CN106480743A - A kind of non-weaving cloth, method for sorting and its application - Google Patents

A kind of non-weaving cloth, method for sorting and its application Download PDF

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Publication number
CN106480743A
CN106480743A CN201610884594.6A CN201610884594A CN106480743A CN 106480743 A CN106480743 A CN 106480743A CN 201610884594 A CN201610884594 A CN 201610884594A CN 106480743 A CN106480743 A CN 106480743A
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natural antibacterial
weaving cloth
deodorant
finishing agent
acid
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Chinese (zh)
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王进
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Zhangzhou Dingxin Electronic Technology Co Ltd
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Zhangzhou Dingxin Electronic Technology Co Ltd
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Priority to CN201610884594.6A priority Critical patent/CN106480743A/en
Publication of CN106480743A publication Critical patent/CN106480743A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11Compounds containing epoxy groups or precursors thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246Esters of unsaturated carboxylic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/342Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • D06M13/463Compounds containing quaternary nitrogen atoms derived from monoamines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12Processes in which the treating agent is incorporated in microcapsules
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00Macromolecular materials of the coating layers
    • D06N2203/02Natural macromolecular compounds or derivatives thereof
    • D06N2203/024Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/165Odour absorbing, deodorizing ability
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/1671Resistance to bacteria, mildew, mould, fungi
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/24Personal care

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention relates to a kind of non-weaving cloth comprising the deodorant finishing agent of natural antibacterial, comprising non-weaving cloth body, it is characterized by the upper epidermis of non-weaving cloth body, layer are coated with the deodorant finish coating of natural antibacterial respectively, fibrous outer in fibre structure net is coated with gap of the natural antibacterial deodorant arrangement between coating, and fiber and fiber and is filled with the deodorant finishing agent composition of natural antibacterial;The weight ratio of the deodorant finishing agent of natural antibacterial and non-weaving cloth body is 0.3% 1.2%, the deodorant finishing agent of the natural antibacterial includes polyoxyethylene sorbitan tristearate, ester based quaternary ammonium salt, natural antibacterial composition, and wherein natural antibacterial composition is made up of components such as shitosan, aloe, chitin, catechin, Tea Polyphenols, tea-seed oils.The present invention is non-stimulated to human body skin, can suppress the invasion of bacterium and grow, high to ammonia absorptivity, and deodorizing effect is projected;Fragrance release is uniform, and fragrance remaining time is long, and added value of product is high.

Description

A kind of non-weaving cloth, method for sorting and its application
Technical field
The present invention relates to fabric finishing field, more particularly to a kind of non-weaving cloth, method for sorting and its application.
Background technology
With the improvement of people's living standards, people are additional except packaging, smell, color, shape etc. except being concerned about commodity The health of oneself and household beyond value, is become more concerned with, also increasingly worries fiber weaving product or nonwovens in daily life In easy breed bacteria potential danger, it is therefore necessary to provide a kind of carrying natural antibacterial fiber and its products so that fiber Product has anti-microbial property, suppresses fibre surface bacterial growth, keeps fibre surface itself clean.
In recent years, the domestic Research on antibacterial to fibre or non-weaving cloth gradually increased, and which is mainly in general fibre Or add in the dressing liquid of non-weaving cloth a small amount of antiseptic method obtain, antiseptic be a class can kill or suppress bacterium, The harmful microbe functional material such as virus, through searching document, the antiseptic that applies in general fibre or non-weaving cloth at present Inorganic antiseptic, organic antibacterial agent and the big series of natural antibacterial agent three are broadly divided into by structure.Wherein:
1)Organic antibacterial agent includes quaternary ammonium salt, imidazoles, pyridines, organic metal class etc., although sterilization speed is fast, and antibacterial is imitated Fruit is notable, but exists and be also easy to produce drug resistance, and heat endurance is poor, and Durability of antimicrobial effect is short, toxicity is big wait not enough, so as to give fiber and its Product brings new healthy hidden danger.
2)Compared with organic antibacterial agent, inorganic antibacterial collection have have a safety feature, heat decomposition temperature height, good stability, resist Bacterium ability is strong and the features such as antibacterial is lasting, research at present at most most extensive.
Inorganic antiseptic is typically to be made up of antibacterial components and carrier, the metal ion with antibacterial activity have silver, chromium, From security and antibiotic property, cobalt, nickel, copper, zinc and iron plasma, consider that silver ion is best jointly.But silver ion antimicrobial agent is direct Using silver ion as antiseptic, there is following defect:First, silver ion is easily reduced in simple substance and is changed into black, impact silver Application of the ion antibacterial agent in light color article, anti-tarnishing ability are poor.Secondly, easily silver oxide precipitates are generated in alkaline environment, Sustained release performance is poor, affects Durability of antimicrobial effect.Again, when silver ion meets article or the environment of chlorion, easily generate silver chlorate and sink Form sediment and lose activity, salt resistant character is poor.Finally, silver carrying amount is relatively low, complex process, and required auxiliary agent species is various.
As can be seen here, silver ion antimicrobial agent is mainly by physical absorption or the method for ion exchange, will be with antibacterial energy The metal of power or metal ion be fixed on the surface of certain carrier for example zeolite, activated carbon, phosphate, silicate, dissolubility glass, The material that makes on the carriers such as porous metals.Patent of invention as Publication No. CN102599164B provides a kind of nano lamellar The preparation method of silver-amino acid complex antiseptic is carried, first silver salt, amino acid, hydromassage that is compared 1:1:2.7 are mixed Close, 30min is stirred at room temperature, 50 DEG C of stirring in water bath 15min, mixing speed are 8000r/min, obtained solution, secondly in 50 DEG C of water In bath under mixing speed 8000r/min add montmorillonite, agitation and filtration, obtain feed liquid, after carry out separation of solid and liquid, be placed in room The lower drying of temperature, obtains fluffy ivory shape anti-bacterial powders, and which has preferable discoloration-resisting, improves the sustained release of antiseptic Performance and salt tolerance.
