CN106479774A - A kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex - Google Patents
A kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex Download PDFInfo
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- CN106479774A CN106479774A CN201510534109.8A CN201510534109A CN106479774A CN 106479774 A CN106479774 A CN 106479774A CN 201510534109 A CN201510534109 A CN 201510534109A CN 106479774 A CN106479774 A CN 106479774A
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- lauryl
- anhydrous sorbitol
- limonene
- sorbitol apeo
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Abstract
The present invention is a kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex, the present invention is under conditions of having chelating agent, complexation carrier and limonene complexation are done with nonionic surfactant lauryl anhydrous sorbitol APEO, generates lauryl anhydrous sorbitol APEO limonene complex.Outward appearance body shape of the present invention be in lemon yellow gel body, in water be in emulsion form body, pH value be 5-6, active matter content 20～80%.The present invention primarily serves the purpose of industrial cleaning agent and civilian abluent it is also possible to be added in cleaning agent formula as intermediate.The present invention has the very good effect dirty except the dirty and heavy glue of heavy oil.
Description
【Technical field】
The present invention is a kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex, it is characterized in that described complex carrier is under conditions of having chelating agent, complexation carrier and limonene complexation are done with nonionic surfactant lauryl anhydrous sorbitol APEO, generates lauryl anhydrous sorbitol APEO limonene complex.
【Background technology】
Limonene another name limonene, alkene, belong to monoterpenes compound, colourless oil liquid, have the lemonish fragrance of class, be widely present in the monocyclic terpene in natural plants, in Pericarpium Citri tangerinae crude oil, content is up to 60-70%；Limonene has multiple physiologically actives and biological function, is widely used in medicine, food, essence and flavoring agent, cosmetics, abluent, pesticide industry；The physical characteristics of limonene, flash-point：46 DEG C, fusing point：- 74.3 DEG C, boiling point：177℃.It is dissolved in ethanol and most of nonvolatile oil, be slightly soluble in glycerol, water insoluble and propylene glycol；Limonene is nontoxic, nuisanceless, the various chemical solvents of current use can be substituted in industrial and civilian cleaning, there is no harmful effect to environment, and have good biological degradability, it is environmental protection cleaning-type solvent, have application in a lot of daily chemical essences, food flavor simultaneously；Limonene has prevention and the feature of suppression tumor promotion, has obvious preventive and therapeutic action to gastric cancer, pulmonary carcinoma, hepatocarcinoma etc., has inhibitory action to cancer of pancreas, has dissolution to cholelithiasis.
Limonene has extraordinary cleansing power to crust body in industrial products, but the hydrophilic of limonene is very bad, and this have impact on limonene and the later stage of cleaning object is processed.
Lauryl anhydrous sorbitol APEO is pale yellow viscous liquid, resistance to hard water, acid, alkali and inorganic salt；For emulsifying and dissolved oil and other water-insoluble material, non-ionic solubilizer, the soluble in water, multi-solvents such as methanol, ethanol, isopropanol, the performance such as there is emulsifying, diffusion, solubilising, stablize；Harmless, there is no zest, be mainly used in cake, ice cream, shortening etc. in the food industry and make；In other respects, can be used as mineral oil emulsion agent, dye solvent, cosmetic emulsifier, foam plasticss stabilizer, pharmaceutical emulsifiers, diffusant and stabilizer, and photo emulsion auxiliary agent.
Present invention is primarily intended to chemical complexing reaction carried out by limonene and lauryl anhydrous sorbitol APEO, change this feature of limonene non-hydrophilic, solve the water solubility problems of limonene；Limonene non-hydrophilic and hydrophilic obtain physical change, substantially increase the later stage process problem that limonene cleans crust body, make its lauryl anhydrous sorbitol APEO limonene complex after to the cleaning of crust body, carry out the later stage again cleans with water, and its heavy oil is dirty, weight glue dirt can clean well；Lauryl anhydrous sorbitol APEO limonene complex possesses extraordinary practical application.
Present invention firstly provides carrier and limonene complexation are done by lauryl anhydrous sorbitol APEO, produce lauryl anhydrous sorbitol APEO limonene complex.
【Content of the invention】
A kind of manufacture method of present invention lauryl anhydrous sorbitol APEO limonene complex, it is characterized in that described complex carrier is hydrophilic non-ionic surfactant lauryl anhydrous sorbitol APEO and non-hydrophilic crude limonene carries out chemical complexing reaction under the conditions of chelating agent, generate hydrophilic lauryl anhydrous sorbitol APEO ether limonene complex.
Lauryl anhydrous sorbitol APEO limonene complex reaction percentage by weight of the present invention：
Lauryl anhydrous sorbitol APEO 10-90%
Limonene 10-90%
Its polyoxyethylene ether of lauryl anhydrous sorbitol APEO of the present invention is ethylene oxide adduct, ethoxymer distribution system 20.
Complex reaction chelating agent usage amount of the present invention is the 0.1-5.0% of overall material.
The yellow usage amount of natural lemon of the present invention is the 0.1-5.0% of overall material.
