CN106480567A - A kind of NEW TYPE OF COMPOSITE textile material and preparation method - Google Patents

A kind of NEW TYPE OF COMPOSITE textile material and preparation method Download PDF

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Publication number
CN106480567A
CN106480567A CN201610873722.7A CN201610873722A CN106480567A CN 106480567 A CN106480567 A CN 106480567A CN 201610873722 A CN201610873722 A CN 201610873722A CN 106480567 A CN106480567 A CN 106480567A
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China
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fiber
composite textile
new type
fibre
textile material
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Inventor
缪建良
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Wuxi Changan Shuguang Glove Factory
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Wuxi Changan Shuguang Glove Factory
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Priority to CN201610873722.7A priority Critical patent/CN106480567A/en
Publication of CN106480567A publication Critical patent/CN106480567A/en
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01HSPINNING OR TWISTING
    • D01H4/00Open-end spinning machines or arrangements for imparting twist to independently moving fibres separated from slivers; Piecing arrangements therefor; Covering endless core threads with fibres by open-end spinning techniques
    • D01H4/04Open-end spinning machines or arrangements for imparting twist to independently moving fibres separated from slivers; Piecing arrangements therefor; Covering endless core threads with fibres by open-end spinning techniques imparting twist by contact of fibres with a running surface
    • D01H4/08Rotor spinning, i.e. the running surface being provided by a rotor
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/36Cored or coated yarns or threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/063Load-responsive characteristics high strength
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial

Abstract

The invention provides a kind of NEW TYPE OF COMPOSITE textile material and preparation method thereof, described composite textile materials are prepared by the following raw material by weight:10~22 parts of carbon fiber;35~55 parts of cotton fiber;10~35 parts of chitin fiber;12~25 parts of modified cellulose fibre.The intensity of described composite textile materials is high, sucting wet air permeability is good, and flexibility is excellent;The production method of described composite textile materials has the advantages that high speed high yield, parent roll, short processes and low production cost simultaneously.

Description

A kind of NEW TYPE OF COMPOSITE textile material and preparation method
Technical field
The invention belongs to spinning engineering field, more particularly, to a kind of textile material and preparation method thereof.
Background technology
In recent years, people increasingly pay close attention to the development of the new yarn of feature, the feature of environmental protection, using several fiber blends, make Obtain the next yarn of blending number and there is respective advantage, the demand of client is met with this, thus also be born out some mixed yarns And its Yarn spinning method.
CN203034166U, authorized announcement date be on July 3rd, 2013 Chinese utility model patent disclose a kind of new Pupa albumen chopped fiber, is made up of animal protein fibre cortex and natural plant fibre sandwich layer;Described animal protein fibre skin Layer is made up of pupa albumen, and natural plant fibre sandwich layer is made up of cotton, wood or bamboo native cellulose;Pupa albumen chopped fiber Composition be to be made up of 10%~40% pupa albumen and 90%~60% native cellulose;This utility model pupa albumen Fiber has the characteristics that real silk and viscose rayon yarn, the advantages of that is, snugness of fit, skin-friendly, bright, drapability are good, its Fabric sheen is soft, feel is smooth, moisture absorption, good permeability.
CN 201310133633.5, the applying date is on April 16th, 2013, and Shen Qing Publication day is in 10 days July in 2013 State's invention patent application discloses a kind of biomass regenerated fiber blending flexible smooth yarn and its production method, mixed yarn raw material bag Containing pupa protein fiber and Lay bamboo fibre, the percentage by weight of described pupa protein fiber and described Lay bamboo fibre is 20~80%:80 ~20%, silkworm protein fiber contains 18 kinds of aminoacid, pro-skin foster skin, and color and luster is noble, and garbage can be with biodegradation;Lay bamboo is fine Dimension dry and wet intensity is high, antibacterial bacteriostatic, comfortable soft, gloss such as silk, and garbage is biodegradable.Also can add in this scribbled One or more other biodegradable biomass regenerated fibers, the percentage by weight of described other fiber summations is 30~ 70%, the percentage by weight of pupa protein fiber and Lay bamboo fibre summation is 30~70% (one of which is not less than 15%).Pass through Compact spinning, the match tight spinning process of network, in conjunction with turning round appropriate low torque spinning technique, the bright and clean softness of institute's yarn, have excellent foster skin Comfortable function, is to knit the new type ideal raw material making woven, knitting high-grade fabric.