However, the inorganic antiseptic based on the metal ions such as silver, zinc, though, heat resistance strong excellent high with antimicrobial efficiency Point, but which is expensive, and environmental protection is short of, meanwhile, the product of Long-Time Service and touch containing metal ions such as silver, zinc can be to human body Liver adversely affect;These defects limit silver ion antimicrobial agent application in the product.Based on previous reasons, natural Antiseptic comes into existence as the situation requires, and compared with aforementioned antiseptic, natural antibacterial agent is extracted from plant, animal or biology, and its source is wide General, low cost, high with safety non-toxic, antimicrobial efficiency, heat-resist, drug resistance is not likely to produce, excellent with environment friendly etc. Point, therefore its application and research are increasingly subject to people's attention.As patent of invention of the notification number for CN103800928B is disclosed Antibacterial deodorant, it is main effective with the alkaloid in plant white leaf rattan source and new cryptolepine analog which is mainly a kind of The antiseptic deodorising product of composition, including weak acid conditioning agent, dipotassium hydrogen phosphate, solubilizer, metal-chelating salt, cyclodextrin, activity Composition, essence, can eliminate peculiar smell in cloth products, while effective bacterium for removing in cloth products or being attached in cloth products and disease Poison, and safely and effectively, fundamentally remove due to bacterial stink.
In sum, the present invention is in the sandwich layer of skin-core structure fiber, by natural antibacterial is combined in spinning process Thing and core layer polymer such as polypropylene, polyester blend melt spinning, can be directly prepared into polypropylene with aromatic function, polyester long Silk or chopped fiber,, compared with the woven textile of traditional afterfinish method, the fibre armaticity of the method production is more for which Persistently, at the same product have the characteristics that soft, fine and smooth and comfortable, while with natural antibacterial active component, cloth products can be eliminated Middle peculiar smell, while effective bacterium for removing in cloth products or being attached in cloth products and virus, and safely and effectively, fundamentally go Remove due to bacterial stink.
Content of the invention
The purpose of the present invention be exactly for providing a kind of non-weaving cloth, the technical scheme that takes to realize above-mentioned target: A kind of non-weaving cloth of the present invention includes non-weaving cloth body, and the non-weaving cloth body is by fibre structure net through thermal finalization It is composited, viscous including spun-bonded non-woven, spunbond melt-blowing nonwoven, Through-Air Thermal Bonded Nonwovens, Nonwovens or chemistry Close non-weaving cloth, it is characterised in that:Upper epidermis in the non-weaving cloth body, that layer is coated with natural antibacterial respectively is deodorant Finish coating;Fibrous outer in fibre structure net be coated with natural antibacterial deodorant arrange coating, and fiber with Gap between fiber is filled with the deodorant finishing agent composition of natural antibacterial;By weight percentage, the deodorant arrangement of natural antibacterial The weight ratio of agent and non-weaving cloth body is 0.3%-1.2%, and the component of the deodorant finishing agent of the natural antibacterial and proportioning are as follows:
Polyoxyethylene sorbitan tristearate 5-20 part;
Ester based quaternary ammonium salt 1-10 part;
Natural antibacterial composition 5-20 part.
Described non-weaving cloth body also includes the non-weaving cloth body in three-layer composite structure, by setting gradually under upper There are non-weaving cloth body upper strata, nanometer superfine fibre intermediate layer, non-weaving cloth body lower floor.The nanometer superfine fibre intermediate layer Square grammes per square metre be 1-4g/m2, the nanometer superfine fibre is by polyethylene terephthalate, poly terephthalic acid fourth two Ester, polypropylene, PLA, polyamide or polyurethane pass through electrostatic silk obtained in electrospinning device.
Used as further preferred version, the natural antibacterial composition is counted by weight, and its component and its deal are such as Under:Shitosan 2-8 part;Aloe 10-15 part;Chitin 3-8 part;Catechin 5-10 part;Tea Polyphenols 10-40 part;Tea-seed oil 5- 25 parts;Tea Saponin 0.1-2 part;Grape seed extract 5-15 part;Citric acid 5-25 part;Amino-acid chelate 5-25 part;Amino acid Derivative 0-10 part;Emulsifying agent 1-8 part.The natural resistance composition can be made natural antibacterial microcapsules, described natural anti- The particle diameter of bacteria microcapsule is less than 3 μm, to improve its slow release and long-lasting.
Used as further preferred version, the deodorant finishing agent of the natural antibacterial also includes polyethylene glycol glycerol ether, its group Divide and fill a prescription as follows:Polyethylene glycol glycerol ether 5-9 part;Polyoxyethylene sorbitan tristearate 8-15 part;Ester group quaternary ammonium Salt 5-8 part;Natural antibacterial composition 10-16 part.
Used as further preferred version, the deodorant finishing agent of the natural antibacterial also includes fragrant slow release body, and fragrance is slow Release the aromatic micro-capsule that body is in cladding core-shell structure, comprising capsule-core, cyst wall, the component of the deodorant finishing agent of the natural antibacterial and Formula is as follows:Polyethylene glycol glycerol ether 5-9 part;Polyoxyethylene sorbitan tristearate 8-15 part;Ester based quaternary ammonium salt 5- 8 parts;Natural antibacterial composition 10-16 part;Fragrant slow release body 3-8 part.
