CN106480753A - A kind of real silk blend polyester fabric digit printing ink and preparation method thereof - Google Patents

A kind of real silk blend polyester fabric digit printing ink and preparation method thereof Download PDF

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Publication number
CN106480753A
CN106480753A CN201610762828.XA CN201610762828A CN106480753A CN 106480753 A CN106480753 A CN 106480753A CN 201610762828 A CN201610762828 A CN 201610762828A CN 106480753 A CN106480753 A CN 106480753A
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China
Prior art keywords
printing ink
real silk
polyester fabric
schardinger dextrin
digit printing
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Application number
CN201610762828.XA
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CN106480753B (en
Inventor
钱安华
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Zhejiang De Yu Import & Export Co Ltd
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Zhejiang De Yu Import & Export Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/649Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6491(Thio)urea or (cyclic) derivatives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8209Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing amide groups

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention provides a kind of real silk blend polyester fabric digit printing ink, including following main component:Reactive dye, sodium alginate, urea, glauber salt, soda ash, poly ethyldiol modified beta cyclodextrin, dispersant and deionized water, by adding poly ethyldiol modified beta cyclodextrin in traditional printing ink, improve the binding ability of beta cyclodextrin and protein in silk, the Color of reactive dye is greatly improved, to real silk surface printing, bright in luster, color fastness is high.

