CN106495971A - Luxuriant medicine is opened without sulfur - Google Patents
Luxuriant medicine is opened without sulfur Download PDFInfo
- Publication number
- CN106495971A CN106495971A CN201610894630.7A CN201610894630A CN106495971A CN 106495971 A CN106495971 A CN 106495971A CN 201610894630 A CN201610894630 A CN 201610894630A CN 106495971 A CN106495971 A CN 106495971A
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- Prior art keywords
- sulfur
- luxuriant medicine
- medicine
- opened
- salt
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Classifications
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- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/06—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being an inorganic oxygen-halogen salt
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/02—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide with an organic non-explosive or an organic non-thermic component
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
The present invention relates to a kind of firecracker formula, specifically discloses one kind and opens luxuriant medicine without sulfur.This opens luxuriant medicine without sulfur includes following component：Potassium hyperchlorate 30～80%, aluminum argentum powder 10～30%, without sulfur composite 10～50%；Described it is made up of following components in percentage by weight without sulfur composite：Salt of weak acid 80～98%, resin 1～10%, wax 1～10%；The salt of weak acid is at least one in carbonate and oxalates.The present invention is with without the sulfur in sulfur composite replacement conventional formulation, after making firecrackers, fusing point is high, mechanical sensitivity is low, stability is high through checking for medicine, substantially increase production security, and after setting off without sulfur dioxide, without venomous injurant, for environmental nonpollution and human body non-hazardous are acted on, and new formulation cost is rationally, generalization is strong.
Description
Technical field
The present invention relates to a kind of firecracker formula, and in particular to one kind opens luxuriant medicine without sulfur.
Background technology
At present, the firecracker medicine main formula that commonly uses on market is potassium hyperchlorate, aluminum argentum powder and sulfur, due to having in formula
Sulfur, produces sulfur dioxide and sulfur trioxide after burning, air is damaged, harm can be also produced to human health.And,
Firecrackers medicament when setting off more produce smog, cause very big pollution to setting off a nearby urban air.In addition, such firecracker is molten
The low, mechanical sensitivity of point is high, unstable properties, and security and stability is poor, and accident easily occurs.
Content of the invention
The technical problem to be solved is to provide low, the stable and safe nothing of a kind of fusing point height, mechanical sensitivity
Sulfur opens luxuriant medicine.By weight percentage, this opens luxuriant medicine without sulfur includes following component：Potassium hyperchlorate 30～80%, aluminum argentum powder 10～
30%, without sulfur composite 10～50%；Described it is made up of following components in percentage by weight without sulfur composite：Salt of weak acid 80
～98%, resin 1～10%, wax 1～10%；The salt of weak acid is at least one in carbonate and oxalates.
Wherein, above-mentioned luxuriant medicine is opened without sulfur and also include crushed crude pearlite 1～10%.
Wherein, above-mentioned luxuriant medicine is opened without sulfur and also include Al-Mg alloy powder 10～30%.
Wherein, above-mentioned luxuriant medicine is opened without sulfur and also include powdered carbon 1～20%.
Wherein, above-mentioned luxuriant medicine is opened without sulfur and also include wood powder 1～20%.
Wherein, above-mentioned open in luxuriant medicine without sulfur, the granularity of the salt of weak acid is 4～200 mesh.
Wherein, above-mentioned open in luxuriant medicine without sulfur, the carbonate is alkali carbonate or alkaline earth metal carbonate, described
Oxalates are alkaline metal oxalate or alkaline-earth metal oxalates.
Compared with prior art, the invention has the advantages that：With without the replacement of sulfur composite in inventive formulation
Sulfur in conventional formulation, after making firecrackers, fusing point is high, mechanical sensitivity is low, stability is high through checking for medicine, substantially increases
Production security, without sulfur dioxide after setting off, without venomous injurant, for environmental nonpollution and human body non-hazardous are acted on, environmental protection
Safety, and new formulation cost is rationally, generalization is strong.
Specific embodiment
The invention provides a kind of fusing point is high, mechanical sensitivity is low, stable and safe opens luxuriant medicine without sulfur.With weight percent
Than meter, this opens luxuriant medicine without sulfur includes following component：Potassium hyperchlorate 30～80%, aluminum argentum powder 10～30%, without sulfur composite 10
～50%；Described it is made up of the component of following percentage by weight without sulfur composite：Salt of weak acid 80～98%, resin 1～10%,
Wax 1～10%；The salt of weak acid is at least one in carbonate and oxalates.