Wherein, the fragrant slow release body is the aromatic micro-capsule in cladding core-shell structure, comprising capsule-core, cyst wall, the capsule Wall is polymer, and the capsule-core is volatile oil or volatile oil and the composition of aluminium hydrosilicate, counts by weight, its group Part and its deal as follows:Capsule-core 20-70%;Cyst wall 30-80%;Emulsifying agent 1-6%.The cyst wall polymer is polyurethane resin, bright One or more in glue, cyclodextrin, low melting point polyamide, epoxy resin, Lauxite, Arabic gum;The volatile oil Essence type include hay-scented type, rose scent, Forest Bath odor type, jasmine fragrance, lavender flavor type, fruit flavouring, lemonene Type and osmanthus flower fragrant, the volatile oil belong to the volatile oil of high temperature resistant type, are resistant to processing temperature 100-160 DEG C.As more Further preferred version, the capsule-core is the composition of volatile oil and aluminium hydrosilicate, i.e., using aluminium hydrosilicate as virtue The carrier of essential oil so that volatile oil is stored inside which after being absorbed by aluminium hydrosilicate microballoon, reaches the effect for persistently holding perfume Really, the volatile oil is 30-45% with the quality accounting of aluminium hydrosilicate:55-70%, its preparation technology are included first by fragrance essence Oil is carried in aluminium hydrosilicate microballoon, is carried out at microencapsulation again after coupling processing is made to aluminium hydrosilicate microsphere surface Reason, is obtained volatile oil microcapsules.
Nano titanium oxide, molecular formula are TiO2, have the characteristics that safety non-toxic, possess certain hydrophily and moisture absorption Property, TiO2Middle Ti-O bond polarity is larger, and the water of adsorption is dissociated because polarizing, and easily forms hydroxyl, and which not only has Automatic cleaning action, also has certain bactericidal property, is applied in the present invention to promote the bactericidal properties from fragrant antimicrobial fiber, protects Hold the cleaning of fiber.Accordingly, as further preferred version, the non-weaving cloth is with described in the deodorant finishing agent of natural antibacterial Finishing agent also includes nano titanium oxide, and its component and formula are as follows:Polyethylene glycol glycerol ether 5%-9%;Polyoxyethylene sorbitan mountain Pears tristearate 8%-15%;Ester based quaternary ammonium salt 5%-8%;Natural antibacterial composition 10-16%;Fragrant slow release body 3%-8%;Receive Rice titanium dioxide 0.5%-5%;Balance of deionized water.
Used as further preferred version, the ester based quaternary ammonium salt is palm cationoid ester based quaternary ammonium salt, stearic acid two Ethanol diester quaternary ammonium, stearic acid triethanolamine ester quaternary, double ethyl stearte base hydroxyethyl methyl sulfate methyl ammoniums, 2,3- One or more in dihydroxypropyl dibasic acid esters ammonium halide, double hydroxyethyl fatty acid ester dimethy lammonium chloride.
Used as further preferred version, the emulsifying agent is neopelex, fatty acid mono glycidol, bay One kind in sour monoglyceride, methyl glycol fatty acid ester, polyoxyethylene sorbitan fatty acid ester, Span-80, odium stearate Or it is several.
Used as further preferred version, the amino-acid chelate is zinc and amino-acids chelate, the zinc and amino-acids chela Compound is formed with Covalent bonding together through chelating technique with zinc ion by the amino acid, and the amino acid is aspartic acid, Soviet Union Propylhomoserin, serine, glutamic acid, glycine, propylhomoserin, phenylalanine, lysine, arginine, histidine, one kind of methionine or several Kind.As further preferred embodiment, the preferred glycine zine of the zinc and amino-acids chelate, threonine zinc, lysine One or more in zinc and zinc methionine.The amino acid derivativges are amino-acid ester, and the amino-acid ester includes lysine One or more in Lauryl Ester, glutamic acid cellulose esters, aspartic acid cellulose esters.
Used as further preferred version, the odor type of the fragrant slow release body includes that hay-scented type, rose scent, Forest Bath are fragrant Type, jasmine fragrance, lavender flavor type, fruit flavouring, lemon flavor and osmanthus flower fragrant.
The method for sorting of non-weaving cloth of the present invention, including following process and step:
1)The preparation of the deodorant finishing agent of natural antibacterial
Step one:The preparation of natural antibacterial deodorant compositions:Citric acid is first dissolved in deionized water and stirs acquisition solution A; Again catechin, Tea Polyphenols, grape seed extract are dissolved in solution A and are mixing uniformly to form solution B respectively;By solution B plus Heat is added in emulsifying agent in solution B and stirs, be subsequently adding Tea Saponin, shitosan, aloe, first to after 50-60 DEG C Shell element, tea-seed oil, amino-acid chelate, amino acid derivativges are simultaneously uniformly mixed;Finally done using spray dryer Dry, size-reduced grinding forms natural antibacterial deodorant compositions powder;
Step 2:Deionized water is heated to 40-60 DEG C, is subsequently adding polyoxyethylene sorbitan tristearate, ester group season Ammonium salt, polyethylene glycol glycerol ether, are uniformly mixed, and form solution C;
Step 3:Under conditions of stirring, toward step(Two)Solution C in add natural antibacterial composition, fragrant slow release body, continue Continuous stirring causes natural antibacterial composition, the dissolving of fragrant slow release body or mixes, and forms solution D;
Step 4:Solution D is cooled to room temperature, discharging, the deodorant finishing agent of natural antibacterial is obtained;
2)The finishing technique of non-weaving cloth
Step one:By process(1)The deodorant dilution agent that arranges of obtained natural antibacterial is formulated as solution of the concentration for 5%-50%, is obtained Dressing liquid;
Step 2:Non-weaving cloth is positioned in dressing liquid and impregnates 5-30min at room temperature;
Step 3:By adjusting the spacing of control roll, by step(Two)The non-weaving cloth of gained carries out drying process;
Step 4:By step(Three)The non-weaving cloth of gained carries out baking and curing process, and drying temperature is 105-110 DEG C so that The deodorant finishing agent of natural antibacterial is 0.3%-1.2% with the weight ratio of non-weaving cloth body.
