CN106493971A - Carbon fibre composite helical spring and preparation method thereof and mould - Google Patents

Carbon fibre composite helical spring and preparation method thereof and mould Download PDF

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Publication number
CN106493971A
CN106493971A CN201611080111.3A CN201611080111A CN106493971A CN 106493971 A CN106493971 A CN 106493971A CN 201611080111 A CN201611080111 A CN 201611080111A CN 106493971 A CN106493971 A CN 106493971A
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China
Prior art keywords
carbon
carbon fiber
fibre composite
mould
helical spring
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CN201611080111.3A
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Chinese (zh)
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CN106493971B (en
Inventor
答建成
周细应
朱玉坤
戚文
杨涛
吴德振
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SHANGHAI CHINA SPRING Corp Ltd
Shanghai University of Engineering Science
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SHANGHAI CHINA SPRING Corp Ltd
Shanghai University of Engineering Science
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Priority to CN201611080111.3A priority Critical patent/CN106493971B/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10Coating or impregnating independently of the moulding or shaping step
    • B29B15/12Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16FSPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION
    • F16F1/00Springs
    • F16F1/02Springs made of steel or other material having low internal friction; Wound, torsion, leaf, cup, ring or the like springs, the material of the spring not being relevant
    • F16F1/04Wound springs
    • F16F1/06Wound springs with turns lying in cylindrical surfaces

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • General Engineering & Computer Science (AREA)
  • Springs (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

The present invention relates to a kind of carbon fibre composite helical spring and preparation method thereof and mould, the spring includes spiral spring wire, spring wire is by mandrel, the middle level being wrapped in outside mandrel and the outer layer composition being wrapped in outside middle level, mandrel is made up of some carbon fiber reinforcements, and the mandrel is in torsion shape, carbon fiber reinforcement is made up of some carbon fiber bundles for being impregnated with resin and one layer of carbon cloth for being impregnated with resin being wrapped in outside some carbon fiber bundles, if middle level is the dried layer carbon cloth for being impregnated with resin or the carbon fiber bundle for being impregnated with resin, outer layer is the protective case being made up of flexible pipe.Compared with prior art, spring light weight of the invention, intensity, rigidity and fatigue life are high, absorb spring self vibration ability by force, while insulation and antirust are good, manufacture method is simple, easy, workable, and cost-effective, economizes on resources;Mould designability is strong, easy, mold fouling is little to mold low cost, mould release.

Description

Carbon fibre composite helical spring and preparation method thereof and mould
Technical field
The present invention relates to a kind of composite spring, more particularly, to a kind of carbon fibre composite helical spring and its system Make method and mould.
Background technology
In recent years, world energy sources crisis and petroleum price rise and environmental problem, an urgent demand automobile is towards light-weighted direction Development, be usually used light material (or new material) substitute traditional material structure lightened as target to realize, further improve Fuel utilization ratio has become one of focus of research.
Light material (or new material) includes high strength steel, aluminum, magnesium and titanium alloy, plastics and composite etc.;With gold Category material compare, carbon fibre composite (such as carbon fibre reinforced plastic (hereinafter, referred to CFRP)) be lightweight, high rigidity, The advantages of high intensity, high antifatigue, wear-resisting and good antivibration absorbing, its specific modulus are higher than 5 times of steel and aluminium alloy, than strong 3 times higher than steel and aluminium alloy, but proportion very little is spent, the weight of per unit volume only has the 20% of steel.Additionally, carbon fiber is multiple Condensation material has higher corrosion resistance and a relatively low thermal expansivity, more more robust than steel and be difficult to get rusty, and car manufactures are Energetically carry out attempting for lightweight composite being applied to interior material for vehicle, vehicle body, leaf spring, vehicle bumper etc..
However, conventional springs (i.e. helical spring) great majority are wound and made, manufacturing process by metal materials (steel) Extremely complex;And physical property of the spring mainly by metal material, realize that by certain conversion regime which stores energy Amount and release energy, so as to make the spring with damping, pooling feature, and be applied to various mechanisms and industrial machinery On part, such as on automobile, locomotive and aerospace field (CN103573892 A).For adapting to the demand of industry development, metal The spring that material is made is difficult to meet use demand, and has reached one from design, selection, manufacture and inspection metal spring Individual bottleneck period.Therefore, preparing coil type spring alternative metals helical spring with carbon fibre composite will become industry development Trend.
