CN106480778A - Cigarette tipping paper and preparation method thereof - Google Patents
Cigarette tipping paper and preparation method thereof Download PDFInfo
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- CN106480778A CN106480778A CN201610891486.1A CN201610891486A CN106480778A CN 106480778 A CN106480778 A CN 106480778A CN 201610891486 A CN201610891486 A CN 201610891486A CN 106480778 A CN106480778 A CN 106480778A
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- tipping paper
- oleophobic hydrophilic
- cigarette
- hydrophilic layer
- oil reservoir
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/828—Paper comprising more than one coating superposed two superposed coatings, the first applied being non-pigmented and the second applied being pigmented
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
Abstract
The present invention provides a kind of cigarette tipping paper, including base paper for tipping paper, it is characterized in that, described base paper for tipping paper includes anti-oil reservoir and oleophobic hydrophilic layer, described anti-oil reservoir and described oleophobic hydrophilic layer are cascadingly set at least one side of described base paper for tipping paper, described anti-oil reservoir and described oleophobic hydrophilic layer are respectively provided with resin matrix, and both resin matrixes are compatible.The present invention further provides a kind of preparation method of above-mentioned cigarette tipping paper.The cigarette tipping paper that the present invention provides, can effectively stop oozing out of liquid fat, meet the requirement of cigarette pack cigarette performance simultaneously.
Description
Technical field
The present invention relates to medicated cigarette field, more particularly to a kind of cigarette tipping paper and preparation method thereof.
Background technology
With the progress of social development, civilization, medicated cigarette has been simply no longer cigarette, but a kind of symbol of identity,
Increasing people selects high-grade cigarette to lift the taste of oneself, more pursues and has functional medicated cigarette, various have anti-
The medicated cigarette of pseudo- function, radium-shine function, fluorescent functional, impermeable function etc. constantly occurs in cigarette market.In the recent period by Yunnan
The quick-fried pearl cigarette that cigar mill, Hefei cigar mill, Wuhu Cigarette Factory are released, is liked by numerous smokers deeply.This new quick-fried pearl cigarette is logical
Cross finger and pinch brokenly the quick-fried pearl capsule being embedded in medicated cigarette cigarette bundle, to reach fragrance and the taste increasing in medicated cigarette aspiration procedure, according to
The composition of quick-fried pearl is different, and medicated cigarette will have different suction tastes, such as Herba Menthae capsule, and royal jelly capsule, Panax Capsule etc., by adding
Plus these materials, finally affect everybody judgment to medicated cigarette.But above-mentioned capsule essence and flavoring agent etc. during pinching brokenly
Infiltration, can be to the bad experience of smoker.
Accordingly, it is desirable to provide the cigarette tipping paper that a kind of oils and fatss that can intercept in cigarette filter rod ooze out, however, generally
The cigarette tipping paper surface that oils and fatss ooze out can be intercepted and there is hydrophobicity, due in actual production process, needing to use aqueouss
Cigarette tipping paper package roll is connected on filter tip and cigarette adhesive, now Aqueous Adhesives and hydrophobicity cigarette tipping paper surface
Between associativity very poor, lead to cigarette tipping paper easily to pop, thus the packaging cigarette performance to medicated cigarette for the tobacco factory can not be met.
Content of the invention
Based on this it is necessary to the oil energy of obstruct and the packaging cigarette to medicated cigarette can not be met for cigarette tipping paper simultaneously
The problem of performance, provides a kind of cigarette tipping paper and preparation method thereof.
A kind of cigarette tipping paper, including base paper for tipping paper it is characterised in that described base paper for tipping paper includes anti-oil reservoir and dredges
Oily hydrophilic layer, described anti-oil reservoir and described oleophobic hydrophilic layer are cascadingly set at least one side of described base paper for tipping paper,
Described anti-oil reservoir and described oleophobic hydrophilic layer are respectively provided with resin matrix, and both resin matrixes are compatible.
