CN106480778B - Cigarette tipping paper and preparation method thereof - Google Patents
Cigarette tipping paper and preparation method thereof Download PDFInfo
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- CN106480778B CN106480778B CN201610891486.1A CN201610891486A CN106480778B CN 106480778 B CN106480778 B CN 106480778B CN 201610891486 A CN201610891486 A CN 201610891486A CN 106480778 B CN106480778 B CN 106480778B
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- tipping paper
- cigarette
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- oil reservoir
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/828—Paper comprising more than one coating superposed two superposed coatings, the first applied being non-pigmented and the second applied being pigmented
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Paper (AREA)
Abstract
The present invention provides a kind of cigarette tipping paper, including base paper for tipping paper, it is characterized in that, the base paper for tipping paper includes anti-oil reservoir and oleophobic hydrophilic layer, the anti-oil reservoir and the oleophobic hydrophilic layer are cascadingly set in at least one side of the base paper for tipping paper, the anti-oil reservoir and the oleophobic hydrophilic layer all have resin matrix, and the resin matrix of the two is compatible.The present invention further provides a kind of preparation methods of above-mentioned cigarette tipping paper.Cigarette tipping paper provided by the invention can effectively prevent the exudation of liquid fat, while meet the requirement of cigarette pack cigarette performance.
Description
Technical field
The present invention relates to cigarette fields, more particularly to a kind of cigarette tipping paper and preparation method thereof.
Background technology
With the developing of society, the progress of civilization, cigarette no longer simple only cigarette, but a kind of symbol of identity,
More and more people select high-grade cigarette to promote the taste of oneself, and more pursuing has functional cigarette, various with anti-
The cigarette of pseudo- function, radium-shine function, fluorescent functional, impermeable function etc. constantly appears in cigarette market.In the recent period by Yunnan
The quick-fried pearl cigarette that cigar mill, Hefei cigar mill, Wuhu Cigarette Factory are released, it is deep to be liked by numerous smokers.This novel quick-fried pearl cigarette is logical
It crosses finger and pinches brokenly the quick-fried pearl capsule in cigarette cigarette beam, to reach the fragrance and taste that increase in cigarette aspiration procedure, according to
The ingredient of quick-fried pearl is different, and cigarette is by with different suction tastes, such as peppermint capsule, royal jelly capsule, Panax Capsule etc., by adding
Add these substances, finally influences everybody judgment to cigarette.However above-mentioned capsule essence and flavoring agent etc. during pinching brokenly
Infiltration can give smoker bad experience.
Accordingly, it is desirable to provide a kind of cigarette tipping paper for the grease exudation that can be obstructed in cigarette filter rod, however, usually
The cigarette tipping paper surface that grease exudation can be obstructed has hydrophobicity, due in the actual production process, needing using aqueous
Cigarette tipping paper package roll is connected on filter tip and cigarette by adhesive, at this time Aqueous Adhesives and hydrophobicity cigarette tipping paper surface
Between associativity it is very poor, cause cigarette tipping paper to be easy to pop, so that packaging cigarette performance of the tobacco factory to cigarette cannot be met.
Invention content
Based on this, it is necessary to cannot meet simultaneously for cigarette tipping paper and obstruct oil energy and to the packaging cigarette of cigarette
The problem of performance, provides a kind of cigarette tipping paper and preparation method thereof.
A kind of cigarette tipping paper, including base paper for tipping paper, which is characterized in that the base paper for tipping paper includes anti-oil reservoir and dredges
Oily hydrophilic layer, the anti-oil reservoir and the oleophobic hydrophilic layer are cascadingly set in at least one side of the base paper for tipping paper,
The anti-oil reservoir and the oleophobic hydrophilic layer all have resin matrix, and the resin matrix of the two is compatible.
The resin matrix of the anti-oil reservoir is in crylic acid resin and polyurethanes in one of the embodiments,
At least one, or in polyphenylalanine, Poly(Phe), rosin resin, butyral resin and polyurethane at least
It is a kind of；The resin matrix of the oleophobic hydrophilic layer is selected from least one of makrolon and polyurethane.
The oleophobic hydrophilic layer further comprises that inorganic filler, the inorganic filler are selected from one of the embodiments,
At least one of activated Calcium carbonate and talcum powder, the mass ratio of the resin matrix and the inorganic filler of the oleophobic hydrophilic layer
It is 1:1~2:1.