CN 201310130277.1, the applying date is on April 16th, 2013, and Shen Qing Publication day is in 10 days July in 2013 State's invention public announcement of a patent application a kind of biomass regenerated fiber blending flexible smooth fabric and its production method, this blended yarn weaved fabric It is with pupa protein fiber and Lay bamboo fibre as raw material, with raw material weight percentages, each Feedstock Component content in finished product fabric For pupa protein fiber:20%~80%, Lay bamboo fibre:20%~80%.Strong using the bamboo fiber blended property of pupa protein fiber and Lay Advantage, one or more other biological matter regenerated fibers can be added in blended yarn weaved fabric, with raw material weight percentages, finished product The content of each raw material components in fabric is pupa protein fiber and Lay bamboo fibre total amount:30%~70% (one of which is not less than 15%), other biomass regenerated fiber total amounts:30%~70%.It is soft that this invention further relates to a kind of biomass regenerated fiber blending The production method of soft light face cleaning material.The Product Green environmental protection of the present invention, flexible smooth, sucting wet air permeability is good, and strength preferably, has Natural bacteria resistance, can be used for taking, home textile and decoration with etc. expensive goods.
The mixed yarn of above-mentioned prior art is all pupa protein fiber and bamboo fibre or the blending with other biological matter fiber Yarn, the bright and clean soft, sucting wet air permeability of this yarn is good, has excellent foster skin comfortable function and natural bacteria resistance, but Be this yarn intensity high not enough it is impossible to be applied to some fields that yarn strength is had high demands;Its Yarn spinning method produces Complex process, quality control and high cost, the quality cost control difficulty therefore passing through bamboo pupa viscose staple fibre blending resultant yarn is big; Due to the multiformity in market, short fiber yarn to be realized mass customized, meet market to bamboo pupa viscose staple fibre performance requirement Change, pupa protein fiber performance and the long and slender dimension of bamboo can only be reached according to the relative ratio adjustment of pupa protein fiber and bamboo fibre The adjustment of performance, thus reaching the change of fiber overall performance, this is difficult in actual production process.Blended weave adopts Be compact spinning, the match tight spinning process of network, its low production efficiency, production procedure is long, and production cost is high.
A kind of Novel composite high-strength textile material of CN 103526372 A and manufacture method, this textile material is included according to weight The azelon of 15~25 parts of mineral fibres of amount number meter, 20~40 parts of Plant fiber and 35~65 parts, its producer Method is to carry out raw material after pretreatment respectively, carries out mixed material, opener, cotton carding, fibre-condensing, drafting and rotor spinning step successively Suddenly, finally obtain finished product.But the intensity of this textile material and hygroscopicity need to improve further.
Content of the invention
In order to overcome drawbacks described above, the invention provides a kind of NEW TYPE OF COMPOSITE textile material and preparation method thereof, described mixed Textile material intensity is high, sucting wet air permeability is good, and has excellent flexibility.
In order to solve above-mentioned technical problem, the technical solution used in the present invention is:
A kind of NEW TYPE OF COMPOSITE textile material, described composite textile materials are prepared by the following raw material by weight:
Described modified cellulose fibre is through small molecule quaternary ammonium salt cation modifying agent and macromolecule season by cellulose fibre Ammonium salt cation modifier, as cation modifier, is modified processing, when the pH value obtaining is 6.5-8.5, such as 6.8, 7.0th, 7.2,7.5,7.8,8.0,8.1 or 8.2 etc., Zeta electrode potential value is the modified cellulose fibre of 5-26mV, such as Zeta Electrode potential value is 8mV, 10mV, 12mV, 15mV, 18mV, 20mV, 22mV or 24mV etc.;Described small molecule quaternary ammonium salt sun from Sub- modifying agent is the epichlorohydrin parent derivant of epoxy quaternary ammonium salt, and described high molecular quaternary cation modifier is backbone chain type Poly-epoxychloropropane dimethylamine.
