CN106479733A - The preparation method of efficient automobile glass cleaner - Google Patents

The preparation method of efficient automobile glass cleaner Download PDF

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Publication number
CN106479733A
CN106479733A CN201610880261.6A CN201610880261A CN106479733A CN 106479733 A CN106479733 A CN 106479733A CN 201610880261 A CN201610880261 A CN 201610880261A CN 106479733 A CN106479733 A CN 106479733A
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consumption
weight portion
preparation
water
filtrate
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卢国孝
石宝军
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Wuhu Ruide Machinery Technology Co Ltd
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Wuhu Ruide Machinery Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2041Dihydric alcohols
    • C11D3/2044Dihydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/10Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)
  • Medicines Containing Plant Substances (AREA)

Abstract

The invention discloses a kind of preparation method of efficient automobile glass cleaner, the preparation method includes:1)Dregs of beans, cottonseed, kudzu powder, luffa, orange peel are fermented in water, filtrate is then filtered to take, stood in then adding activated carbon to filtrate so that fermentation extract is obtained;2)Sweet wormwood, mulberry leaf, China rose, Chinese honey locust, the root of Dahurain angelica and dried orange peel are placed in water and are soaked, filtrate is then filtered to take so that extracts of Chinese herbal medicine is obtained;3)Water, NPE, ethylene glycol, nano diatomite, sodium lauroyl sarcosine, orris root, disodium ethylene diamine tetraacetate, fermentation extract are mixed with extracts of Chinese herbal medicine so that efficient automobile glass cleaner is obtained.There is to vehicle glass excellent cleaning effect and environmentally friendly by cleaning agent obtained in the method;In addition, the preparation method has raw material being easy to get and the simple feature of operation.