Wherein in an embodiment, the resin matrix of described anti-oil reservoir is selected from crylic acid resin and polyurethaness
At least one, or in polyphenylalanine, Poly(Phe) Poly(DL-phenylalanine), rosin resin, butyral resin and polyurethane at least
A kind of；The resin matrix of described oleophobic hydrophilic layer is selected from least one in Merlon and polyurethane.
Wherein in an embodiment, described oleophobic hydrophilic layer further includes inorganic filler, and described inorganic filler is selected from
At least one in activated Calcium carbonate and Pulvis Talci, the resin matrix of described oleophobic hydrophilic layer and the mass ratio of described inorganic filler
For 1:1～2:1.
Wherein in an embodiment, the two sides of described cigarette tipping paper all includes the described anti-oil reservoir being cascading
With described oleophobic hydrophilic layer.
Wherein in an embodiment, at least one side of described cigarette tipping paper includes multiple described anti-oil reservoirs and multiple
Described oleophobic hydrophilic layer is arranged alternately.
Wherein in an embodiment, described anti-oil reservoir or described oleophobic hydrophilic layer are multiple structure.
A kind of preparation method of cigarette tipping paper is it is characterised in that include：
S11, provides a base paper for tipping paper, and described base paper for tipping paper has the first relative face and the second face；
S12, provides oil-proof paint, prints or be coated with described oil-proof paint on described first face, and first anti-oil reservoir is obtained；
S13, provides oleophobic hydrophilic coating, and this oleophobic hydrophilic coating and above-mentioned oil-proof paint are respectively provided with compatible resin base
Body；
S14, prints on the described first anti-oil reservoir or is coated with described oleophobic hydrophilic coating, and first oleophobic hydrophilic layer is obtained,
Obtain described cigarette tipping paper.
Wherein in an embodiment, described oil-proof paint be water-borne acrylic resin class and aqueous polyurethane apoplexy due to endogenous wind extremely
Few one kind, or in oiliness polyphenylalanine, rosin resin, butyral resin, Poly(Phe) Poly(DL-phenylalanine) and oiliness polyurethane at least
A kind of；Described oleophobic hydrophilic coating includes binder, inorganic filler, second alcohol and water, and described binder is waterborne, polycarbonate, water
Property polyurethane at least one, described inorganic filler be activated Calcium carbonate and Pulvis Talci at least one, wherein, described company
The mass percent of splicing is 15～30%, and the mass percent of described inorganic filler is 15～30%, the quality of described ethanol
Percentage ratio is 20～30%, and the mass percent of described water is 20～30%.
Wherein in an embodiment, the fineness of described oleophobic hydrophilic coating is less than 30 μm.
Wherein in an embodiment, the preparation method of described cigarette tipping paper further includes at described base paper for tipping paper
The second face print or be coated with described oil-proof paint and described oleophobic hydrophilic coating successively, obtain the second anti-oil reservoir and the second oleophobic
The step of hydrophilic layer.
The cigarette tipping paper that the present invention provides has the anti-oil reservoir being cascading and oleophobic hydrophilic layer so that cigarette is with connecing
Dress paper has oleophobic hydrophile function, this oleophobic hydrophilic can the oozing out of liquid barrier oils and fatss completely, and can be good at fitting
Answer the packaging cigarette in medicated cigarette seaming operation, solve cigarette paper market well to this oleophobic hydrophile function type cigarette
Wilderness demand with tipping paper.
Between described anti-oil reservoir and the resin matrix of oleophobic hydrophilic layer, there is the good compatibility, and good film-forming property, therefore,
The stickiness of described anti-oil reservoir and oleophobic hydrophilic layer is fine.
By setting in described oleophobic hydrophilic layer the composition of resin matrix and inorganic filler and ratio so that described oleophobic
Hydrophilic layer has less water absorption, so that described cigarette tipping paper remains in transport, storage with during using
Satisfactory moisture content.