The two sides of the cigarette tipping paper includes the anti-oil reservoir being cascading in one of the embodiments,
With the oleophobic hydrophilic layer.
Include in one of the embodiments, multiple anti-oil reservoirs and multiple in at least one side of the cigarette tipping paper
The oleophobic hydrophilic layer is arranged alternately.
The anti-oil reservoir or the oleophobic hydrophilic layer are multilayered structure in one of the embodiments,.
A kind of preparation method of cigarette tipping paper, which is characterized in that including：
S11, provides a base paper for tipping paper, and the base paper for tipping paper has opposite the first face and the second face；
S12 provides oil-proof paint, and the oil-proof paint is printed or be coated on first face, and the first anti-oil reservoir is made；
S13 provides oleophobic hydrophilic coating, which is respectively provided with compatible resin base with above-mentioned oil-proof paint
Body；
S14 prints on the described first anti-oil reservoir or is coated with the oleophobic hydrophilic coating, and the first oleophobic hydrophilic layer is made,
Obtain the cigarette tipping paper.
In one of the embodiments, the oil-proof paint be in water-based acrylic resin class and water-based polyurethane extremely
In few a kind of or oiliness polyphenylalanine, rosin resin, butyral resin, Poly(Phe) and oiliness polyurethane at least
It is a kind of；The oleophobic hydrophilic coating includes binder, inorganic filler, second alcohol and water, and the binder is waterborne, polycarbonate, water
Property at least one of polyurethane, the inorganic filler is at least one of activated Calcium carbonate and talcum powder, wherein the company
The mass percent of splicing is 15~30%, and the mass percent of the inorganic filler is 15~30%, the quality of the ethyl alcohol
Percentage is 20~30%, and the mass percent of the water is 20~30%.
The fineness of the oleophobic hydrophilic coating is less than 30 μm in one of the embodiments,.
The preparation method of the cigarette tipping paper further comprises in the base paper for tipping paper in one of the embodiments,
The second face print or be coated with the oil-proof paint and the oleophobic hydrophilic coating successively, obtain the second anti-oil reservoir and the second oleophobic
The step of hydrophilic layer.
Cigarette tipping paper provided by the invention has the anti-oil reservoir that is cascading and oleophobic hydrophilic layer so that cigarette is with connecing
Filling paper has an oleophobic hydrophile function, this oleophobic hydrophily can liquid barrier grease completely exudation, and can be good at fitting
The packaging cigarette in cigarette seaming operation is answered, solves cigarette paper market well to this oleophobic hydrophile function type cigarette
With the wilderness demand of tipping paper.
There is good compatibility, and good film-forming property between the anti-oil reservoir and the resin matrix of oleophobic hydrophilic layer, therefore,
The stickiness of the anti-oil reservoir and oleophobic hydrophilic layer is fine.
By the ingredient and ratio that set resin matrix and inorganic filler in the oleophobic hydrophilic layer so that the oleophobic
Hydrophilic layer has smaller water imbibition, so that the cigarette tipping paper remains during transport, storage and use
Satisfactory moisture content.
The preparation method of cigarette tipping paper provided by the invention prepares an anti-oil reservoir first on the base paper for tipping paper,
Not only the base paper for tipping paper can have been made not absorb water when printing and being coated with the oleophobic water-repellent paint deformation, but also can be in the cigarette
With tipping paper using when play the role of be isolated grease, the oleophobic hydrophilic layer can meet the cigarette tipping paper to pack cigarette
The requirement of performance.
Description of the drawings
Fig. 1 is the structural schematic diagram of cigarette tipping paper provided by the invention；
Fig. 2 is another structural schematic diagram of cigarette tipping paper provided by the invention；
Fig. 3 is the structural schematic diagram of cigarette provided by the invention；
Fig. 4 is the flow chart of the preparation method of cigarette tipping paper provided by the invention.
Specific implementation mode
Referring to Fig. 1, the present invention provides a kind of cigarette tipping paper 1, including base paper for tipping paper 10, the first anti-oil reservoir 20 and the
One oleophobic hydrophilic layer 30, the base paper for tipping paper 1 have opposite the first face and the second face, the first anti-oil reservoir 20 and institute
The first oleophobic hydrophilic layer 30 is stated to be cascadingly set on first face.The one anti-oil reservoir 20 and the first oleophobic hydrophilic layer 30
The effect of liquid barrier grease is all had, the first oleophobic hydrophilic layer 30 makes the cigarette tipping paper 1 have good packaging
Cigarette performance.