Many researcheres have been attempted manufacturing coil type spring using CFRP.However, because the easily pressurized stresss under compression of CFRP or The impact of shear stress, produces coil type spring by single carbon fibre tow and is difficult to produce enough tension force and carry to elastomer For bounce (103388642 A of CN).Separately have, the spring that carbon fibre composite makes is faced with some challenges, such as elasticity Poor, frangible, anisotropy is high, and these characteristics are substantially to be not suitable for spring, from and the carbon fibre composite spring produced Deformation is little, and coefficient of elasticity is low, and bearing load is little.Therefore, using the high-tensile that carbon fibre composite is unique, design is a kind of The composite spring of special construction can be only achieved big bearing capacity (2014/014481 A1 of WO;WO 02/099307 A1;US 2852424 A;US 4773633 A;US 8857801 B2;US 7857294 B2;US 5685525 A;US 4260143 A; CN 104690984 A;CN 103221199 A).Therefore, in the urgent need to develop one kind can realize mitigate weight, have excellent Durability and replace the carbon fibre composite helical spring structure of ordinary metallic material helical spring most important.
The making fibre reinforced composites coil type spring that currently mentions manufacture method is good, operation difficulty big, consumption When taking a lot of work, it is desirable to which equipment capital input is big, waste of material is serious, and the carbon fibre composite component costs of production are high.(EP 0637700B1;US 8490530B2;CN 1480658A;CN 1651795A;CN 1232931A;CN 101439580A)
Additionally, existing manufacture fibre reinforced composites spring forming mould (2647481 A1 of EP;US 4434121 A;US 5988612 A;US 4473217 A;US 6986203 B2;102909870 A of CN), design process is complicated, molds into This height, the die-filling and demoulding are difficult, low production efficiency.And during mould closure heating, as carbon fiber is infiltrated by resin Uneven and cause product surface or inside to there is bubble, cause surface irregularity.In process of production due to resin reaction Internal stress is produced, when helping without external force, internal stress cannot be offset, strong influence, meeting can be produced to the strength character of product Directly affect the service life of product.
Content of the invention
The purpose of the present invention be exactly in order to overcome defect that above-mentioned prior art is present and provide a kind of not only have light weight, The advantages of intensity height, rigidity height, high fatigue life and strong absorption spring self vibration ability, and the good carbon of insulation and antirust Fibrous composite helical spring.
Further object is that propose a kind of method for making carbon fibre composite helical spring and its Mould, the manufacture method are simple, easy, workable, and cost-effective, economize on resources;In addition, the present invention is involved And mould designability is strong, die sinking low cost, mould release are easy, mold fouling is little.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of carbon fibre composite helical spring, including spiral spring wire, described spring wire is by mandrel, bag The middle level being rolled in outside mandrel and the outer layer composition being wrapped in outside middle level, described mandrel are made up of some carbon fiber reinforcements, And the mandrel is in shape is reversed, if described carbon fiber reinforcement by some carbon fiber bundles for being impregnated with resin and is wrapped in this One layer outside dry root carbon fiber bundle is impregnated with the carbon cloth composition of resin, if described middle level is the dried layer carbon for being impregnated with resin Fiber cloth is impregnated with the carbon fiber bundle of resin, and described outer layer is the protective case being made up of flexible pipe.
Used as preferred technical scheme, the torsion number of turns of described mandrel is 15~60 circles/rice.
Mandrel is played a supporting role by the torsion of a fixing turn, and can absorb the vibrations of itself during spring movement Effect.
As preferred technical scheme, constitute the carbon cloth or carbon fiber bundle in middle level and the central shaft of mandrel in 25~ 75 ° of angle.
25~75 ° of angle can reduce shearing stress effect in carbon fibre composite helical spring loading process, and increase Its mechanical performance.