The preparation method of the cigarette tipping paper that the present invention provides, prepares an anti-oil reservoir on described base paper for tipping paper first,
Both described base paper for tipping paper can have been made will not to absorb water deformation when printing and be coated with described oleophobic water-repellent paint, again can be in described cigarette
The effect of isolation oils and fatss is played with tipping paper, described oleophobic hydrophilic layer can meet described cigarette tipping paper to packaging cigarette when being used
The requirement of performance.
Brief description
The structural representation of the cigarette tipping paper that Fig. 1 provides for the present invention；
Another structural representation of the cigarette tipping paper that Fig. 2 provides for the present invention；
The structural representation of the medicated cigarette that Fig. 3 provides for the present invention；
The flow chart of the preparation method of the cigarette tipping paper that Fig. 4 provides for the present invention.
Specific embodiment
Refer to Fig. 1, the present invention provides a kind of cigarette tipping paper 1, including base paper for tipping paper 10, the first anti-oil reservoir 20 and the
One oleophobic hydrophilic layer 30, described base paper for tipping paper 1 has the first relative face and the second face, described first anti-oil reservoir 20 and institute
State the first oleophobic hydrophilic layer 30 to be cascadingly set on described first face.A described anti-oil reservoir 20 and the first oleophobic hydrophilic layer 30
It is respectively provided with the effect of liquid barrier oils and fatss, described first oleophobic hydrophilic layer 30 makes described cigarette tipping paper 1 have good packaging
Cigarette performance.
Described first anti-oil reservoir 20 and described first oleophobic hydrophilic layer 30 are respectively provided with resin matrix, and both resin matrixes
Compatible, so that having good coating performance between this two-layer.Described first anti-oil reservoir 20 and described first oleophobic hydrophilic layer
30 resin matrix can not select fragrant resinoid, because fragrant resinoid is in building-up process, the thing of monomer or auxiliary agent class
Matter can affect fragrant resinoid VOC content, and cigarette tipping paper has to the content of VOC and strictly limits.Described first anti-oil reservoir
20 resin matrix is selected from least one in crylic acid resin and polyurethaness, or is selected from polyphenylalanine, poly
At least one in Phenylalanine, rosin resin, butyral resin and polyurethane；The resin base of described first oleophobic hydrophilic layer 30
At least one in the optional self-polycarbonate of body and polyurethane, above resin matrix is respectively provided with preferable film property.
Described first oleophobic hydrophilic layer 30 further includes inorganic filler, the resin matrix of described first oleophobic hydrophilic layer 30
Mass ratio with described inorganic filler is 1:1～2:1.Described inorganic filler is selected from least in activated Calcium carbonate and Pulvis Talci
Kind.Described inorganic filler is dispersed in described first oleophobic hydrophilic layer 30.There is hydrophilic resin matrix typically all have
There is very strong water absorption, can constantly absorb water during the follow-up transport of described cigarette tipping paper 1, storage and preparation medicated cigarette, from
And lead to the moisture content of described cigarette tipping paper to exceed required standard；Add described inorganic filler can reduce described first oleophobic
The water absorption of hydrophilic layer 30, thus all the time by the moisture control of described cigarette tipping paper 1 in prescribed limit.
Described first oleophobic hydrophilic layer 30 also can further include in the auxiliary agents such as slipping agent, anti-settling agent, defoamer, levelling agent
At least one so that described first oleophobic hydrophilic layer 30 is more smooth, smooth.Described slipping agent can be wax powder.Described anti-settling
Agent can be ionic surfactant.Described defoamer can be emulsified silicone oil, higher alcohols fatty acid ester compound.Described stream
Flat agent can be in polydimethylsiloxane (PDMS), alkyl-modified organosiloxane and polyether polyester azo polyether polyeste
A kind of or several.It is appreciated that those skilled in the art can select to above-mentioned auxiliary agent according to actual needs.