Description

A kind of real silk blend polyester fabric digit printing ink and preparation method thereof
Technical field
The present invention relates to digital printing technology field, more particularly to a kind of real silk blend polyester fabric digit printing ink And preparation method thereof.
Background technology
Digital ink-jet printed technology is a big expansion of the inkjet printing in industrial application.Modern computer inkjet printing When technology is used for printing in textiles, can be with various input mediums such as scanner, digital camera, digital camera etc., need The pattern that wants with digital input computer, after various mapping software color separation in printing systems are processed, then through computer control The digital inkjet printing machine of system, is directly ejected into printing ink on various fabrics, the various patterns needed for printing out, this Plant printing technique and be referred to as digital inking printing.
In recent years, digital printing technology has obtained rapid development.Compared with Conventional decal, digit printing technique is cleaned, Production process flexibly, can remotely be ordered goods, be included supply chain network, be the direction of following printing in textiles technology development.
At present, digit printing kind includes the fabric of the types such as cotton, hair, chemical fibre, also has the fabrics such as a small amount of design silk, by In the characteristic of real silk, its surface is relatively smooth, no matter digital direct printing is therefore adopted, or digital transfer printing, can all deposit Colour vividness is inadequate, fidelity not enough, print off the product quality that comes low;Product color fastness is low, it is impossible to meets washing and requires Problem, and the continuous development with Modern Textile Industry, terylene imitated silk face fabric are increasingly subject to people's attention, wherein add Accounting of the imitative silk face fabric of part real silk in silk fabrics is larger, and during stamp, the dyeing of terylene and cocoon fiber is equal Even property is difficult point.
Content of the invention
In order to solve the problems, such as in background technology, the present invention provides a kind of real silk blend polyester fabric digit printing ink And preparation method thereof.
A kind of real silk blend polyester fabric digit printing ink, including the composition of following percentage by weight:
Reactive dye 8-15%
Sodium alginate 1-2%
Urea 2-5%
Glauber salt 2-4%
Soda ash 0.5-2%
Poly ethyldiol modified beta-schardinger dextrin 1-3%
Dispersant 0.2-0.5%
Deionized water surplus.
Preferably, described dispersant isX-405 wetting agent.
A kind of real silk blend polyester fabric preparation method of digit printing ink, comprises the following steps:
Under the conditions of A, 60-80 DEG C, poly ethyldiol modified beta-schardinger dextrin is dissolved in deionized water, polyethylene glycol is added, is stirred After mixing 3-5 hour, room temperature is down to, stands, filter, dry, obtain modified beta-schardinger dextrin;
B, by modified beta-schardinger dextrin, dispersant and deionized water mix after, stir;
C, addition surplus stock, continue stirring, stir.
Preferably, in described step A, the mol ratio of ethylene glycol and beta-schardinger dextrin is 1:(5-7).
Preferably, in described step A, beta-schardinger dextrin is 1 with the mass ratio of deionized water:(20-30).
Preferably, the molecular weight of described polyethylene glycol is 3500-5000.
Cyclodextrin (Cyclodextr in, abbreviation CD) is amylose in the cyclodextrin glucose produced by bacillus A series of general name of the lower cyclic oligosaccharides for generating of based transferase effect, usually contains 6~12 D- glucopyranose units.Its Middle study more and be the molecule containing 6,7,8 glucose units with important practical usage, be referred to as Alpha-, beta- and gama- cyclodextrin.According to the result of X- line crystal diffraction, infrared spectrum and spectral analysis of the nuclear magnetic resonance, Determine that each D (+)-glucopyranose for constituting cyclodextrin molecular is chair conformation.Each glucose unit is all with Isosorbide-5-Nitrae-glucosides Bond synthesis ring.As the glycosidic bond for connecting glucose unit can not be rotated freely, cyclodextrin is not cylindric molecule but summary Tapered annulus.
As the outer rim (Rim) of cyclodextrin is hydrophilic and inner chamber (Cavi ty) is hydrophobic, thus it can provide one as enzyme Individual hydrophobic binding site, as the various appropriate objects (Guest) of main body (Host) envelope, such as organic molecule, inorganic ions And gas molecule etc..The hydrophobic and characteristic of external hydrophilic of its inner chamber makes which can be according to Van der Waals force, hydrophobic interaction power, master Matching effect between guest molecule etc. and many organic and inorganic molecule form inclusion compound and molecular assembled system, become chemistry and Chemical research person research object interested.This selective tetra-inclusion complex is usually said molecular recognition, and its result is Form Subjective and Objective inclusion complex (Host-GuestComplex).Cyclodextrin is that the preferable host similar to enzyme for being found so far divides Son, and itself just has the characteristic of catalator.Therefore, in the fields such as catalysis, separation, food and medicine, cyclodextrin is received Great attention is arrived and has extensively applied.Due to solubility of the cyclodextrin in water and inclusion ability, change the physics and chemistry of cyclodextrin Characteristic has become one of free-revving engine of Chemical modified cyclodextrin.