Carbon fiber strength in the present invention is high, and has certain hygroscopicity, and described cotton fiber is conventional Plant fiber, Production cost is relatively low, and has preferable skin-friendly;Chitin fiber production cost is relatively low, and can improve the intensity of yarn And bacteria resistance, its mass specific resistance 108g Ω/cm simultaneously2Level is relatively low in the fibre, has preferable antistatic property, Modified cellulose fibre has higher intensity, and has good hygroscopicity.The mutual synergism of described four kinds of fibers, makes The textile material intensity that must be obtained greatly improves, and has excellent hygroscopicity and flexibility.
The composite textile materials that the present invention provides include the following raw material by weight:10~22 parts of carbon fiber, such as 12 parts, 13 parts, 14 parts, 15 parts, 18 parts, 20 parts or 21 parts etc.;35~55 parts of cotton fiber, such as 36 parts, 37 parts, 38 parts, 40 parts, 42 parts, 45 Part, 47 parts, 49 parts or 52 parts etc.;10~35 parts of chitin fiber, such as 12 parts, 13 parts, 15 parts, 18 parts, 20 parts, 23 parts, 25 parts, 28 parts, 30 parts, 32 parts or 34 parts etc.;12~25 parts of modified cellulose fibre, such as 13 parts, 15 parts, 16 parts, 18 parts, 20 parts, 22 parts Or 24 parts etc..
The NEW TYPE OF COMPOSITE textile material that the present invention provides is applied to woven, knitting, the thus weaving face fabric of kind yarn weaving, There is the texture of metal, the effect of armor.
As preferred technical scheme, described composite textile materials are prepared by the following raw material by weight:
As most preferred technical scheme, described composite textile materials are prepared by the following raw material by weight:
A diameter of 55 μm~65 μm of described modified cellulose fibre, such as 56 μm, 58 μm, 60 μm, 62 μm or 64 μm etc..
Preferably, the fiber number of described modified cellulose fibre is 620dtex~640dtex, such as 623dtex, 628dtex, 630dtex, 632dtex, 635dtex or 638dtex etc..
Length 2~the 5mm longer than the length of carbon fiber of described cotton fiber, such as long 3mm, 4mm or 5mm etc.;
Preferably, the length of described chitin fiber 2~5mm longer than the length of carbon fiber, such as long 2mm, 3mm, 4mm or 5mm etc..
Due to identical line density and the longer fiber of fiber, under the centrifugal action when twisting in high-speed rotor, form yarn The outer looping layer of cortex, yam surface property shows the property of longer fibers, and sandwich layer forms compacted zone due to the twisting initial stage Yarn, such carbon fiber forms the sandwich layer of mixed yarn, increases the bulk strength of hybrid yams, intensity greatly improves, and cotton fiber and first Shell cellulose fiber forms the top layer of blended yarns, so that the bright and clean softness of yarn, sucting wet air permeability are good, have excellent foster skin and relaxes Suitable function and natural bacteria resistance.
The fineness of described carbon fiber is 0.55~1.22dtex, such as 0.65dtex, 0.75dtex, 0.85dtex, 0.95dtex, 1.00dtex, 1.05dtex, 1.15dtex or 1.20dtex etc., length is 26~33mm, such as 27mm, 28mm, 29mm, 30mm, 31mm or 32mm etc., doing is by force 6.0~6.9cN/dtex, such as 6.1cN/dtex, 6.2cN/dtex, 6.3cN/ Dtex, 6.4cN/dtex, 6.5cN/dtex or 6.7cN/dtex etc..Volume to weight ratio cotton fiber, chitin fiber due to carbon fiber Big with modified cellulose fibre, such specification is conducive to making it close with the weight of other fibers, is unlikely to utilizing gravity When separating impurity, fiber loss.