Refer to Fig. 2, the second face of described cigarette tipping paper 1 can be further provided with the second anti-oil reservoir 22.Described second
Second oleophobic hydrophilic layer 32 can be further provided with oleophobic hydrophilic layer 22.Described second anti-oil reservoir 22 and described first anti-oil reservoir
20 is identical, and described second oleophobic hydrophilic layer 32 is identical with described first oleophobic hydrophilic layer 30, will not be described here.
Described first anti-oil reservoir 20, the first oleophobic hydrophilic layer 30, the second anti-oil reservoir 22 or the second oleophobic hydrophilic layer 32
Think multiple structure, thus reaching effective purpose stoping liquid fat from oozing out.
Described first anti-oil reservoir 20 and described first oleophobic hydrophilic layer 30 can be further the of described base paper for tipping paper 1
Simultaneously go up and be alternately configured.Described second anti-oil reservoir 22 and described second oleophobic hydrophilic layer 32 can be further in described tippings
Alternately it is configured on second face of paper body paper 1.
Refer to Fig. 3, the present invention further provides a kind of medicated cigarette, including described cigarette tipping paper 1, filter tip 2 and cigarette 3,
Described cigarette tipping paper 1 wraps up described filter tip 2 and described cigarette 3, and described filter tip 2 and described cigarette 3 are linked together.
The medicated cigarette that the present invention provides is not easy to pop during storage and use, and has the effect intercepting oils and fatss, can
To provide good experience to smoker.
Refer to Fig. 4, the present invention further provides a kind of preparation method of cigarette tipping paper, including：
S11, provides a base paper for tipping paper, and described base paper for tipping paper has the first relative face and the second face；
S12, provides oil-proof paint, prints or be coated with described oil-proof paint on described first face, and first anti-oil reservoir is obtained；
S13, provides oleophobic hydrophilic coating, and this oleophobic hydrophilic coating and above-mentioned oil-proof paint are respectively provided with compatible resin base
Body；
S14, prints on the described first anti-oil reservoir or is coated with described oleophobic hydrophilic coating, and first oleophobic hydrophilic layer is obtained,
Obtain described cigarette tipping paper.
In step s 12, after described oil-proof paint is printed or applied to described base paper for tipping paper, in described oil-proof paint
All volatilization finishes, thus obtaining the described first anti-oil reservoir solvent.Described first anti-oil reservoir one side can be printed in step S13
Or when being coated with described oleophobic hydrophilic coating, prevent described base paper for tipping paper water suction deformation, on the other hand also can be for described cigarette with connecing
Dress paper provides the performance of isolation oils and fatss.Further, can repeatedly print on described base paper for tipping paper or apply according to actual needs
Oil-proof paint described in cloth, to obtain the anti-oil reservoir of multilamellar first, thus reach effective purpose stoping liquid fat from oozing out.
The resin matrix of described oil-proof paint is selected from least one in crylic acid resin and polyurethaness, or choosing
At least one from polyphenylalanine, Poly(Phe) Poly(DL-phenylalanine), rosin resin, butyral resin and polyurethane.Described grease proofing painting
Material can be water paint or oil paint.Described oil-proof paint is water-borne acrylic resin class and aqueous polyurethane
At least one of apoplexy due to endogenous wind, or oiliness polyphenylalanine, rosin resin, butyral resin, Poly(Phe) Poly(DL-phenylalanine) and oiliness polyurethane
In at least one.
In step s 13, after described oleophobic hydrophilic coating is printed or applied to the described first anti-oil reservoir, described solvent is whole
Volatilization is complete, thus obtaining described first oleophobic hydrophilic layer.The optional self-polycarbonate of resin matrix of described oleophobic hydrophilic coating
With at least one in polyurethane.
