.03MPa, gone out with 70-80 rev/min of speed rotary evaporation at temperature 65-70 DEG C organic
Solvent, obtains mixing latex；
（2）Lanthana, cerium sesquioxide are mixed, in adding 2-2.5 times of concentration that measures for the salpeter solution of 65wt%, stir to
It is completely dissolved, being subsequently adding the ammonium bicarbonate soln with the concentration of nitric acid equivalent for 50wt% carries out precipitation, heavy by obtained
Starch is filtered, and is put in vacuum drying oven and is dried with 60-70 DEG C after deionized water cleaning, and after taking-up, calcination 60-90 minutes, obtain
Arrive modified RE；
（3）Zinc nitrate is mixed with hexamethylenetetramine, 85-90 DEG C is heated to, magnetic agitation 90-120 minute, drum is then placed on
Dry in wind drying machine, obtain nano zine oxide stand-by；Stearic acid is added in the 3-4 times of dehydrated alcohol that measures, ultrasonic disperse 30-
Oleum Cinnamomi, barium metaborate and above-mentioned nano zine oxide are added after 40 minutes, 60-70 DEG C is heated to, continues magnetic agitation 2-3 little
When after stand 50-60 minutes, finally use dehydrated alcohol centrifuge washing, and solid is put in drying baker dries 90- with 80-85 DEG C
120 minutes, obtain modified zinc oxide；
（4）Silane coupler KH560 is dissolved in the 4-5 times of deionized water that measures, step is subsequently adding（2）The product for obtaining, surpasses
Sound adds step after dispersion 30-40 minutes（1）、（3）The product for obtaining, adds remaining residual components after dispersion 10-15 minutes, uses
Mechanical agitation 2-3 hour, is finally putting on grinder and grinds, and crosses 400 mesh sieves and obtains final product.
It is an advantage of the invention that：The present invention adopts water prescription, and safety non-toxic is environmentally friendly, first with chlorosulfonation
Polyethylene latex carries out composite modified with polychloroprene latex, improves fire-retardant, the ageing-resistant performance of coating；By silane coupler
KH560 is added in coating with modified RE compounding, excellent with coating system compatibility performance, and the numerous empty rail of rare earth ion
Road can catch unstable free radical, cause which to lose activity, and be conducive to Stabilization, improve corrosion resistance and resistance to ag(e)ing,
Rare earth ion can also form coordinate bond with the hydroxyl in coating molecule, methylol isopolarity group simultaneously, make coating produce coordination
Polymerization drying, so that improve the quick-drying of paint film.
The present invention generates nano zine oxide using the reaction of zinc nitrate and hexamethylenetetramine, then by add Oleum Cinnamomi,
The compositions such as barium metaborate are compounded, and carry out surface modification by stearic acid, obtain antimildew and antibacterial effect enhanced modified oxidized
Zinc, is added in the preparation of coating, can effectively press down mycostatic generation；The full aqueouss of composite anti-corrosion coating that the present invention makes,
Environmentally friendly, each component cooperative effect is good, and film forming is short for drying time, and flintiness is good, and anti-corrosion is weather-proof, and film adhesive is good, can
For yard piping, metal machinery equipment, chemical industry equipment anti-corrosion, extend service life.
Specific embodiment
A kind of enhanced chloro-sulfonated polyethylene anti-corrosive coating of modified zinc oxide antibacterial and mouldproof, by following weight portion（Kilogram）'s
Raw material is made：Chlorosulfonated polyethylene latex 60, polychloroprene latex 35, polyoxyethylene aliphatic alcohol ether 7, appropriate deionized water, silane idol
Connection agent KH5602.5, lanthana 2, cerium sesquioxide 1.5, concentration for 65wt% salpeter solution is appropriate, concentration for 50wt% carbon
Sour hydrogen ammonium salt solution, Rutile type titanium dioxide 10, aluminium triphosphate 2, Oleum Cinnamomi 5, barium metaborate 3, zinc nitrate 3, six methines four
Amine 3, stearic acid 4, appropriate dehydrated alcohol.
