CN106752420A - A kind of chlorosulfonation base ethene composite anticorrosion coating for adding organic Modification of Montmorillonite zinc powder - Google Patents

A kind of chlorosulfonation base ethene composite anticorrosion coating for adding organic Modification of Montmorillonite zinc powder Download PDF

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Publication number
CN106752420A
CN106752420A CN201611010843.5A CN201611010843A CN106752420A CN 106752420 A CN106752420 A CN 106752420A CN 201611010843 A CN201611010843 A CN 201611010843A CN 106752420 A CN106752420 A CN 106752420A
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zinc powder
montmorillonite
minutes
concentration
chlorosulfonation
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闻承岳
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • C09D123/32—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
    • C09D123/34—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur by chlorosulfonation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/10—Anti-corrosive paints containing metal dust
    • C09D5/106—Anti-corrosive paints containing metal dust containing Zn
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of chlorosulfonation base ethene composite anticorrosion coating for adding organic Modification of Montmorillonite zinc powder, it is made from the following raw materials in parts by weight：Chlorosulfonated polyethylene latex 60 65, polychloroprene latex 35 40, polyoxyethylene aliphatic alcohol ether 78, appropriate deionized water, silane coupler KH5602.5 3, lanthana 23, cerium sesquioxide 1.5 2, concentration are for the salpeter solution of 65wt% is appropriate, concentration is ammonium bicarbonate soln, rutile type titanium white 10 12, methyl acrylate 1 1.5, calgon 0.8 1, flake zinc powder 67, organic montmorillonite 34, Ludox 8 9.5, the potassium hydroxide 1 1.2 of 50wt%.The paint machine excellent performance that the present invention is made, the surface adhesion forces such as metal are good, covering power, floating capacity and screening ability advantages, antiseptic property is excellent, and process is simple is easy to Industry Control, is worthy to be popularized.

