CN106479640A - A kind of normal propyl alcohol gasoline engine engine oil base oil - Google Patents

A kind of normal propyl alcohol gasoline engine engine oil base oil Download PDF

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Publication number
CN106479640A
CN106479640A CN201610856446.3A CN201610856446A CN106479640A CN 106479640 A CN106479640 A CN 106479640A CN 201610856446 A CN201610856446 A CN 201610856446A CN 106479640 A CN106479640 A CN 106479640A
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China
Prior art keywords
oil
base oil
propyl alcohol
normal propyl
engine
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CN201610856446.3A
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Chinese (zh)
Inventor
黄福川
马骁飞
韦开焕
李康春
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NANNING YUYAN NEW ENERGY SCIENCE & TECHNOLOGY Co Ltd
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NANNING YUYAN NEW ENERGY SCIENCE & TECHNOLOGY Co Ltd
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Priority to CN201610856446.3A priority Critical patent/CN106479640A/en
Publication of CN106479640A publication Critical patent/CN106479640A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/003Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022Ethene
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024Propene
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/066Arylene diamines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2290/00Mixtures of base materials or thickeners or additives
    • C10M2290/04Synthetic base oils
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40Low content or no content compositions
    • C10N2030/45Ash-less or low ash content
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/54Fuel economy
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/78Fuel contamination
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • C10N2040/251Alcohol fueled engines

Abstract

The invention discloses a kind of normal propyl alcohol gasoline engine engine oil base oil, oil based on being combined using HVIH base oil and polyalphaolefin, coordinate multiple compound additives, including:Detersive, dispersant, oxidation and corrosion inhibitor, anti-foaming agent, viscosity index improver, antirust agent, antioxidant, metal deactivator, reinforcing agent.The composition of the present invention has low ash content, prevents spark from blocking, good high temperature lubricating, detergent-dispersant performance, dissolubility, base number retentivity, anti-corrosive properties, antirust, emulsion resistance, anti-shearing, wear resistence and anti-alcohols contaminative.

Description

A kind of normal propyl alcohol gasoline engine engine oil base oil
Technical field
A kind of normal propyl alcohol gasoline engine engine oil base oil of the present invention belongs to petrol engine lubricating oil field.
Background technology
Normal propyl alcohol, also known as 1- propyl alcohol, propyl alcohol, molecular formula (C3H7OH), molecular weight is 60.10, is water white liquid, Water, ethanol, ether is dissolved in, is had as ethanol smell.Ethene obtains propionic aldehyde through carbonylation synthesis, then obtains through reduction.It is mainly used to do and fires The bactericide of material oil, agricultural chemicals and medical material, perfume base.As solvent and for pharmacy, paint and cosmetics.Its fusing point- 127 DEG C, relative density 0.80,97.1 DEG C of boiling point, 15 DEG C of flash-point, the cosolvent of ethanol is also used for, also can be called in as fuel In gasoline, ratio 0~20%.
Increasingly serious with energy crisis and environmental problem, the fuel combination of alcohols and traditional fossil fuel or completely Alcohols replaces fuel to be increasingly subject to pay attention to.Wherein normal propyl alcohol is applied because of the breakthrough of dixie cup method and on the engine.Mixed Close in fuel, alcohols is affected to be showed its distinctive flammability by active group, contributes to improving to fuel combination further Fired state, it helps reduce discharge.
Content of the invention
The technical problem to be solved in the present invention is to provide a kind of with low ash content, prevents spark from blocking, good high temperature Lubricity, detergent-dispersant performance, dissolubility, base number retentivity, anti-corrosive properties, antirust, emulsion resistance, anti-shearing, wear resistence and anti-alcohols The normal propyl alcohol gasoline engine engine oil base oil of contaminative.
The present invention employs the following technical solutions solution above-mentioned technical problem:
A kind of normal propyl alcohol gasoline engine engine oil base oil, oil based on being combined using HVIH base oil and poly alpha olefin, Coordinate multiple compound additives, its each mass percent become to be grouped into:
Component Mass percentage content
Base oil Surplus
Detersive 4%~6%
Dispersant 3%~5%
Oxidation and corrosion inhibitor 0.8%~1.5%
Anti-foaming agent 10~30ppm
Viscosity index improver 2%~6%
Antirust agent 0.2%~0.5%
Antioxidant 0.1%~0.3%
Metal deactivator 0.05%~0.1%
Reinforcing agent 2~3%
Each constituent mass percentage summation is 100% above.
Base oil is complex as using the HVIH base oil of mass ratio 50% and 50% poly alpha olefin.
Detersive is the middle base number calcium mahogany sulfonate T102 of mass ratio 50% and 50% super base number synthesis sulfonic acid magnesium T107 Compound;
Dispersant is boronation polyisobutene succinimide T161B.
Oxidation and corrosion inhibitor is sulphur phosphorus pair octyl group basic zinc salt T203 of mass ratio 50% and 50% dialkyl dithio ammonia Carbamate is combined.
Anti-foaming agent is methyl-silicone oil T901.
Viscosity index improver is ethylene-propylene copolymer T613.
Antirust agent be the petroleum sodium sulfonate T702 of mass ratio 50% and 50% benzotriazole T706 compound.
Antioxidant is dialkyl diphenylamine T534;Metal deactivator is 2-mercaptobenzimidazole.
Reinforcing agent is calcium sulfenyl phenolate T115A.
The beneficial effects of the present invention is:
The composition of the present invention has low ash content, prevents spark from blocking, good high temperature lubricating, detergent-dispersant performance, Dissolubility, base number retentivity, anti-corrosive properties, antirust, emulsion resistance, anti-shearing, wear resistence and anti-alcohols contaminative.
Specific embodiment
Embodiment 1:
Following component is in harmonious proportion by mass percentage and is formed:
Each constituent mass percentage summation is equal to 100% above.
Embodiment 2:
Following component is in harmonious proportion by mass percentage and is formed:
Each constituent mass percentage summation is equal to 100% above.
Embodiment 3:
Following component is in harmonious proportion by mass percentage and is formed:
Each constituent mass percentage summation is equal to 100% above.
1 typical technology index of embodiment:

Claims (9)

1. a kind of normal propyl alcohol gasoline engine engine oil base oil, it is characterised in that:Make using HVIH base oil and poly alpha olefin are compound Based on oil, coordinate multiple compound additives, its each mass percent become to be grouped into:
Component Mass percentage content Base oil Surplus Detersive 4%~6% Dispersant 3%~5% Oxidation and corrosion inhibitor 0.8%~1.5% Anti-foaming agent 10~30ppm Viscosity index improver 2%~6% Antirust agent 0.2%~0.5% Antioxidant 0.1%~0.3% Metal deactivator 0.05%~0.1% Reinforcing agent 2~3%
Each constituent mass percentage summation is 100% above.
2. a kind of normal propyl alcohol gasoline engine engine oil base oil as claimed in claim 1, it is characterised in that:Using mass ratio 50% HVIH base oil and 50% poly alpha olefin be complex as base oil.
3. a kind of normal propyl alcohol gasoline engine engine oil base oil as claimed in claim 1, it is characterised in that detersive is mass ratio 50% middle base number calcium mahogany sulfonate T102 and 50% super base number synthesis sulfonic acid magnesium T107 are combined;Dispersant is the poly- isobutyl of boronation Alkene succimide T161B.
4. a kind of normal propyl alcohol gasoline engine engine oil base oil as claimed in claim 1, it is characterised in that oxidation and corrosion inhibitor is matter Amount compares 50% sulphur phosphorus pair octyl group basic zinc salt T203 and 50% dialkyl dithio amino formate is combined.
5. a kind of normal propyl alcohol gasoline engine engine oil base oil as claimed in claim 1, it is characterised in that anti-foaming agent is methyl silicon Oily T901.
6. a kind of normal propyl alcohol gasoline engine engine oil base oil as claimed in claim 1, it is characterised in that viscosity index improver It is ethylene-propylene copolymer T613.
7. a kind of normal propyl alcohol gasoline engine engine oil base oil as claimed in claim 1, it is characterised in that antirust agent is mass ratio 50% petroleum sodium sulfonate T702 and the compound of 50% benzotriazole T706.
8. a kind of normal propyl alcohol gasoline engine engine oil base oil as claimed in claim 1, it is characterised in that antioxidant is dialkyl group Diphenylamines T534;Metal deactivator is 2-mercaptobenzimidazole.
9. a kind of normal propyl alcohol gasoline engine engine oil base oil as claimed in claim 1, it is characterised in that reinforcing agent is sulfuration alkane Base phenol calcium T115A.
CN201610856446.3A 2016-09-26 2016-09-26 A kind of normal propyl alcohol gasoline engine engine oil base oil Pending CN106479640A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113913231A (en) * 2020-07-08 2022-01-11 中国石油化工股份有限公司 National six engine oil compatible with biofuel and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040014613A1 (en) * 1999-07-15 2004-01-22 Ashland Inc. Penetrating lubricant composition
CN104087383A (en) * 2014-07-14 2014-10-08 广西大学 Engine oil composition with diisopropyl ether as fuel
CN104962362A (en) * 2015-07-20 2015-10-07 广西大学 Lubricating agent for piston type cam engine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040014613A1 (en) * 1999-07-15 2004-01-22 Ashland Inc. Penetrating lubricant composition
CN104087383A (en) * 2014-07-14 2014-10-08 广西大学 Engine oil composition with diisopropyl ether as fuel
CN104962362A (en) * 2015-07-20 2015-10-07 广西大学 Lubricating agent for piston type cam engine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113913231A (en) * 2020-07-08 2022-01-11 中国石油化工股份有限公司 National six engine oil compatible with biofuel and preparation method thereof
CN113913231B (en) * 2020-07-08 2022-12-13 中国石油化工股份有限公司 National six engine oil compatible with biofuel and preparation method thereof

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