CN106492860A - A kind of preparation method of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst - Google Patents
A kind of preparation method of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst Download PDFInfo
- Publication number
- CN106492860A CN106492860A CN201610911880.7A CN201610911880A CN106492860A CN 106492860 A CN106492860 A CN 106492860A CN 201610911880 A CN201610911880 A CN 201610911880A CN 106492860 A CN106492860 A CN 106492860A
- Authority
- CN
- China
- Prior art keywords
- phosphate
- yttrium
- concentration
- manganese
- composite catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 21
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 title claims abstract description 19
- 239000002131 composite material Substances 0.000 title claims abstract description 18
- 229910000164 yttrium(III) phosphate Inorganic materials 0.000 title claims abstract description 18
- UXBZSSBXGPYSIL-UHFFFAOYSA-K yttrium(iii) phosphate Chemical compound [Y+3].[O-]P([O-])([O-])=O UXBZSSBXGPYSIL-UHFFFAOYSA-K 0.000 title claims abstract description 18
- 229910000398 iron phosphate Inorganic materials 0.000 title claims abstract description 15
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 7
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000019799 monosodium phosphate Nutrition 0.000 claims abstract description 6
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical class [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims abstract description 6
- NGDQQLAVJWUYSF-UHFFFAOYSA-N 4-methyl-2-phenyl-1,3-thiazole-5-sulfonyl chloride Chemical compound S1C(S(Cl)(=O)=O)=C(C)N=C1C1=CC=CC=C1 NGDQQLAVJWUYSF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000000926 separation method Methods 0.000 claims abstract description 4
- KWMKCPAIFULUBU-UHFFFAOYSA-N phosphoric acid yttrium Chemical compound [Y].P(O)(O)(O)=O KWMKCPAIFULUBU-UHFFFAOYSA-N 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 8
- 239000011259 mixed solution Substances 0.000 abstract description 5
- 238000001556 precipitation Methods 0.000 abstract description 5
- 230000015556 catabolic process Effects 0.000 abstract description 4
- 238000006731 degradation reaction Methods 0.000 abstract description 4
- 239000013078 crystal Substances 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000001699 photocatalysis Effects 0.000 description 6
- 239000002351 wastewater Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 238000007146 photocatalysis Methods 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 238000004042 decolorization Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 2
- YYYARFHFWYKNLF-UHFFFAOYSA-N 4-[(2,4-dimethylphenyl)diazenyl]-3-hydroxynaphthalene-2,7-disulfonic acid Chemical compound CC1=CC(C)=CC=C1N=NC1=C(O)C(S(O)(=O)=O)=CC2=CC(S(O)(=O)=O)=CC=C12 YYYARFHFWYKNLF-UHFFFAOYSA-N 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229960000907 methylthioninium chloride Drugs 0.000 description 2
- STZCRXQWRGQSJD-UHFFFAOYSA-M sodium;4-[[4-(dimethylamino)phenyl]diazenyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(C)C)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-UHFFFAOYSA-M 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- FLWIXYADULTFKM-UHFFFAOYSA-N OO.[O-2].[O-2].[Mn+4] Chemical compound OO.[O-2].[O-2].[Mn+4] FLWIXYADULTFKM-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003933 environmental pollution control Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- -1 iron ion Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/187—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
-
- B01J35/39—
-
- B01J35/61—
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/40—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Abstract
The present invention discloses a kind of preparation method of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst, in turn includes the following steps:Be 0.1~0.5mol/L ferrous nitrate and by the mixing of yttrium nitrate solution that 5~10mL concentration is 0.1~0.5mol/L by 10mL concentration, 0.2~0.4g manganese dioxide is added in mixed solution, be stirred vigorously the H that lower 2~5mL of Deca mass concentrations are 30%2O2, continuing 30~60min of stirring, then 10~15mL of Deca concentration is 0.2~0.8mol/L sodium dihydrogen phosphates thereto, after 60~100min of stirring, solid is washed with deionized 3~5 times by precipitation, solid-liquid separation, is dried at 105 DEG C;The product that drying is obtained is calcined 5~8h at 400~600 DEG C, you can obtain a kind of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst.Obtained catalyst has preferable crystal structure and has larger specific surface area, stable, and light degradation treatment effeciency is high.
