CN106496668A - Good elastomeric material of a kind of water resistance and preparation method thereof - Google Patents
Good elastomeric material of a kind of water resistance and preparation method thereof Download PDFInfo
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- CN106496668A CN106496668A CN201611038285.3A CN201611038285A CN106496668A CN 106496668 A CN106496668 A CN 106496668A CN 201611038285 A CN201611038285 A CN 201611038285A CN 106496668 A CN106496668 A CN 106496668A
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- parts
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- water resistance
- elastomeric material
- vermiculite
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of good elastomeric material of water resistance, is made up of according to weight portion following raw material：Vermiculite, vegetable oil, natural rubber, butadiene-styrene rubber, haloflex, stearic acid, bamboo carbon powder, microcrystalline wax, barium carbonate powder, mica powder, oxide powder, sulphur, talcum powder, plasticizer, coupling agent, antioxidant and quartz sand.The present invention also disclosed the preparation method of the elastomeric material.Raw material sources of the present invention are extensive, preparation process is simple, low production cost, it is adaptable to large-scale industrial production；In the present invention, bamboo carbon powder and coupling agent coordinate the water resistance that can improve material with the use of the physical property that can improve rubber, microcrystalline wax and vegetable oil, and product physical property, ageing-resistant performance and the water resistance for obtaining is good, wide market.
Description
Technical field
The present invention relates to a kind of elastomeric material, the good elastomeric material of specifically a kind of water resistance.
Background technology
The rubber of early stage is taken from the latex of the plants such as rubber tree, Russian dandelion, make after processing with elasticity, insulation
Property, the material of impermeable water and air, are a kind of elastomeric macromolecular compounds.Rubber is divided into natural rubber and synthetic rubber two
Kind.Natural rubber is processed into after extraction colloid from the plants such as rubber tree, Russian dandelion；Synthetic rubber is then passed through by various monomers
Polymerisation and obtain.With the development of science and technology, rubber is widely used in each side of industry and life, is the life of people
Facility is brought with production.Simulated leather rubber is exactly relatively common a kind of elastomeric material in life, and simulated leather rubber is used for making
Make the products such as shoes, although existing simulated leather rubber good physical performance, elastic good with anti-wear performance, poor waterproof properties,
This just brings inconvenience for the use of people.
Content of the invention
It is an object of the invention to provide a kind of good elastomeric material of water resistance, to solve to propose in above-mentioned background technology
Problem.
For achieving the above object, the present invention provides following technical scheme：
A kind of good elastomeric material of water resistance, is made up of according to weight portion following raw material：Vermiculite 2-4 parts, vegetable oil 5-9
Part, natural rubber 30-48 parts, butadiene-styrene rubber 18-27 parts, haloflex 8-15 parts, stearic acid 2-6 parts, bamboo carbon powder 1-4
Part, microcrystalline wax 2-8 parts, barium carbonate powder 2-5 parts, mica powder 3-7 parts, oxide powder 4-7 parts, sulphur 2-3 parts, talcum powder
0.5-4 parts, plasticizer 2-3 parts, coupling agent 3-5 parts, antioxidant 1-2 parts and quartz sand 2-6 parts.
As further scheme of the invention：Vegetable oil using soybean oil, rapeseed oil, corn oil and olive oil one kind or
The multiple mixture of person, oxide powder are a kind of or many using magnesia, zirconium oxide, calcium oxide, zinc oxide and sodium oxide molybdena
The mixture that plants.
As further scheme of the invention：Plasticizer adopts dioctyl phthalate, and coupling agent is using silane coupled
Agent, antioxidant adopt antioxidant 1010.
The preparation method of the good elastomeric material of the water resistance, comprises the following steps that：
Step one, natural rubber is refined on a mill so that the plasticity of natural rubber is more than 0.48；
Step 2, by vermiculite 900-1050 degree Celsius of lower roasting 5-10 minute, obtains the vermiculite that foams；
Step 3, by refining after natural rubber, butadiene-styrene rubber and haloflex send into mill carries out conjunction refining, close refining
Time be 2-4 minutes, then add foaming vermiculite, vegetable oil, stearic acid, bamboo carbon powder, microcrystalline wax, brium carbonate powder
End, mica powder, oxide powder, talcum powder and quartz sand carry out banburying, and mixing temperature is 125-145 degree Celsius, mixing time
For 5-10 minutes；
Product in banbury, after banburying terminates, is carried out blanking, scribing and is cooled to normal temperature by step 4；
Banburying product is added automatic bag tilting machine and adds sulphur, plasticizer, coupling agent and antioxygen by step 5 again
Agent, is cut into adhesive tape after the 6-15 minutes that turn refining automatically；
Step 6, the adhesive tape for cutting is put in mould and 3-6 point of pressing on the vulcanizer that temperature is 150 degrees Celsius
Clock, pressure are 13-17MPa, are then cooled down.