A kind of enhanced chloro-sulfonated polyethylene anti-corrosive coating of modified zinc oxide antibacterial and mouldproof according to claims 1,
It is prepared from by following concrete grammar：
（1）Chlorosulfonated polyethylene latex is mixed with polychloroprene latex, in input emulsator, is subsequently adding, polyoxyethylene fatty alcohol
Ether and the deionized water of total amount equivalent, are stirred to form primary emulsion with the speed of 200 turns/part, then are sent to rotary evaporation
In device, it is 0.01MPa, organic solvent is gone out with 70 revs/min of speed rotary evaporation at 65 DEG C of temperature in vacuum, obtain epoxy glue
Breast；
（2）Lanthana, cerium sesquioxide are mixed, and in the concentration of 2 times of amounts being added for the salpeter solution of 65wt%, are stirred to complete
Dissolving, being subsequently adding the ammonium bicarbonate soln with the concentration of nitric acid equivalent for 50wt% carries out precipitation, by the precipitate for obtaining
Filter, be put in vacuum drying oven after deionized water cleaning and dried with 60 DEG C, calcination 60 minutes after taking-up obtain modified dilute
Soil；
（3）Zinc nitrate is mixed with hexamethylenetetramine, 85 DEG C are heated to, then magnetic agitation 90 minutes is placed on forced air drying
Dry in machine, obtain nano zine oxide stand-by；Stearic acid is added in the dehydrated alcohol of 3 times of amounts, ultrasonic disperse added after 30 minutes
Enter Oleum Cinnamomi, barium metaborate and above-mentioned nano zine oxide, be heated to 60 DEG C, continue magnetic agitation and 50 minutes are stood after 2 hours,
Dehydrated alcohol centrifuge washing is finally used, and solid is put in drying baker with 80 DEG C of dryings 90 minutes, obtain modified zinc oxide；
（4）Silane coupler KH560 is dissolved in the deionized water of 4 times of amounts, step is subsequently adding（2）The product for obtaining, ultrasound
Dispersion added step after 30 minutes（1）、（3）The product for obtaining, dispersion added remaining residual components after 10 minutes, used mechanical agitation
2 hours, it is finally putting on grinder and grinds, crosses 400 mesh sieves and obtain final product.
The coating property of the present embodiment is tested, fineness is less than 50 μm, and adhesive force reaches 1 grade, acid resistance (10% sulfur
Acid) alkali resistance (10% sodium hydroxide) salt water resistance 7 days is non-foaming, do not fall off, non-corrosive.
Claims (2)
1. the enhanced chloro-sulfonated polyethylene anti-corrosive coating of a kind of modified zinc oxide antibacterial and mouldproof, it is characterised in that by following weight
The raw material of part is made：Chlorosulfonated polyethylene latex 60-65, polychloroprene latex 35-40, polyoxyethylene aliphatic alcohol ether 7-8, deionized water
In right amount, silane coupler KH5602.5-3, lanthana 2-3, cerium sesquioxide 1.5-2, concentration are fitted for the salpeter solution of 65wt%
Amount, concentration are the ammonium bicarbonate soln of 50wt%, Rutile type titanium dioxide 10-12, aluminium triphosphate 2-3, Oleum Cinnamomi 5-6, inclined boron
Sour barium 3-4, zinc nitrate 3-4, hexamethylenetetramine 3-4, stearic acid 4-5, appropriate dehydrated alcohol.