Description

A kind of chlorosulfonation base ethene composite anticorrosion coating for adding organic Modification of Montmorillonite zinc powder
Technical field
Answered the present invention relates to technical field, more particularly to a kind of chlorosulfonation base ethene for adding organic Modification of Montmorillonite zinc powder Close anticorrosive paint.
Background technology
Corrosion and corrosion protection is the industry distinct issues such as chemical industry, light industry, metallurgy, electric power, weaving, printing and dyeing, ship processed, building. Caused damage because of corrosion every year huge, anticorrosive work is particularly important, chloro-sulfonated polyethylene anti-corrosive coating, with excellent Good rotproofness, particularly splendid pliability, is used widely, once once deep by people in the industry along with inexpensive The favor of scholar.With developing rapidly for modern industry level, propose that higher, tightened up to bear environment rotten to anticorrosive paint The ability of erosion.The antiseptic property of the chlorosulfonated polythylene coatings of conventional formulation production is typically extremely difficult to require.Conventional chlorine sulphur It is mostly solvent type to change polyethylene anti-corrosion coating, not only causes the waste of a large amount of solvents, and solvent for use is poisonous, Yi Hui Hair, pollutes to environment, does not meet environmental requirement, and water paint has technique cleaning, advanced technology, low emission, low energy Consumption, safe and harmless advantage, therefore, research hydrophilic chlorosulfonated polyethylene anticorrosive coating has great social benefit and economy Benefit.
《The development of water chlorosulfonated polyethylene anti-corrosion coatings》With chlorosulfonated polyethylene latex and water-base epoxy tree in one text Fat is compounded, and water-based anticorrosive paint is made by evaporating kettle removed under reduced pressure solvent, and the coating property being made is excellent, strong adaptability, is applied Nonpoisonous and tasteless during brush, nonflammable, production process is simple, easy construction.Due to the addition of aqueous epoxy resins, painting is improve Corrosion Protection is reduced while the adhesive force of material, it is impossible to be effectively improved the combination property of chlorosulfonated polyethylene, Gu need Hydrophilic chlorosulfonated polyethylene coating is further modified, to meet the demand of industry development.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of organic Modification of Montmorillonite zinc powder of addition Chlorosulfonation base ethene composite anticorrosion coating.
The present invention is achieved by the following technical solutions：
A kind of chlorosulfonation base ethene composite anticorrosion coating for adding organic Modification of Montmorillonite zinc powder, by the raw material system of following weight portion Into：Chlorosulfonated polyethylene latex 60-65, polychloroprene latex 35-40, polyoxyethylene aliphatic alcohol ether 7-8, appropriate deionized water, silane Coupling agent KH5602.5-3, lanthana 2-3, cerium sesquioxide 1.5-2, concentration are for the salpeter solution of 65wt% is appropriate, concentration is The ammonium bicarbonate soln of 50wt%, rutile type titanium white 10-12, methyl acrylate 1-1.5, calgon 0.8-1, scale Shape zinc powder 6-7, organic montmorillonite 3-4, Ludox 8-9.5, potassium hydroxide 1-1.2.
A kind of chlorosulfonation base ethene composite anti-corrosive for adding organic Modification of Montmorillonite zinc powder is applied according to claims 1 Material, is prepared from by following specific method：
（1）Chlorosulfonated polyethylene latex is mixed with polychloroprene latex, in input emulsifier, is subsequently adding, polyoxyethylene fatty alcohol The deionized water of ether and total amount equivalent, stirs to form primary emulsion with the speed of 200-300 turns/part, then is sent to rotation In evaporator, gone out with 70-80 revs/min of speed rotary evaporation in the case where vacuum is 0.01-0.03MPa, 65-70 DEG C of temperature organic Solvent, obtains mixing latex；
（2）Lanthana, cerium sesquioxide are mixed, the 2-2.5 times of concentration measured is added in the salpeter solution of 65wt%, stirring is extremely It is completely dissolved, is subsequently adding the concentration with nitric acid equivalent for the ammonium bicarbonate soln of 50wt% carries out precipitation reaction, it is heavy by what is obtained Starch is filtered, and is put into after being cleaned with deionized water in vacuum drying chamber with 60-70 DEG C of drying, calcination 60-90 minutes after taking-up, is obtained To modified RE；
（3）It is stand-by by potassium hydroxide solution is formed in 6-7 times of deionized water measured of potassium hydroxide solution, then Ludox is heated To 60-70 DEG C, constant temperature adds above-mentioned potassium hydroxide solution while stirring after stirring 30-40 minutes, with 300-400 revs/min of speed Degree stirring adds flake zinc powder, organic montmorillonite after 10-15 minutes, continues to stir 40-50 minutes under constant temperature, obtains mixing slurry Material；