The first anti-oil reservoir 20 and the first oleophobic hydrophilic layer 30 all have resin matrix, and the resin matrix of the two
It is compatible, to have good coating performance between making this two layers.The first anti-oil reservoir 20 and the first oleophobic hydrophilic layer
30 resin matrix cannot select fragrant resinoid, because fragrant resinoid is in the synthesis process, the object of monomer or auxiliary agent class
Matter can influence fragrant resinoid VOC content, and cigarette tipping paper has the content of VOC and strictly limits.The first anti-oil reservoir
20 resin matrix can be selected from least one of crylic acid resin and polyurethanes, or selected from polyphenylalanine, poly
At least one of phenylalanine, rosin resin, butyral resin and polyurethane；The resin base of the first oleophobic hydrophilic layer 30
At least one of the optional self-polycarbonate of body and polyurethane, the above resin matrix all has preferable film forming.
The first oleophobic hydrophilic layer 30 further comprises inorganic filler, the resin matrix of the first oleophobic hydrophilic layer 30
Mass ratio with the inorganic filler is 1:1~2:1.The inorganic filler in activated Calcium carbonate and talcum powder at least one
Kind.The inorganic filler is dispersed in the first oleophobic hydrophilic layer 30.Generally all have with hydrophilic resin matrix
There is very strong water imbibition, can constantly absorb water during the subsequent transport of the cigarette tipping paper 1, storage and preparation cigarette, from
And the moisture content of the cigarette tipping paper is caused to exceed required standard；The inorganic filler, which is added, can reduce by first oleophobic
The water imbibition of hydrophilic layer 30, to always by the moisture control of the cigarette tipping paper 1 in prescribed limit.
The first oleophobic hydrophilic layer 30 can also further comprise in the auxiliary agents such as slipping agent, anti-settling agent, antifoaming agent, levelling agent
At least one so that the first oleophobic hydrophilic layer 30 is more smooth, smooth.The slipping agent can be wax powder.It is described anti-settling
Agent can be ionic surfactant.The antifoaming agent can be silicone emulsion, higher alcohols fatty acid ester compound.The stream
Flat agent can be in dimethyl silicone polymer (PDMS), alkyl-modified organosiloxane and polyether polyester azo polyether polyeste
It is a kind of or several.It is appreciated that those skilled in the art can according to actual needs select above-mentioned auxiliary agent.
Referring to Fig. 2, the second face of the cigarette tipping paper 1 can be further provided with the second anti-oil reservoir 22.Described second
The second oleophobic hydrophilic layer 32 can be further provided on oleophobic hydrophilic layer 22.The second anti-oil reservoir 22 and the described first anti-oil reservoir
20 is identical, and the second oleophobic hydrophilic layer 32 and the first oleophobic hydrophilic layer 30 are identical, and details are not described herein.
The first anti-oil reservoir 20, the first oleophobic hydrophilic layer 30, the second anti-oil reservoir 22 or the second oleophobic hydrophilic layer 32
Multilayered structure is thought, to achieve the purpose that effectively to prevent liquid fat to ooze out.
The first anti-oil reservoir 20 and the first oleophobic hydrophilic layer 30 can be further the of the base paper for tipping paper 1
It is upper on one side to be alternately configured.The second anti-oil reservoir 22 and the second oleophobic hydrophilic layer 32 can be further in the tippings
It is alternately configured on second face of paper body paper 1.
Referring to Fig. 3, the present invention further provides a kind of cigarette, including the cigarette tipping paper 1, filter tip 2 and cigarette 3,
The cigarette tipping paper 1 wraps up the filter tip 2 and the cigarette 3, and the filter tip 2 and the cigarette 3 are linked together.
Cigarette provided by the invention is not easy to pop during storage and use, and has the function of obstructing grease, can
To provide good experience to smoker.
Referring to Fig. 4, the present invention further provides a kind of preparation methods of cigarette tipping paper, including：
S11, provides a base paper for tipping paper, and the base paper for tipping paper has opposite the first face and the second face；
S12 provides oil-proof paint, and the oil-proof paint is printed or be coated on first face, and the first anti-oil reservoir is made；
S13 provides oleophobic hydrophilic coating, which is respectively provided with compatible resin base with above-mentioned oil-proof paint
Body；
S14 prints on the described first anti-oil reservoir or is coated with the oleophobic hydrophilic coating, and the first oleophobic hydrophilic layer is made,
Obtain the cigarette tipping paper.