Wherein, above-mentioned luxuriant medicine is opened without sulfur and also include crushed crude pearlite 1～10%.
Wherein, above-mentioned luxuriant medicine is opened without sulfur and also include Al-Mg alloy powder 10～30%.
Wherein, above-mentioned luxuriant medicine is opened without sulfur and also include powdered carbon 1～20% or wood powder 1～20%.
Wherein, above-mentioned open in luxuriant medicine without sulfur, the granularity of the salt of weak acid is 4～200 mesh.
Wherein, in the above-mentioned composite without sulfur, the carbonate is alkali carbonate or alkaline earth metal carbonate, such as
Sodium carbonate, potassium carbonate, Calcium Carbonate, brium carbonate etc.；The oxalates are alkaline metal oxalate or alkaline-earth metal oxalates, such as grass
Sour sodium, potassium oxalate, calcium oxalate, barium oxalate etc..
Wherein, in the above-mentioned composite without sulfur, the resin is resin commonly used in the art, such as phenolic resin, Lac or pine
Perfume (or spice), preferably phenolic resin；The wax is preferably polyethylene glycol wax, i.e. PE waxes.
Above-mentioned prepared without sulfur composite material component in accordance with the following methods：Salt of weak acid is put into mixing plant, Ran Houjia
Enter resin, the resin is added in the form of resin ethanol solution, resin accounts for the 1～30% of resin ethanol solution weight；Treat which
After mixing homogeneously with the salt of weak acid, pelletize, drying obtain granule, then gained granule are coated with wax, mistake after cladding
200～300 mesh sieves, classification, obtain without sulfur composite.
The present invention is further explained with reference to embodiment and is illustrated, but and be not so limited protection model of the invention
Enclose；Also, where not making specified otherwise in the present invention, it is considered this area routine operation.
Embodiment 1
Luxuriant medicine is opened without sulfur to be mixed to get by the component of following percentage by weight：Potassium hyperchlorate 40%, aluminum argentum powder 15%, without sulfur
Composite 45%.Wherein, without sulfur composite, (components in weight percent is：Sodium carbonate 85%, phenolic resin 8%, PE waxes
7%) prepared by following methods：First the sodium carbonate that granularity is 100 mesh is added in mixing plant, phenolic aldehyde tree is subsequently adding
The ethanol solution of fat, wherein phenolic resin account for the 15% of solution weight；After solution is mixed thoroughly with sodium carbonate, pelletize,
Dry, obtain granule, then gained granule is coated with PE waxes, after cladding, cross 200 mesh sieves, classification rejects granularity unqualified
Product.
Above-mentioned gained opens luxuriant medicine through Ministry of ordnance Industry's the 2nd 13 institute inspection without sulfur, and assay is shown in Table 1, from table 1
Can be drawn a conclusion：1 gained of embodiment opens without sulfur that luxuriant medicine fusing point is high, mechanical sensitivity is low, stability is high, substantially increases production
Safety, without sulfur dioxide after setting off, without venomous injurant, for environmental nonpollution, for human body non-hazardous.
1. tradition of table is opened luxuriant medicine containing sulfur and opens luxuriant medicine performance comparison without sulfur
Embodiment 2
Luxuriant medicine is opened without sulfur to be mixed to get by the component of following percentage by weight：Potassium hyperchlorate 60%, aluminum argentum powder 15%, without sulfur
Composite 20%, crushed crude pearlite 5%.Wherein, without sulfur composite, (components in weight percent is：Barium oxalate 90%, phenolic aldehyde tree
5%) fat 5%, PE waxes is prepared by following methods：First in mixing plant, then the barium oxalate that granularity is 50 mesh is added
The ethanol solution of phenolic resin, wherein phenolic resin is added to account for the 25% of solution weight；Treat that solution is thoroughly mixed with barium oxalate
After even, pelletize, drying obtain granule, then gained granule are coated with PE waxes, cross 200 mesh sieves after cladding, and classification is rejected
Granularity substandard product.
Above-mentioned gained opens luxuriant medicine through Ministry of ordnance Industry's the 2nd 13 institute inspection without sulfur, and assay is shown in Table 2, from table 2
Can be drawn a conclusion：2 gained of embodiment opens without sulfur that luxuriant medicine fusing point is high, mechanical sensitivity is low, stability is high, substantially increases production
Safety, without sulfur dioxide after setting off, without venomous injurant, for environmental nonpollution, for human body non-hazardous.