The fineness of described cotton fiber is 0.65~1.95dtex, such as 0.75dtex, 0.85dtex, 0.95dtex, 1.02dtex, 1.15dtex, 1.25dtex, 1.35dtex, 1.45dtex, 1.65dtex, 1.85dtex or 1.90dtex etc., long Spend for 30~38mm, such as 32mm, 33mm, 35mm, 36mm or 37mm etc., doing is by force 2.3~3.8cN/dtex, such as 2.5cN/ Dtex, 2.8cN/dtex, 3.0cN/dtex, 3.2cN/dtex, 3.4cN/dtex, 3.5cN/dtex or 3.6cN/dtex etc..This The specification of sample advantageously forms the structure of close concentric circular, improves the intensity of rotor yarn and controls the length of chopped fiber in degree turn In the diameter range of cup, give a discount when preventing fiber from twisting under the centrifugal action that revolving cup rotates, thus producing cotton knot to deteriorate yarn Line quality or cause the end breakage rate of yarn to increase.
The fineness of described chitin fiber is 0.65~1.95dtex, such as 0.75dtex, 0.85dtex, 0.95dtex, 1.02dtex, 1.15dtex, 1.25dtex, 1.35dtex, 1.45dtex, 1.65dtex, 1.85dtex or 1.90dtex etc., long Spend for 30~38mm, such as 32mm, 33mm, 35mm, 36mm or 37mm etc., doing is by force 2.3~3.8cN/dtex, such as 2.5cN/ Dtex, 2.8cN/dtex, 3.0cN/dtex, 3.2cN/dtex, 3.4cN/dtex, 3.5cN/dtex or 3.6cN/dtex etc., egg White matter content is 3~8%, such as 4%, 5%, 6% or 7% etc..The advantage selecting such specification is the carapace as outer looping Cellulose fiber, fibre length ensures that yarn outer surface is chitin fiber in resultant yarn, and simultaneously enough intensity makes chitin fine Dimension and carbon fiber, cotton fiber and modified cellulose fibre become an overall yarn, and protein content is too high, and to reduce fiber strong Degree, increases cost, and is unfavorable for the overall quality of yarn.
On the other hand, the invention provides a kind of method producing described NEW TYPE OF COMPOSITE textile material:Raw material is entered respectively After row pretreatment, carry out mixed material, opener, cotton carding, fibre-condensing, drafting and rotor spinning step successively, finally obtain finished product.
Described pretreatment is to use griping cotton machine, raw material is loosened and tears into little fibre bundle, wind deliver to cleaner unit by dust with thin Little fiber removes, then removes, through weight trash separator, the debris that proportion is more than little fibre bundle.Described preprocess method is conducive to keeping away Exempt from that loosening of different fibers is torn, dedusting and weight remove.
Preferably, described mixed material is to mix in fibre device in frequency conversion metering dedusting, according to a certain percentage by after pretreatment Raw material be sufficiently mixed, concurrently separate and remove the trifle in the world in raw material, then enter one by two-stage multi-mixer, opener Trifle in the world in step shredding mixed material and removal raw material, and make the fiber fully ratio uniform mixing on request of each kind.Described Frequency conversion is measured dedusting mixed fibre device and can be reached abundant and partly slagging-off the effect of multiple fiber mixing;Adjusted by controlling fibre weight Section plate ensures the ratio of composite fibre component accurately so that fiber mix homogeneously, and dedusting remove impurity is thorough.