Compared with prior art, the invention has the beneficial effects as follows：Extensively, preparation process is simple is raw for raw material sources of the present invention
Produce low cost, it is adaptable to large-scale industrial production；In the present invention, bamboo carbon powder and coupling agent are used cooperatively and can improve rubber
The physical property of glue, microcrystalline wax and vegetable oil coordinate the water resistance that can improve material, the product physical property for obtaining, resistance to
Ageing properties and water resistance are good, wide market.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of good elastomeric material of water resistance, is made up of according to weight portion following raw material：2 parts of vermiculite, 5 parts of vegetable oil,
30 parts of natural rubber, 18 parts of butadiene-styrene rubber, 8 parts of haloflex, 2 parts of stearic acid, 1 part of bamboo carbon powder, 2 parts of microcrystalline wax, carbon
2 parts of sour barium dust, 3 parts of mica powder, 4 parts of oxide powder, 2 parts of sulphur, 0.5 part of talcum powder, 2 parts of plasticizer, 3 parts of coupling agent,
2 parts of 1 part of antioxidant and quartz sand.Vegetable oil adopts magnesia, oxygen using corn oil and the mixture of olive oil, oxide powder
Change the mixture of zinc and sodium oxide molybdena.
The preparation method of the good elastomeric material of the water resistance, comprises the following steps that：
Step one, natural rubber is refined on a mill so that the plasticity of natural rubber is 0.5；
Step 2, by vermiculite in 900 degrees Celsius of lower roastings 5 minutes, obtains the vermiculite that foams；
Step 3, by refining after natural rubber, butadiene-styrene rubber and haloflex send into mill carries out conjunction refining, close refining
Time be 3 minutes, then add foaming vermiculite, vegetable oil, stearic acid, bamboo carbon powder, microcrystalline wax, barium carbonate powder,
Mica powder, oxide powder, talcum powder and quartz sand carry out banburying, and mixing temperature is 125 degrees Celsius, and mixing time is 5 minutes；
Product in banbury, after banburying terminates, is carried out blanking, scribing and is cooled to normal temperature by step 4；
Banburying product is added automatic bag tilting machine and adds sulphur, plasticizer, coupling agent and antioxygen by step 5 again
Agent, is cut into adhesive tape after turning refining automatically 6 minutes；
Step 6, the adhesive tape for cutting is put in mould and 3 points of pressing on the vulcanizer that temperature is 150 degrees Celsius
Clock, pressure are 13MPa, are then cooled down.
Embodiment 2
A kind of good elastomeric material of water resistance, is made up of according to weight portion following raw material：3 parts of vermiculite, 7 parts of vegetable oil,
37 parts of natural rubber, 22 parts of butadiene-styrene rubber, 12 parts of haloflex, 4 parts of stearic acid, 2 parts of bamboo carbon powder, 5 parts of microcrystalline wax, carbon
4 parts of sour barium dust, 5 parts of mica powder, 6 parts of oxide powder, 2.5 parts of sulphur, 2 parts of talcum powder, 2 parts of plasticizer, 4 parts of coupling agent,
4 parts of 1.5 parts of antioxidant and quartz sand.Plasticizer adopts dioctyl phthalate, coupling agent to adopt silane coupler, antioxidant
Using antioxidant 1010.
The preparation method of the good elastomeric material of the water resistance, comprises the following steps that：
Step one, natural rubber is refined on a mill so that the plasticity of natural rubber is 0.52；
Step 2, by vermiculite in 940 degrees Celsius of lower roastings 7 minutes, obtains the vermiculite that foams；
Step 3, by refining after natural rubber, butadiene-styrene rubber and haloflex send into mill carries out conjunction refining, close refining
Time be 3 minutes, then add foaming vermiculite, vegetable oil, stearic acid, bamboo carbon powder, microcrystalline wax, barium carbonate powder,
Mica powder, oxide powder, talcum powder and quartz sand carry out banburying, and mixing temperature is 132 degrees Celsius, and mixing time is 7 minutes；
Product in banbury, after banburying terminates, is carried out blanking, scribing and is cooled to normal temperature by step 4；
Banburying product is added automatic bag tilting machine and adds sulphur, dioctyl phthalate, silane by step 5 again
Coupling agent and antioxidant 1010, are cut into adhesive tape after turning refining automatically 9 minutes；
Step 6, the adhesive tape for cutting is put in mould and 5 points of pressing on the vulcanizer that temperature is 150 degrees Celsius
Clock, pressure are 15MPa, are then cooled down.