The application mainly in medical and hygiene article, disposable sanitary articles of the purposes of non-weaving cloth of the present invention.
The beneficial effect that the present invention is realized:Natural antibacterial deodorant compositions finishing agent is present invention employs, can also be by day So antibacterial and deodouring composition finishing agent mixes finishing agent with from compounding formation of fragrant slow release body, and therefore, the present invention has following several Individual effect:
1)The natural antibacterial deodorant compositions finishing agent being coated with non-weaving cloth is non-stimulated to human body skin, mutually opposes human body skin There is wetting and antimicrobial protection effect, the invasion of bacterium can be suppressed and grown, to ammonia absorptivity height, antibacterial and mouldproof and deodorant effect Fruit is very prominent, applies the present invention to medicine and hygiene fieldses, particularly disposable sanitary articles field, can not only solve at present Disposable sanitary articles cause sultry humidity because absorbing the body fluid of people, and then cause erythema, red hip, itch and smelly ask Topic, and then careful care human body skin.
2)The essence microcapsule from fragrant slow release body is added in natural antibacterial deodorant compositions finishing agent, is released with fragrance Put uniformly, the feature of fragrance remaining time length, good stability, the different demands for arranging processing can be weaved after meeting, is given out a sweet perfume Fragrance.
Specific embodiment
Term " volatile oil ":Volatile oil is a kind of plants essential oil that can distribute aromatic odor, its be by multiple chemistry The mixture of material composition, can be divided into aliphatic, aromatic series and 3 big class compound of terpene by chemical constitution and theirs is oxygen-containing Derivative such as alcohol, aldehyde, ketone, acid, ester, lactone, ether and terpenes etc..Essential oil is readily flowed transparency liquid or body of paste mostly, In colourless, faint yellow, and for the physical property of essential oil, most of essential oils are water insoluble or are slightly soluble in water, and from fragrance plant The obtained essential oil containing fragrant part of thing typically all has certain volatility at room temperature.
Plants essential oil has certain inhibitory action to bacterium or mould, and such as single iodoacetate ester of terpene has very strong Antifungal activity, rosemary have stronger broad-spectrum antibacterial performance, and clove oil has excellent sterilization and fungistatic effect.
Additionally, tea-seed oil can suppress the respiration of bacterium, increase the permeability of somatic cells matter so as to which self-dissolving occurs Effect and dead.
Term " microcapsules ":Microcapsules technology is one of high-tech emerging technology of 21 century industrial circle focus development, Microcapsules technology can effectively overcome the problem that essential oil volatility is high, action time is short, extend the storage time of volatile materials, carry High material stability, particularly, microcapsules technology refer to by a certain purpose thing with various natural, semi-synthetic or synthesis high score Sub- film(Cyst wall)Cladding gets up to form microcapsules completely, and capsule-core material tunica wall is coated and isolated with external environment, reduces outer The impact of boundary's condition change, but under suitable condition, but when cyst wall is destroyed, capsule-core material is discharged, that is, rely on capsule The shielding action protection core of wall.The method of microencapsulation is divided into chemical method, physical-chemical process and Physical, and such as chemical method includes Interfacial polymerization, emulsion process, situ aggregation method, supercritical fluid technique etc., physical method include spray drying process, electrostatic precipitation Method etc., the spray drying process in the preferred Physical of the present invention.
With regard to grape seed extract, grape seed extract is a kind of polyphenols of new and effective natural anti-oxidation, Containing abundant bioflavonoid and OPC, anti-inflammatory, antiallergy and antioxidant effect are notable.
A kind of non-weaving cloth of the present invention, comprising non-weaving cloth body, the non-weaving cloth body is by fibre structure Net is composited through thermal finalization, non-woven including spun-bonded non-woven, spunbond melt-blowing nonwoven, Through-Air Thermal Bonded Nonwovens, hot rolling Cloth or chemical adhesion non-weaving cloth, its design feature are to be coated with the upper epidermis of the non-weaving cloth body, layer respectively The deodorant finish coating of natural antibacterial;Fibrous outer in fibre structure net is coated with natural antibacterial deodorant and arranges painting Layer, and the gap between fiber and fiber is filled with the deodorant finishing agent composition of natural antibacterial;By weight percentage, natural The weight ratio of antibacterial and deodouring finishing agent and non-weaving cloth body is 0.3%-1.2%, the group of the deodorant finishing agent of the natural antibacterial Divide and proportioning is as follows:Polyoxyethylene sorbitan tristearate 5-20 part;Ester based quaternary ammonium salt 1-10 part;Natural antibacterial is combined Thing 5-20 part.