Preferably, described rotor spinning adopts one-level or two grades of cotton cardings, 8500~9500 revs/min of cotton carding roller rotating speed, revolving cup Using 36~40mm diameter, rotor speed is 75000~100000 revs/min, draws yarn speed and is 120~130 ms/min, winding speed Spend for 115~125 ms/min.The selection of these parameters adjusting is suitable for use with semiautomatic rotor spinning machine, using revolving cup diameter The yarn of adjustment weaving plurality of specifications, takes into account the high efficiency of spinning while ensureing yarn qualities.
Compared with prior art, the present invention has advantages below:
1st, the raw material of the composite textile materials that the present invention provides includes carbon fiber, cotton fiber, chitin fiber and modification fibre Cellulose fiber, the yarn strength after spinning is greatly improved due to the effect of carbon fiber, and yarn is done by force up to 3.9~4.1cN/ Dtex, can be used for the field that some have high demands to yarn strength, and the application of cotton fiber and modified cellulose fibre simultaneously makes it inhale Green permeability preferably, and has excellent foster skin comfortable function and natural antibacterial bacteriostatic sexual function.
2nd, the method provided by the present invention for producing described composite textile materials has rotor spinning high speed high yield, big volume The advantages of cylinder, short processes and low production cost, it is advantageously implemented the heavy industrialization customized production of yarn, production and city can be made Field flexibly seamless connection.
Specific embodiment
To further illustrate technical scheme below by specific embodiment.
Embodiment 1
The NEW TYPE OF COMPOSITE textile material of this enforcement, is prepared by following raw material in parts by weight:
Described modified cellulose fibre is through small molecule quaternary ammonium salt cation modifying agent and macromolecule season by cellulose fibre Ammonium salt cation modifier, as cation modifier, is modified processing, when the pH value obtaining is 6.5-7.0, Zeta electrode Potential value is the modified cellulose fibre of 5-10mV;Described small molecule quaternary ammonium salt cation modifying agent is the table of epoxy quaternary ammonium salt Chloropharin parent derivant, described high molecular quaternary cation modifier is the poly-epoxychloropropane dimethylamine of backbone chain type.
The fineness of described carbon fiber is 1.0dtex, and length is 30mm, and doing is by force 6.0cN/dtex.
The fineness of described cotton fiber is 1.69dtex, and length is 35mm, and doing is by force 2.3cN/dtex.
The fineness of described chitin fiber is 1.69dtex, and length is 35mm, and doing is by force 2.3cN/dtex, protein content For 3%.
A diameter of 60 μm of described modified cellulose fibre, fiber number is 625dtex.
The method producing the NEW TYPE OF COMPOSITE textile material in the present embodiment, is to carry out raw material after pretreatment respectively, successively Carry out mixed material, opener, cotton carding, fibre-condensing, drafting and rotor spinning step, finally obtain finished product.
Described pretreatment is to use griping cotton machine, raw material is loosened and tears into little fibre bundle, wind deliver to cleaner unit by dust with thin Little fiber removes, then removes, through weight trash separator, the debris that proportion is more than little fibre bundle.
Described mixed material is to mix in fibre device in frequency conversion metering dedusting, enters pretreated raw material according to a certain percentage Row is sufficiently mixed, and concurrently separates and remove the trifle in the world in raw material, then by the further mixed material of multi-mixer and removes former Trifle in the world in material.
Described rotor spinning adopts one-level or two grades of cotton cardings, 8500 revs/min of cotton carding roller rotating speed, and revolving cup adopts 40mm diameter, Rotor speed is 90000 revs/min, draws yarn speed and is 125 ms/min, winding speed is 115 ms/min.
The dry of the composite textile materials obtaining is by force 8.9cN/dtex, and its hygroscopicity is 95%, and flexibility is good.