Embodiment 3
A kind of good elastomeric material of water resistance, is made up of according to weight portion following raw material：4 parts of vermiculite, 9 parts of vegetable oil,
45 parts of natural rubber, 24 parts of butadiene-styrene rubber, 13 parts of haloflex, 5 parts of stearic acid, 3 parts of bamboo carbon powder, 6 parts of microcrystalline wax, carbon
5 parts of sour barium dust, 6 parts of mica powder, 7 parts of oxide powder, 3 parts of sulphur, 3.5 parts of talcum powder, 3 parts of plasticizer, coupling agent 4.5
5 parts of part, 2 parts of antioxidant and quartz sand.Vegetable oil adopts soybean oil, oxide powder to adopt magnesia.Plasticizer is using adjacent benzene
Diformazan dioctyl phthalate, coupling agent adopt silane coupler, antioxidant to adopt antioxidant 1010.
The preparation method of the good elastomeric material of the water resistance, comprises the following steps that：
Step one, natural rubber is refined on a mill so that the plasticity of natural rubber is 0.55；
Step 2, by vermiculite in 1035 degrees Celsius of lower roastings 8 minutes, obtains the vermiculite that foams；
Step 3, by refining after natural rubber, butadiene-styrene rubber and haloflex send into mill carries out conjunction refining, close refining
Time be 3 minutes, then add foaming vermiculite, soybean oil, stearic acid, bamboo carbon powder, microcrystalline wax, barium carbonate powder,
Mica powder, magnesium oxide powder, talcum powder and quartz sand carry out banburying, and mixing temperature is 142 degrees Celsius, and mixing time is 8 minutes；
Product in banbury, after banburying terminates, is carried out blanking, scribing and is cooled to normal temperature by step 4；
Banburying product is added automatic bag tilting machine and adds sulphur, dioctyl phthalate, silane by step 5 again
Coupling agent and antioxidant 1010, are cut into adhesive tape after turning refining automatically 12 minutes；
Step 6, the adhesive tape for cutting is put in mould and 4 points of pressing on the vulcanizer that temperature is 150 degrees Celsius
Clock, pressure are 16MPa, are then cooled down.
Embodiment 4
A kind of good elastomeric material of water resistance, is made up of according to weight portion following raw material：4 parts of vermiculite, 9 parts of vegetable oil,
48 parts of natural rubber, 27 parts of butadiene-styrene rubber, 15 parts of haloflex, 6 parts of stearic acid, 4 parts of bamboo carbon powder, 8 parts of microcrystalline wax, carbon
5 parts of sour barium dust, 7 parts of mica powder, 7 parts of oxide powder, 3 parts of sulphur, 4 parts of talcum powder, 3 parts of plasticizer, 5 parts of coupling agent, anti-
6 parts of 2 parts of oxygen agent and quartz sand.Mixture of the vegetable oil using soybean oil, rapeseed oil, corn oil and olive oil, oxide powder
Mixture using magnesia, zirconium oxide, calcium oxide, zinc oxide and sodium oxide molybdena.Plasticizer adopts dioctyl phthalate, even
Connection agent adopts silane coupler, antioxidant to adopt antioxidant 1010.
The preparation method of the good elastomeric material of the water resistance, comprises the following steps that：
Step one, natural rubber is refined on a mill so that the plasticity of natural rubber is 0.49；
Step 2, by vermiculite in 1050 degrees Celsius of lower roastings 8 minutes, obtains the vermiculite that foams；
Step 3, by refining after natural rubber, butadiene-styrene rubber and haloflex send into mill carries out conjunction refining, close refining
Time be 4 minutes, then add foaming vermiculite, vegetable oil, stearic acid, bamboo carbon powder, microcrystalline wax, barium carbonate powder,
Mica powder, oxide powder, talcum powder and quartz sand carry out banburying, and mixing temperature is 145 degrees Celsius, and mixing time is 6 minutes；
Product in banbury, after banburying terminates, is carried out blanking, scribing and is cooled to normal temperature by step 4；
Banburying product is added automatic bag tilting machine and adds sulphur, dioctyl phthalate, silane by step 5 again
Coupling agent and antioxidant 1010, are cut into adhesive tape after turning refining automatically 15 minutes；
Step 6, the adhesive tape for cutting is put in mould and 6 points of pressing on the vulcanizer that temperature is 150 degrees Celsius
Clock, pressure are 17MPa, are then cooled down.
Comparative example
Except vegetable oil is not contained, remaining component and preparation method of comparative example 1 is with embodiment 1.
The product of embodiment 1-4, the product of comparative example 1 and existing product are carried out performance detection, testing result is shown in Table 1.
Table 1
As it can be seen from table 1 product and existing product of the water imbibition of embodiment 1-4 product less than comparative example 1, embodiment
Product and existing product of the physical property and ageing-resistant performance of 1-4 products higher than comparative example 1.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Contain an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical scheme in each embodiment can also form those skilled in the art through appropriately combined
Understandable other embodiment.