In one embodiment, described oleophobic hydrophilic coating includes binder, inorganic filler, second alcohol and water, wherein, described company
Splicing is waterborne, polycarbonate, at least one in aqueous polyurethane, and described inorganic filler is in activated Calcium carbonate and Pulvis Talci
At least one, the mass percent of described binder is 15～30%, the mass percent of described inorganic filler is 15～
30%, the mass percent of described ethanol is 20～30%, and the mass percent of described water is 20～30%.When second alcohol and water is complete
After full volatilization, described binder is changed into base material, and described inorganic filler is dispersed in described base material, thus obtaining described
First oleophobic hydrophilic layer.
Inorganic filler is added in described oleophobic hydrophilic coating, the water absorption of described first oleophobic hydrophilic layer can be reduced,
Thus all the time by the moisture control of described cigarette tipping paper in prescribed limit.Described second alcohol and water can coordinate described inorganic
Filler and described binder, the viscosity of described oleophobic hydrophilic coating are controlled in 20s～30s (20-30 DEG C, English 3# looks into grace
Cup), to meet the paintability of described oleophobic hydrophilic coating.
Preferably, the fineness of described oleophobic hydrophilic coating is less than 30 μm, so that described oleophobic hydrophilic coating has well
Printing and Painting effect, prevent the problems such as knife line, stifled version when using.
Described oleophobic hydrophilic coating may further include in the auxiliary agents such as slipping agent, anti-settling agent, defoamer, levelling agent extremely
Few one kind, to obtain the first more smooth, smooth oleophobic hydrophilic layer.The matter of described slipping agent, anti-settling agent, defoamer or levelling agent
Amount percentage ratio is 0.1～1%.Described slipping agent can be wax powder.Described anti-settling agent can be ionic surfactant.Described
Defoamer can be emulsified silicone oil, higher alcohols fatty acid ester compound.Described levelling agent can be polydimethylsiloxane
(PDMS), one of alkyl-modified organosiloxane and polyether polyester azo polyether polyeste or several.
In one embodiment, it is further provided a kind of preparation method of described oleophobic hydrophilic coating, including：
S21, second alcohol and water is mixed, stirs, obtain a solution；
S22, described binder is added described solution, stirs, obtain an emulsion；
S23, described inorganic filler is added to above-mentioned emulsion, stirs, and obtains a suspension；
S24, above-mentioned suspension is carried out sand milling, obtains described oleophobic hydrophilic coating.
Further include between described step S23 and step S24 that one adds described slipping agent, anti-settling in described suspension
At least one step in the auxiliary agents such as agent, defoamer, levelling agent.
The purpose of described sand milling makes the described coating of refinement.The time of described sand milling is 30～90 minutes.
Further, can repeatedly print on the described first anti-oil reservoir or the described oleophobic of coating be hydrophilic according to actual needs
Coating, to obtain the first oleophobic hydrophilic layer described in multilamellar, thus effectively improve the packaging cigarette performance of described cigarette tipping paper.
In step S12 and S14, the mode of printing can be intaglio printing, flexographic printing etc., and coating method can be scraped
Painting, three-roll coating, spraying, comma coating, reverse coating etc..
The preparation method of described cigarette tipping paper may further include described base paper for tipping paper second face printing or
Be coated with described oil-proof paint, the step obtaining the second anti-oil reservoir, the step for essentially identical with described step S12, here is no longer
Repeat.This step can be carried out after step s 12 it is also possible to carry out after step s 14.Now, described first anti-oil reservoir
Jointly liquid fat can be intercepted with the second anti-oil reservoir, thus greatly strengthen described cigarette tipping paper to intercept oils and fatss
Performance.
The preparation method of described cigarette tipping paper may further include prints or coating institute on the described second anti-oil reservoir
State oleophobic hydrophilic coating, the step obtaining the second oleophobic hydrophilic layer, the step for essentially identical with described step S12, here is not
Repeat again.Now, the two sides of described cigarette tipping paper is provided with anti-oil reservoir and oleophobic hydrophilic layer.