Description

The preparation method of efficient automobile glass cleaner
Technical field
A kind of the present invention relates to glass cleaner, in particular it relates to preparation method of efficient automobile glass cleaner.
Background technology
Automobile has become as the necessity of people's life, and such as car, bus, as the operation of automobile is chronically at In exposed environment, and then the surface of vehicle glass is caused very easily to deposit dust or other dirts.These dusts or Other dirts can occur the reaction of some row with glass surface, and then the vestige of glass surface is extremely difficult to clean off.
Automobile glass cleaning agent of the prior art is generally individually the cleaning agent of broad spectrum type, and the cleaning agent of broad spectrum type is to glass The cleaning effect on surface is undesirable, and easily glass surface is caused to damage.Cleaning agent of the prior art contains more simultaneously Volatile harmful substance, such as dichloromethane and trichloro ethylene, harmful to human body and environment.
Content of the invention
It is an object of the invention to provide a kind of preparation method of efficient automobile glass cleaner, by clear obtained in the method Clean dose has excellent cleaning effect and environmentally friendly to vehicle glass;In addition, the preparation method has raw material being easy to get and work The simple feature of sequence.
To achieve these goals, the invention provides a kind of preparation method of efficient automobile glass cleaner, including:
1)Dregs of beans, cottonseed, kudzu powder, luffa, orange peel are fermented in water, filtrate is then filtered to take, then by activity Charcoal is stood in adding to filtrate so that fermentation extract is obtained;
2)Sweet wormwood, mulberry leaf, China rose, Chinese honey locust, the root of Dahurain angelica and dried orange peel are placed in water and are soaked, filtrate is then filtered to take to be obtained Extracts of Chinese herbal medicine;
3)By water, NPE, ethylene glycol, nano diatomite, sodium lauroyl sarcosine, orris root, ethylenediamine Tetraacethyl disodium, fermentation extract are mixed with extracts of Chinese herbal medicine so that efficient automobile glass cleaner is obtained.
Present invention also offers a kind of preparation method of efficient automobile glass cleaner, the efficient automobile glass cleaner leads to Cross above-mentioned preparation method to be prepared.
In technique scheme, the present invention is caused obtained clear by the synergy between each step and each raw material Clean dose has excellent cleaning effect and environmentally friendly to vehicle glass;In addition, the preparation method has raw material being easy to get and work The simple feature of sequence.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
Specific embodiment to the present invention is described in detail below.It should be appreciated that described herein concrete Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides a kind of preparation method of efficient automobile glass cleaner, including:
1)Dregs of beans, cottonseed, kudzu powder, luffa, orange peel are fermented in water, filtrate is then filtered to take, then by activity Charcoal is stood in adding to filtrate so that fermentation extract is obtained;
2)Sweet wormwood, mulberry leaf, China rose, Chinese honey locust, the root of Dahurain angelica and dried orange peel are placed in water and are soaked, filtrate is then filtered to take to be obtained Extracts of Chinese herbal medicine;
3)By water, NPE, ethylene glycol, nano diatomite, sodium lauroyl sarcosine, orris root, ethylenediamine Tetraacethyl disodium, fermentation extract are mixed with extracts of Chinese herbal medicine so that efficient automobile glass cleaner is obtained.
1 the step of above-mentioned preparation method)In, the condition of fermentation can be selected in wide scope, but in order to improve Obtained cleaning agent has excellent cleaning effect to vehicle glass, it is preferable that in step 1)In, fermentation at least meets following bar Part:Fermentation temperature is 65-80 DEG C, and fermentation time is 8-12h.
1 the step of above-mentioned preparation method)In, the condition of standing can be selected in wide scope, but in order to improve Obtained cleaning agent has excellent cleaning effect to vehicle glass, it is preferable that in step 1)In, standing at least meets following bar Part:Dwell temperature is 25-40 DEG C, and time of repose is 10-20h.
1 the step of above-mentioned preparation method)In, the consumption of each material can be selected in wide scope, but in order to carry High obtained cleaning agent has excellent cleaning effect to vehicle glass, it is preferable that in step 1)In, with respect to 100 weight portions Dregs of beans, the consumption of cottonseed is 24-33 weight portion, and the consumption of kudzu powder is 40-56 weight portion, and the consumption of luffa is 14-28 Weight portion, the consumption of orange peel is 50-64 weight portion, and the consumption of water is 200-300 weight portion.