（4）Silane coupler KH560 is dissolved in the 4-5 times of deionized water measured, step is subsequently adding（2）The product for obtaining, surpasses Sound adds step after disperseing 30-40 minutes（1）、（3）The product for obtaining, dispersion adds remaining residual components after 10-15 minutes, uses Mechanical agitation 2-3 hours, it is finally putting on grinder and grinds, crosses 400 mesh sieves and obtain final product.
It is an advantage of the invention that：The present invention uses water prescription, and safety non-toxic is environmentally friendly, first with chlorosulfonation Polyethylene latex carries out composite modified with polychloroprene latex, improves fire-retardant, the ageing-resistant performance of coating；By silane coupler KH560 and modified RE compounding are added in coating, excellent with coating system compatibility performance, and rare earth ion numerous empty rail Road can catch unstable free radical, cause it to lose activity, and be conducive to stabilization, improve corrosion resistance and resistance to ag(e)ing, Rare earth ion can also form coordinate bond with the hydroxyl in coating molecule, methylol isopolarity group simultaneously, coating is produced coordination Polymerization drying, so as to improve the quick-drying of paint film.
The present invention is mixed the compositions such as Ludox and organo montmorillonite by a series of reaction, then is answered with flake zinc powder Match somebody with somebody, the moisture dispersibility of zinc powder can be improved, so as to improve the mechanical strength of coating and the slickness of film；Present invention system Into paint machine excellent performance, the surface adhesion forces such as metal are good, covering power, floating capacity and screening ability advantage are prominent Go out, antiseptic property is excellent, process is simple is easy to Industry Control, be worthy to be popularized.
Specific embodiment
A kind of chlorosulfonation base ethene composite anticorrosion coating for adding organic Modification of Montmorillonite zinc powder, by following weight portion（It is public Jin）Raw material be made：Chlorosulfonated polyethylene latex 60, polychloroprene latex 35, polyoxyethylene aliphatic alcohol ether 7, appropriate deionized water, silicon Alkane coupling agent KH5602.5, lanthana 2, cerium sesquioxide 1.5, concentration are for the salpeter solution of 65wt% is appropriate, concentration is 50wt% Ammonium bicarbonate soln, rutile type titanium white 10, methyl acrylate 1, calgon 0.8, flake zinc powder 6, You Jimeng De- stone 3, Ludox 8, potassium hydroxide 1.
A kind of chlorosulfonation base ethene composite anti-corrosive for adding organic Modification of Montmorillonite zinc powder is applied according to claims 1 Material, is prepared from by following specific method：
（1）Chlorosulfonated polyethylene latex is mixed with polychloroprene latex, in input emulsifier, is subsequently adding, polyoxyethylene fatty alcohol The deionized water of ether and total amount equivalent, stirs to form primary emulsion, then be sent to rotary evaporation with the speed of 200 turns/part In device, organic solvent is gone out with 70 revs/min of speed rotary evaporation in the case where vacuum is 0.01MPa, 65 DEG C of temperature, obtain epoxy glue Breast；
（2）Lanthana, cerium sesquioxide are mixed, 2 times of concentration of amount is added in the salpeter solution of 65wt%, stirring is to complete Dissolving, is subsequently adding the concentration with nitric acid equivalent for the ammonium bicarbonate soln of 50wt% carries out precipitation reaction, the sediment that will be obtained Filtering, is put into vacuum drying chamber with 60 DEG C of drying after being cleaned with deionized water, and calcination 60 minutes after taking-up obtain modified dilute Soil；
（3）It is stand-by by potassium hydroxide solution is formed in 6 times of deionized waters of amount of potassium hydroxide solution, then Ludox is heated to 60 DEG C, constant temperature adds above-mentioned potassium hydroxide solution while stirring after stirring 30 minutes, is stirred 10 minutes with 300 revs/min of speed Flake zinc powder, organic montmorillonite are added afterwards, continues to stir 40 minutes under constant temperature, obtain mixed slurry；
（4）Silane coupler KH560 is dissolved in 4 times of deionized waters of amount, step is subsequently adding（2）The product for obtaining, ultrasound Dispersion adds step after 30 minutes（1）、（3）The product for obtaining, dispersion adds remaining residual components after 10 minutes, uses mechanical agitation 2 hours, it is finally putting on grinder and grinds, crosses 400 mesh sieves and obtain final product.
Coating property to the present embodiment is tested, and fineness is less than 50 μm, and adhesive force reaches 1 grade, acid resistance (10% sulphur Acid) alkali resistance (10% NaOH) salt water resistance 7 days is non-foaming, do not fall off, non-corrosive.

