CN106496823A - A kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type and preparation method - Google Patents
A kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type and preparation method Download PDFInfo
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- CN106496823A CN106496823A CN201610881609.3A CN201610881609A CN106496823A CN 106496823 A CN106496823 A CN 106496823A CN 201610881609 A CN201610881609 A CN 201610881609A CN 106496823 A CN106496823 A CN 106496823A
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- chlorinated polyethylene
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- polyethylene rubber
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/286—Chlorinated polyethylene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
Abstract
The present invention relates to one kind had both had cold resistant property, there is flame-retarding characteristic again, and also be compliant with a kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type of RoHS, REACH and PAHs environmental regulation requirement and preparation method, in parts by mass：100 parts of chlorinated polyethylene rubber, 6～12 parts of DOA, 6～12 parts of DOS, 5～10 parts of antimony oxide, 70～90 parts of inorganic filler, 20～30 parts of reinforcing agent, 2～4 parts of lubricant, 2～4 parts of age resistor, 10～15 parts of activating agent, 2～4 parts of auxiliary curing agent, 2～4 parts of tasteless vulcanizing agent.Advantage：One is that the environment-friendly type of the present invention resists cold fire-retardant chlorinated polyethylene rubber sheath material not only with excellent tolerance to cold and anti-flammability, but also with excellent mechanical property, physical and mechanical propertiess and processing characteristics, fully achieve the performance standard of cold-resistant fire-retardant Plastic-sheathed Cable protective cover material；Two is that the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type of the invention meets RoHS, REACH and PAHs environmental regulation requirement, and will not give off an unpleasant smell in process of manufacture.
Description
Technical field
The present invention relates to a kind of not only had cold resistant property but also the environment friendly chlorinated polyethylene rubber sheath with flame-retarding characteristic
Material and preparation method, category electric insulation macromolecular material manufacture field.
Background technology
CN103923403A, title " a kind of electric wire LSOH anti-flaming rubber and preparation method thereof ", its by with
The raw material of lower weight portion is made：100～150 parts of ethylene propylene diene rubber, 45～65 parts of methyl vinyl silicone rubber, nylon 1010
30～50 parts, 15～25 parts of grafting maleic anhydride with ethylene propylene terpolymer, 2～4 parts of tert-butyl catechol, terpene resin 5～10
Part, 4～6 parts of rosin glyceride, 10～15 parts of tall oil, 3～5 parts of zinc oxide, 1～2 part of stearic acid, antioxidant 4010NA 1.5
～2.5 parts, 1,076 1～2 parts of age resistor, 2～3 parts of diphenylguanidine TDM, 1～2 part of accelerator DZ, 16～22 parts of magnesium hydroxide,
10～15 parts of mica powder.Its weak point：Using magnesium hydroxide single component flame retardant agent, flame retardant effect is bad, and its resistance to electric arc
Performance is also be not as good as aluminium hydroxide；Ethylene propylene diene rubber and methyl vinyl silicone rubber is expensive, addition big, prepared
Rubber mass cost is just very high.
Content of the invention
Purpose of design：The weak point in background technology is avoided, design is a kind of not only to have been had cold resistant property but also there is fire-retardant spy
The environment friendly chlorinated polyethylene rubber protective cover material of property and preparation method.
