CN106495300A - A kind of phosphorus-removing carrier and method for sewage disposal device - Google Patents

A kind of phosphorus-removing carrier and method for sewage disposal device Download PDF

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Publication number
CN106495300A
CN106495300A CN201611178041.5A CN201611178041A CN106495300A CN 106495300 A CN106495300 A CN 106495300A CN 201611178041 A CN201611178041 A CN 201611178041A CN 106495300 A CN106495300 A CN 106495300A
Authority
CN
China
Prior art keywords
dephosphorization
phosphorus
shell
carrier
removing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611178041.5A
Other languages
Chinese (zh)
Inventor
李旻
任亮
严巾堪
潘三
曲凯
刘厚文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Zhongche Environmental Protection Equipment Co ltd
Original Assignee
Shandong Zhongche Huateng Environmental Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Zhongche Huateng Environmental Technology Co Ltd filed Critical Shandong Zhongche Huateng Environmental Technology Co Ltd
Priority to CN201611178041.5A priority Critical patent/CN106495300A/en
Priority to PCT/CN2016/111712 priority patent/WO2018112884A1/en
Publication of CN106495300A publication Critical patent/CN106495300A/en
Priority to ZA2019/04607A priority patent/ZA201904607B/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Removal Of Specific Substances (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The present invention relates to a kind of phosphorus-removing carrier and method for sewage disposal device, belongs to sewage disposal correlative technology field.Mainly include:Housing, the enclosure interior have in the storage warehouse for being used for accommodating dephosphorization agent, storage warehouse and there is dephosphorization agent;One end of the storage warehouse is closed by storehouse lid, and the other end is the slow release interface for discharging dephosphorization agent;Wherein, when the dephosphorization agent does not exhaust, housing is in suspended state in sewage;When the dephosphorization agent exhausts, housing is in floating state in sewage.The present invention is by designing brand-new structure so as to can be suspended in sewage during release dephosphorization agent, dephosphorization agent floats up to the water surface after exhausting, and without the need for transforming to existing sewage disposal device, usage cycles are long, it is easy to safeguard.

Description

Dephosphorization carrier and method for sewage treatment equipment
Technical Field
The invention relates to the technical field related to sewage treatment, in particular to a dephosphorization carrier and a dephosphorization method for sewage treatment equipment.
Background
The nitrogen and phosphorus nutrient elements in the water body are the main causes of water body eutrophication. Wherein the phosphorus in the water body mainly comes from sewage discharged into the water body. Therefore, removing phosphorus from wastewater is an important way to improve the water environment.
At present, the phosphorus removal method for domestic sewage mainly comprises chemical phosphorus removal, electrochemical phosphorus removal and biological phosphorus removal. Wherein, biological phosphorus removal needs to construct alternate anaerobic and aerobic links, phosphorus is excessively taken by phosphorus accumulating bacteria in an aerobic state, and phosphorus in sewage is removed by discharging phosphorus-rich excess sludge. Because the biological phosphorus removal process is controlled complicatedly, the biological phosphorus removal process is generally applied to less sewage treatment equipment.
Chemical phosphorus removal refers to the process of adding a chemical agent to form insoluble phosphate precipitate and then removing phosphorus from sewage through solid-liquid separation. The conventional chemical phosphorus removal needs to be provided with a dosing facility or equipment, including a medicament storage device, a medicament dissolving and dosing device, a medicament mixing and flocculating device and other measures, which undoubtedly can greatly increase the cost.