2 the step of above-mentioned preparation method)In, the consumption of each material can be selected in wide scope, but in order to carry High obtained cleaning agent has excellent cleaning effect to vehicle glass, it is preferable that in step 2)In, with respect to 100 weight portions Sweet wormwood, the consumption of mulberry leaf is 75-88 weight portion, and the consumption of China rose is 20-31 weight portion, and the consumption of Chinese honey locust is 40-58 weight Part, the consumption of the root of Dahurain angelica is 33-38 weight portion, and the consumption of dried orange peel is 29-41 weight portion, and the consumption of water is 200-300 weight portion.
2 the step of above-mentioned preparation method)In, the condition of immersion can be selected in wide scope, but in order to improve Obtained cleaning agent has excellent cleaning effect to vehicle glass, it is preferable that in step 2)In, soak and at least meet following bar Part:Soaking temperature is 55-65 DEG C, and soak time is 36-72h.
3 the step of above-mentioned preparation method)In, the consumption of each material can be selected in wide scope, but in order to carry High obtained cleaning agent has excellent cleaning effect to vehicle glass, it is preferable that in step 3)In, with respect to 100 weight portions Water, the consumption of NPE is 10-11 weight portion, and the consumption of ethylene glycol is 29-44 weight portion, nano diatomite Consumption is 7-11 weight portion, and the consumption of sodium lauroyl sarcosine is 4-7 weight portion, and the consumption of orris root is 11-17 weight portion, The consumption of disodium ethylene diamine tetraacetate is 1-3 weight portion, and the consumption of the extract that ferments is 33-43 weight portion, extracts of Chinese herbal medicine Consumption be 27-40 weight portion.
3 the step of above-mentioned preparation method)In, the condition of mixing can be selected in wide scope, but in order to improve Obtained cleaning agent has excellent cleaning effect to vehicle glass, it is preferable that in step 3)In, mixing at least meets following bar Part:Mixing temperature is 15-35 DEG C, and incorporation time is 30-50min.
3 the step of above-mentioned preparation method)In, nano diatomite, the particle diameter of orris root can be selected in wide scope Select, but there is to vehicle glass excellent cleaning effect in order to improve obtained cleaning agent, it is preferable that in step 3)In, nanometer Diatomaceous particle diameter is 20-30nm, and the particle diameter of orris root is 0.1-0.3mm.
Present invention also offers a kind of preparation method of efficient automobile glass cleaner, the efficient automobile glass cleaner leads to Cross above-mentioned preparation method to be prepared.
Hereinafter will be described the present invention by embodiment.
Embodiment 1
1)By dregs of beans, cottonseed, kudzu powder, luffa, orange peel and water according to 100:28:46:20:58:250 weight ratio is in 70 DEG C Bottom fermentation 10h, then filters to take filtrate, stands 15h and carried so that fermentation is obtained in then adding activated carbon to filtrate at 30 DEG C Take liquid;
2)By sweet wormwood, mulberry leaf, China rose, Chinese honey locust, the root of Dahurain angelica, dried orange peel and water according to 100:80:25:48:35:31:250 weight ratio 45h is soaked at 60 DEG C, then filter to take filtrate so that extracts of Chinese herbal medicine is obtained;
3)By water, NPE, ethylene glycol, nano diatomite(Particle diameter is 25nm), sodium lauroyl sarcosine, iris Root powder(Particle diameter is 0.2mm), disodium ethylene diamine tetraacetate, fermentation extract and extracts of Chinese herbal medicine be according to 100:10.5:34:9: 5:15:2:38:30 weight ratio mixes 40min so that efficient automobile glass cleaner A1 is obtained at 25 DEG C.
Embodiment 2
1)By dregs of beans, cottonseed, kudzu powder, luffa, orange peel and water according to 100:24:40:14:50:200 weight ratio is in 65 DEG C Bottom fermentation 8h, then filters to take filtrate, stands 10h and extracted so that fermentation is obtained in then adding activated carbon to filtrate at 25 DEG C Liquid;
2)By sweet wormwood, mulberry leaf, China rose, Chinese honey locust, the root of Dahurain angelica, dried orange peel and water according to 100:75:20:40:33:29:200 weight ratio 36h is soaked at 55 DEG C, then filter to take filtrate so that extracts of Chinese herbal medicine is obtained;