The compound of cyclodextrin is present in natural, it is also possible to artificial synthesized.Industrial, many dyestuffs are made with cyclodextrin Matrix;And the medicinal plant of not rare medical functions, such as aloe, all contain cyclodextrin complexes.For example in the middle of the gel of aloe Cyclodextrin complexes, have anti-inflammatory, detumescence, pain relieving, the effectiveness of antipruritic and bacteria growing inhibiting, natural vulnerary can be used as. Additionally, using cyclodextrin cyclodextrin method be produce hydrogen peroxide the best approach.
By beta-schardinger dextrin with poly ethyldiol modified in the present invention, can not only improve solubility of the beta-schardinger dextrin in water and Dispersive property, improves the contact surface of beta-schardinger dextrin and silk, and also improves the combination of beta-schardinger dextrin and protein in silk Performance, is conducive to improving the Color of reactive dye.
The real silk blend polyester fabric digit printing ink of the present invention, including following main component:Reactive dye, marine alga Sour sodium, urea, glauber salt, soda ash, poly ethyldiol modified beta-schardinger dextrin, dispersant and deionized water, by traditional stamp Poly ethyldiol modified beta-schardinger dextrin is added in ink, improves the binding ability of beta-schardinger dextrin and protein in silk, activity dye The Color of material is greatly improved, to real silk surface printing, bright in luster, and color fastness is high, especially fine to real silk blend polyester The dyeing uniformity of dimension is very good.
Specific implementation method
Embodiment 1
A kind of real silk blend polyester fabric digit printing ink, including the composition of following percentage by weight:
Reactive dye 12%
Sodium alginate 1.5%
Urea 3%
Glauber salt 3%
Soda ash 1.2%
Poly ethyldiol modified beta-schardinger dextrin 1.5%
Dispersant 0.3%
Deionized water surplus;
Described dispersant isX-405 wetting agent;
A kind of real silk blend polyester fabric preparation method of digit printing ink, comprises the following steps:
A, under the conditions of 75 DEG C, poly ethyldiol modified beta-schardinger dextrin is dissolved in deionized water, adds polyethylene glycol, stirring After 3.5 hours, room temperature is down to, stands, filter, dry, obtain modified beta-schardinger dextrin;
B, by modified beta-schardinger dextrin, dispersant and deionized water mix after, stir;
C, addition surplus stock, continue stirring, stir;
In described step A, the mol ratio of ethylene glycol and beta-schardinger dextrin is 1:6;
In described step A, beta-schardinger dextrin is 1 with the mass ratio of deionized water:25;
The molecular weight of described polyethylene glycol is 3500-5000.
Embodiment 2
A kind of real silk blend polyester fabric digit printing ink, including the composition of following percentage by weight:
Reactive dye 15%
Sodium alginate 1%
Urea 5%
Glauber salt 2%
Soda ash 0.5%
Poly ethyldiol modified beta-schardinger dextrin 3%
Dispersant 0.2%
Deionized water surplus;
Described dispersant isX-405 wetting agent;
A kind of real silk blend polyester fabric preparation method of digit printing ink, comprises the following steps:
A, under the conditions of 80 DEG C, poly ethyldiol modified beta-schardinger dextrin is dissolved in deionized water, adds polyethylene glycol, stirring 3 After hour, room temperature is down to, stands, filter, dry, obtain modified beta-schardinger dextrin;
B, by modified beta-schardinger dextrin, dispersant and deionized water mix after, stir;
C, addition surplus stock, continue stirring, stir;
In described step A, the mol ratio of ethylene glycol and beta-schardinger dextrin is 1:7;
In described step A, beta-schardinger dextrin is 1 with the mass ratio of deionized water:20;
The molecular weight of described polyethylene glycol is 3500-5000.
Embodiment 3
A kind of real silk blend polyester fabric digit printing ink, including the composition of following percentage by weight:
Reactive dye 8%
Sodium alginate 2%
Urea 2%
Glauber salt 4%
Soda ash 2%
Poly ethyldiol modified beta-schardinger dextrin 1%
Dispersant 0.5%
Deionized water surplus;
Described dispersant isX-405 wetting agent;
A kind of real silk blend polyester fabric preparation method of digit printing ink, comprises the following steps:
A, under the conditions of 60 DEG C, poly ethyldiol modified beta-schardinger dextrin is dissolved in deionized water, adds polyethylene glycol, stirring 5 After hour, room temperature is down to, stands, filter, dry, obtain modified beta-schardinger dextrin;
B, by modified beta-schardinger dextrin, dispersant and deionized water mix after, stir;
C, addition surplus stock, continue stirring, stir;
In described step A, the mol ratio of ethylene glycol and beta-schardinger dextrin is 1:5;
In described step A, beta-schardinger dextrin is 1 with the mass ratio of deionized water:30;
The molecular weight of described polyethylene glycol is 3500-5000.
Real silk blend polyester fabric to embodiment 1-3 carries out spray printing with digit printing ink, and the resistance to of test fabric is soaped Color fastness, colour fastness to rubbing, fastness to light are tested, and the results are shown in Table 1.
Table 1:
By test data it is recognised that the printing ink made of the present invention, for real silk blend polyester fiber stamp, color jail Degree is high, even across being cleaned multiple times, remain to colour-fast, fade, keep original color and vividness.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept equivalent or change in addition, should all be included within the scope of the present invention.