The chinese patent application No. 201410624036.7 provides a phosphorus removal method for sewage treatment equipment, which adopts a slow-release phosphorus removal agent installed on a return pipe of the sewage treatment equipment, and does not need a specially-assigned person to administer the phosphorus removal agent on duty. But the disadvantages are that in the implementation process:
1. an additional medicament barrel or other modes are needed to store and install the slow-release phosphorus removal agent in the sewage treatment equipment;
2. chemical phosphorus removal generally requires a medicament mixing process, and the slow-release phosphorus removing agent is only dissolved by utilizing the tiny power of gas stripping reflux liquid in a mode of installing the slow-release phosphorus removing agent on a reflux pipe of sewage treatment equipment, so that the phosphorus removing agent is not beneficial to realizing the complete mixing of the phosphorus removing agent and water, and the utilization rate of the phosphorus removing agent is low;
3. the mode of installing the slow-release phosphorus removing agent on the return pipe of the sewage treatment equipment limits the storage amount of the slow-release phosphorus removing agent, and the frequent addition of the phosphorus removing agent is easily caused;
4. the preferable conditions of chemical phosphorus removal are low SS and low DS environments, and the mode of refluxing the phosphorus removing agent and the reflux liquid to the previous process often causes that the investment environment of the phosphorus removing agent is not suitable (high SS and high DS environments) and the waste of the phosphorus removing agent is easily caused.
Electrochemical phosphorus removal adopts an electrolysis mode, iron ions or aluminum ions are generated by utilizing electric energy electrolysis to generate insoluble phosphate precipitate, and then phosphorus is removed from sewage through solid-liquid separation. The method has the defects that the electrolysis polar plate needs to be frequently replaced, and the energy consumption of the electrolysis device is higher.
In addition, the existing phosphorus removal methods are all not suitable for upgrading and modifying existing sewage treatment equipment because additional phosphorus removal devices need to be installed and are limited by installation space, power consumption and the like.
Therefore, how to design a phosphorus removal device which is convenient to be adopted in the existing sewage treatment equipment, has long service time and low maintenance frequency and does not need to modify the sewage treatment equipment is a problem which needs to be solved by the technical personnel in the field.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a dephosphorization carrier for sewage treatment equipment. According to the invention, by designing a brand new structure, the phosphorus removal agent can be suspended in sewage in the process of releasing the phosphorus removal agent, and the phosphorus removal agent floats to the water surface after being used up, so that the existing sewage treatment equipment is not required to be modified, the service cycle is long, and the maintenance is easy.
In order to achieve the purpose, the invention adopts the following technical scheme:
a dephosphorization vector for a sewage treatment plant, comprising:
a shell body, a plurality of first connecting rods and a plurality of second connecting rods,
the inside of the shell is provided with a storage bin for containing a phosphorus removing agent, and the phosphorus removing agent is arranged in the storage bin;
one end of the storage bin is sealed by a bin cover, and the other end of the storage bin is a slow release interface for releasing the phosphorus removing agent;
wherein,
the shell is in a suspension state in the sewage when the phosphorus removing agent is not used up;
the shell is in a floating state in the sewage when the phosphorus removing agent is exhausted.
The phosphorus removal carrier can become a carrier of microorganisms when in use, and chemical phosphorus removal can be realized when the phosphorus removal agent is dissolved. According to different choices, the phosphorus removal agent can adopt solid iron salt or aluminum salt.
Preferably, the phosphorus removal agent is solid polymeric ferric sulfate.
Preferably, a floating body is arranged on one side of the shell close to the bin cover.
Preferably, the slow release interface comprises a microporous plate and a water filtering fabric arranged on the outer side of the microporous plate, and the storage bin is sequentially connected with the microporous plate and the water filtering fabric in a sealing manner;
compared with the center of gravity of the dephosphorization carrier, the position of the metallic iron block is closer to the floating center of the dephosphorization carrier;
namely, the distance between the slow release interface and the center of gravity of the dephosphorization carrier is less than the distance between the slow release interface and the floating center of the dephosphorization carrier.
Preferably, the micropore plate is a stainless steel plate with through holes with the hole diameter of 0.3-0.8 mm.
Preferably, the water-filtering fabric is a nonwoven geotextile.
Preferably, the bin cover and/or the storage bin are iron.
Preferably, the bin cover and/or the storage bin contain metal iron blocks. Compared with the center of gravity of the dephosphorization carrier, the position of the metallic iron block is closer to the floating center of the dephosphorization carrier; namely, the distance between the metal iron block and the center of gravity of the dephosphorization carrier is less than the distance between the slow release interface and the floating center of the dephosphorization carrier.