Design：In order to realize above-mentioned purpose of design.The present invention using chlorinated polyethylene rubber as matrix material, with
Dioctyl adipate（DOA）And di-n-octyl sebacate（DOS）For composite elasticizer, with environment-friendly type antimony oxide as fire retardant,
With environment-friendly type white carbon black as reinforcing agent, have developed a kind of cold tolerance and all extraordinary Plastic-sheathed Cable of fire resistance is protected with environment-friendly type
Cover material.1st, add the design of the composite elasticizer being made up of DOA and DOS in chlorinated polyethylene rubber, be the skill of the present invention
One of art feature.The purpose of so design is：DOA and DOS belong to cold resisting type plasticizer, and cold tolerance is excellent, and works as DOA
Simultaneously then there is good cooperative effect the used time with DOS, can further improve the cold tolerance of sizing material.2nd, in chlorinated polyethylene rubber
The middle environment-friendly type antimony oxide that adds, as the design of fire retardant, is the two of technical characteristic of the invention.The purpose for so designing
It is：Antimony oxide is a kind of addition type inorganic combustion inhibitor, and large usage quantity during exclusive use, flame retardant effect are poor, and work as its with
Halogen compounds（Such as chlorinated polyethylene）And then there is good cooperative effect the used time, significantly improve flame retardant effect.3rd, in chlorination
Add environment-friendly type white carbon black in polyethylene rubber as the design of reinforcing agent, be the three of technical characteristic of the invention.So design
Purpose is：White carbon black can strengthen the mechanical property of sizing material so as to good mechanical property.4th, in chlorinated polyethylene rubber
Middle add tasteless vulcanizing agent dual-tert-butyl cumene hydroperoxide（BIPB）Design, be the present invention technical characteristic four.This
The purpose of sample design is：Conventional vulcanization agent cumyl peroxide（DCP）Can give out in process of manufacture unpleasant
Abnormal smells from the patient, and tasteless vulcanizing agent BIPB will not give off an unpleasant smell in process of manufacture, more environmentally-friendly.5th, poly- in chlorination
Add the design of anti-aging agent RD and MB in ethylene rubber, be the five of technical characteristic of the invention.The purpose of so design is：RD
It is used in conjunction with two kinds of age resistor of MB, cooperative effect can be produced, so as to improves the heat aging performance of sizing material.6th, in chlorinated polyethylene
Add auxiliary curing agent Triallyl isocyanurate in alkene rubber（TAIC）Design, be the present invention technical characteristic six.This
The purpose of sample design is：It can shorten the cure time of chlorinated polyethylene rubber, make sulfuration more abundant, it can be ensured which has
There are good physical and mechanical propertiess.7th, add paraffin in chlorinated polyethylene rubber as the design of lubricant, be of the invention
The seven of technical characteristic.The purpose of so design is：The lubricant that paraffin is used as cable sheath material, in process of manufacture
In not only can accelerate the diffusion of filler, improve extrusion molding speed, increase mould flow, and the easily demoulding.8th, this
The design of bright integral material scheme, is the eight of technical characteristic of the invention.The purpose of so design is：The present invention is poly- with chlorination
Ethylene rubber is base material, by scientific design and test, in 100 parts of chlorinated polyethylene rubbers, add 6～12 parts of DOA, 6～
12 parts of DOS, 5～10 parts of antimony oxides, 70～90 parts of inorganic fillers, 20～30 portions of reinforcing agents, 2～4 parts of lubricants, 2～4 parts
Age resistor, 10～15 parts of activating agents, 2～4 parts of auxiliary curing agents, 2～4 parts of tasteless vulcanizing agents, not only avoid between material due to
Choosing amount is not mutually exclusive caused by science, and promotes mutually coordinated between each composition and promote, and makes the material of compounding
Performance can fully meet the purpose of design of the present invention.
Technical scheme 1：A kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type, in parts by mass：Chlorinated polyethylene
100 parts, 6～12 parts DOA of alkene rubber, 6～12 parts of DOS, 5～10 parts of antimony oxides, 70～90 parts of inorganic fillers, 20～30 parts
Reinforcing agent, 2～4 parts of lubricants, 2～4 parts of age resistor, 10～15 parts of activating agents, 2～4 parts of auxiliary curing agents, 2～4 parts of tasteless sulfurations
Agent.
Technical scheme 2：A kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath preparation method for material of environment-friendly type, will using banbury
100 parts of chlorinated polyethylene rubbers, 6～12 parts of DOA, 6～12 parts of DOS, 5～10 parts of antimony oxides, 70～90 parts of inorganic fillers,
20～30 portions of reinforcing agents, 2～4 parts of lubricants, 2～4 parts of age resistor, 10～15 portions of activating agents, 2～4 parts of auxiliary curing agents, 2～4 parts
Tasteless vulcanizing agent end count is refined, and mixing time is 10～20 minutes, and the temperature of banbury is 90～110 DEG C, and main frame electric current is
80～120A；Sample is vulcanized using vulcanizing press, and vulcanizing press temperature is 172～177 DEG C, and pressure is 14～16MPa, when
Between be 9～11min.