In step s 12, after the oil-proof paint is printed or applied to the base paper for tipping paper, in the oil-proof paint
All volatilization finishes solvent, to obtain the described first anti-oil reservoir.On the one hand the first anti-oil reservoir can be printed in step S13
Or when being coated with the oleophobic hydrophilic coating, base paper for tipping paper water suction deformation is prevented, on the other hand also can be the cigarette with connecing
Fill the performance that paper provides isolation grease.Further, can repeatedly it print or apply on the base paper for tipping paper according to actual needs
Oil-proof paint described in cloth, to obtain the first anti-oil reservoir of multilayer, to achieve the purpose that effectively to prevent liquid fat to ooze out.
The resin matrix of the oil-proof paint can be selected from least one of crylic acid resin and polyurethanes, Huo Zhexuan
From at least one of polyphenylalanine, Poly(Phe), rosin resin, butyral resin and polyurethane.The grease proofing painting
Material can be water paint, can also be oil paint.The oil-proof paint is water-based acrylic resin class and aqueous polyurethane
At least one of class or oiliness polyphenylalanine, rosin resin, butyral resin, Poly(Phe) and oiliness polyurethane
At least one of.
In step s 13, after the oleophobic hydrophilic coating is printed or applied to the described first anti-oil reservoir, the solvent is whole
Volatilization is complete, to obtain the first oleophobic hydrophilic layer.The optional self-polycarbonate of resin matrix of the oleophobic hydrophilic coating
At least one of with polyurethane.
In one embodiment, the oleophobic hydrophilic coating includes binder, inorganic filler, second alcohol and water, wherein the company
Splicing is at least one of waterborne, polycarbonate, aqueous polyurethane, and the inorganic filler is in activated Calcium carbonate and talcum powder
At least one, the mass percent of the binder is 15~30%, the mass percent of the inorganic filler is 15~
30%, the mass percent of the ethyl alcohol is 20~30%, and the mass percent of the water is 20~30%.When second alcohol and water is complete
After full volatilization, the binder is changed into base-material, and the inorganic filler is dispersed in the base-material, described to obtain
First oleophobic hydrophilic layer.
Inorganic filler is added in the oleophobic hydrophilic coating, the water imbibition of the first oleophobic hydrophilic layer can be reduced,
To always by the moisture control of the cigarette tipping paper in prescribed limit.The second alcohol and water can coordinate described inorganic
Filler and the binder, by the viscosity control of the oleophobic hydrophilic coating, in 20s~30s, (20-30 DEG C, English 3# looks into grace
Cup), to meet the paintability of the oleophobic hydrophilic coating.
Preferably, the fineness of the oleophobic hydrophilic coating is less than 30 μm, so that the oleophobic hydrophilic coating has well
Printing and Painting effect prevent occurring the problems such as knife line, stifled version when using.
The oleophobic hydrophilic coating may further include in the auxiliary agents such as slipping agent, anti-settling agent, antifoaming agent, levelling agent extremely
Few one kind, to obtain the first more smooth, smooth oleophobic hydrophilic layer.The matter of the slipping agent, anti-settling agent, antifoaming agent or levelling agent
It is 0.1~1% to measure percentage.The slipping agent can be wax powder.The anti-settling agent can be ionic surfactant.It is described
Antifoaming agent can be silicone emulsion, higher alcohols fatty acid ester compound.The levelling agent can be dimethyl silicone polymer
(PDMS), alkyl-modified organosiloxane and one kind in polyether polyester azo polyether polyeste or several.
In one embodiment, it is further provided a kind of preparation method of the oleophobic hydrophilic coating, including：
Second alcohol and water is mixed, is stirred evenly by S21, obtains a solution；
The binder is added the solution, stirs evenly, obtain a lotion by S22；
The inorganic filler is added to above-mentioned emulsion, stirred evenly, obtains a suspension by S23；
Above-mentioned suspension is sanded S24, obtains the oleophobic hydrophilic coating.
Further comprise that one is added the slipping agent, anti-settling in the suspension between the step S23 and step S24
The step of at least one of auxiliary agents such as agent, antifoaming agent, levelling agent.