Preferably, a floating body is disposed on the housing.
Preferably, the floating body is positioned at one side close to the bin cover in the shell, and the floating body enables the gravity center and the floating center of the dephosphorization carrier not to coincide.
When the phosphorus removing agent is stored in the shell, the density is 0.94-0.97g/cm3When the phosphorus removing agent is exhausted, the density is 0.80-0.90g/cm3
The dephosphorization carrier can automatically float to the water surface when the dephosphorization agent is exhausted through the density difference, so that the maintenance personnel can conveniently identify and supplement.
While providing the structural scheme, the invention also provides a method for utilizing the phosphorus removal carrier, which mainly comprises the following steps:
A. opening the bin cover, and adding a phosphorus removing agent into the storage bin;
B. closing the bin cover, and throwing the shell into a sewage treatment tank;
C. the shell is suspended in the sewage, and after the phosphorus removing agent is exhausted, the shell floats on the water surface;
D. and fishing out the shell by using a magnet, and reloading the phosphorus removing agent.
The invention has the beneficial effects that:
(1) can be directly widely applied to sewage treatment equipment to replace or supplement the existing carriers. The sewage treatment equipment without the phosphorus removal function can be improved without great improvement and additional dosing facilities or equipment, so that the sewage treatment equipment without the phosphorus removal function has the phosphorus removal function.
(2) The physical slow release of the phosphorus removing agent is realized by the microporous material and the water-filtering type fabric, and compared with a phosphorus removing agent (such as a slow release phosphorus removing agent) adopting chemical slow release, the phosphorus removing agent capable of being stored has higher purity (the slow release phosphorus removing agent and the like need to be added with additional slow release raw materials, and the phosphorus removing agent is often diluted), so that the capacity is larger, the service time is longer, and the maintenance frequency is lower.
(3) The shell is in a suspension state when containing the phosphorus removing agent, and automatically floats out of the water surface when the phosphorus removing agent is exhausted, so that the content of the phosphorus removing agent in the shell does not need to be frequently observed, and the method is very convenient.
(4) No additional power supply is required for the phosphorus removal process.
Drawings
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 is a front view of the present invention;
FIG. 3 is a top view of the present invention;
FIG. 4 is a diagram of the status of the application of the phosphorus removal agent when it is not exhausted;
FIG. 5 is a schematic view of the situation when the phosphorus removing agent is exhausted;
FIG. 6 is an enlarged view of a portion of FIG. 2 at I;
FIG. 7 is an enlarged view of a portion of FIG. 2 at II;
in the figure, 1, a shell, 2, a storage bin, 3, a bin cover, 4, a phosphorus removing agent, 5, a slow release interface, 6, a microporous material, 7, a water filtering fabric, 8, a floating body, 9, a fixing ring and 10, sewage.
Detailed Description
The present invention will be described in detail below with reference to the accompanying drawings.
Example (b): a dephosphorization carrier for sewage treatment equipment, the structure of which is shown in fig. 1-3, fig. 6 and fig. 7, comprising:
has a housing 1 for attachment of a biofilm; a storage bin 2 for storing a phosphorus removing agent 4 is arranged in the shell 1;
the shell 1 should be selected as spherical as possible to control the center of gravity and the center of buoyancy.
Two ends of the storage bin 2 are respectively provided with a bin cover 3 and a slow release interface 5;
the bin cover 3 can be opened and closed and is used for supplementing a phosphorus removing agent 4;
the bin cover 3 is made of metal iron, the surface of the bin cover is plated with nickel, and metal iron blocks can be contained inside the bin cover;
the phosphorus removing agent 4 adopts solid high-molecular polymeric ferric sulfate;
the slow release interface 5 is the only contact interface between the phosphorus removing agent 4 in the storage bin 2 and water around the phosphorus removing carrier;
the slow release interface 5 is a 2-layer composite structure consisting of a microporous material 6 and a water-filtering fabric 7;
the microporous material 6 is in contact with the phosphorus removing agent 4 and is a stainless steel microporous plate with the thickness of 0.4-0.6mm and the perforation diameter of 0.3-0.8 mm;
the water-filtering type fabric 7 is contacted with water around the dephosphorization carrier and is a water-filtering type non-woven geotextile with the thickness of 0.5-1.0 mm;
a floating body 8 is arranged on one side of the shell 1 close to the bin cover 3.