As further preferred embodiment, polyethylene glycol can be added in the deodorant finishing agent of described natural antibacterial Glycerin ether, its component and formula are as follows:Polyethylene glycol glycerol ether 5-9 part;Polyoxyethylene sorbitan tristearate 8-15 Part;Ester based quaternary ammonium salt 5-8 part;Natural antibacterial composition 10-16 part.
As further preferred embodiment, fragrant slow release can be added in the deodorant finishing agent of described natural antibacterial Body, its component and formula are as follows:Polyethylene glycol glycerol ether 5-9 part;Polyoxyethylene sorbitan tristearate 8-15 part;Ester Based quaternary ammonium salt 5-8 part;Natural antibacterial composition 10-16 part;Fragrant slow release body 3-8 part.Wherein, the fragrant slow release body be in The aromatic micro-capsule of cladding core-shell structure, comprising capsule-core, cyst wall, the cyst wall is polymer, the capsule-core be volatile oil or Volatile oil and the composition of aluminium hydrosilicate, are counted by weight, and its component and its deal are as follows:Capsule-core 20-70%;Cyst wall 30-80%;Emulsifying agent 1-6%.The cyst wall polymer is polyurethane resin, gelatin, cyclodextrin, low melting point polyamide, asphalt mixtures modified by epoxy resin One or more in fat, Lauxite, Arabic gum;The essence type of the volatile oil include hay-scented type, rose scent, Forest Bath odor type, jasmine fragrance, lavender flavor type, fruit flavouring, lemon flavor and osmanthus flower fragrant, the volatile oil belong to resistance to Megathermal volatile oil, is resistant to processing temperature 100-160 DEG C.Used as further preferred version, the capsule-core is fragrance Essential oil and the composition of aluminium hydrosilicate, i.e., using aluminium hydrosilicate as the carrier of volatile oil so that volatile oil is hydrated Alumina silicate microballoon is stored inside which after absorbing, and reaches the effect for persistently holding perfume, the matter of the volatile oil and aluminium hydrosilicate Amount accounting is 30-45%:55-70%, its preparation technology include first volatile oil to be carried in aluminium hydrosilicate microballoon, to water Closing after alumina silicate microsphere surface makees coupling processing carries out microencapsulation process again, and volatile oil microcapsules are obtained.
Natural antibacterial composition of the present invention is counted by weight, and its component and its deal are as follows:Shitosan 2-8 Part;Aloe 10-15 part;Chitin 3-8 part;Catechin 5-10 part;Tea Polyphenols 10-40 part;Tea-seed oil 5-25 part;Tea Saponin 0.1-2 part;Grape seed extract 5-15 part;Citric acid 5-25 part;Amino-acid chelate 5-25 part;Amino acid derivativges 0-10 Part;Emulsifying agent 1-8 part.Used as further preferred embodiment, natural antibacterial composition is counted by weight, its component and Its deal is as follows:Shitosan 3-5 part;Aloe 12-13 part;Chitin 5-6 part;Catechin 6-8 part;Tea Polyphenols 15-20 part;Tea Seed oil 8-12 part;Tea Saponin 0.5-1 part;Grape seed extract 8-10 part;Citric acid 10-15 part;Amino-acid chelate 10-15 Part;Amino acid derivativges 3-6 part;Emulsifying agent 3-5 part.The natural antibacterial composition can be according to the system of aromatic micro-capsule in the present invention Standby technique makes the natural antibacterial microcapsules of cladding core-shell structure, the particle diameter of the natural antibacterial microcapsules below 3 μm, its capsule Core is natural antibacterial composition, and cyst material and its auxiliary agent, cladding process step are by the preparation technology of aromatic micro-capsule of the present invention Carry out, to improve the slow release of natural antibacterial composition and long-lasting.
Used as further preferred embodiment, the ester based quaternary ammonium salt is palm cationoid ester based quaternary ammonium salt, tristearin Sour diethanol diester quaternary ammonium, stearic acid triethanolamine ester quaternary, double ethyl stearte base hydroxyethyl methyl sulfate methyl ammoniums, One or more in 2,3- dihydroxypropyl dibasic acid esters ammonium halides, double hydroxyethyl fatty acid ester dimethy lammonium chloride, concrete Preferred stearic acid diethanol diester quaternary ammonium in embodiment.
The emulsifying agent is neopelex, fatty acid mono glycidol, lauric monoglyceride, propylene glycol fatty One or more in acid esters, polyoxyethylene sorbitan fatty acid ester, Span-80, odium stearate, in specific embodiment In preferably Span-80, polyoxyethylene sorbitan fatty acid ester.
One kind in the zinc and amino-acids chelate, preferably glycine zine, threonine zinc, lysine-zn and zinc methionine or Several;The amino acid derivativges are preferably amino-acid ester, and the amino-acid ester includes Lysine Lauryl Ester, glutamic acid fiber One or more in plain ester, aspartic acid cellulose esters.
In order to make further understanding to the present invention, now which is explained by specific embodiment.
Embodiment 1
The non-weaving cloth of the present embodiment includes non-weaving cloth body, and the non-weaving cloth body is combined through thermal finalization by fibre structure net Form, non-including spun-bonded non-woven, spunbond melt-blowing nonwoven, Through-Air Thermal Bonded Nonwovens, Nonwovens or chemical adhesion Woven cloths, the non-weaving cloth body construction feature of the present embodiment are as follows:
1)Upper epidermis, layer in non-weaving cloth body is coated with the deodorant finish coating of natural antibacterial respectively.
2)Fibrous outer in fibre structure net is coated with natural antibacterial deodorant and arranges coating, and fiber and fibre Gap between dimension is filled with the deodorant finishing agent composition of natural antibacterial.