Claims (2)

1. a kind of chlorosulfonation base ethene composite anticorrosion coating for adding organic Modification of Montmorillonite zinc powder, it is characterised in that by following The raw material of weight portion is made：Chlorosulfonated polyethylene latex 60-65, polychloroprene latex 35-40, polyoxyethylene aliphatic alcohol ether 7-8, go from Sub- appropriate amount of water, silane coupler KH5602.5-3, lanthana 2-3, cerium sesquioxide 1.5-2, concentration are the salpeter solution of 65wt% In right amount, concentration is ammonium bicarbonate soln, rutile type titanium white 10-12, methyl acrylate 1-1.5, the calgon of 50wt% 0.8-1, flake zinc powder 6-7, organic montmorillonite 3-4, Ludox 8-9.5, potassium hydroxide 1-1.2.
2. a kind of chlorosulfonation base ethene composite anti-corrosive for adding organic Modification of Montmorillonite zinc powder is applied according to claims 1 Material, it is characterised in that be prepared from by following specific method：
（1）Chlorosulfonated polyethylene latex is mixed with polychloroprene latex, in input emulsifier, is subsequently adding, polyoxyethylene fatty alcohol The deionized water of ether and total amount equivalent, stirs to form primary emulsion with the speed of 200-300 turns/part, then is sent to rotation In evaporator, gone out with 70-80 revs/min of speed rotary evaporation in the case where vacuum is 0.01-0.03MPa, 65-70 DEG C of temperature organic Solvent, obtains mixing latex；
（2）Lanthana, cerium sesquioxide are mixed, the 2-2.5 times of concentration measured is added in the salpeter solution of 65wt%, stirring is extremely It is completely dissolved, is subsequently adding the concentration with nitric acid equivalent for the ammonium bicarbonate soln of 50wt% carries out precipitation reaction, it is heavy by what is obtained Starch is filtered, and is put into after being cleaned with deionized water in vacuum drying chamber with 60-70 DEG C of drying, calcination 60-90 minutes after taking-up, is obtained To modified RE；
（3）It is stand-by by potassium hydroxide solution is formed in 6-7 times of deionized water measured of potassium hydroxide solution, then Ludox is heated To 60-70 DEG C, constant temperature adds above-mentioned potassium hydroxide solution while stirring after stirring 30-40 minutes, with 300-400 revs/min of speed Degree stirring adds flake zinc powder, organic montmorillonite after 10-15 minutes, continues to stir 40-50 minutes under constant temperature, obtains mixing slurry Material；
（4）Silane coupler KH560 is dissolved in the 4-5 times of deionized water measured, step is subsequently adding（2）The product for obtaining, surpasses Sound adds step after disperseing 30-40 minutes（1）、（3）The product for obtaining, dispersion adds remaining residual components after 10-15 minutes, uses Mechanical agitation 2-3 hours, it is finally putting on grinder and grinds, crosses 400 mesh sieves and obtain final product.
CN201611010843.5A 2016-11-17 2016-11-17 A kind of chlorosulfonation base ethene composite anticorrosion coating for adding organic Modification of Montmorillonite zinc powder Withdrawn CN106752420A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115637073A (en) * 2022-11-08 2023-01-24 河南兴安新型建筑材料有限公司 Nano-coated aerated concrete reinforcement preservative and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101525505A (en) * 2009-04-03 2009-09-09 河海大学 Watery zinc-aluminium heavy-duty coating in compounding squama shape and preparation method thereof
CN103756377A (en) * 2014-01-22 2014-04-30 沈阳工业大学 Modified silicate waterborne zinc-rich anticorrosive coating employing organic montmorillonite as anti-settling dispersant
CN105761866A (en) * 2016-04-13 2016-07-13 天长市天豪制冷设备厂 High-performance nano lithium-zinc ferrite core material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101525505A (en) * 2009-04-03 2009-09-09 河海大学 Watery zinc-aluminium heavy-duty coating in compounding squama shape and preparation method thereof
CN103756377A (en) * 2014-01-22 2014-04-30 沈阳工业大学 Modified silicate waterborne zinc-rich anticorrosive coating employing organic montmorillonite as anti-settling dispersant
CN105761866A (en) * 2016-04-13 2016-07-13 天长市天豪制冷设备厂 High-performance nano lithium-zinc ferrite core material

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张兆玉等: "《新编化工产品配方工艺手册》", 31 March 1997, 吉林科学技术出版社 *
曹鸿璋等: "稀土助剂改性水性氯磺化聚乙烯防腐涂料性能研究", 《稀土》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115637073A (en) * 2022-11-08 2023-01-24 河南兴安新型建筑材料有限公司 Nano-coated aerated concrete reinforcement preservative and preparation method thereof

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