2. tradition of table is opened luxuriant medicine containing sulfur and opens luxuriant medicine performance comparison without sulfur
Embodiment 3
Luxuriant medicine is opened without sulfur to be mixed to get by the component of following percentage by weight：Potassium hyperchlorate 53%, aluminum argentum powder 12%, without sulfur
Composite 18%, crushed crude pearlite 2%, Al-Mg alloy powder 15%.Wherein, without sulfur composite, (components in weight percent is：Weak
3%) hydrochlorate 95%, Colophonium 2% and PE waxes is prepared by following methods：First by salt of weak acid that granularity is 200 mesh (wherein,
The percentage by weight of potassium carbonate is 23%, and the percentage by weight of calcium oxalate is subsequently adding Colophonium for 77%) adding in mixing plant
Ethanol solution, wherein Colophonium accounts for the 25% of solution weight；After solution is mixed thoroughly with salt of weak acid, pelletize, drying are obtained
Granule is arrived, then gained granule is coated with PE waxes, after cladding, cross 300 mesh sieves, granularity substandard product is rejected in classification.
Above-mentioned gained opens luxuriant medicine through Ministry of ordnance Industry's the 2nd 13 institute inspection without sulfur, and assay is shown in Table 3, from table 3
Can be drawn a conclusion：3 gained of embodiment opens without sulfur that luxuriant medicine fusing point is high, mechanical sensitivity is low, stability is high, substantially increases production
Safety, without sulfur dioxide after setting off, without venomous injurant, for environmental nonpollution, for human body non-hazardous.
3. tradition of table is opened luxuriant medicine containing sulfur and opens luxuriant medicine performance comparison without sulfur
Embodiment 4
Luxuriant medicine is opened without sulfur to be mixed to get by the component of following percentage by weight：Potassium hyperchlorate 32%, aluminum argentum powder 20%, without sulfur
Composite 28%, crushed crude pearlite 6%, Al-Mg alloy powder 12%, powdered carbon 2%.Wherein, without sulfur composite (percentage by weight
Component is：6%) salt of weak acid 90%, phenolic resin 4% and PE waxes is prepared by following methods：It is 200 purposes first by granularity
Salt of weak acid (wherein, the percentage by weight of potassium carbonate is 86%, during the percentage by weight of calcium oxalate is for 14%) addition mixing plant,
The ethanol solution of Colophonium is subsequently adding, wherein phenolic resin accounts for the 20% of solution weight；Treat that solution is thoroughly mixed with salt of weak acid
After even, pelletize, drying obtain granule, then gained granule are coated with PE waxes, cross 300 mesh sieves after cladding, and classification is rejected
Granularity substandard product.
Above-mentioned gained opens luxuriant medicine through Ministry of ordnance Industry's the 2nd 13 institute inspection without sulfur, and assay is shown in Table 4, from table 4
Can be drawn a conclusion：4 gained of embodiment opens without sulfur that luxuriant medicine fusing point is high, mechanical sensitivity is low, stability is high, substantially increases production
Safety, without sulfur dioxide after setting off, without venomous injurant, for environmental nonpollution, for human body non-hazardous.
4. tradition of table is opened luxuriant medicine containing sulfur and opens luxuriant medicine performance comparison without sulfur
Embodiment 5
Luxuriant medicine is opened without sulfur to be mixed to get by the component of following percentage by weight：Potassium hyperchlorate 34%, aluminum argentum powder 14%, without sulfur
Composite 12%, crushed crude pearlite 8%, Al-Mg alloy powder 20%, wood powder 12%.Wherein, without sulfur composite (percentage by weight
Component is：6%) salt of weak acid 90%, phenolic resin 4% and PE waxes is prepared by following methods：It is 200 purposes first by granularity
Salt of weak acid (wherein, the percentage by weight of potassium carbonate is 86%, during the percentage by weight of calcium oxalate is for 14%) addition mixing plant,
The ethanol solution of Colophonium is subsequently adding, wherein phenolic resin accounts for the 20% of solution weight；Treat that solution is thoroughly mixed with salt of weak acid
After even, pelletize, drying obtain granule, then gained granule are coated with PE waxes, cross 300 mesh sieves after cladding, and classification is rejected
Granularity substandard product.