The preparation method of described cigarette tipping paper may further include described first face or the second face replace printing or
The step being coated with described oil-proof paint and oleophobic hydrophilic coating, obtains the first anti-oil reservoir and the first oleophobic parent of alternately laminated setting
Water layer, or the second anti-oil reservoir and the second oleophobic hydrophilic layer.
Embodiment 1
In the present embodiment, the formula (mass percent) of oleophobic hydrophilic coating is as follows：30% waterborne, polycarbonate, 15% work
Property Calcium Carbonate, 25% ethanol, 26% water, 1% slipping agent, 1% sagging inhibitor, 1% levelling agent, 1% defoamer.Described oleophobic parent
The preparation method of water paint is as follows：
(1) second alcohol and water is mixed, stir, obtain a solution；
(2) waterborne, polycarbonate is added above-mentioned solution, stir, obtain an emulsion；
(3) activated Calcium carbonate is added in above-mentioned emulsion, stirs, obtain a suspension；
(4) slipping agent, anti-settling agent, defoamer, levelling agent are added in above-mentioned suspension；
(5) the suspension sand milling 60min that step (4) is obtained, obtain fineness be 25 μm, viscosity be 22s (24 DEG C, English
3# looks into grace cup) oleophobic hydrophilic coating.
The preparation method of described cigarette tipping paper is as follows：
(1) use water-borne acrylic resin class emulsion, by way of intaglio printing, print one layer on base paper for tipping paper
Or the anti-oil reservoir of multilamellar；
(2) use above-mentioned oleophobic hydrophilic coating, print one or more layers by way of intaglio printing on anti-oil reservoir and dredge
Oily hydrophilic layer, obtains described cigarette tipping paper.
The present embodiment carries out picture and text printing in the isolation aspect of described cigarette tipping paper or sealing coat reverse side further.
Embodiment 2
In the present embodiment, the formula (mass percent) of oleophobic hydrophilic coating is as follows：30% waterborne, polycarbonate/polyurethane
Mixed emulsion, 15% Pulvis Talci, 28% ethanol, 25% water, 0.5% slipping agent, 0.5% sagging inhibitor, 0.5% levelling agent,
0.5% defoamer.
The preparation method of described oleophobic hydrophilic coating is as follows：
(1) second alcohol and water is mixed, stir, obtain a solution；
(2) waterborne, polycarbonate/polyurethane mixed emulsion is added above-mentioned solution, stir, obtain an emulsion；
(3) Pulvis Talci is added in above-mentioned emulsion, stirs, obtain a suspension；
(4) slipping agent, anti-settling agent, defoamer, levelling agent are added in above-mentioned suspension；
(5) the suspension sand milling 60min that step (4) is obtained, obtain fineness be 23 μm, viscosity 22s (25 DEG C, English
3# looks into grace cup) oleophobic hydrophilic coating.
The preparation method of described cigarette tipping paper is as follows：
(1) use oiliness polyaminoester emulsion, spray one or more layers on base paper for tipping paper by way of spraying grease proofing
Layer；
(2) use above-mentioned oleophobic hydrophilic coating, one or more layers oleophobic parent is sprayed by way of spraying on anti-oil reservoir
Water layer, obtains described cigarette tipping paper.
The present embodiment carries out picture and text printing in the isolation aspect of described cigarette tipping paper or sealing coat reverse side further.
Embodiment 3
In the present embodiment, the formula (mass percent) of oleophobic hydrophilic coating is as follows：24% waterborne, polycarbonate/polyurethane
Mixed emulsion, 24% Pulvis Talci, 20% ethanol, 30% water, 0.5% slipping agent, 0.5% sagging inhibitor, 0.5% levelling agent,
0.5% defoamer.
The preparation method of described oleophobic hydrophilic coating is as follows：
(1) second alcohol and water is mixed, stir, obtain a solution；
(2) waterborne, polycarbonate/polyurethane mixed emulsion is added above-mentioned solution, stir, obtain an emulsion；
(3) Pulvis Talci is added in above-mentioned emulsion, stirs, obtain a suspension；
(4) slipping agent, anti-settling agent, defoamer, levelling agent are added in above-mentioned suspension；
(5) the suspension sand milling 60min that step (4) is obtained, obtain fineness be 25 μm, viscosity 23s (24 DEG C, English
3# looks into grace cup) oleophobic hydrophilic coating.