As preferred technical scheme, the carbon cloth and the carbon for constituting carbon fiber layer reinforcement of carbon fiber reinforcement is constituted Angle of the central shaft of fibre bundle in 5~30 °.
Constitute the carbon cloth of carbon fiber reinforcement and transition zone constituted by the network structure that is necessarily crosslinked, crosslinking netted Structure can overcome the carbon fiber interlocking of composite material interface, the transition zone to be related to asking for whole helical spring layering Topic, especially determines the fatigue life of composite helical spring, can effectively improve its fatigue life by being arranged on the layer.
Used as preferred technical scheme, described carbon fiber reinforcement contains 30~50 carbon fiber bundles.In the quantitative range Carbon fibe beam cause final obtained spiral paralysis that there is reasonable forming shape, too many or its molding shape can be affected very little Shape.
Used as preferred technical scheme, described flexible pipe includes plastic flexible pipe, rubber hose or silicon rubber hose.
The protective case can eliminate the external defects of whole carbon fibre composite spring, so as to being formed smooth and being dried Surface.
The manufacture method of described carbon fibre composite helical spring, comprises the following steps:
(1) preparation of prepreg:Carbon fiber bundle and carbon cloth surface are cleaned, then in 50~120 DEG C of temperature Isothermal holding is carried out under degree so that the dipping of follow-up glue is more abundant;
(2) glue configuration:By epoxy resin, defoamer, toughener and fire retardant mass ratio 100:1.5~2.5: 0.5~1.5:After 15~30 minutes are incubated at 50~70 DEG C after 0.5~1.5 proportional arrangement, amine curing agent is added, described The mass ratio of amine curing agent and epoxy resin be 100:5~10, then application of vacuum 2~20 minutes, that is, obtain glue;
(3) dipping of prepreg:The surface spraying silane coupler of carbon fiber bundle and carbon cloth after isothermal holding, Then the glue that spraying process (2) is obtained;
(4) carbon fibre composite preformed member is prepared:In some carbon fiber bundle outer wrappings processed through step (3) One layer of one layer of carbon cloth processed through step (3), forms carbon fiber reinforcement, then turns round some carbon fiber reinforcements Turn, if wrapping up carbon cloth or the carbon fiber bundle processed through step (3) that dried layer is processed through step (3), be arranged flexible pipe, right Which applies multiple pressure, obtains carbon fibre composite preformed member;
(5) molding:Carbon fibre composite preformed member is loaded by mould matched moulds by filament winding process, then Elevated cure in vacuum drying oven, removes mould and obtains carbon fibre composite helical spring after cooling.
Used as preferred technical scheme, the elevated cure process in described step (5) includes:
After 10~30min is placed under (a) room temperature environment, 70~80 DEG C are warming up to the heating rate of 2~10 DEG C/min, and Keep 20~35min;
B () is warming up to 95~105 DEG C with the heating rate of 3~10 DEG C/min, and keep 10~25min;
C () is warming up to 120~135 DEG C with the heating rate of 4~10 DEG C/min, and keep 10~25min.
The mould of described carbon fibre composite helical spring is made, including core and is set in outside core External mold and retaining mechanism, described core are cylindrical, and lateral surface is provided with helical groove, and described external mold is cylindrical, It is made up of first for being detachably connected exceptionally mould and the second exceptionally mould, the cross section of the described first exceptionally mould and the second exceptionally mould Semicircular arc, the medial surface of external mold is provided with the helical groove on helical groove, and external mold medial surface and core Helical groove on lateral surface matches, and constitutes complete spiral type circular groove.
Used as preferred technical scheme, described retaining mechanism includes that the circular band with nut and screw are constituted, institute The circular band that states is set in outside external mold;The central axis at the two ends of described core further respectively have thread groove, described Fixing axle has been threaded connection in thread groove.