2. the enhanced chloro-sulfonated polyethylene anti-corrosive coating of a kind of modified zinc oxide antibacterial and mouldproof according to claims 1, its
It is characterised by, is prepared from by following concrete grammar：
（1）Chlorosulfonated polyethylene latex is mixed with polychloroprene latex, in input emulsator, is subsequently adding, polyoxyethylene fatty alcohol
Ether and the deionized water of total amount equivalent, stir to form primary emulsion with the speed of 200-300 turn/part, then are sent to rotate
In vaporizer, vacuum be 0.01-0.03MPa, gone out with 70-80 rev/min of speed rotary evaporation at temperature 65-70 DEG C organic
Solvent, obtains mixing latex；
（2）Lanthana, cerium sesquioxide are mixed, in adding 2-2.5 times of concentration that measures for the salpeter solution of 65wt%, stir to
It is completely dissolved, being subsequently adding the ammonium bicarbonate soln with the concentration of nitric acid equivalent for 50wt% carries out precipitation, heavy by obtained
Starch is filtered, and is put in vacuum drying oven and is dried with 60-70 DEG C after deionized water cleaning, and after taking-up, calcination 60-90 minutes, obtain
Arrive modified RE；
（3）Zinc nitrate is mixed with hexamethylenetetramine, 85-90 DEG C is heated to, magnetic agitation 90-120 minute, drum is then placed on
Dry in wind drying machine, obtain nano zine oxide stand-by；Stearic acid is added in the 3-4 times of dehydrated alcohol that measures, ultrasonic disperse 30-
Oleum Cinnamomi, barium metaborate and above-mentioned nano zine oxide are added after 40 minutes, 60-70 DEG C is heated to, continues magnetic agitation 2-3 little
When after stand 50-60 minutes, finally use dehydrated alcohol centrifuge washing, and solid is put in drying baker dries 90- with 80-85 DEG C
120 minutes, obtain modified zinc oxide；
（4）Silane coupler KH560 is dissolved in the 4-5 times of deionized water that measures, step is subsequently adding（2）The product for obtaining, surpasses
Sound adds step after dispersion 30-40 minutes（1）、（3）The product for obtaining, adds remaining residual components after dispersion 10-15 minutes, uses
Mechanical agitation 2-3 hour, is finally putting on grinder and grinds, and crosses 400 mesh sieves and obtains final product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611010899.0A CN106497246A (en) | 2016-11-17 | 2016-11-17 | A kind of enhanced chloro-sulfonated polyethylene anti-corrosive coating of modified zinc oxide antibacterial and mouldproof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611010899.0A CN106497246A (en) | 2016-11-17 | 2016-11-17 | A kind of enhanced chloro-sulfonated polyethylene anti-corrosive coating of modified zinc oxide antibacterial and mouldproof |
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| CN106497246A true CN106497246A (en) | 2017-03-15 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101311119A (en) * | 2007-05-25 | 2008-11-26 | 中国科学院合肥物质科学研究院 | Reticular nano hole zinc oxide micron hollow ball and preparation method thereof |
| CN105462379A (en) * | 2015-12-02 | 2016-04-06 | 铜陵市肆得科技有限责任公司 | Special water-borne rust-associated anti-rust coating having antibacterial and antifungal functions and applied to pump valve |
| CN106118524A (en) * | 2016-06-24 | 2016-11-16 | 合肥得润电子器件有限公司 | The micropore radiating insulating binder that a kind of waterproof mildew-resistant strengthens |
-
2016
- 2016-11-17 CN CN201611010899.0A patent/CN106497246A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101311119A (en) * | 2007-05-25 | 2008-11-26 | 中国科学院合肥物质科学研究院 | Reticular nano hole zinc oxide micron hollow ball and preparation method thereof |
| CN105462379A (en) * | 2015-12-02 | 2016-04-06 | 铜陵市肆得科技有限责任公司 | Special water-borne rust-associated anti-rust coating having antibacterial and antifungal functions and applied to pump valve |
| CN106118524A (en) * | 2016-06-24 | 2016-11-16 | 合肥得润电子器件有限公司 | The micropore radiating insulating binder that a kind of waterproof mildew-resistant strengthens |
Non-Patent Citations (3)
| Title |
|---|
| 张兆玉等: "《新编化工产品配方工艺手册》", 31 March 1997, 吉林科学技术出版社 * |
| 曹鸿璋等: ""稀土助剂改性水性氯磺化聚乙烯防腐涂料性能研究"", 《稀土》 * |
| 董永春: "《纺织助剂化学》", 31 January 2010, 上海东华大学出版社 * |
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