3)By water, NPE, ethylene glycol, nano diatomite(Particle diameter is 20nm), sodium lauroyl sarcosine, iris Root powder(Particle diameter is 0.1mm), disodium ethylene diamine tetraacetate, fermentation extract and extracts of Chinese herbal medicine be according to 100:10:29:7:4: 11:1:33:27 weight ratio mixes 30min so that efficient automobile glass cleaner A2 is obtained at 15 DEG C.
Embodiment 3
1)By dregs of beans, cottonseed, kudzu powder, luffa, orange peel and water according to 100:33:56:28:64:300 weight ratio is in 80 DEG C Bottom fermentation 12h, then filters to take filtrate, stands 20h and carried so that fermentation is obtained in then adding activated carbon to filtrate at 40 DEG C Take liquid;
2)By sweet wormwood, mulberry leaf, China rose, Chinese honey locust, the root of Dahurain angelica, dried orange peel and water according to 100:88:31:58:38:41:300 weight ratio 72h is soaked at 65 DEG C, then filter to take filtrate so that extracts of Chinese herbal medicine is obtained;
3)By water, NPE, ethylene glycol, nano diatomite(Particle diameter is 30nm), sodium lauroyl sarcosine, iris Root powder(Particle diameter is 0.3mm), disodium ethylene diamine tetraacetate, fermentation extract and extracts of Chinese herbal medicine be according to 100:11:44:11: 7:17:3:43:40 weight ratio mixes 50min so that efficient automobile glass cleaner A3 is obtained at 35 DEG C.
Comparative example 1
Method according to embodiment 1 carries out cleaning agent B1, except for the difference that, step 1 is obtained)In not using dregs of beans.
Comparative example 2
Method according to embodiment 1 carries out cleaning agent B2, except for the difference that, step 1 is obtained)In not using cottonseed.
Comparative example 3
Method according to embodiment 1 carries out cleaning agent B3, except for the difference that, step 1 is obtained)In not using kudzu powder.
Comparative example 4
Method according to embodiment 1 carries out cleaning agent B4, except for the difference that, step 1 is obtained)In not using luffa.
Comparative example 5
Method according to embodiment 1 carries out cleaning agent B5, except for the difference that, step 1 is obtained)In not using orange peel.
Comparative example 6
Method according to embodiment 1 carries out cleaning agent B6, except for the difference that, step 2 is obtained)In not using sweet wormwood, mulberry leaf.
Comparative example 7
Method according to embodiment 1 carries out cleaning agent B7, except for the difference that, step 2 is obtained)In not using China rose, Chinese honey locust.
Comparative example 8
Method according to embodiment 1 carries out cleaning agent B8, except for the difference that, step 2 is obtained)In not using the root of Dahurain angelica, dried orange peel.
Comparative example 9
Method according to embodiment 1 carries out cleaning agent B9, except for the difference that, step 3 is obtained)In not using fermentation extract.
Comparative example 10
Method according to embodiment 1 carries out cleaning agent B10, except for the difference that, step 3 is obtained)In not using extracts of Chinese herbal medicine.
Test case 1
1)By above-mentioned cleaning agent and water according to 1:100 weight is then cleaned vehicle glass respectively, is then entered with clear water than dilution Row secondary cleaning, determines the contact angle of the vehicle glass after cleaning finally by SLOOC optical contact angle analyzer, and contact angle is got over Little, lyophily is got on the surface of vehicle glass, represents that its wetability is better;And high contact angle represents that its surface shows hydrophobicity, surface Organic contamination is heavier or surface adhesion force is poor;Testing result is shown in Table 1.
2)The ODP value of detection trade company cleaning agent(Refer to certain material within its atmospheric lifetime phase, the global ozone loss for causing The ratio of the ozone loss caused with respect to the CFC-11 discharge of homogenous quantities), ODP value is less to represent cleaning agent more environmental protection, tool Body the results are shown in Table.
Table 1
Contact angle/° ODP
A1 9 0.013
A2 8 0.014
A3 10 0.015
B1 33 0.25
B2 32 0.33
B3 25 0.24
B4 37 0.19
B5 36 0.17
B6 33 0.20
B7 30 0.31
B8 31 0.28
B9 40 0.37
B10 42 0.38
By above-described embodiment, comparative example and detection example, the cleaning agent that the present invention is provided has excellent to vehicle glass Cleaning effect, and environmentally friendly.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment Detail, in the range of the technology design of the present invention, multiple simple variant can be carried out to technical scheme, this A little simple variant belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can The combination of energy is no longer separately illustrated.
Additionally, can also be combined between a variety of embodiments of the present invention, as long as which is without prejudice to this The thought of invention, its should equally be considered as content disclosed in this invention.