Compared with prior art, the invention has the advantages that:
Carbon fiber (reinforced resin base) the composite helical spring of the present invention, can not only meet mechanical property (intensity And rigidity) on requirement, and with very strong resistance to corrosion.Additionally, carbon fibre composite helical spring can be realized Light-weighted target so as to be widely used on components of damping needed for some;In addition, the making composite spiral bullet The method of spring and its mould, the manufacture method are simple, easy, workable, and cost-effective, economize on resources;Separately Outward, involved mould designability of the invention is strong, and easily, mold fouling is few for die sinking low cost, mould release.
Description of the drawings
Fig. 1 is the structural representation of the helical spring of the present invention and the cross-sectional view of spring wire;
Fig. 2 is the structural representation of the spring wire of the present invention;
Fig. 3 is the structural representation of the mandrel with middle level of the helical spring of the present invention;
Fig. 4 is the structural representation of the mandrel (carbon cloth without carbon fiber reinforcement is constituted) of the present invention;
Fig. 5 is the structural representation of the outer carbon cloth parcel of mandrel in embodiment 1;
Fig. 6 is the structural representation of outer layer in embodiment 1;
Fig. 7 is the flow chart of the manufacture method of carbon fibre composite helical spring in embodiment 1;
Fig. 8 is the schematic diagram of elevated cure process in the manufacture method of carbon fibre composite helical spring in embodiment 1;
Fig. 9 is the structural representation of the core of the mould of the present invention and the first exceptionally mould.
In figure, 1 is mandrel, and 11 is carbon fiber reinforcement, and 111 for constituting the carbon fiber bundle of carbon fiber reinforcement, and 112 is structure Into the carbon cloth of carbon fiber reinforcement, 2 is middle level, and 21 for constituting the carbon cloth in middle level, and 3 is outer layer, and 4 is the center of mandrel Axle, 5 is spring wire, and 61 is core, and 62 is external mold, and 63 is helical groove, and 64 is fixing axle.
Specific embodiment
The present invention is described in detail with specific embodiment below in conjunction with the accompanying drawings.
Embodiment 1
A kind of carbon fibre composite helical spring, as shown in figs. 1 to 6, including spiral spring wire 5, described Spring wire 5 is made up of mandrel 1, the middle level being wrapped in outside mandrel 12 and the outer layer 3 being wrapped in outside middle level 2, and mandrel 1 is by some carbon Fibre reinforcement 11 is constituted, and the mandrel 1 is in reversing shape, and described carbon fiber reinforcement 11 is by being impregnated with some of resin Carbon fiber bundle and one layer of carbon cloth for being impregnated with resin being wrapped in outside some carbon fiber bundles are constituted, and generally select composition The Carbon fibe beam of carbon fiber reinforcement is 30~50, and the present embodiment selects 30 (Fig. 1 is only used as illustrating), described middle level 2 If for being impregnated with the dried layer carbon cloth of resin or being impregnated with the carbon fiber bundle of resin, it is to be impregnated with that the present embodiment selects middle level 2 If the dried layer carbon cloth of resin, described outer layer 3 are the protective case being made up of flexible pipe.
The Choice of Resin epoxy resin of the present embodiment, by epoxy resin-impregnated so that between carbon fiber bundle, Carbon fibe beam Not only by physical bond between carbon cloth and between carbon cloth and carbon cloth and good by chemical action It is combined together.
Specifically, as shown in figure 4, the torsion number of turns of mandrel can be 15~60 circles/rice, the present embodiment selects to reverse the number of turns For 30 circles/rice, constitute in the carbon cloth 112 of carbon fiber reinforcement and the carbon fiber bundle 111 of composition carbon fiber layer reinforcement Heart axle can be in 5~30 ° of angle, and it is 25 ° that the present embodiment selects the angle.Constitute every layer of carbon cloth parcel mandrel in middle level When need the angle that with the central shaft of shaft core can be in 25~75 °, the present embodiment selects the angle for 45 °, such as Fig. 3 and Fig. 5 institutes Show.
The flexible pipe for constituting outer layer includes that plastic flexible pipe, rubber hose or silicon rubber hose, the present embodiment select plastic flexible pipe, Be wrapped on the prepreg that mandrel and middle level are constituted, and releasing agent scribbled between middle level and outer layer, by coating release agent so that The more smooth zero defect in the carbon fibre composite helical spring surface of preparation.