Compared with background technology, one is that the environment-friendly type of the present invention resists cold fire-retardant chlorinated polyethylene rubber sheath material not to the present invention
Only there is excellent tolerance to cold and anti-flammability, but also with excellent mechanical property, physical and mechanical propertiess and processing characteristics, complete
The performance standard of cold-resistant fire-retardant Plastic-sheathed Cable protective cover material can be reached entirely；Two is that the environment-friendly type of the present invention resists cold fire-retardant chlorinated gathering
Ethylene rubber protective cover material meets RoHS, REACH and PAHs environmental requirement, and will not give out in process of manufacture unpleasant
Abnormal smells from the patient.
Specific embodiment
Embodiment 1：A kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type, is characterized in that in parts by mass：Chlorine
Change 100 parts, 6～12 parts DOA of polyethylene rubber, 6～12 parts of DOS, 5～10 parts of antimony oxides, 70～90 parts of inorganic fillers, 20
～30 parts of reinforcing agents, 2～4 parts of lubricants, 2～4 parts of age resistor, 10～15 parts of activating agents, 2～4 parts of auxiliary curing agents, 2～4 parts of nothings
Taste vulcanizing agent.The chlorinity of the chlorinated polyethylene rubber is 35% ± 1%, and meeting RoHS, REACH and PAHs environmental regulation will
Ask.The antimony oxide is environment-friendly type antimony oxide, meets RoHS environmental regulation requirements.The inorganic filler is Pulvis Talci
And Calcium Carbonate.The reinforcing agent is environment-friendly type white carbon black, meets PAHs environmental regulation requirements.The lubricant is paraffin.Described anti-
Old agent is RD and MB.The activating agent is light magnesium oxide.The auxiliary curing agent is TAIC.The tasteless vulcanizing agent is BIPB.
Embodiment 2：On the basis of embodiment 1,100 parts, 6 parts DOA of chlorinated polyethylene rubber, 6 parts of DOS, 5 part of three oxidation
Two antimony, 70 parts of inorganic fillers, 20 parts of reinforcing agents, 2 parts of lubricants, 2 parts of age resistor, 10 parts of activating agents, 2 parts of auxiliary curing agents, 2 parts of nothings
Taste vulcanizing agent.
Embodiment 3：On the basis of embodiment 1,100 parts, 12 parts DOA of chlorinated polyethylene rubber, 12 parts of DOS, 10 part three
Aoxidize two antimony, 90 parts of inorganic fillers, 30 portions of reinforcing agents, 4 parts of lubricants, 4 parts of age resistor, 15 portions of activating agents, 4 parts of auxiliary curing agents, 4
The tasteless vulcanizing agent of part.
Embodiment 4：On the basis of embodiment 1,100 parts, 9 parts DOA of chlorinated polyethylene rubber, 9 parts of DOS, 7.5 part of three oxygen
Change two antimony, 80 parts of inorganic fillers, 25 portions of reinforcing agents, 3 parts of lubricants, 3 parts of age resistor, 12.5 portions of activating agents, 3 parts of auxiliary curing agents, 3
The tasteless vulcanizing agent of part.
Embodiment 5：On the basis of embodiment 1, prepared by a kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type
Method, using banbury by 100 parts of chlorinated polyethylene rubbers, 6～12 parts of DOA, 6～12 parts of DOS, 5～10 parts of antimony oxides,
70～90 parts of inorganic fillers, 20～30 portions of reinforcing agents, 2～4 parts of lubricants, 2～4 parts of age resistor, 10～15 portions of activating agents, 2～4
Part auxiliary curing agent, 2～4 parts of tasteless vulcanizing agent end count are refined, and mixing time is 10～20 minutes, and the temperature of banbury is 90～
110 DEG C, main frame electric current is 80～120A；Sample is vulcanized using vulcanizing press, and vulcanizing press temperature is 172～177 DEG C, pressure
Power 14 is～16MPa, and the time is 9～11min.
Embodiment 6：On the basis of embodiment 5, vulcanizing press temperature is 175 DEG C, and pressure is 15MPa, and the time is
10min
Embodiment 7：On the basis of embodiment 1 and 5,100 parts of chlorinated polyethylene rubber, 9 parts of DOA, DOS 9 is accurately weighed
Part, 7.5 parts of antimony oxide, inorganic filler Pulvis Talci/Calcium Carbonate=60:20 parts, 25 parts of reinforcing agent environment-friendly type white carbon black, lubrication
3 parts of agent paraffin, anti-aging agent RD/MB=1.5：1.5 parts, 12.5 parts of activating agent light magnesium oxide, 3 parts of auxiliary curing agent TAIC, tasteless
3 parts of vulcanizing agent BIPB.Of the present invention environment-friendly type cold-resistant fire-retardant chlorinated polyethylene rubber sheath material is finally obtained, and stretching is strong
Spend for 10.8MPa, elongation at break is 350%, brittle temperature is -35 DEG C, and oxygen index (OI) is 30%, meet RoHS, REACH and
PAHs environmental regulations are required, and will not be given off an unpleasant smell in process of manufacture.