The preparation method of described cigarette tipping paper is as follows：
(1) use oiliness polyaminoester emulsion, spray one or more layers on base paper for tipping paper by way of spraying grease proofing
Layer；
(2) use above-mentioned oleophobic hydrophilic coating, one or more layers oleophobic parent is sprayed by way of spraying on anti-oil reservoir
Water layer, obtains described cigarette tipping paper.
The present embodiment carries out picture and text printing in the isolation aspect of described cigarette tipping paper or sealing coat reverse side further.
Embodiment 4
In the present embodiment, the formula (mass percent) of oleophobic hydrophilic coating is as follows：20% waterborne, polycarbonate, 24% work
Property Calcium Carbonate, 30% ethanol, 20% water, 1% slipping agent, 1% sagging inhibitor, 1% levelling agent, 1% defoamer.
The preparation method of described oleophobic hydrophilic coating is as follows：
(1) second alcohol and water is mixed, stir, obtain a solution；
(2) waterborne, polycarbonate is added above-mentioned solution, stir, obtain an emulsion；
(3) activated Calcium carbonate is added in above-mentioned emulsion, stirs, obtain a suspension；
(4) slipping agent, anti-settling agent, defoamer, levelling agent are added in above-mentioned suspension；
(5) the suspension sand milling 60min that step (4) is obtained, obtain fineness be 24 μm, viscosity 22s (25 DEG C, English
3# looks into grace cup) oleophobic hydrophilic coating.
The preparation method of described cigarette tipping paper is as follows：
(1) use water-borne acrylic resin class emulsion, by way of intaglio printing, print one layer on base paper for tipping paper
Or the anti-oil reservoir of multilamellar；
(2) use above-mentioned oleophobic hydrophilic coating, print one or more layers by way of intaglio printing on anti-oil reservoir and dredge
Oily hydrophilic layer, obtains described cigarette tipping paper.
The present embodiment carries out picture and text printing in the isolation aspect of described cigarette tipping paper or sealing coat reverse side further.
Embodiment described above only have expressed the several embodiments of the present invention, and its description is more concrete and detailed, but simultaneously
Therefore the restriction to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, some deformation can also be made and improve, these broadly fall into the guarantor of the present invention
Shield scope.Therefore, the protection domain of patent of the present invention should be defined by claims.
Claims (10)
1. a kind of cigarette tipping paper, including base paper for tipping paper it is characterised in that described base paper for tipping paper includes anti-oil reservoir and oleophobic
Hydrophilic layer, described anti-oil reservoir and described oleophobic hydrophilic layer are cascadingly set at least one side of described base paper for tipping paper, institute
State anti-oil reservoir and described oleophobic hydrophilic layer is respectively provided with resin matrix, and both resin matrixes are compatible.
2. cigarette tipping paper according to claim 1 is it is characterised in that the resin matrix of described anti-oil reservoir is selected from acrylic acid
At least one in resinae and polyurethaness, or it is selected from polyphenylalanine, Poly(Phe) Poly(DL-phenylalanine), rosin resin, butyral
At least one in resin and polyurethane；The resin matrix of described oleophobic hydrophilic layer is selected from Merlon and polyurethane at least
A kind of.
3. cigarette tipping paper according to claim 2 is it is characterised in that described oleophobic hydrophilic layer further includes inorganic filling out
Material, described inorganic filler be selected from activated Calcium carbonate and Pulvis Talci at least one, the resin matrix of described oleophobic hydrophilic layer with
The mass ratio of described inorganic filler is 1:1～2:1.