Description
Technical field
The present invention relates to novel environmental pollution control material field, more particularly to a kind of iron phosphate/manganese phosphate/yttrium phosphate is compound
The preparation method of catalyst.
Background technology
With the development of science and technology, the murder by poisoning organic pollution produced in industrial and agricultural production seriously threatens environment and people
The health of class, seeks a kind of new and effective environmental improvement technology and has great importance.Photocatalysis technology is because of its energy-conservation, height
Effect, contaminant degradation are thorough, non-secondary pollution advantage, have become a kind of emerging environmental improvement with important application prospect at present
Technology.In recent years, the development of new and effective visible-light photocatalyst becomes an important research content in photocatalysis technology,
Wherein there is the catalysis material of surface plasma resonance effect, because of its unique Surface Physical Chemistry property and efficiently visible
Light photocatalysis performance, becomes one of focus of research.
However, the visible-light photocatalysis material that is reported at present is most with higher photo-generated carrier recombination rate and poor
Visible absorption, cause its quantum efficiency relatively low.Therefore, new and effective visible-light photocatalysis material is developed, expands quasiconductor
Material spectrum response range and promotion light induced electron and hole are efficiently separated, and are become current catalysis material research field and are badly in need of
The problem in science of solution.
Content of the invention
The purpose of the present invention is for overcoming the shortcomings of in prior art during photocatalytic pollutant degradation, there is provided a kind of phosphorus
The preparation method of sour ferrum/manganese phosphate/yttrium phosphate composite catalyst.
For this purpose, the invention provides technical scheme below, a kind of system of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst
Preparation Method, in turn includes the following steps:
1) it is 0.1~0.5mol/L ferrous nitrate and by nitre that 5~10mL concentration is 0.1~0.5mol/L by 10mL concentration
Sour yttrium solution mixing, adds 0.2~0.4g manganese dioxide in mixed solution, and being stirred vigorously lower 2~5mL of Deca mass concentrations is
30% H2O2, continue 30~60min of stirring, then 10~15mL of Deca concentration be 0.2~0.8mol/L sodium dihydrogen phosphate thereto
Solution, after 60~100min of stirring, solid is washed with deionized 3~5 times by precipitation, solid-liquid separation, is dried at 105 DEG C;
2) product that obtains will be dried and calcines 5~8h at 400~600 DEG C, you can obtain a kind of iron phosphate/manganese phosphate/
Yttrium phosphate composite catalyst.
The present invention has following superiority:In this process using hydrogen peroxide manganese dioxide reduction simultaneous oxidation iron ion,
Manganese is progressively transformed in solution during reaction by solid, can be formed with the phosphate radical for adding uniform compound
Body.Obtained catalyst has preferable crystal structure and has larger specific surface area, stable, and light degradation treatment effeciency is high.
Specific embodiment
Describe the present invention with reference to embodiment in detail, but the present invention is not limited to this.
Embodiment 1
By 10mL concentration be 0.5mol/L ferrous nitrate and by 10mL concentration for 0.5mol/L yttrium nitrate solution mix, to
0.4g manganese dioxide is added in mixed solution, the H that lower Deca 5mL mass concentration is 30% is stirred vigorously2O2, continue stirring
60min, then Deca 15mL concentration is 0.8mol/L sodium dihydrogen phosphates thereto, after stirring 100min, precipitation, solid-liquid point
From, solid is washed with deionized 5 times, at 105 DEG C dry;The product that drying is obtained is calcined 8h at 600 DEG C, you can
Obtain a kind of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst.
It is used for processing waste water containing acid scarlet by obtained iron phosphate/manganese phosphate/yttrium phosphate composite catalyst:0.5g phosphoric acid
Ferrum/manganese phosphate/yttrium phosphate composite catalyst is added in the acid scarlet waste water that 50mL concentration is 20mg/L, in 300w Metal halogen lamps
Under irradiation, 1h is reacted, percent of decolourization is 94.8%.
Embodiment 2
By 10mL concentration be 0.1mol/L ferrous nitrate and by 5mL concentration for 0.1mol/L yttrium nitrate solution mix, to
0.2g manganese dioxide is added in mixed solution, the H that lower Deca 2mL mass concentration is 30% is stirred vigorously2O2, continue stirring
30min, then Deca 10mL concentration is 0.2mol/L sodium dihydrogen phosphates thereto, after stirring 60min, precipitation, solid-liquid separation,
Solid is washed with deionized 3 times, is dried at 105 DEG C;The product that drying is obtained is calcined 5h at 400 DEG C, you can
Arrive a kind of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst.