The purpose of the sand milling makes the refinement coating.The time of the sand milling is 30~90 minutes.
Further, it can repeatedly be printed on the described first anti-oil reservoir according to actual needs or to be coated with the oleophobic hydrophilic
Coating, to obtain the first oleophobic hydrophilic layer described in multilayer, to effectively improve the packaging cigarette performance of the cigarette tipping paper.
In step S12 and S14, the mode of printing can be intaglio printing, flexographic printing etc., and coating method can be scraped
Painting, three-roll coating, spraying, comma coating, reverse coating etc..
The preparation method of the cigarette tipping paper may further include the base paper for tipping paper the second face printing or
The step of being coated with the oil-proof paint, obtaining the second anti-oil reservoir, the step for it is essentially identical with the step S12, herein no longer
It repeats.The step can carry out after step s 12, can also carry out after step s 14.At this point, the first anti-oil reservoir
Liquid fat can be obstructed jointly with the second anti-oil reservoir, grease is obstructed to greatly strengthen the cigarette tipping paper
Performance.
The preparation method of the cigarette tipping paper, which may further include, prints on the described second anti-oil reservoir or is coated with institute
The step of stating oleophobic hydrophilic coating, obtaining the second oleophobic hydrophilic layer, the step for it is essentially identical with the step S12, herein not
It repeats again.At this point, the two sides of the cigarette tipping paper is both provided with anti-oil reservoir and oleophobic hydrophilic layer.
The preparation method of the cigarette tipping paper may further include first face or the second face alternately printing or
The step of being coated with the oil-proof paint and oleophobic hydrophilic coating obtains the first anti-oil reservoir and the first oleophobic parent of alternately laminated setting
Water layer or the second anti-oil reservoir and the second oleophobic hydrophilic layer.
Embodiment 1
The formula (mass percent) of oleophobic hydrophilic coating is as follows in the present embodiment：30% waterborne, polycarbonate, 15% are lived
Property calcium carbonate, 25% ethyl alcohol, 26% water, 1% slipping agent, 1% sagging inhibitor, 1% levelling agent, 1% antifoaming agent.The oleophobic parent
The preparation method of water paint is as follows：
(1) second alcohol and water is mixed, is stirred evenly, obtain a solution；
(2) above-mentioned solution is added in waterborne, polycarbonate, stirred evenly, obtain a lotion；
(3) activated Calcium carbonate is added in above-mentioned emulsion, is stirred evenly, obtain a suspension；
(4) slipping agent, anti-settling agent, antifoaming agent, levelling agent are added in above-mentioned suspension；
(5) 60min is sanded in the suspension obtained step (4), obtain fineness be 25 μm, viscosity be 22s (24 DEG C, it is English
3# looks into grace cup) oleophobic hydrophilic coating.
The preparation method of the cigarette tipping paper is as follows：
(1) water-based acrylic resin class lotion is used, prints one layer on base paper for tipping paper by way of intaglio printing
Or the anti-oil reservoir of multilayer；
(2) above-mentioned oleophobic hydrophilic coating is used, one or more layers is printed on anti-oil reservoir by way of intaglio printing and dredges
Oily hydrophilic layer obtains the cigarette tipping paper.
The present embodiment further carries out picture and text printing in the isolation level of the cigarette tipping paper or separation layer reverse side.
Embodiment 2
The formula (mass percent) of oleophobic hydrophilic coating is as follows in the present embodiment：30% waterborne, polycarbonate/polyurethane
Mixed emulsion, 15% talcum powder, 28% ethyl alcohol, 25% water, 0.5% slipping agent, 0.5% sagging inhibitor, 0.5% levelling agent,
0.5% antifoaming agent.
The preparation method of the oleophobic hydrophilic coating is as follows：
(1) second alcohol and water is mixed, is stirred evenly, obtain a solution；
(2) above-mentioned solution is added in waterborne, polycarbonate/polyurethane mixed emulsion, stirs evenly, obtains a lotion；
(3) talcum powder is added in above-mentioned emulsion, is stirred evenly, obtain a suspension；
(4) slipping agent, anti-settling agent, antifoaming agent, levelling agent are added in above-mentioned suspension；
(5) 60min is sanded in the suspension obtained step (4), obtain fineness be 23 μm, viscosity 22s (25 DEG C, it is English
3# looks into grace cup) oleophobic hydrophilic coating.