Above-mentioned gained opens luxuriant medicine through Ministry of ordnance Industry's the 2nd 13 institute inspection without sulfur, and assay is shown in Table 5, from table 5
Can be drawn a conclusion：5 gained of embodiment opens without sulfur that luxuriant medicine fusing point is high, mechanical sensitivity is low, stability is high, substantially increases production
Safety, without sulfur dioxide after setting off, without venomous injurant, for environmental nonpollution, for human body non-hazardous.
5. tradition of table is opened luxuriant medicine containing sulfur and opens luxuriant medicine performance comparison without sulfur
Above-described embodiment is only for clearly explanation example, the not restriction made by embodiment.For
For person of an ordinary skill in the technical field, the change of other multi-forms can also be made on the basis of the above description
Or change, here cannot be illustrated one by one to all of embodiment, and thus extended obvious change or
Change is still within the protection domain that invention is created.
Claims (7)
1. luxuriant medicine is opened without sulfur, it is characterised in that by weight percentage, this opens luxuriant medicine without sulfur includes following component：Potassium hyperchlorate
30～80%, aluminum argentum powder 10～30%, without sulfur composite 10～50%；Described without sulfur composite by following percentage by weight
Component constitute：Salt of weak acid 80～98%, resin 1～10%, wax 1～10%；The salt of weak acid is in carbonate and oxalates
At least one.
2. according to claim 1 luxuriant medicine is opened without sulfur, it is characterised in that described open luxuriant medicine without sulfur and also include crushed crude pearlite 1
～10%.
3. according to claim 2 luxuriant medicine is opened without sulfur, it is characterised in that described open luxuriant medicine without sulfur and also include Al-Mg alloy powder
10～30%.
4. according to claim 3 open luxuriant medicine without sulfur, it is characterised in that described without sulfur open luxuriant medicine also include powdered carbon 1～
20%.
5. according to claim 3 open luxuriant medicine without sulfur, it is characterised in that described without sulfur open luxuriant medicine also include wood powder 1～
20%.
6. luxuriant medicine is opened without sulfur according to any one of Claims 1 to 5, it is characterised in that the granularity of the salt of weak acid is 4～
200 mesh.
7. according to claim 6 luxuriant medicine is opened without sulfur, it is characterised in that the carbonate is alkali carbonate or alkali
Earth metal carbonate, the oxalates are alkaline metal oxalate or alkaline-earth metal oxalates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610894630.7A CN106495971A (en) | 2016-10-13 | 2016-10-13 | Luxuriant medicine is opened without sulfur |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610894630.7A CN106495971A (en) | 2016-10-13 | 2016-10-13 | Luxuriant medicine is opened without sulfur |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106495971A true CN106495971A (en) | 2017-03-15 |
Family
ID=58294371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610894630.7A Pending CN106495971A (en) | 2016-10-13 | 2016-10-13 | Luxuriant medicine is opened without sulfur |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106495971A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106905087A (en) * | 2017-04-11 | 2017-06-30 | 浏阳市颐和隆烟花集团有限公司 | A kind of fireworks and firecrackers opens bag insensitiveness composite |
| CN106966845A (en) * | 2017-02-15 | 2017-07-21 | 湖南荣晖实业有限公司 | Without sulphur firecrackers medicine |
| CN110330399A (en) * | 2019-07-23 | 2019-10-15 | 湖南荣晖新材料有限公司 | A kind of fireworks and firecrackers composite material and preparation method and application |
| CN114456018A (en) * | 2021-11-30 | 2022-05-10 | 廖德祥 | Retarding agent for fireworks and firecrackers explosive |
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| CN103224435A (en) * | 2013-05-03 | 2013-07-31 | 醴陵神马花炮有限公司 | Sulfur-free firecracker drug |
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| CN102219624A (en) * | 2011-03-31 | 2011-10-19 | 南京理工大学 | Firecracker medicament taking modified barium nitrate as main body oxidant |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106966845A (en) * | 2017-02-15 | 2017-07-21 | 湖南荣晖实业有限公司 | Without sulphur firecrackers medicine |
| CN106905087A (en) * | 2017-04-11 | 2017-06-30 | 浏阳市颐和隆烟花集团有限公司 | A kind of fireworks and firecrackers opens bag insensitiveness composite |
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| CN110330399A (en) * | 2019-07-23 | 2019-10-15 | 湖南荣晖新材料有限公司 | A kind of fireworks and firecrackers composite material and preparation method and application |
| CN114456018A (en) * | 2021-11-30 | 2022-05-10 | 廖德祥 | Retarding agent for fireworks and firecrackers explosive |
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Application publication date: 20170315 |
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