Claims (4)
1. the good elastomeric material of a kind of water resistance, it is characterised in that be made up of according to weight portion following raw material：Vermiculite 2-4 parts,
Vegetable oil 5-9 parts, natural rubber 30-48 parts, butadiene-styrene rubber 18-27 parts, haloflex 8-15 parts, stearic acid 2-6 parts, bamboo charcoal
Powder 1-4 parts, microcrystalline wax 2-8 parts, barium carbonate powder 2-5 parts, mica powder 3-7 parts, oxide powder 4-7 parts, sulphur 2-3
Part, talcum powder 0.5-4 parts, plasticizer 2-3 parts, coupling agent 3-5 parts, antioxidant 1-2 parts and quartz sand 2-6 parts.
2. the good elastomeric material of water resistance according to claim 1, it is characterised in that the vegetable oil adopts soybean
One or more mixture of oil, rapeseed oil, corn oil and olive oil, oxide powder adopt magnesia, zirconium oxide, oxygen
Change one or more mixture of calcium, zinc oxide and sodium oxide molybdena.
3. the good elastomeric material of water resistance according to claim 1 and 2, it is characterised in that the plasticizer is using adjacent
Dioctyl phthalate, coupling agent adopt silane coupler, antioxidant to adopt antioxidant 1010.
4. a kind of preparation method of the good elastomeric material of water resistance as described in claim 1-3 is arbitrary, it is characterised in that tool
Body step is as follows：
Step one, natural rubber is refined on a mill so that the plasticity of natural rubber is more than 0.48；
Step 2, by vermiculite 900-1050 degree Celsius of lower roasting 5-10 minute, obtains the vermiculite that foams；
Step 3, by refining after natural rubber, butadiene-styrene rubber and haloflex send into mill carries out conjunction refining, close refining when
Between for 2-4 minutes, then add foaming vermiculite, vegetable oil, stearic acid, bamboo carbon powder, microcrystalline wax, barium carbonate powder, cloud
Female powder, oxide powder, talcum powder and quartz sand carry out banburying, and mixing temperature is 125-145 degree Celsius, and mixing time is 5-10
Minute；
Product in banbury, after banburying terminates, is carried out blanking, scribing and is cooled to normal temperature by step 4；
Banburying product is added automatic bag tilting machine and adds sulphur, plasticizer, coupling agent and antioxidant by step 5 again, from
Adhesive tape is cut into after the dynamic 6-15 minutes that turn refining；
Step 6, the adhesive tape for cutting is put in mould and pressing 3-6 minutes on the vulcanizer that temperature is 150 degrees Celsius,
Pressure is 13-17MPa, is then cooled down.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201611038285.3A CN106496668A (en) | 2016-11-23 | 2016-11-23 | Good elastomeric material of a kind of water resistance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611038285.3A CN106496668A (en) | 2016-11-23 | 2016-11-23 | Good elastomeric material of a kind of water resistance and preparation method thereof |
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| CN106496668A true CN106496668A (en) | 2017-03-15 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982283A (en) * | 2019-11-15 | 2020-04-10 | 谢广 | Method for manufacturing inorganic nonmetal storage material |
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|---|---|---|---|---|
| CN1986719A (en) * | 2006-12-21 | 2007-06-27 | 绍兴市油毛毡厂 | Chlorinated polyethylene rubber waterproof coiled material and production method thereof |
| CN104387707A (en) * | 2014-12-16 | 2015-03-04 | 钟再华 | Ultra-low-temperature-resistant high-toughness flame-retardant fire hose lining rubber tube and preparation method thereof |
| CN104710654A (en) * | 2013-12-13 | 2015-06-17 | 于顺傈 | Impact resistant floor rubber material |
| CN104774348A (en) * | 2015-03-18 | 2015-07-15 | 南京东亚橡塑制品有限公司 | Rubber material added with heat stabilizer (HS-80) and preparation method thereof |
-
2016
- 2016-11-23 CN CN201611038285.3A patent/CN106496668A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986719A (en) * | 2006-12-21 | 2007-06-27 | 绍兴市油毛毡厂 | Chlorinated polyethylene rubber waterproof coiled material and production method thereof |
| CN104710654A (en) * | 2013-12-13 | 2015-06-17 | 于顺傈 | Impact resistant floor rubber material |
| CN104387707A (en) * | 2014-12-16 | 2015-03-04 | 钟再华 | Ultra-low-temperature-resistant high-toughness flame-retardant fire hose lining rubber tube and preparation method thereof |
| CN104774348A (en) * | 2015-03-18 | 2015-07-15 | 南京东亚橡塑制品有限公司 | Rubber material added with heat stabilizer (HS-80) and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982283A (en) * | 2019-11-15 | 2020-04-10 | 谢广 | Method for manufacturing inorganic nonmetal storage material |
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Application publication date: 20170315 |