Wherein, the outer side of the water-filtering type fabric 7 is also provided with a fixing ring 9, and the fixing ring 9 is used for preventing the water-filtering type fabric 7 and the microporous material 6 from falling off.
The floating body 8 is fixed on the shell 1 and is annular. The floating body 8 is used for enabling the gravity center and the floating center of the dephosphorization carrier not to coincide, enabling the bin cover 3 containing the metal iron block (not shown in the figure) to be deviated to the lighter side (namely to the side of the floating center) of the dephosphorization carrier, so that when the dephosphorization agent is exhausted and the dephosphorization carrier automatically floats to the water surface, the dephosphorization carrier is exposed out of the water surface from one side of the bin cover 3 containing the metal iron block, and a maintainer can conveniently utilize the magnet to take out the dephosphorization carrier floating to the water surface from the water.
The slow release interface 5 is positioned on the lighter side (i.e. the side deviated to the center of buoyancy) of the phosphorus removal carrier, when disturbance force such as aeration does not exist in water, the slow release interface 5 is in the direction of facing downwards under the action of buoyancy of the water and the self gravity of the phosphorus removal carrier, and the probability of impurities accumulated on the surface of the slow release interface 5 can be reduced.
The working principle of the invention is as follows: the biofilm carriers are treated with water to store the phosphorous removal agent. The dephosphorization carrier comprises a storage bin 2 for storing a dephosphorization agent. The storage bin 2 can be opened and closed to replenish the phosphorous removal agent 4. The phosphorus removing agent 4 adopts solid iron salt or aluminum salt.
In use, the dephosphorizing agent 4 in the storage bin 2 is in contact with the water around the dephosphorizing carrier only through the slow-release interface 5. The slow release interface 5 is a composite structure of a microporous material and a water-filtering fabric. The microporous material 6 and the drainage fabric 7 allow a slow release of the phosphorous removal agent into the surrounding sewage 10.
The water-filtering fabric 7 also provides a barrier to insoluble impurities in the water, thereby protecting the microporous material 6 from clogging. When the phosphorus removal carrier stores the phosphorus removal agent, the density is close to that of water, when the phosphorus removal agent is exhausted, the density is smaller than that of water, and the phosphorus removal carrier can automatically float to the water surface when the phosphorus removal agent is exhausted so as to be convenient for maintenance personnel to identify and supplement.
Preferably, the position of the floating body 8 is designed to be biased to the side with the metallic iron block (i.e. the upper part of the shell 1) and away from the slow release interface (i.e. the lower part of the shell 1), so that the center of gravity and the center of buoyancy of the phosphorus removal carrier are not coincident. The metal iron block is arranged on the lighter side (i.e. the side deviated to the floating center) of the dephosphorization carrier, so that when the dephosphorization agent is exhausted and the dephosphorization carrier automatically floats to the water surface, the dephosphorization carrier is exposed out of the water surface from one side of the metal iron block, and a maintainer can conveniently utilize the magnet to take out the dephosphorization carrier floating to the water surface from the water.
The slow release interface 5 is arranged on the heavier side (i.e. the side deviated to the gravity center) of the phosphorus removal carrier, and when disturbance force such as aeration does not exist in water, the slow release interface is in the direction of facing downwards under the action of buoyancy and self gravity of the water, so that the probability of impurities accumulated on the surface of the slow release interface can be reduced.
As shown in FIG. 4, when the phosphorus removal carrier is in a suspension state in the use state, i.e. the storage bin stores the phosphorus removal agent 4, the phosphorus removal carrier is in a suspension state.
As shown in FIG. 5, when the phosphorus removal carrier is in a floating state after the phosphorus removal agent stored in the storage bin is exhausted, the phosphorus removal carrier is exposed out of the water surface at one side of the bin cover 3 containing the metal iron blocks, so that maintenance personnel can conveniently take out the phosphorus removal carrier floating on the water surface from the water by using the magnet.