The preparation method of the cigarette tipping paper is as follows：
(1) oiliness polyaminoester emulsion is used, it is grease proofing that one or more layers is sprayed on base paper for tipping paper by way of spraying
Layer；
(2) above-mentioned oleophobic hydrophilic coating is used, sprays one or more layers oleophobic parent on anti-oil reservoir by way of spraying
Water layer obtains the cigarette tipping paper.
The present embodiment further carries out picture and text printing in the isolation level of the cigarette tipping paper or separation layer reverse side.
Embodiment 3
The formula (mass percent) of oleophobic hydrophilic coating is as follows in the present embodiment：24% waterborne, polycarbonate/polyurethane
Mixed emulsion, 24% talcum powder, 20% ethyl alcohol, 30% water, 0.5% slipping agent, 0.5% sagging inhibitor, 0.5% levelling agent,
0.5% antifoaming agent.
The preparation method of the oleophobic hydrophilic coating is as follows：
(1) second alcohol and water is mixed, is stirred evenly, obtain a solution；
(2) above-mentioned solution is added in waterborne, polycarbonate/polyurethane mixed emulsion, stirs evenly, obtains a lotion；
(3) talcum powder is added in above-mentioned emulsion, is stirred evenly, obtain a suspension；
(4) slipping agent, anti-settling agent, antifoaming agent, levelling agent are added in above-mentioned suspension；
(5) 60min is sanded in the suspension obtained step (4), obtain fineness be 25 μm, viscosity 23s (24 DEG C, it is English
3# looks into grace cup) oleophobic hydrophilic coating.
The preparation method of the cigarette tipping paper is as follows：
(1) oiliness polyaminoester emulsion is used, it is grease proofing that one or more layers is sprayed on base paper for tipping paper by way of spraying
Layer；
(2) above-mentioned oleophobic hydrophilic coating is used, sprays one or more layers oleophobic parent on anti-oil reservoir by way of spraying
Water layer obtains the cigarette tipping paper.
The present embodiment further carries out picture and text printing in the isolation level of the cigarette tipping paper or separation layer reverse side.
Embodiment 4
The formula (mass percent) of oleophobic hydrophilic coating is as follows in the present embodiment：20% waterborne, polycarbonate, 24% are lived
Property calcium carbonate, 30% ethyl alcohol, 20% water, 1% slipping agent, 1% sagging inhibitor, 1% levelling agent, 1% antifoaming agent.
The preparation method of the oleophobic hydrophilic coating is as follows：
(1) second alcohol and water is mixed, is stirred evenly, obtain a solution；
(2) above-mentioned solution is added in waterborne, polycarbonate, stirred evenly, obtain a lotion；
(3) activated Calcium carbonate is added in above-mentioned emulsion, is stirred evenly, obtain a suspension；
(4) slipping agent, anti-settling agent, antifoaming agent, levelling agent are added in above-mentioned suspension；
(5) 60min is sanded in the suspension obtained step (4), obtain fineness be 24 μm, viscosity 22s (25 DEG C, it is English
3# looks into grace cup) oleophobic hydrophilic coating.
The preparation method of the cigarette tipping paper is as follows：
(1) water-based acrylic resin class lotion is used, prints one layer on base paper for tipping paper by way of intaglio printing
Or the anti-oil reservoir of multilayer；
(2) above-mentioned oleophobic hydrophilic coating is used, one or more layers is printed on anti-oil reservoir by way of intaglio printing and dredges
Oily hydrophilic layer obtains the cigarette tipping paper.
The present embodiment further carries out picture and text printing in the isolation level of the cigarette tipping paper or separation layer reverse side.
Several embodiments of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously
Cannot the limitation to the scope of the claims of the present invention therefore be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention
Protect range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (7)
1. a kind of cigarette tipping paper, including base paper for tipping paper, which is characterized in that the base paper for tipping paper includes anti-oil reservoir and oleophobic
Hydrophilic layer, the anti-oil reservoir and the oleophobic hydrophilic layer are cascadingly set in at least one side of the base paper for tipping paper, institute
It states anti-oil reservoir and the oleophobic hydrophilic layer all has resin matrix, and the resin matrix of the two is compatible；
The resin matrix of the anti-oil reservoir is selected from least one of crylic acid resin and polyurethanes, or is selected from polyphenyl third
At least one of propylhomoserin, Poly(Phe), rosin resin, butyral resin and polyurethanes；The oleophobic hydrophilic layer
Resin matrix is selected from least one of makrolon and polyurethanes；
The oleophobic hydrophilic layer further comprises inorganic filler, the inorganic filler in activated Calcium carbonate and talcum powder extremely
Few one kind, the resin matrix of the oleophobic hydrophilic layer are 1 with the mass ratio of the inorganic filler:1~2:1.