4. cigarette tipping paper according to claim 1 is it is characterised in that the two sides of described cigarette tipping paper is all included successively
The described anti-oil reservoir being stacked and described oleophobic hydrophilic layer.
5. the cigarette tipping paper according to claim 1 or 4 is it is characterised in that at least one side of described cigarette tipping paper
It is arranged alternately including multiple described anti-oil reservoirs and multiple described oleophobic hydrophilic layer.
6. the cigarette tipping paper according to claim 1 or 4 is it is characterised in that described anti-oil reservoir or described oleophobic hydrophilic layer
For multiple structure.
7. a kind of preparation method of cigarette tipping paper is it is characterised in that include：
S11, provides a base paper for tipping paper, and described base paper for tipping paper has the first relative face and the second face；
S12, provides oil-proof paint, prints or be coated with described oil-proof paint on described first face, and first anti-oil reservoir is obtained；
S13, provides oleophobic hydrophilic coating, and this oleophobic hydrophilic coating and above-mentioned oil-proof paint are respectively provided with compatible resin matrix；
S14, prints on the described first anti-oil reservoir or is coated with described oleophobic hydrophilic coating, and first oleophobic hydrophilic layer is obtained, and obtains
Described cigarette tipping paper.
8. the preparation method of cigarette tipping paper according to claim 7 is it is characterised in that described oil-proof paint is aqueouss third
Olefin(e) acid resinae and at least one of aqueous polyurethane apoplexy due to endogenous wind, or oiliness polyphenylalanine, rosin resin, butyral resin, many
At least one in polyphenylalanine and oiliness polyurethane；Described oleophobic hydrophilic coating include binder, inorganic filler, ethanol and
Water, described binder is waterborne, polycarbonate, at least one in aqueous polyurethane, described inorganic filler be activated Calcium carbonate and
At least one in Pulvis Talci, wherein, the mass percent of described binder is 15～30%, the quality hundred of described inorganic filler
Divide than being 15～30%, the mass percent of described ethanol is 20～30%, the mass percent of described water is 20～30%.
9. cigarette tipping paper according to claim 7 preparation method it is characterised in that described oleophobic hydrophilic coating thin
Degree is less than 30 μm.
10. the preparation method of cigarette tipping paper according to claim 7 is it is characterised in that the system of described cigarette tipping paper
Described oil-proof paint and described oleophobic are printed or be coated with the second face that Preparation Method further includes at described base paper for tipping paper successively
Hydrophilic coating, the step obtaining the second anti-oil reservoir and the second oleophobic hydrophilic layer.
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| CN109811583A (en) * | 2018-12-27 | 2019-05-28 | 安徽集友新材料股份有限公司 | For the high gloss oil of the molten ink layer surface of printed matter alcohol, printed matter and preparation method thereof and cigarette |
| CN110644280A (en) * | 2019-09-26 | 2020-01-03 | 安徽集友纸业包装有限公司 | Back coating material for cigarette tipping paper, cigarette tipping paper and preparation method thereof |
| WO2021056937A1 (en) * | 2019-09-26 | 2021-04-01 | 前海国健华烟科技（深圳）有限公司 | Heating and non-burning herbaceous atomizing rod paper tube |
| CN115726223A (en) * | 2022-12-01 | 2023-03-03 | 安徽集友纸业包装有限公司 | Cigarette tipping paper and preparation method and application thereof |
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| CN110644280B (en) * | 2019-09-26 | 2022-04-08 | 安徽集友纸业包装有限公司 | Back coating material for cigarette tipping paper, cigarette tipping paper and preparation method thereof |
| CN115726223A (en) * | 2022-12-01 | 2023-03-03 | 安徽集友纸业包装有限公司 | Cigarette tipping paper and preparation method and application thereof |
| CN115726223B (en) * | 2022-12-01 | 2023-10-31 | 安徽集友纸业包装有限公司 | Tipping paper for cigarettes and preparation method and application thereof |
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|---|---|
| CN106480778B (en) | 2018-10-19 |
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