3)By weight percentage, the deodorant finishing agent of natural antibacterial is 0.3%- with the weight ratio of non-weaving cloth body 1.2%.
In the present embodiment, the component of the deodorant finishing agent of natural antibacterial and proportioning as follows:Polyoxyethylene sorbitan three is hard Resin acid ester 5-20 part;Polyethylene glycol glycerol ether 5-9 part;Ester based quaternary ammonium salt 1-10 part;Natural antibacterial composition 5-20 part, fragrance Sustained release 3-8 part.
Embodiment 2
In the present embodiment, process for preparation of the arrangement of non-weaving cloth comprising the deodorant finishing agent of natural antibacterial and non-weaving cloth Arrangement process, its detailed process and step are as follows:
(One)The preparation of the deodorant finishing agent of natural antibacterial
1)Preparation:
The dispensing of natural antibacterial deodorant compositions:Shitosan 2kg;6 kg of aloe;2.5 kg of chitin;3 kg of catechin;Tea 9 kg of polyphenol;5 kg of tea-seed oil;0.4 kg of Tea Saponin;4.5 kg of grape seed extract;6 kg of citric acid;Amino-acid chelate 6 kg;2.5 kg of amino acid derivativges;2 kg of emulsifying agent, deionized water 100kg.
The dispensing of the deodorant finishing agent of natural antibacterial:10 kg of polyoxyethylene sorbitan tristearate;Polyethylene glycol glycerol 6 kg of ether;5 kg of ester based quaternary ammonium salt;10 kg of natural antibacterial composition;6 kg of fragrant slow release body;63 kg of deionized water.
Non-weaving cloth:PP spunbonded nonwovens, square grammes per square metre are 18g/m2.
2)Preparation process
Step one:The preparation of natural antibacterial deodorant compositions:Citric acid is first dissolved in deionized water and stirs acquisition solution A; Again catechin, Tea Polyphenols, grape seed extract are dissolved in solution A and are mixing uniformly to form solution B respectively;By solution B plus Heat is added in emulsifying agent in solution B and stirs, be subsequently adding Tea Saponin, shitosan, aloe, first to after 50-60 DEG C Shell element, tea-seed oil, amino-acid chelate, amino acid derivativges are simultaneously uniformly mixed;Finally done using spray dryer Dry, size-reduced grinding forms natural antibacterial deodorant compositions powder.
Step 2:Deionized water is heated to 40-60 DEG C, is subsequently adding polyoxyethylene sorbitan tristearate, ester Based quaternary ammonium salt, polyethylene glycol glycerol ether, are uniformly mixed, and form solution C.
Step 3:Under conditions of stirring, toward step(Two)Solution C in add natural antibacterial composition, fragrant slow release Body, continues stirring and causes natural antibacterial composition, the dissolving of fragrant slow release body or mix, form solution D.
Step 4:Solution D is cooled to room temperature, discharging, the deodorant finishing agent of natural antibacterial is obtained.
(Two)The finishing technique of non-weaving cloth
Step one:By process(One)The deodorant dilution agent that arranges of obtained natural antibacterial is formulated as the solution that concentration is 20%, is obtained whole Reason liquid.
Step 2:Non-weaving cloth is positioned in dressing liquid and impregnates 20-30min. at room temperature
Step 3:By adjusting the spacing of control roll, by step(Two)The non-weaving cloth of gained carries out drying process.
Step 4:Drying temperature is set as 110 DEG C, by step(Three)The non-weaving cloth of gained carries out baking and curing process.
A kind of non-weaving cloth, and the weight of the deodorant finishing agent of natural antibacterial and non-weaving cloth body have been obtained by above step The ratio of amount is 0.4%.
The non-weaving cloth physical property of the present embodiment is:Square grammes per square metre is 18.07g/m2, the fracture strength of 50mm width is 24N.
Embodiment 3
In the present embodiment, dispensing of the arrangement of non-weaving cloth comprising the deodorant finishing agent of natural antibacterial is as follows:
The dispensing of natural antibacterial deodorant compositions:Shitosan 2kg;6 kg of aloe;2.5 kg of chitin;3 kg of catechin;Tea 9 kg of polyphenol;5 kg of tea-seed oil;0.4 kg of Tea Saponin;4.5 kg of grape seed extract;6 kg of citric acid;Amino-acid chelate 6 kg;2.5 kg of amino acid derivativges;2 kg of emulsifying agent, deionized water 100kg.
The dispensing of the deodorant finishing agent of natural antibacterial:Polyoxyethylene sorbitan tristearate 15kg;Polyethylene glycol glycerol 8 kg of ether;7 kg of ester based quaternary ammonium salt;Natural antibacterial deodorant compositions 15kg;4 kg of fragrant slow release body, 51 kg of deionized water.
Non-weaving cloth:Polypropylene Through-Air Thermal Bonded Nonwovens, square grammes per square metre are 16g/m2.
A kind of non-weaving cloth comprising the deodorant finishing agent of natural antibacterial, and day is obtained by the process and step of embodiment 2 So antibacterial and deodouring finishing agent is 0.6% with the weight ratio of non-weaving cloth body.
The physical property of the non-weaving cloth comprising the deodorant finishing agent of natural antibacterial of the present embodiment of the present embodiment is:Square Grammes per square metre is 16.10g/m2, the fracture strength of 50mm width is 15N.
Embodiment 4
The present embodiment to embodiment 2, the antibacterial of the obtained non-weaving cloth comprising the deodorant finishing agent of natural antibacterial of embodiment 3, remove Smelly and fragrant performance is tested.