Embodiment 2
The NEW TYPE OF COMPOSITE textile material of this enforcement, is prepared by following raw material by weight:
Described modified cellulose fibre is through small molecule quaternary ammonium salt cation modifying agent and macromolecule season by cellulose fibre Ammonium salt cation modifier, as cation modifier, is modified processing, when the pH value obtaining is 7.5-8.0, Zeta electrode Potential value is the modified cellulose fibre of 10-12mV;Described small molecule quaternary ammonium salt cation modifying agent is epoxy quaternary ammonium salt Epichlorohydrin parent derivant, described high molecular quaternary cation modifier is the poly-epoxychloropropane dimethylamine of backbone chain type.
The fineness of described carbon fiber is 1.1dtex, and length is 32mm, and doing is by force 6.2cN/dtex.
The fineness of described cotton fiber is 1.72dtex, and length is 35mm, and doing is by force 2.4cN/dtex.
The fineness of described chitin fiber is 1.78dtex, and length is 36mm, and doing is by force 2.5cN/dtex, protein content For 4%.
A diameter of 60 μm of described modified cellulose fibre, fiber number is 630dtex.
The method producing the NEW TYPE OF COMPOSITE textile material in the present embodiment, is to carry out raw material after pretreatment respectively, successively Carry out mixed material, opener, cotton carding, fibre-condensing, drafting and rotor spinning step, finally obtain finished product.
Described pretreatment is to use griping cotton machine, raw material is loosened and tears into little fibre bundle, wind deliver to cleaner unit by dust with thin Little fiber removes, then removes, through weight trash separator, the debris that proportion is more than little fibre bundle.
Described mixed material is to mix in fibre device in frequency conversion metering dedusting, enters pretreated raw material according to a certain percentage Row is sufficiently mixed, and concurrently separates and remove the trifle in the world in raw material, then by the further mixed material of multi-mixer and removes former Trifle in the world in material.
Described rotor spinning adopts one-level or two grades of cotton cardings, 9000 revs/min of cotton carding roller rotating speed, and revolving cup adopts 38mm diameter, Rotor speed is 80000 revs/min, draws yarn speed and is 130 ms/min, winding speed is 125 ms/min.
The dry of the composite textile materials obtaining is by force 9.5cN/dtex, and its hygroscopicity is 92%, and flexibility is good.
Embodiment 3
The NEW TYPE OF COMPOSITE textile material of this enforcement, is prepared by following raw material by weight:
Described modified cellulose fibre is through small molecule quaternary ammonium salt cation modifying agent and macromolecule season by cellulose fibre Ammonium salt cation modifier, as cation modifier, is modified processing, when the pH value obtaining is 8.0-8.5, Zeta electrode Potential value is the modified cellulose fibre of 18-20mV;Described small molecule quaternary ammonium salt cation modifying agent is epoxy quaternary ammonium salt Epichlorohydrin parent derivant, described high molecular quaternary cation modifier is the poly-epoxychloropropane dimethylamine of backbone chain type.
The fineness of described carbon fiber is 0.55dtex, and length is 33mm, and doing is by force 6.5cN/dtex.
The fineness of described cotton fiber is 0.65dtex, and length is 36mm, and doing is by force 2.8cN/dtex.
The fineness of described chitin fiber is 0.85dtex, and length is 38mm, and doing is by force 3.2cN/dtex, protein content For 6%.
A diameter of 65 μm of described modified cellulose fibre, fiber number is 640dtex.
The method producing the NEW TYPE OF COMPOSITE textile material in the present embodiment, is to carry out raw material after pretreatment respectively, successively Carry out mixed material, opener, cotton carding, fibre-condensing, drafting and rotor spinning step, finally obtain finished product.
Described pretreatment is to use griping cotton machine, raw material is loosened and tears into little fibre bundle, wind deliver to cleaner unit by dust with thin Little fiber removes, then removes, through weight trash separator, the debris that proportion is more than little fibre bundle.
Described mixed material is to mix in fibre device in frequency conversion metering dedusting, enters pretreated raw material according to a certain percentage Row is sufficiently mixed, and concurrently separates and remove the trifle in the world in raw material, then by the further mixed material of multi-mixer and removes former Trifle in the world in material.