2. cigarette tipping paper according to claim 1, which is characterized in that the two sides of the cigarette tipping paper includes successively
The anti-oil reservoir and the oleophobic hydrophilic layer being stacked.
3. cigarette tipping paper according to claim 1 or 2, which is characterized in that in at least one side of the cigarette tipping paper
It is arranged alternately including multiple anti-oil reservoirs and multiple oleophobic hydrophilic layers.
4. cigarette tipping paper according to claim 1 or 2, which is characterized in that the anti-oil reservoir or the oleophobic hydrophilic layer
For multilayered structure.
5. a kind of preparation method of cigarette tipping paper, which is characterized in that including：
S11, provides a base paper for tipping paper, and the base paper for tipping paper has opposite the first face and the second face；
S12 provides oil-proof paint, and the oil-proof paint is printed or be coated on first face, and the first anti-oil reservoir is made；
S13 provides oleophobic hydrophilic coating, which is respectively provided with compatible resin matrix with above-mentioned oil-proof paint；
S14 prints on the described first anti-oil reservoir or is coated with the oleophobic hydrophilic coating, and the first oleophobic hydrophilic layer is made, and obtains
The cigarette tipping paper, wherein：
The oil-proof paint is at least one of water-based acrylic resin class and water-based polyurethane or the third ammonia of oiliness polyphenyl
At least one of acid, rosin resin, butyral resin, Poly(Phe) and oiliness polyurethanes；The hydrophilic painting of oleophobic
Material includes binder, inorganic filler, second alcohol and water, the binder be in waterborne, polycarbonate, water-based polyurethane at least
One kind, the inorganic filler are at least one of activated Calcium carbonate and talcum powder, wherein the mass percent of the binder
It is 15~30%, the mass percent of the inorganic filler is 15~30%, and the mass percent of the ethyl alcohol is 20~30%,
The mass percent of the water is 20~30%.
6. the preparation method of cigarette tipping paper according to claim 5, which is characterized in that the oleophobic hydrophilic coating it is thin
Degree is less than 30 μm.
7. the preparation method of cigarette tipping paper according to claim 5, which is characterized in that the preparation of the cigarette tipping paper
Method further comprises that the oil-proof paint and oleophobic parent are printed or be coated in the second face in the base paper for tipping paper successively
Water paint, the step of obtaining the second anti-oil reservoir and the second oleophobic hydrophilic layer.
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| CN109811583A (en) * | 2018-12-27 | 2019-05-28 | 安徽集友新材料股份有限公司 | For the high gloss oil of the molten ink layer surface of printed matter alcohol, printed matter and preparation method thereof and cigarette |
| CN210809257U (en) * | 2019-09-26 | 2020-06-23 | 前海国健华烟科技（深圳）有限公司 | Heating non-combustible plant herb atomization rod paper tube |
| CN110644280B (en) * | 2019-09-26 | 2022-04-08 | 安徽集友纸业包装有限公司 | Back coating material for cigarette tipping paper, cigarette tipping paper and preparation method thereof |
| CN115726223B (en) * | 2022-12-01 | 2023-10-31 | 安徽集友纸业包装有限公司 | Tipping paper for cigarettes and preparation method and application thereof |
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| ES2421621T3 (en) * | 2011-07-28 | 2013-09-04 | Delfortgroup Ag | Oil resistant filter wrapping paper |
| CN103726403A (en) * | 2013-11-25 | 2014-04-16 | 龙游特美纸制品有限公司 | Production method of white tipping base paper for cigarettes |
| CN104449032A (en) * | 2015-01-17 | 2015-03-25 | 曲靖麒麟福牌印刷有限公司 | White printing ink for printing tipping paper for cigarettes and preparation method |
| CN104831588A (en) * | 2015-03-13 | 2015-08-12 | 云南中烟工业有限责任公司 | Tipping paper preventing liquid leakage, preparation method and application of same |
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