Claims (6)

1. a kind of real silk blend polyester fabric digit printing ink, it is characterised in that including the composition of following percentage by weight:
Reactive dye 8-15%
Sodium alginate 1-2%
Urea 2-5%
Glauber salt 2-4%
Soda ash 0.5-2%
Poly ethyldiol modified beta-schardinger dextrin 1-3%
Dispersant 0.2-0.5%
Deionized water surplus.
2. real silk blend polyester fabric digit printing ink as claimed in claim 1, it is characterised in that described dispersant For TRITON X-405 wetting agent.
3. a kind of real silk blend polyester fabric preparation method of digit printing ink, it is characterised in that comprise the following steps:
Under the conditions of A, 60-80 DEG C, poly ethyldiol modified beta-schardinger dextrin is dissolved in deionized water, polyethylene glycol is added, stir 3-5 After hour, room temperature is down to, stands, filter, dry, obtain modified beta-schardinger dextrin;
B, by modified beta-schardinger dextrin, dispersant and deionized water mix after, stir;
C, addition surplus stock, continue stirring, stir.
4. the real silk blend polyester fabric as claimed in claim 3 preparation method of digit printing ink, it is characterised in that institute In the step of stating A, the mol ratio of ethylene glycol and beta-schardinger dextrin is 1:(5-7).
5. the real silk blend polyester fabric as claimed in claim 3 preparation method of digit printing ink, it is characterised in that institute In the step of stating A, beta-schardinger dextrin is 1 with the mass ratio of deionized water:(20-30).
6. the real silk blend polyester fabric as claimed in claim 3 preparation method of digit printing ink, it is characterised in that institute The molecular weight of the polyethylene glycol that states is 3500-5000.
CN201610762828.XA 2016-08-31 2016-08-31 A kind of silk blend polyester fabric digit printing ink and preparation method thereof Expired - Fee Related CN106480753B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109097980A (en) * 2018-07-23 2018-12-28 含山县海达服饰有限公司 A kind for the treatment of process improving swimming trunks polyester fabric equalization
CN113774691A (en) * 2021-09-17 2021-12-10 浙江迎丰科技股份有限公司 Printing ink auxiliary agent and preparation method thereof
CN115595809A (en) * 2022-10-25 2023-01-13 东莞市伊时针织印花有限公司(Cn) Acid dye for protein fiber fabric and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN101280526A (en) * 2008-05-26 2008-10-08 东华大学 Method for dyeing mercerization baffeta with deep color on reactive dyes
CN102108641A (en) * 2011-01-12 2011-06-29 郑州鸿盛数码科技股份有限公司 Digital printing active dye jet ink
CN102408751A (en) * 2010-09-26 2012-04-11 大丰市千采精细化工有限公司 Acid dye
CN103642190A (en) * 2013-12-12 2014-03-19 东华大学 Polyethylene glycol modified cyclodextrin, as well as preparation and application thereof
CN103774464A (en) * 2013-12-31 2014-05-07 吉林中粮生化有限公司 Application of mycose-contained cyclodextrin inclusion compound in dyeing
CN104726956A (en) * 2015-03-13 2015-06-24 东华大学 Preparation method of cyclodextrin compound modified polyurethane elastic fibers
CN105008468A (en) * 2013-03-07 2015-10-28 奥西-技术有限公司 Ink composition
CN105369652A (en) * 2015-10-08 2016-03-02 深圳市墨库图文技术有限公司 Ink and preparing method thereof
CN105803827A (en) * 2016-04-01 2016-07-27 华南师范大学 Ink-jet ink and application thereof
CN105860668A (en) * 2016-06-07 2016-08-17 湖北科亿华科技有限公司 Manufacturing method of edible printing ink for ink jet printing and using method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280526A (en) * 2008-05-26 2008-10-08 东华大学 Method for dyeing mercerization baffeta with deep color on reactive dyes
CN102408751A (en) * 2010-09-26 2012-04-11 大丰市千采精细化工有限公司 Acid dye
CN102108641A (en) * 2011-01-12 2011-06-29 郑州鸿盛数码科技股份有限公司 Digital printing active dye jet ink
CN105008468A (en) * 2013-03-07 2015-10-28 奥西-技术有限公司 Ink composition
CN103642190A (en) * 2013-12-12 2014-03-19 东华大学 Polyethylene glycol modified cyclodextrin, as well as preparation and application thereof
CN103774464A (en) * 2013-12-31 2014-05-07 吉林中粮生化有限公司 Application of mycose-contained cyclodextrin inclusion compound in dyeing
CN104726956A (en) * 2015-03-13 2015-06-24 东华大学 Preparation method of cyclodextrin compound modified polyurethane elastic fibers
CN105369652A (en) * 2015-10-08 2016-03-02 深圳市墨库图文技术有限公司 Ink and preparing method thereof
CN105803827A (en) * 2016-04-01 2016-07-27 华南师范大学 Ink-jet ink and application thereof
CN105860668A (en) * 2016-06-07 2016-08-17 湖北科亿华科技有限公司 Manufacturing method of edible printing ink for ink jet printing and using method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109097980A (en) * 2018-07-23 2018-12-28 含山县海达服饰有限公司 A kind for the treatment of process improving swimming trunks polyester fabric equalization
CN113774691A (en) * 2021-09-17 2021-12-10 浙江迎丰科技股份有限公司 Printing ink auxiliary agent and preparation method thereof
CN113774691B (en) * 2021-09-17 2023-08-08 浙江迎丰科技股份有限公司 Printing ink auxiliary agent and preparation method thereof
CN115595809A (en) * 2022-10-25 2023-01-13 东莞市伊时针织印花有限公司(Cn) Acid dye for protein fiber fabric and preparation method thereof

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Denomination of invention: A digital printing ink for silk polyester blended fabric and its preparation method

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