The manufacture method of the carbon fibre composite helical spring is comprised the following steps:
(1) preparation of prepreg:Carbon fiber bundle and carbon cloth surface are cleaned, then in 50~120 DEG C of temperature Isothermal holding is carried out under degree, and the present embodiment selects 100 DEG C of holding temperature.
Wherein carbon fiber bundle and carbon cloth are formed by carbon fiber wire, and specific cleaning step is cleaned to which using abluent 10~15 minutes.
(2) glue configuration:By epoxy resin, defoamer, toughener and fire retardant mass ratio 100:1.5~2.5: 0.5~1.5:After 15~30 minutes are incubated under 50~70 DEG C of water-bath after 0.5~1.5 proportional arrangement, present certain Flowable state, brings placement out 10~15 minutes, adds the mass ratio of amine curing agent, described amine curing agent and epoxy resin For 100:5~10, application of vacuum 2~20 minutes in there-necked flask are then put it into, that is, obtains glue.
It is 100 that the present embodiment selects the mass ratio of epoxy resin, defoamer, toughener, fire retardant and amine curing agent:2: 1:1:8.
(3) dipping of prepreg:Carbon fiber bundle and carbon cloth after by isothermal holding is laid on testing stand, on its surface Spraying silane coupler, the glue that then spraying process (2) is obtained.
(4) prepare carbon fibre composite preformed member (process meanses are in the prepreg of dipping):Through step (3) place One layer of one layer of carbon cloth processed through step (3) of some carbon fiber bundle outer wrappings of reason, forms carbon fiber reinforcement, so Afterwards some carbon fiber reinforcements are reversed, if the carbon cloth that processes through step (3) of parcel dried layer or through step (3) place The carbon fiber bundle of reason, is arranged flexible pipe, applies multiple pressure using pressurized equipment to which, obtains carbon fibre composite preforming Part.
(5) molding:Carbon fibre composite preformed member is loaded by mould matched moulds by filament winding process, then Elevated cure in vacuum drying oven, removes mould and obtains carbon fibre composite helical spring after furnace cooling.
Elevated cure process wherein in step (5) is comprised the following steps:
After 10~30min is placed under (a) room temperature environment, 70~80 DEG C are warming up to the heating rate of 2~10 DEG C/min, and Keep 20~35min;
B () is warming up to 95~105 DEG C with the heating rate of 3~10 DEG C/min, and keep 10~25min;
C () is warming up to 120~135 DEG C with the heating rate of 4~10 DEG C/min, and keep 10~25min.
Elevated cure process in the present embodiment is as shown in Figure 8.
(6) processed afterwards:(pruning) is modified, carbon fibre composite coil type spring as shown in Figure 1 is obtained.
Make the present embodiment carbon fibre composite helical spring mould as shown in figure 9, including core 61 with And the external mold that is set in outside core 61 and retaining mechanism, described core 61 is cylindrical, and lateral surface is provided with helical groove 63, the central axis at the two ends of described core 61 further respectively have thread groove, are connected by screw thread in described thread groove It is connected to fixing axle 64.Described external mold is cylindrical, is made up of first for being detachably connected exceptionally mould and the second exceptionally mould, described The first exceptionally mould 62 and the second exceptionally mould cross section semicircular arc, the medial surface of external mold is provided with helical groove The helical groove 63 on 61 lateral surface of helical groove 63 and core on 63, and external mold medial surface matches, and has constituted Whole spiral type circular groove.Retaining mechanism includes that circular band and the screw with nut, described circular band are set in external mold Outward.

Claims (10)

1. a kind of carbon fibre composite helical spring, including spiral spring wire (5), described spring wire (5) is by core Axle (1), it is wrapped in the outer middle level (2) of mandrel (1) and is wrapped in middle level (2) outer layer (3) composition outward, it is characterised in that is described Mandrel (1) be made up of some carbon fiber reinforcements (11), and the mandrel (1) in reverse shape, described fibre reinforced Body (11) is impregnated with resin by some carbon fiber bundles for being impregnated with resin and be wrapped in outside some carbon fiber bundles one layer Carbon cloth composition, described middle level (2) is if be the dried layer carbon cloth for being impregnated with resin or the carbon fiber for being impregnated with resin Beam, described outer layer (3) is the protective case being made up of flexible pipe.