(One)Anti-microbial property test
Detection sample:Embodiment 2, the obtained non-weaving cloth comprising the deodorant finishing agent of natural antibacterial of embodiment 3, control sample.Its Middle control sample is the non-weaving cloth arranged without the deodorant finishing agent of natural antibacterial in embodiment 2 or embodiment 3.
Anti-microbial property detects foundation:JIS Z 2801:2000《The detection of antibacterial product anti-microbial property and par》.
Bacterium is used in detection:Escherichia coli(Escherichia coli)ATCC 25822.
Staphylococcus aureus(Staphylcococcus aureus)ATCC 6538.
Testing result is as shown in table 1:
(Two)Fragranced stability test
Detection sample:Embodiment 2, the obtained non-weaving cloth comprising the deodorant finishing agent of natural antibacterial of embodiment 3.
Fragrance Detection of Stability method:The sample is placed 365 days under field conditions (factors) through washing 100 times.
Evaluation method:Via the evaluation group that spices expert constitutes, fragrance is qualitatively judged by sense of smell.
Evaluation result:Each sample is respectively provided with fragrance, and fragrance is pure, illustrates that the invention is obtained deodorant comprising natural antibacterial The fragrance stability of the non-weaving cloth of finishing agent is high, and aroma-keeping time is long, wash resistant.
(Three)Deodoriging properties are tested
Detection sample:Embodiment 2, the obtained non-weaving cloth comprising the deodorant finishing agent of natural antibacterial of embodiment 3.
Detection method:Non-weaving cloth comprising the deodorant finishing agent of natural antibacterial is positioned over known odor concentration C0Closed In container, foul smell composition is the mixed gas being made up of ammonia, hydrogen sulfide gas, closed placement 30-60min, then with detection Odor concentration C in the closed instrument of instrument test1, and clearance of the sample to foul smell is calculated as follows, test result such as 2 institute of table Show.
Computing formula:Foul smell clearance(%)=(C0- C1)/ C0× 100%, C in formula0For foul smell initial concentration, C1It is to be wrapped The residual odor concentration after non-weaving cloth absorption containing the deodorant finishing agent of natural antibacterial.
Embodiment 5
The non-weaving cloth comprising the deodorant finishing agent of natural antibacterial obtained by embodiment 2, embodiment 3 is mainly used in disposable hygienic Application in product, the disposable sanitary articles include the leakproof edge of opaque liquid, the surface layer of liquid permeability, guide layer, absorption Core wrap layer, and the bottom of opaque liquid.
Non-weaving cloth comprising the deodorant finishing agent of natural antibacterial as disposable sanitary articles leakproof edge non-weaving cloth, Impervious cover sheet non-weaving cloth, permeability guide layer non-weaving cloth, the integument non-weaving cloth of osmotic absorption core body and work It is counterdie composite non-weaving cloth compound with the counterdie of bottom etc..
Additionally, the application from fragrant natural antibacterial Odor-Removing Nonwoven Fabrics mainly in medical and hygiene article of the present invention, such as As medical protective garment cloth, medical sheet, pillow mattress liner application, meanwhile, be alternatively arranged as deodorant used in shoes sterilization material, And wardrobe material etc..
Embodiment 6
The present embodiment testing example 2, the obtained non-weaving cloth comprising the deodorant finishing agent of natural antibacterial of embodiment 3 are to physiology salt The permeance property of water.Test result is as follows:
Wherein, method of testing refers to method of testing of the sanitary goods industry to non-weaving cloth to physiological saline permeance property, specifically As follows:
Step 1:Take standard filter paper 3-5 to open, non-weaving cloth is cut to and standard filter paper sample of the same size, is placed in standard On filter paper, smooth after insert in LISTER permeameter, the filling opening of its Instrumental faces the center position of non-weaving cloth.
Step 2:Take in 5ml physiological saline injection LISTER liquid storage cylinder, open liquid feeding switching fluid and non-weaving cloth is penetrated into, and Synchronously start by manual time-keeping, when physiological saline completely penetrates through non-weaving cloth, i.e., when non-woven cloth cover upper liquid body disappears, timing is tied Bundle, records first time time of penetration T1.
Step 3:Repeat step after 60s(2), record second time of penetration T2.
Step 4:Repeat step after 60s(2), third time time of penetration T3 is recorded, other times of penetration test class according to this Push away.
Although the present invention describes specific case study on implementation, the scope of the present invention is not limited to above-mentioned concrete reality Example is applied, without departing from the case in the spirit of the invention, the various modifications to the present invention, variations and alternatives each fall within the guarantor of the present invention Shield scope.

Claims (9)

1. a kind of non-weaving cloth, comprising non-weaving cloth body, the non-weaving cloth body is combined through thermal finalization by fibre structure net Form, non-including spun-bonded non-woven, spunbond melt-blowing nonwoven, Through-Air Thermal Bonded Nonwovens, Nonwovens or chemical adhesion Woven cloths, it is characterised in that:Upper epidermis, layer in the non-weaving cloth body is coated with the deodorant arrangement of natural antibacterial respectively Agent coating;Fibrous outer in fibre structure net is coated with the deodorant finish coating of natural antibacterial, and in fibre structure Gap in net between fiber and fiber is filled with the deodorant finishing agent composition of natural antibacterial;By weight percentage, natural anti- The weight ratio of the deodorant finishing agent of bacterium and non-weaving cloth body is 0.3%-1.2%, the component of the deodorant finishing agent of the natural antibacterial And proportioning is as follows:
Polyoxyethylene sorbitan tristearate 5-20 part;
Ester based quaternary ammonium salt 1-10 part;
Natural antibacterial composition 5-20 part;
Wherein, the natural antibacterial composition is counted by weight, and its component and its deal are as follows:Shitosan 2-8 part;Aloe 10-15 part;Chitin 3-8 part;Catechin 5-10 part;Tea Polyphenols 10-40 part;Tea-seed oil 5-25 part;Tea Saponin 0.1-2 part;Portugal Grape seed extract 5-15 part;Citric acid 5-25 part;Amino-acid chelate 5-25 part;Amino acid derivativges 0-10 part;Emulsifying agent 1-8 Part.