It is to be understood that：Although above-described embodiment is contrasted to the mentality of designing of the present invention, detailed word is retouched
State, but these word descriptions, simply the simple text of mentality of designing of the present invention is described, rather than to mentality of designing of the present invention
Restriction, any combination, increase or modification without departing from mentality of designing of the present invention each fallen within protection scope of the present invention.
Claims (12)
1. a kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type, is characterized in that in parts by mass：Chlorinated polyethylene rubber
100 parts of glue, 6～12 parts of DOA, 6～12 parts of DOS, 5～10 parts of antimony oxide, 70～90 parts of inorganic filler, reinforcing agent 20～
30 parts, 2～4 parts of lubricant, 2～4 parts of age resistor, 10～15 parts of activating agent, 2～4 parts of auxiliary curing agent, tasteless vulcanizing agent 2～4
Part.
2. the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type according to claim 1, is characterized in that：The chlorination
The chlorinity of polyethylene rubber is 35% ± 1%, meets RoHS, REACH and PAHs environmental regulation requirement.
3. the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type according to claim 1, is characterized in that：Three oxygen
Change two antimony for environment-friendly type antimony oxide, meet RoHS environmental regulation requirements.
4. the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type according to claim 1, is characterized in that：Described inorganic
Filler is Pulvis Talci and Calcium Carbonate.
5. the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type according to claim 1, is characterized in that：The reinforcement
Agent is environment-friendly type white carbon black, meets PAHs laws and regulations requirements.
6. the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type according to claim 1, is characterized in that：The lubrication
Agent is paraffin.
7. the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type according to claim 1, is characterized in that：Described anti-old
Agent is RD and MB.
8. the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type according to claim 1, is characterized in that：The activity
Agent is light magnesium oxide.
9. the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type according to claim 1, is characterized in that：Described help sulfur
Agent is Triallyl isocyanurate（TAIC）.
10. the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type according to claim 1, is characterized in that：The sulfur
Agent is dual-tert-butyl cumene hydroperoxide（BIPB）.
A kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath preparation method for material of 11. environment-friendly types, is characterized in that：Will using banbury
100 parts of chlorinated polyethylene rubbers, 6～12 parts of DOA, 6～12 parts of DOS, 5～10 parts of antimony oxides, 70～90 parts of inorganic fillers,
20～30 portions of reinforcing agents, 2～4 parts of lubricants, 2～4 parts of age resistor, 10～15 portions of activating agents, 2～4 parts of auxiliary curing agents, 2～4 parts
Tasteless vulcanizing agent end count is refined, and mixing time is 10～20 minutes, and the temperature of banbury is 90～110 DEG C, and main frame electric current is
80～120A；Sample is vulcanized using vulcanizing press, and vulcanizing press temperature is 172～177 DEG C, and pressure is 14～16MPa, when
Between be 9～11min.