2. carbon fibre composite helical spring according to claim 1, it is characterised in that the torsion of described mandrel (1) Number turn-take for 15~60 circles/rice.
3. carbon fibre composite helical spring according to claim 1, it is characterised in that constitute the carbon cloth in middle level (21) or carbon fiber bundle and mandrel (1) angle of the central shaft (4) in 25~75 °.
4. carbon fibre composite helical spring according to claim 1, it is characterised in that constitute carbon fiber reinforcement The central shaft of carbon cloth (112) and the carbon fiber bundle (111) for constituting carbon fiber layer reinforcement is in 5~30 ° of angle.
5. the carbon fibre composite helical spring according to claim 1 or 4, it is characterised in that described carbon fiber increases Strong body (11) contains 30~50 carbon fiber bundles.
6. carbon fibre composite helical spring according to claim 1, it is characterised in that described flexible pipe includes plastics Flexible pipe, rubber hose or silicon rubber hose.
7. the manufacture method of carbon fibre composite helical spring as claimed in claim 1, it is characterised in that including following step Suddenly:
(1) preparation of prepreg:Carbon fiber bundle and carbon cloth surface are cleaned, then at a temperature of 50~120 DEG C Carry out isothermal holding;
(2) glue configuration:By epoxy resin, defoamer, toughener and fire retardant mass ratio 100:1.5~2.5:0.5~ 1.5:After 15~30 minutes are incubated at 50~70 DEG C after 0.5~1.5 proportional arrangement, amine curing agent, described amine is added Class firming agent is 100 with the mass ratio of epoxy resin:5~10, then application of vacuum 2~20 minutes, that is, obtain glue;
(3) dipping of prepreg:The surface spraying silane coupler of carbon fiber bundle and carbon cloth after isothermal holding, then The glue that spraying process (2) is obtained;
(4) carbon fibre composite preformed member is prepared:In one layer of some carbon fiber bundle outer wrappings processed through step (3) Through one layer of carbon cloth that step (3) is processed, carbon fiber reinforcement is formed, then some carbon fiber reinforcements is reversed, If carbon cloth or the carbon fiber bundle processed through step (3) that parcel dried layer is processed through step (3), are arranged flexible pipe, to which Apply multiple pressure, obtain carbon fibre composite preformed member;
(5) molding:Carbon fibre composite preformed member is loaded by mould matched moulds by filament winding process, then true Elevated cure in empty baking oven, removes mould and obtains carbon fibre composite helical spring after cooling.
8. the manufacture method of carbon fibre composite helical spring according to claim 7, it is characterised in that described step Suddenly the elevated cure process in (5) includes:
After 10~30min is placed under (a) room temperature environment, 70~80 DEG C are warming up to the heating rate of 2~10 DEG C/min, and are kept 20~35min;
B () is warming up to 95~105 DEG C with the heating rate of 3~10 DEG C/min, and keep 10~25min;
C () is warming up to 120~135 DEG C with the heating rate of 4~10 DEG C/min, and keep 10~25min.
9. the mould of carbon fibre composite helical spring as claimed in claim 1 is made, it is characterised in that including core Mould (61) and the outer external mold of core (61) and retaining mechanism is set in, described core (61) is cylindrical, and lateral surface sets There is helical groove (63), described external mold is cylindrical, be made up of first for being detachably connected exceptionally mould and the second exceptionally mould, The cross section of the exceptionally mould of described first (62) and the second exceptionally mould is semicircular arc, and the medial surface of external mold is provided with helical form Helical groove (63) phase on groove (63), and the helical groove (63) and core (61) lateral surface on external mold medial surface Coupling, constitutes complete spiral type circular groove.
10. the mould of carbon fibre composite helical spring according to claim 9, it is characterised in that described Retaining mechanism includes that circular band and the screw with nut, described circular band are set in outside external mold;Described core (61) central axis at two ends further respectively have thread groove, have been threaded connection fixing axle in described thread groove (64).