2. a kind of non-weaving cloth according to claim 1, it is characterised in that:The deodorant finishing agent of the natural antibacterial also includes Polyethylene glycol glycerol ether, the component of the deodorant finishing agent of the natural antibacterial and fills a prescription as follows:
Polyethylene glycol glycerol ether 5-9 part;
Polyoxyethylene sorbitan tristearate 8-15 part;
Ester based quaternary ammonium salt 5-8 part;
Natural antibacterial composition 10-16 part.
3. a kind of non-weaving cloth according to claim 1, it is characterised in that:The deodorant finishing agent of the natural antibacterial also includes Fragrant slow release body, fragrant slow release body are the aromatic micro-capsule in cladding core-shell structure, comprising capsule-core, cyst wall, the natural antibacterial The component of deodorant finishing agent and fill a prescription as follows:
Polyethylene glycol glycerol ether 5-9 part;
Polyoxyethylene sorbitan tristearate 8-15 part;
Ester based quaternary ammonium salt 5-8 part;
Natural antibacterial composition 10-16 part;
Fragrant slow release body 3-8 part.
4. a kind of non-weaving cloth according to claim 1, it is characterised in that:The ester based quaternary ammonium salt is palm cationoid Ester based quaternary ammonium salt, stearic acid diethanol diester quaternary ammonium, stearic acid triethanolamine ester quaternary, double ethyl stearte base ethoxys In methylsulfuric acid ammonium methyl, 2,3- dihydroxypropyl dibasic acid esters ammonium halide, double hydroxyethyl fatty acid ester dimethy lammonium chloride one Plant or several.
5. a kind of non-weaving cloth according to claim 1, it is characterised in that:The emulsifying agent is DBSA Sodium, fatty acid mono glycidol, lauric monoglyceride, methyl glycol fatty acid ester, polyoxyethylene sorbitan fatty acid ester, One or more in Span-80, odium stearate.
6. a kind of non-weaving cloth according to claim 1, it is characterised in that:The amino-acid chelate is zinc and amino-acids chela Compound, including one or more in glycine zine, threonine zinc, lysine-zn and zinc methionine;The amino acid derivativges For amino-acid ester, the amino-acid ester is included in Lysine Lauryl Ester, glutamic acid cellulose esters, aspartic acid cellulose esters One or more.
7. a kind of non-weaving cloth according to claim 4, it is characterised in that:The odor type of the fragrant slow release body includes hay-scented Type, rose scent, Forest Bath odor type, jasmine fragrance, lavender flavor type, fruit flavouring, lemon flavor and osmanthus flower fragrant.
8. a kind of method for sorting of the non-weaving cloth as described in the arbitrary right of claim 1 to 7, including following process and step:
1)The preparation of the deodorant finishing agent of natural antibacterial
Step one:The preparation of natural antibacterial deodorant compositions:Citric acid is first dissolved in deionized water and stirs acquisition solution A; Again catechin, Tea Polyphenols, grape seed extract are dissolved in solution A and are mixing uniformly to form solution B respectively;By solution B plus Heat is added in emulsifying agent in solution B and stirs, be subsequently adding Tea Saponin, shitosan, aloe, first to after 50-60 DEG C Shell element, tea-seed oil, amino-acid chelate, amino acid derivativges are simultaneously uniformly mixed;Finally done using spray dryer Dry, size-reduced grinding forms natural antibacterial deodorant compositions powder;
Step 2:Deionized water is heated to 40-60 DEG C, is subsequently adding polyoxyethylene sorbitan tristearate, ester group season Ammonium salt, polyethylene glycol glycerol ether, are uniformly mixed, and form solution C;
Step 3:Under conditions of stirring, toward step(Two)Solution C in add natural antibacterial composition, fragrant slow release body, continue Continuous stirring causes natural antibacterial composition, the dissolving of fragrant slow release body or mixes, and forms solution D;
Step 4:Solution D is cooled to room temperature, discharging, the deodorant finishing agent of natural antibacterial is obtained;
2)The finishing technique of non-weaving cloth
Step one:By process(1)The deodorant dilution agent that arranges of obtained natural antibacterial is formulated as solution of the concentration for 5%-50%, is obtained Dressing liquid;
Step 2:Non-weaving cloth is positioned in dressing liquid and impregnates 5-30min at room temperature;
Step 3:By adjusting the spacing of control roll, by step(Two)The non-weaving cloth of gained carries out drying process;
Step 4:By step(Three)The non-weaving cloth of gained carries out baking and curing process, and drying temperature is 105-110 DEG C so that The deodorant finishing agent of natural antibacterial is 0.3%-1.2% with the weight ratio of non-weaving cloth body.
9. a kind of non-weaving cloth as described in the arbitrary right of claim 1 to 7 is in medical and hygiene article, disposable sanitary articles Application.
CN201610884594.6A 2016-10-11 2016-10-11 A kind of non-weaving cloth, method for sorting and its application Pending CN106480743A (en)

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