It is used for processing wastewater containing methylene blue by obtained iron phosphate/manganese phosphate/yttrium phosphate composite catalyst:0.5g phosphoric acid
Ferrum/manganese phosphate/yttrium phosphate composite catalyst is added in the methylene blue waste water that 50mL concentration is 20mg/L, in 300w Metal halogen lamps
Under irradiation, 1h is reacted, percent of decolourization is 97.5%.
Embodiment 3
By 10mL concentration be 0.1mol/L ferrous nitrate and by 8mL concentration for 0.4mol/L yttrium nitrate solution mix, to
0.2g manganese dioxide is added in mixed solution, the H that lower Deca 2mL mass concentration is 30% is stirred vigorously2O2, continue stirring
50min, then Deca 15mL concentration is 0.8mol/L sodium dihydrogen phosphates thereto, after stirring 100min, precipitation, solid-liquid point
From, solid is washed with deionized 5 times, at 105 DEG C dry;The product that drying is obtained is calcined 8h at 600 DEG C, you can
Obtain a kind of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst.
It is used for processing the waste water of II containing gold orange by obtained iron phosphate/manganese phosphate/yttrium phosphate composite catalyst:0.5g phosphoric acid
Ferrum/manganese phosphate/yttrium phosphate composite catalyst is added in the gold orange II waste water that 100mL concentration is 10mg/L, in 300w Metal halogen lamps
Under irradiation, 1h is reacted, percent of decolourization is 96.8%.
Claims (1)
1. a kind of preparation method of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst, it is characterised in that:1) by 10mL concentration it is
0.1~0.5mol/L ferrous nitrate and by the mixing of yttrium nitrate solution that 5~10mL concentration is 0.1~0.5mol/L, molten to mixing
0.2~0.4g manganese dioxide is added in liquid, the H that lower 2~5mL of Deca mass concentrations are 30% is stirred vigorously2O2, continue stirring 30
~60min, then 10~15mL of Deca concentration is 0.2~0.8mol/L sodium dihydrogen phosphates thereto, stirs 60~100min
Afterwards, precipitate, solid is washed with deionized 3~5 times by solid-liquid separation, dry at 105 DEG C;
2) product that drying is obtained is calcined 5~8h at 400~600 DEG C, you can obtain a kind of iron phosphate/manganese phosphate/phosphoric acid
Yttrium composite catalyst.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610911880.7A CN106492860A (en) | 2016-10-19 | 2016-10-19 | A kind of preparation method of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610911880.7A CN106492860A (en) | 2016-10-19 | 2016-10-19 | A kind of preparation method of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106492860A true CN106492860A (en) | 2017-03-15 |
Family
ID=58294448
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610911880.7A Pending CN106492860A (en) | 2016-10-19 | 2016-10-19 | A kind of preparation method of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106492860A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108772081A (en) * | 2018-07-12 | 2018-11-09 | 武汉工程大学 | A kind of method FePO4 heterogeneous visible light Fenton catalyst and handle organic wastewater |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0272132A (en) * | 1988-09-08 | 1990-03-12 | Mitsui Toatsu Chem Inc | Production of phenol |
CN103464186A (en) * | 2013-09-29 | 2013-12-25 | 天津工业大学 | Lead phosphate and silver phosphate composite photocatalyst and preparation method thereof |
CN103539097A (en) * | 2013-10-30 | 2014-01-29 | 渤海大学 | Preparation method of multi-shape alkaline manganese phosphate microcrystal |
CN103551170A (en) * | 2013-10-23 | 2014-02-05 | 三棵树涂料股份有限公司 | Hydroxyl apatite layer-wrapped photocatalytic nano titanium dioxide powder and application thereof |
CN104801323A (en) * | 2015-04-17 | 2015-07-29 | 北京师范大学 | Lithium iron phosphate visible-light catalyst and preparation method thereof |
-
2016
- 2016-10-19 CN CN201610911880.7A patent/CN106492860A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0272132A (en) * | 1988-09-08 | 1990-03-12 | Mitsui Toatsu Chem Inc | Production of phenol |
CN103464186A (en) * | 2013-09-29 | 2013-12-25 | 天津工业大学 | Lead phosphate and silver phosphate composite photocatalyst and preparation method thereof |