CN201611080111.3A 2016-11-30 2016-11-30 Carbon fibre composite helical spring and preparation method thereof and molding die Expired - Fee Related CN106493971B (en)

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CN107160710A (en) * 2017-07-25 2017-09-15 哈尔滨工业大学 A kind of composite material rectangular section floating die assembly and the method that spring is prepared using the mould
CN107285796A (en) * 2017-07-21 2017-10-24 湖南金博碳素股份有限公司 C-base composte material helical spring and production method
CN107650396A (en) * 2017-09-08 2018-02-02 常熟市瑞思知识产权服务有限公司 A kind of preparation method of composite helical spring
CN107989885A (en) * 2017-11-30 2018-05-04 江阴振宏重型锻造有限公司 A kind of wind power principal axis and its processing technology equipped with enhancement layer
CN108953438A (en) * 2018-07-30 2018-12-07 江苏凯威新材料科技有限公司 A kind of wirerope with favorable elasticity
CN110512155A (en) * 2019-07-11 2019-11-29 江苏长龄液压股份有限公司 A kind of tapered spring blank and processing tool and processing technology
CN111355010A (en) * 2020-03-16 2020-06-30 北京航空航天大学 Composite material helical antenna and preparation method thereof
CN111520425A (en) * 2020-03-31 2020-08-11 吉林大学 Bionic composite material spiral spring
CN112537057A (en) * 2020-11-26 2021-03-23 湖南碳谷新材料有限公司 Carbon-carbon support ring preparation mold and preparation method
CN112873913A (en) * 2021-02-03 2021-06-01 四川大学 Preparation method of composite material of spiral spring structure fiber and thermosetting resin
CN114872350A (en) * 2022-05-18 2022-08-09 奇瑞汽车股份有限公司 Method for manufacturing coil spring and variable pitch coil spring

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CN106438796A (en) * 2016-11-08 2017-02-22 浙江工业大学 Composite spiral spring
CN107285796B (en) * 2017-07-21 2020-09-04 湖南金博碳素股份有限公司 Carbon-based composite material spiral spring and production method thereof
CN107285796A (en) * 2017-07-21 2017-10-24 湖南金博碳素股份有限公司 C-base composte material helical spring and production method
CN107160710A (en) * 2017-07-25 2017-09-15 哈尔滨工业大学 A kind of composite material rectangular section floating die assembly and the method that spring is prepared using the mould
CN107650396A (en) * 2017-09-08 2018-02-02 常熟市瑞思知识产权服务有限公司 A kind of preparation method of composite helical spring
CN107989885A (en) * 2017-11-30 2018-05-04 江阴振宏重型锻造有限公司 A kind of wind power principal axis and its processing technology equipped with enhancement layer
CN107989885B (en) * 2017-11-30 2023-10-17 振宏重工(江苏)股份有限公司 Wind power main shaft with reinforcing layer and processing technology thereof
CN108953438A (en) * 2018-07-30 2018-12-07 江苏凯威新材料科技有限公司 A kind of wirerope with favorable elasticity
CN110512155A (en) * 2019-07-11 2019-11-29 江苏长龄液压股份有限公司 A kind of tapered spring blank and processing tool and processing technology
CN111355010A (en) * 2020-03-16 2020-06-30 北京航空航天大学 Composite material helical antenna and preparation method thereof
CN111520425A (en) * 2020-03-31 2020-08-11 吉林大学 Bionic composite material spiral spring
CN111520425B (en) * 2020-03-31 2021-06-01 吉林大学 Bionic composite material spiral spring
CN112537057A (en) * 2020-11-26 2021-03-23 湖南碳谷新材料有限公司 Carbon-carbon support ring preparation mold and preparation method
CN112873913A (en) * 2021-02-03 2021-06-01 四川大学 Preparation method of composite material of spiral spring structure fiber and thermosetting resin
CN114872350A (en) * 2022-05-18 2022-08-09 奇瑞汽车股份有限公司 Method for manufacturing coil spring and variable pitch coil spring

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