Claims (10)

1. a kind of preparation method of efficient automobile glass cleaner, it is characterised in that include:
1)Dregs of beans, cottonseed, kudzu powder, luffa, orange peel are fermented in water, filtrate is then filtered to take, then by activity Charcoal is stood in adding to the filtrate so that fermentation extract is obtained;
2)Sweet wormwood, mulberry leaf, China rose, Chinese honey locust, the root of Dahurain angelica and dried orange peel are placed in water and are soaked, filtrate is then filtered to take to be obtained Extracts of Chinese herbal medicine;
3)By water, NPE, ethylene glycol, nano diatomite, sodium lauroyl sarcosine, orris root, ethylenediamine Tetraacethyl disodium, the fermentation extract are mixed with extracts of Chinese herbal medicine so that the efficient automobile glass cleaner is obtained.
2. preparation method according to claim 1, wherein, in step 1)In, the fermentation at least meets following condition:Send out Ferment temperature is 65-80 DEG C, and fermentation time is 8-12h.
3. preparation method according to claim 1, wherein, in step 1)In, the standing at least meets following condition:Quiet Temperature is put for 25-40 DEG C, time of repose is 10-20h.
4. the preparation method according to any one in claim 1-3, wherein, in step 1)In, with respect to 100 weight portions The dregs of beans, the consumption of the cottonseed is 24-33 weight portion, and the consumption of the kudzu powder is 40-56 weight portion, the sponge gourd The consumption of network is 14-28 weight portion, and the consumption of the orange peel is 50-64 weight portion, and the consumption of the water is 200-300 weight Part.
5. preparation method according to claim 4, wherein, in step 2)In, with respect to the sweet wormwood of 100 weight portions, institute The consumption for stating mulberry leaf is 75-88 weight portion, and the consumption of the China rose is 20-31 weight portion, and the consumption of the Chinese honey locust is 40-58 Weight portion, the consumption of the root of Dahurain angelica is 33-38 weight portion, and the consumption of the dried orange peel is 29-41 weight portion, and the consumption of the water is 200-300 weight portion.
6. preparation method according to claim 5, wherein, in step 2)In, the immersion at least meets following condition:Soak Temperature is 55-65 DEG C, and soak time is 36-72h.
7. the preparation method according to claim 5 or 6, wherein, in step 3)In, with respect to the water of 100 weight portions, institute The consumption for stating NPE is 10-11 weight portion, and the consumption of the ethylene glycol is 29-44 weight portion, the nanometer Diatomaceous consumption is 7-11 weight portion, and the consumption of the sodium lauroyl sarcosine is 4-7 weight portion, the use of the orris root Measure as 11-17 weight portion, the consumption of the disodium ethylene diamine tetraacetate is 1-3 weight portion, and the consumption of the fermentation extract is 33-43 weight portion, the consumption of the extracts of Chinese herbal medicine is 27-40 weight portion.
8. preparation method according to claim 7, wherein, in step 3)In, the mixing at least meets following condition:Mixing Temperature is 15-35 DEG C, and incorporation time is 30-50min.
9. preparation method according to claim 7, wherein, in step 3)In, the particle diameter of the nano diatomite is 20- 30nm, the particle diameter of the orris root is 0.1-0.3mm.
10. a kind of preparation method of efficient automobile glass cleaner, it is characterised in that the efficient automobile glass cleaner passes through Preparation method in claim 1-9 described in any one is prepared.
CN201610880261.6A 2016-10-09 2016-10-09 The preparation method of efficient automobile glass cleaner Pending CN106479733A (en)

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CN106987378A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987470A (en) * 2017-03-17 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of glass ferment cleaning agent
CN106987377A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987379A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987380A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987381A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987345A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987368A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN107189864A (en) * 2017-06-16 2017-09-22 广西顺帆投资有限公司 Automobile glass cleaning agent
CN109456859A (en) * 2018-11-16 2019-03-12 怀化学院 A kind of natural cleaning agent and preparation method thereof

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CN104342328A (en) * 2014-10-26 2015-02-11 青岛克立克信息技术有限公司 Powerful glass detergent
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CN106987470A (en) * 2017-03-17 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of glass ferment cleaning agent
CN106987378A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987377A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987379A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987380A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987381A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987345A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN106987368A (en) * 2017-03-18 2017-07-28 长沙协浩吉生物工程有限公司 A kind of compound method of vehicle glass ferment cleaning agent
CN107189864A (en) * 2017-06-16 2017-09-22 广西顺帆投资有限公司 Automobile glass cleaning agent
CN109456859A (en) * 2018-11-16 2019-03-12 怀化学院 A kind of natural cleaning agent and preparation method thereof

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