The cold-resistant fire-retardant chlorinated polyethylene rubber sheath preparation method for material of 12. environment-friendly types according to claim 11, its feature
It is：The tensile strength of the cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type is 10.8MPa, and elongation at break is 350%, low
Warm brittle temperature is -35 DEG C, and oxygen index (OI) is 30%, meets RoHS, REACH and PAHs environmental regulation requirement.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610881609.3A CN106496823A (en) | 2016-10-10 | 2016-10-10 | A kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610881609.3A CN106496823A (en) | 2016-10-10 | 2016-10-10 | A kind of cold-resistant fire-retardant chlorinated polyethylene rubber sheath material of environment-friendly type and preparation method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107200945A (en) * | 2017-07-27 | 2017-09-26 | 芜湖融汇化工有限公司 | A kind of tasteless type cable cover(ing) sizing material and preparation method thereof |
| CN107286485A (en) * | 2017-07-27 | 2017-10-24 | 芜湖融汇化工有限公司 | A kind of tear-proof type cable cover(ing) sizing material and preparation method thereof |
| CN107383647A (en) * | 2017-07-31 | 2017-11-24 | 安徽新智电力科技有限公司 | A kind of Ultraviolet-resistancable cable sheath material and preparation method thereof |
| CN108129762A (en) * | 2017-12-06 | 2018-06-08 | 淮北市天相电缆有限责任公司 | A kind of novel environment-friendly cable insulation protective cover material |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101221836A (en) * | 2007-12-21 | 2008-07-16 | 江苏中煤电缆集团有限公司 | Low temperature resistant anti-crack rubber sleeve flexible cable used for wind power generation |
| CN101597410A (en) * | 2009-07-02 | 2009-12-09 | 俞国麟 | Grease proofing, fire-retardant chlorinated polyethylene sheath material of good weatherability and preparation method thereof |
| CN102702629A (en) * | 2012-05-03 | 2012-10-03 | 广东日丰电缆股份有限公司 | Flame-retardant heat-resistant wear-resistant radiation cross-linking chlorinated polyethylene rubber and preparation method thereof |
| CN103589101A (en) * | 2013-11-21 | 2014-02-19 | 无锡市明珠电缆有限公司 | Chlorinated polyethylene rubber for environment-friendly, flame-retardant and low-temperature-resistant wind energy cable, and preparation method |
| CN103613870A (en) * | 2013-11-18 | 2014-03-05 | 无锡市沪安电线电缆有限公司 | Preparation method of environmental low temperature resistant and acid and alkali resistant cable sheath rubbers |
| CN105001539A (en) * | 2015-07-29 | 2015-10-28 | 傅兴琴 | Preparation method of cold-resistant and flame-retardant cable sheath material |
| CN105385052A (en) * | 2015-09-23 | 2016-03-09 | 南京七四二五橡塑有限责任公司 | Rubber composition of low-temperature resistant environmentally-friendly chlorinated polyethylene and preparation method thereof |
-
2016
- 2016-10-10 CN CN201610881609.3A patent/CN106496823A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101221836A (en) * | 2007-12-21 | 2008-07-16 | 江苏中煤电缆集团有限公司 | Low temperature resistant anti-crack rubber sleeve flexible cable used for wind power generation |
| CN101597410A (en) * | 2009-07-02 | 2009-12-09 | 俞国麟 | Grease proofing, fire-retardant chlorinated polyethylene sheath material of good weatherability and preparation method thereof |
| CN102702629A (en) * | 2012-05-03 | 2012-10-03 | 广东日丰电缆股份有限公司 | Flame-retardant heat-resistant wear-resistant radiation cross-linking chlorinated polyethylene rubber and preparation method thereof |
| CN103613870A (en) * | 2013-11-18 | 2014-03-05 | 无锡市沪安电线电缆有限公司 | Preparation method of environmental low temperature resistant and acid and alkali resistant cable sheath rubbers |
| CN103589101A (en) * | 2013-11-21 | 2014-02-19 | 无锡市明珠电缆有限公司 | Chlorinated polyethylene rubber for environment-friendly, flame-retardant and low-temperature-resistant wind energy cable, and preparation method |
| CN105001539A (en) * | 2015-07-29 | 2015-10-28 | 傅兴琴 | Preparation method of cold-resistant and flame-retardant cable sheath material |
| CN105385052A (en) * | 2015-09-23 | 2016-03-09 | 南京七四二五橡塑有限责任公司 | Rubber composition of low-temperature resistant environmentally-friendly chlorinated polyethylene and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107200945A (en) * | 2017-07-27 | 2017-09-26 | 芜湖融汇化工有限公司 | A kind of tasteless type cable cover(ing) sizing material and preparation method thereof |
| CN107286485A (en) * | 2017-07-27 | 2017-10-24 | 芜湖融汇化工有限公司 | A kind of tear-proof type cable cover(ing) sizing material and preparation method thereof |
| CN107383647A (en) * | 2017-07-31 | 2017-11-24 | 安徽新智电力科技有限公司 | A kind of Ultraviolet-resistancable cable sheath material and preparation method thereof |
| CN108129762A (en) * | 2017-12-06 | 2018-06-08 | 淮北市天相电缆有限责任公司 | A kind of novel environment-friendly cable insulation protective cover material |
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Application publication date: 20170315 |