CN103551170A (en) * | 2013-10-23 | 2014-02-05 | 三棵树涂料股份有限公司 | Hydroxyl apatite layer-wrapped photocatalytic nano titanium dioxide powder and application thereof |
CN103539097A (en) * | 2013-10-30 | 2014-01-29 | 渤海大学 | Preparation method of multi-shape alkaline manganese phosphate microcrystal |
CN104801323A (en) * | 2015-04-17 | 2015-07-29 | 北京师范大学 | Lithium iron phosphate visible-light catalyst and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
邵淑文等,: ""金属磷酸盐在光催化材料中的研究进展"", 《应用化工》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108772081A (en) * | 2018-07-12 | 2018-11-09 | 武汉工程大学 | A kind of method FePO4 heterogeneous visible light Fenton catalyst and handle organic wastewater |
CN108772081B (en) * | 2018-07-12 | 2021-01-29 | 武汉工程大学 | FePO4 heterogeneous visible light Fenton catalyst and method for treating organic wastewater |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3885039A1 (en) | Graphite-like carbon nitride doped modified microsphere catalyst, and preparation method therefor and application thereof | |
CN102614902B (en) | Synthetic method for supported silver phosphate/silver catalyst | |
CN109939643A (en) | α-Fe2O3Adulterate the preparation method and applications of charcoal | |
CN105344379B (en) | A kind of hydrotalcite load FePC visible ray fenton catalyst and its preparation method and application | |
CN103691462B (en) | Preparation method of peel-off type bentonite supported silver phosphate catalyst | |
CN102600870B (en) | Loaded type silver phosphate/polyphosphoric silver/silver chloride compound water treatment photo-catalyst and preparation method thereof | |
CN107486200A (en) | A kind of preparation method of the compound wolframic acid Mn catalyst of carbon | |
CN106964333B (en) | Rare earth supported catalyst for treating sewage, preparation method and application thereof, and method for treating sewage by catalytic oxidation of ozone | |
CN106492860A (en) | A kind of preparation method of iron phosphate/manganese phosphate/yttrium phosphate composite catalyst | |
CN106984346A (en) | A kind of preparation method of silver orthophosphate compound phosphoric acid bismuth photochemical catalyst | |
CN102489291B (en) | Method for preparing expanded graphite load nanometer bismuth vanadate photochemical catalyst | |
CN109626518A (en) | Magnetic graphite alkenyl Fen+The method of the heterogeneous Fenton processing dyeing waste water of three-diemsnional electrode | |
CN106378168A (en) | Preparation method of manganese phosphate/yttrium phosphate composite catalyst | |
CN108160070A (en) | Preparation method of amorphous manganese oxide of potassium ion doping and products thereof and application | |
CN106311296A (en) | Preparation method of iron phosphate/yttrium phosphate composite catalyst | |
CN106881122A (en) | A kind of silver orthophosphate loads the preparation method of trbasic zinc phosphate photochemical catalyst | |
CN110639580B (en) | Composite photocatalyst and batch wastewater treatment method based on same | |
CN106378165A (en) | Preparation method of yttrium oxide/silver phosphate composite catalyst | |
CN107096553A (en) | A kind of silver orthophosphate loads the preparation method of cobalt phosphate/silver chlorate photochemical catalyst | |
CN106378167B (en) | A kind of preparation method of iron oxide copper oxide compound phosphoric acid yttrium catalyst | |
CN106391068B (en) | A kind of preparation method of manganese oxide/yttrium phosphate composite catalyst | |
CN106423230B (en) | A kind of preparation method of nickel oxide compound phosphoric acid yttrium catalyst | |
CN106391087B (en) | A kind of preparation method of novismuth compound phosphoric acid yttrium catalyst | |
CN106492857A (en) | A kind of preparation method of cobalt oxide compound phosphoric acid yttrium catalyst | |
CN106378166B (en) | A kind of preparation method of nickel oxide zinc oxide compound phosphoric acid yttrium catalyst |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170315 |
|
WD01 | Invention patent application deemed withdrawn after publication |