After having adopted above-mentioned structure, this device can directly throw in the sewage treatment pond and carry out the dephosphorization, and need not to reform transform sewage treatment device, also need not to drag for and observes the dephosphorization agent quality, and automatic come-up when the dephosphorization agent exhausts can used repeatedly after replenishing once more.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to the embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention, the parts not specifically described or shown being exaggerated for clarity of presentation and for clarity of illustration in the prior art and not in any greater detail herein. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and features disclosed herein.

Claims (10)

1. A dephosphorization carrier for sewage treatment equipment is characterized by comprising:
a shell body, a plurality of first connecting rods and a plurality of second connecting rods,
the inside of the shell is provided with a storage bin for containing a phosphorus removing agent, and the phosphorus removing agent is arranged in the storage bin;
one end of the storage bin is sealed by a bin cover, and the other end of the storage bin is a slow release interface for releasing the phosphorus removing agent;
wherein,
the shell is in a suspension state in the sewage when the phosphorus removing agent is not used up;
the shell is in a floating state in the sewage when the phosphorus removing agent is exhausted.
2. The dephosphorization carrier according to claim 1, wherein a floating body is arranged on one side of the shell close to the cover.
3. The dephosphorization vector according to claim 1, wherein the slow release interface comprises a microporous plate and a water filtering fabric arranged outside the microporous plate, and the storage bin is sequentially hermetically connected with the microporous plate and the water filtering fabric;
the distance between the slow release interface and the center of gravity of the phosphorus removal carrier is less than the distance between the slow release interface and the floating center of the phosphorus removal carrier.
4. The dephosphorization vector according to claim 1, wherein the micro-porous plate is a stainless steel plate with through holes with a diameter of 0.3-0.8 mm.
5. The dephosphorization carrier according to claim 1, wherein the water-filtering fabric is a non-woven geotextile.
6. The dephosphorization carrier according to claim 1, wherein the cover and/or the storage compartment are iron.
7. The dephosphorization carrier according to claim 1, wherein the cover and/or the storage compartment contain metallic iron blocks;
the distance between the metal iron block and the center of gravity of the dephosphorization carrier is less than the distance between the slow release interface and the floating center of the dephosphorization carrier.
8. The dephosphorization carrier according to claim 1, wherein a floating body is disposed on the housing.
9. The dephosphorization carrier according to claim 1, wherein the floating body is located near a side of the shell near the cover, and the floating body makes the center of gravity and the center of buoyancy of the dephosphorization carrier misaligned.
10. A method of using the phosphorus removal carrier of any of claims 1-9, comprising the steps of:
A. opening the bin cover, and adding a phosphorus removing agent into the storage bin;
B. closing the bin cover, and throwing the shell into a sewage treatment tank;
C. the shell is suspended in the sewage, and after the phosphorus removing agent is exhausted, the shell floats on the water surface;
D. and fishing out the shell by using a magnet, and reloading the phosphorus removing agent.
CN201611178041.5A 2016-12-19 2016-12-19 A kind of phosphorus-removing carrier and method for sewage disposal device Pending CN106495300A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201611178041.5A CN106495300A (en) 2016-12-19 2016-12-19 A kind of phosphorus-removing carrier and method for sewage disposal device
PCT/CN2016/111712 WO2018112884A1 (en) 2016-12-19 2016-12-23 Phosphorus removal carrier for use with sewage treatment device and method
ZA2019/04607A ZA201904607B (en) 2016-12-19 2019-07-15 Phosphorus removal carrier for sewage treatment device and method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611178041.5A CN106495300A (en) 2016-12-19 2016-12-19 A kind of phosphorus-removing carrier and method for sewage disposal device

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Publication number Priority date Publication date Assignee Title
CN109970162A (en) * 2019-03-28 2019-07-05 浙江大学 A kind of novel dephosphorization sustained release agent and preparation method thereof

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