Described rotor spinning adopts one-level or two grades of cotton cardings, 8500 revs/min of cotton carding roller rotating speed, and revolving cup adopts 40mm diameter, Rotor speed is 90000 revs/min, draws yarn speed and is 125 ms/min, winding speed is 115 ms/min.
The dry of the composite textile materials obtaining is by force 9.3cN/dtex, and its hygroscopicity is 100%, and flexibility is good.
Embodiment 4
The NEW TYPE OF COMPOSITE textile material of this enforcement, is prepared by following raw material by weight:
Described modified cellulose fibre is through small molecule quaternary ammonium salt cation modifying agent and macromolecule season by cellulose fibre Ammonium salt cation modifier, as cation modifier, is modified processing, when the pH value obtaining is 6.5-7.5, Zeta electrode Potential value is the modified cellulose fibre of 20-26mV;Described small molecule quaternary ammonium salt cation modifying agent is epoxy quaternary ammonium salt Epichlorohydrin parent derivant, described high molecular quaternary cation modifier is the poly-epoxychloropropane dimethylamine of backbone chain type.
The fineness of described carbon fiber is 0.85dtex, and length is 33mm, and doing is by force 6.9cN/dtex.
The fineness of described cotton fiber is 0.65dtex, and length is 37mm, and doing is by force 3.8cN/dtex.
The fineness of described chitin fiber is 1.69dtex, and length is 35mm, and doing is by force 3.4cN/dtex, protein content For 6%.
A diameter of 55 μm of described modified cellulose fibre, fiber number is 620dtex.
The method of the NEW TYPE OF COMPOSITE textile material in the present embodiment, is to carry out raw material after pretreatment respectively, carries out successively Mixed material, opener, cotton carding, fibre-condensing, drafting and rotor spinning step, finally obtain finished product.
Described pretreatment is to use griping cotton machine, raw material is loosened and tears into little fibre bundle, wind deliver to cleaner unit by dust with thin Little fiber removes, then removes, through weight trash separator, the debris that proportion is more than little fibre bundle.
Described mixed material is to mix in fibre device in frequency conversion metering dedusting, enters pretreated raw material according to a certain percentage Row is sufficiently mixed, and concurrently separates and remove the trifle in the world in raw material, then by the further mixed material of multi-mixer and removes former Trifle in the world in material.
Described rotor spinning adopts one-level or two grades of cotton cardings, 8500 revs/min of cotton carding roller rotating speed, and revolving cup adopts 40mm diameter, Rotor speed is 90000 revs/min, draws yarn speed and is 125 ms/min, winding speed is 115 ms/min.
The dry of the composite textile materials obtaining is by force 10.2cN/dtex, and its hygroscopicity is 102%, and flexibility is excellent.
Comparative example 1
Except replacing with addition to reinforced plastic glass fibre carbon fiber, remaining is same as Example 4.
The dry of the composite textile materials obtaining is by force 5.1cN/dtex, and its hygroscopicity is 52%, and flexibility is general.
Comparative example 2
Except replacing with addition to flaxen fiber cotton fiber, remaining is same as Example 4.
The dry of the composite textile materials obtaining is by force 5.6cN/dtex, and its hygroscopicity is 62%, and flexibility is general.
Comparative example 3
Except replacing with addition to pupa protein fiber chitin fiber, remaining is same as Example 4.
The dry of the composite textile materials obtaining is by force 4.2cN/dtex, and its hygroscopicity is 55%, and flexibility is poor.
Comparative example 4
In addition to not containing modified cellulose fibre, remaining is same as Example 4.
The dry of the composite textile materials obtaining is by force 4.9cN/dtex, and its hygroscopicity is 61%, and flexibility is good.
Applicant states, the foregoing is only the specific embodiment of the present invention, but protection scope of the present invention not office It is limited to this, person of ordinary skill in the field is it will be clearly understood that any belong to those skilled in the art and take off in the present invention In the technical scope of dew, the change or replacement that can readily occur in, all fall within protection scope of the present invention and open within the scope of.