It is rustless steel that device is answered in complexation of the present invention, the material opening reactor such as glass, enamel.
Complex reaction temperature control of the present invention is at 30-80 DEG C.
Outward appearance of the present invention is in lemon yellow gel, and 1% aqueous solution is emulsion state, pH value is 6-7, surface-active substance >=60%.
What the present invention was dirty to the heavy oil dirt on the crusts such as metal surface, glass surface, frosting, weight glue has very strong cleaning effect.
Complexation process route of the present invention：With in temperature controlled reactor, temperature control is in 30-80
DEG C, stirring, sequentially add lauryl anhydrous sorbitol APEO, limonene, chelating agent, natural lemon Huang；After reactor complex reaction 2 hours, overall material is in gelinite, and temperature is down to 35 ± 2 DEG C of qualified rear dischargings after testing.Finished product need to be placed in container and preserve.
【Specific embodiment】
Embodiment one：
Throwing raw materials ratio：50 parts of lauryl anhydrous sorbitol APEO, 50 parts of limonene, chelating agent are the 0.5% of overall material, natural lemon is yellow is the 0.5% of overall material.
Complexation process route：With in temperature controlled chuck stainless steel cauldron, temperature control is in 30-80
DEG C, stirring, sequentially add 50 parts of lauryl anhydrous sorbitol APEO, 50 parts of limonene, chelating agent be the 0.5% of overall material, natural lemon yellow for the 0.5% of overall material；After reactor complex reaction 2 hours, overall material is in gelinite, and temperature is down to 35 ± 2 DEG C of qualified rear dischargings after testing.Finished product need to be placed in container and preserve.
Embodiment two：
Throwing raw materials ratio：60 parts of lauryl anhydrous sorbitol APEO, 40 parts of limonene, chelating agent are the 0.7% of overall material, natural lemon is yellow is the 0.5% of overall material.
Complexation process route：With in temperature controlled chuck stainless steel cauldron, temperature control is in 30-80
DEG C, stirring, sequentially add 20 parts of lauryl anhydrous sorbitol APEO, 80 parts of limonene, chelating agent be the 0.7% of overall material, natural lemon yellow for the 0.5% of overall material；After reactor complex reaction 2 hours, overall material is in gelinite, and temperature is down to 35 ± 2 DEG C of qualified rear dischargings after testing.Finished product need to be placed in container and preserve.
Embodiment three：
Throwing raw materials ratio：80 parts of lauryl anhydrous sorbitol APEO, 20 parts of limonene, chelating agent are the 0.9% of overall material, natural lemon is yellow is the 0.5% of overall material；.
Complexation process route：With in temperature controlled chuck stainless steel cauldron, temperature control is in 30-80
DEG C, stirring, sequentially add 30 parts of lauryl anhydrous sorbitol APEO, 70 parts of limonene, chelating agent be the 0.9% of overall material, natural lemon yellow for the 0.5% of overall material；After reactor complex reaction 2 hours, overall material is in gelinite, and temperature is down to 35 ± 2 DEG C of qualified rear dischargings after testing.Finished product need to be placed in container and preserve.
Claims (7)
1. a kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex, it is characterized in that described complex carrier is under conditions of having chelating agent, complexation carrier and limonene complexation are done with nonionic surfactant lauryl anhydrous sorbitol APEO, generates lauryl anhydrous sorbitol APEO limonene complex.
2. a kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex according to claim 1 is it is characterised in that lauryl anhydrous sorbitol APEO limonene complex reaction percentage by weight：
Lauryl anhydrous sorbitol APEO 10-90%,
Limonene 10-90%.
3. a kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex according to claim 1 is it is characterised in that lauryl anhydrous sorbitol APEO is hydrophilic non-ionic surfactant.
4. the manufacture method of a kind of lauryl anhydrous sorbitol APEO limonene complex according to claim 1, it is characterized in that its polyoxyethylene ether of lauryl anhydrous sorbitol APEO is ethylene oxide adduct, ethoxymer distribution system 20.
5. it is characterised in that chelating agent is metal alkaline complexing agent, its usage amount is 0.1-5.0% to a kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex according to claim 1.
6. the system of a kind of lauryl anhydrous sorbitol APEO limonene complex according to claim 1
Make method it is characterised in that the yellow usage amount of natural lemon is 0.1-5.0%.
7. a kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex according to claim 1 is it is characterised in that its complex reaction temperature control is at 30-80 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510534109.8A CN106479774A (en) | 2015-08-27 | 2015-08-27 | A kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510534109.8A CN106479774A (en) | 2015-08-27 | 2015-08-27 | A kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex |
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| CN106479774A true CN106479774A (en) | 2017-03-08 |
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| CN201510534109.8A Pending CN106479774A (en) | 2015-08-27 | 2015-08-27 | A kind of manufacture method of lauryl anhydrous sorbitol APEO limonene complex |
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- 2015-08-27 CN CN201510534109.8A patent/CN106479774A/en active Pending
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170308 |
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| WD01 | Invention patent application deemed withdrawn after publication |