Claims (10)

1. a kind of NEW TYPE OF COMPOSITE textile material it is characterised in that:Described composite textile materials are by weight by the following raw material system Standby obtain:
Described modified cellulose fibre is through small molecule quaternary ammonium salt cation modifying agent and high molecular quaternary by cellulose fibre Cation modifier, as cation modifier, is modified processing, when the pH value obtaining is 6.5-8.5, Zeta electrode potential It is worth the modified cellulose fibre for 5-26mV;Described small molecule quaternary ammonium salt cation modifying agent is the epichlorohydrin of epoxy quaternary ammonium salt Parent derivant, described high molecular quaternary cation modifier is the poly-epoxychloropropane dimethylamine of backbone chain type.
2. a kind of NEW TYPE OF COMPOSITE textile material according to claim 1 it is characterised in that:Described composite textile materials press weight Amount number is prepared by the following raw material:
3. a kind of NEW TYPE OF COMPOSITE textile material according to claim 1 and 2 it is characterised in that:Described composite textile materials Prepared by the following raw material by weight:
4. a kind of NEW TYPE OF COMPOSITE textile material according to one of claim 1-3 it is characterised in that:Described modified cellulose A diameter of 55 μm~65 μm of fiber;
Preferably, the fiber number of described modified cellulose fibre is 620dtex~640dtex.
5. a kind of NEW TYPE OF COMPOSITE textile material according to one of claim 1-4 it is characterised in that:The length of described cotton fiber Spend 2~5mm longer than the length of carbon fiber;
Preferably, the length of described chitin fiber 2~5mm longer than the length of carbon fiber.
6. a kind of NEW TYPE OF COMPOSITE textile material according to one of claim 1-5 it is characterised in that:Described carbon fiber thin Spend for 0.55~1.22dtex, length is 30~33mm, doing is by force 6.0~6.9cN/dtex.
7. a kind of NEW TYPE OF COMPOSITE textile material according to one of claim 1-6 it is characterised in that:Described cotton fiber thin Spend for 0.65~1.95dtex, length is 30~38mm, doing is by force 2.3~3.8cN/dtex.
8. a kind of NEW TYPE OF COMPOSITE textile material according to one of claim 1-7 it is characterised in that:Described chitin fiber Fineness be 0.65~1.95dtex, length is 30~38mm, and doing is by force 2.3~3.8cN/dtex, protein content is 3~ 8%.
9. a kind of preparation method of the NEW TYPE OF COMPOSITE textile material as described in one of claim 1-8 it is characterised in that:Described system Preparation Method is to carry out raw material after pretreatment respectively, carries out mixed material, opener, cotton carding, fibre-condensing, drafting and rotor spinning successively Step, finally obtains finished product.
10. NEW TYPE OF COMPOSITE textile material according to claim 9 preparation method it is characterised in that:Described pretreatment is With griping cotton machine, raw material is loosened and tears into little fibre bundle, wind is delivered to cleaner unit and removed dust with fiber fines, then removes through weight The debris that proportion is more than little fibre bundle are removed by miscellaneous device;
Preferably, described mixed material is to mix in fibre device in frequency conversion metering dedusting to carry out;
Preferably, described rotor spinning adopts one-level or two grades of cotton cardings, 8500~9500 revs/min of cotton carding roller rotating speed, and revolving cup adopts 36~40mm diameter, rotor speed is 75000~100000 revs/min, draws yarn speed and is 120~130 ms/min, winding speed is 115~125 ms/min.
CN201610873722.7A 2016-09-30 2016-09-30 A kind of NEW TYPE OF COMPOSITE textile material and preparation method Pending CN106480567A (en)

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CN114687017A (en) * 2020-12-30 2022-07-01 苏州多道自动化科技有限公司 Intelligent feeding device and method for functional components of fasciated yarn

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Application publication date: 20170308